EP2826887B1 - Verfahren zum Auftragen einer wässrigen Behandlungslösung auf die Oberfläche eines bewegten Stahlbands - Google Patents

Verfahren zum Auftragen einer wässrigen Behandlungslösung auf die Oberfläche eines bewegten Stahlbands Download PDF

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Publication number
EP2826887B1
EP2826887B1 EP14161660.7A EP14161660A EP2826887B1 EP 2826887 B1 EP2826887 B1 EP 2826887B1 EP 14161660 A EP14161660 A EP 14161660A EP 2826887 B1 EP2826887 B1 EP 2826887B1
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EP
European Patent Office
Prior art keywords
steel strip
treatment solution
strip
aqueous
solution
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EP14161660.7A
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German (de)
English (en)
French (fr)
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EP2826887A1 (de
Inventor
Andrea Dr. Marmann
Michael Wild
Paul Michels
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ThyssenKrupp Rasselstein GmbH
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ThyssenKrupp Rasselstein GmbH
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/021Apparatus for spreading or distributing liquids or other fluent materials already applied to the surface of an elongated body, e.g. a wire, a tube
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/023Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface
    • B05C11/025Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface with an essentially cylindrical body, e.g. roll or rod
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/40Distributing applied liquids or other fluent materials by members moving relatively to surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/002Pretreatement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/04Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
    • B05D3/0466Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/12Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/76Applying the liquid by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • B05D2202/10Metallic substrate based on Fe
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2252/00Sheets
    • B05D2252/02Sheets of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218Pretreatment, e.g. heating the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment

Definitions

  • the invention relates to a method and an apparatus for discharging an aqueous processing solution onto the surface of a steel belt moving at a predetermined belt speed in a belt running direction.
  • the surface-active substance is sprayed on at least one tube which is arranged at a distance from the coated steel strip surface and has at least one bore through which the aqueous solution of the surface-active substance is sprayed onto the or each metal-coated surface of the steel strip.
  • the excess portion of the solution is squeezed off the surface by means of squeezing rollers.
  • the wet film of the surfactant remaining on the coated steel belt surface is finally dried so that a dry, thin film of the surfactant with a coverage of between 2 and 10 mg / m 2 remains on the metal coated surface of the steel belt.
  • Another method for treating a metal strip provided with a steel strip, in particular a tinplate strip, with a post-treatment agent is from DE 10 2012 102 082 B3 known.
  • an aqueous aftertreatment solution is sprayed onto the metal-coated surface of the steel strip by a spray process.
  • spraying the aqueous solution of Aftertreatment agent by a spray process is also the application of the aftertreatment agent by a dipping process into consideration, in which the steel strip is passed through a tank filled with the liquid aftertreatment agent.
  • both the conventional spraying methods and the known immersing methods have the disadvantage that large amounts of the aqueous processing solution are required and that the excess portion of the processing solution, which is squeezed from the surface of the steel strip, for example, by means of squeezing rollers, collected in collecting tanks and sent for reprocessing must become.
  • Reprocessing a treatment solution that has once been applied to a metal-coated surface of a steel strip proves to be costly and expensive because the treatment solution can be contaminated by application to the steel strip surface, for example, metal ions from the metal coating of the steel strip.
  • application of an aqueous treatment solution on a tinplate surface leads to contamination of the treatment solution with tin ions from the tin coating.
  • a further object of the invention is to provide a method for applying an aqueous treatment solution to the surface of a moving steel strip, with which the treatment solution can be applied as fresh as possible after its application to the steel strip surface to avoid aging effects.
  • the application process should also be feasible at high belt speeds of the moving steel strip.
  • an aqueous treatment solution is applied to the surface of a steel belt moving at a predetermined belt speed in a belt running direction by applying the aqueous treatment solution to one or both surfaces of the moving steel belt with a rotary sprayer having a plurality of spray rotors juxtaposed transversely to the belt running direction to which the aqueous processing solution is supplied and which are rotated by a drive to spray the aqueous processing solution in the form of a fine spray jet on the or each surface of the steel strip by centrifugal force and form a wet film of the aqueous solution there.
  • the moving steel strip is dried with a gas stream and cleaned.
  • the smoothing rollers are expediently arranged with respect to the steel strip surface (s) such that they exert little or no pressure on the wet film of the aqueous treatment solution and therefore no or only a minimal proportion of the applied treatment solution from the steel strip surface squeezing off.
  • the sprayed-on wet film is evened out, it is dried so that a dry coating of the treatment substance remains on the treated steel strip or surfaces.
  • the dry coverage of the treatment solution after drying is between 1 and 50 mg / m 2 .
  • the gas stream with which the moving steel strip is cleaned and dried before applying the aqueous treatment solution is expediently provided by an air knife and inflated as a laminar flow of hot air onto the surface of the moving steel strip. As a result, disruptive foreign particles are blown off the steel strip surface and the steel strip surface is dried.
  • the amount of the aqueous treatment solution fed to the spray rotors of the rotary sprayer per unit time is expediently adapted to the belt speed.
  • the amount of treatment solution supplied to the spray rotors per unit time and based on the width of the steel strip and per side is preferably between 0.4 and 5.5 liters per minute and meter and is more preferably in a range between 1 and 3.5 liters per minute and meters, the belt speed is usually between 200 and 700 m / min.
  • the coating of the wet film of the treatment solution sprayed onto the or each surface side of the steel strip with the spray rotors is correspondingly in the preferred range of 2 to 8 ml / m 2 per side of the steel strip and preferably between 4 and 6 ml / m 2 and particularly preferably at ca. 5 ml / m 2 .
  • the smoothing rollers preferably comprise a pair of smoothing rollers with two driven and staggered arranged smoothing rollers.
  • the distance of the smoothing rollers to the steel strip surface is expediently adjustable and adaptable to the sprayed with the rotary sprayer amount (edition) of the wet film of the treatment solution.
  • the rotary sprayer 2 is expediently connected via a supply line to a storage container in which the aqueous treatment solution is stored.
  • the aqueous treatment solution may be supplied to the rotary sprayer from the container and via the supply line by means of a pump.
  • only fresh treatment solution is expediently stored in order to avoid aging problems.
  • the treatment solution stored in the storage container does not come into contact with a (possibly metal-coated) steel sheet before its application to the steel strip surface, which leads to contamination of the fresh treatment solution (for example by detachment of the metal ions from the metal coating) could.
  • the inventive method is characterized primarily by its resource-saving handling of the treatment solution to be applied and by its cost-effectiveness. It is, in contrast to the known application method, only the exact amount of the treatment solution sprayed onto the steel strip surface, without any excess of treatment solution would have to be blown off or squeezed again. As a result, it is no longer necessary to collect squeezed from the steel belt surface excesses of the treatment solution and supply a reprocessing. As a result, post-treated wastewater incurred in reprocessing processes can be avoided.
  • the application method according to the invention is suitable for applying different treatment solutions to moving steel strips.
  • passivation solutions or aftertreatment solutions for reducing the coefficient of friction can be applied to tinplate surfaces using the method according to the invention.
  • the method according to the invention can also be used in a corresponding manner for the application of other aqueous treatment solutions on tinplate surfaces or also on the surface of steel strips coated with other metallic coatings (such as coatings containing zinc or chromium) are.
  • the process of the present invention may also be used to apply aqueous processing solutions to uncoated steel belts, such as to apply an aqueous conversion coating to the surface of blackplate (hot or cold rolled, non-descaled and uncoated steel sheet).
  • FIG. 1 a device for carrying out the method according to the invention for applying an aqueous treatment solution to the surface of a moving steel strip is shown schematically.
  • the steel strip 1 is guided over a plurality of deflection rollers U and moves at a predetermined belt speed v in a strip running direction, which in FIG. 1 marked with an arrow.
  • the belt speed is regularly more than 200 m / min and up to 750 m / min.
  • the steel strip 1 can be a steel strip coated with a metal coating and cold-rolled, for example a tinplate strip or a galvanized steel strip. However, it may also be uncoated steel sheet, such as a black-plate tape.
  • the steel strip 1 is moved by a transport device not shown here with a predetermined belt speed v in a strip running direction and thereby guided over deflection rollers U.
  • a first drying device 4 to dry and clean the surfaces of the steel strip 1.
  • the first drying device 4 is formed for example by an "air knife", which is a laminar hot air flow to the surfaces of the with Belt speed v by moving steel strip 1 blows, thereby drying the steel strip surfaces and blow off disturbing foreign particles.
  • the first drying device 4 is followed by a rotary sprayer 2.
  • the rotary sprayer is in FIG. 2 shown in detail.
  • the rotary sprayer 2 has a plurality of transverse to the strip running direction next to each other and spaced spray nozzles 3.
  • the spray rotors 3 are connected to a reservoir 9 via a central supply line 6 and diverted branch lines 6a, 6b, 6c, etc. thereof.
  • the aqueous treatment solution is stored, which is to be applied to the steel strip surface.
  • the aqueous treatment solution is expediently pumped by means of a pump 8 into the supply line 6, from where it is conducted into the branch lines 6a, 6b, 6c, wherein each branch line is connected to one of the spray rotors 3.
  • a flow meter 11 is expediently provided in the supply line 6.
  • the aqueous treatment solution is fed to the spray rotors 3 of the rotary sprayer 2.
  • the spray rotors 3 each have a plate set in rotation by a drive. Due to the rotation of the plate of the spray rotors 3, the supplied aqueous treatment solution is conveyed outwards to the plate rim by the centrifugal force.
  • the rim of the plate is shaped such that the aqueous treatment solution in the form of fine droplets flies away from the rim of the rotating plate.
  • the droplet diameter depending on the viscosity and the surface tension of the treatment solution used, is usually between 30 and 70 micrometers.
  • the droplets of the treatment solution flowing away from the edge of the plate are sprayed in full around the rotating plate of the spray rotors 3.
  • the spray rotors 3 are arranged transversely to the strip running direction so that the spraying jets 12 adjacent spray rotors 3 overlap on the surface of the steel strip 1 in order to provide a uniform application of the aqueous treatment solution over the entire width B of the steel strip 1.
  • the amount of aqueous treatment solution supplied to the spray rotors 3 per unit of time is expediently adapted to the belt speed v, with which the steel belt 1 moves.
  • ⁇ t ⁇ B 1.0 to 3.5 liters per minute and meter.
  • the amount of the wet film of the treatment solution sprayed with the spray rotors 3 on the surface of the steel strip 1 is between 2 and 8 ml / m 2, and more preferably between 4 and 6 ml / m 2, and more preferably about 5 ml / m 2 .
  • the aqueous treatment solution can be sprayed by means of the rotary sprayer 2 either only on one side of the steel strip 1 or on both sides of the surfaces of the steel strip 1. Possibly.
  • 1 rotary sprayer 2 are arranged on both sides of the carried steel strip.
  • the steel strip 1 After applying the aqueous processing solution as a wet film on the or each surface of the steel strip 1, the steel strip 1 is performed between rotationally driven smoothing rollers 5a, 5b.
  • the smoothing rollers 5 serve to even out the applied wet film of the aqueous solution.
  • the staggered arrangement of the smoothing rollers 5a, 5b is shown in the figures.
  • the smoothing rollers 5a, 5b are arranged relative to one another in such a way that the connecting line of the axes of rotation of the smoothing rollers running parallel to one another and parallel to the steel belt surface has an angle of approximately 30 ° to 60 ° in cross section with the steel belt 1 passed through the two smoothing rollers ° and in particular of about 45 °.
  • the smoothing rollers used here exert no substantial contact pressure on the steel belt surface. As a result, no or only a very small proportion of the sprayed treatment solution is squeezed from the steel strip surface.
  • the smoothing roller pair 5 only leads to a homogenization of the wet film of the treatment solution over the entire surface of the steel strip. This ensures a constant application of a wet film of the treatment solution with homogeneous layer thickness over the entire surface of the steel strip and it is achieved that no excess treatment solution accumulates, which would have to be collected and recycled.
  • the steel strip 1 is passed through a second drying device 7.
  • the second drying device 7 may be a drying oven or an infrared or hot air dryer.
  • a uniform dry coating of the treatment solution remains on the or each surface of the steel strip 1, wherein the dry coating after drying is generally between 1 and 50 mg / m 2 and preferably between 2 and 30 mg / m 2 .
  • the dry coverage of the treatment solution is particularly preferably about 10 mg / m 2 .
  • the aqueous treatment solution may be, for example, a chromium-free, surface-active passivation solution, as described in US Pat DE 10 2005 045 034 A1 for chromium-free passivation of tinplate surfaces has been described.
  • the aqueous treatment solution may also be a chromium-free passivation solution for the passivation of tinplate, which contains water-soluble inorganic compounds of the elements zirconium and titanium or aluminum.
  • Such aqueous treatment solutions can be used in a two-pass passivation of tinplate, wherein in a first stage anodic oxidation of the tinplate surface is carried out and in a second stage, the application of the aqueous treatment solution on the tinplate surface, wherein the treatment solution water-soluble inorganic compounds of zirconium and / or titanium or aluminum.
  • the application of the aqueous treatment solution can be carried out with the method according to the invention.
  • the application of the aqueous treatment solution with the method according to the invention is then preceded by the first step of the anodic oxidation of the tinplate surface.
  • aqueous electrolyte eg., A soda solution
  • anodic oxidation of the tinplate surface forms a particularly inert oxidation layer on the tinned surface of the tinplate, which consists essentially of (inert) tetravalent tin oxide SnO 2 and protects the tinplate surface against natural growth of an oxide layer by atmospheric oxygen as well as against reactions with sulfur-containing materials.
  • a chromium-free aqueous aftertreatment agent which in particular contains titanium and / or zirconium, can therefore protect the tinned surface of the steel strip completely against corrosion and against discoloration of the surface by reaction of the tin with sulfur ,
  • a metallic or organic conversion coating on a black plate (uncoated, cold or hot rolled steel sheet) can be applied.
  • the method according to the invention is suitable, for example, for applying conversion coatings to blackplate which contain metallic constituents such as titanium, zirconium, manganese, zinc or even phosphorus or organic constituents such as polyacrylate or polycarboxylate.
  • Such conversion coatings provide good protection of the surface of the blackplate against corrosion, so that appropriately treated blackplate, for example, can be used as a substitute for steel sheet coated with a metallic anti-corrosion layer of chromium (such as ECCS, "electrolytic chromium coated steeel").

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Nozzles (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
EP14161660.7A 2013-07-16 2014-03-26 Verfahren zum Auftragen einer wässrigen Behandlungslösung auf die Oberfläche eines bewegten Stahlbands Active EP2826887B1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102013107505.3A DE102013107505A1 (de) 2013-07-16 2013-07-16 Verfahren zum Auftragen einer wässrigen Behandlungslösung auf die Oberfläche eines bewegten Stahlbands

Publications (2)

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EP2826887A1 EP2826887A1 (de) 2015-01-21
EP2826887B1 true EP2826887B1 (de) 2016-03-23

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Country Status (9)

Country Link
US (1) US20150024137A1 (es)
EP (1) EP2826887B1 (es)
JP (1) JP6391279B2 (es)
CN (1) CN104289394B (es)
BR (1) BR102014015410B1 (es)
CA (1) CA2851472C (es)
DE (1) DE102013107505A1 (es)
ES (1) ES2572562T3 (es)
RU (1) RU2651545C2 (es)

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DE102015104974B3 (de) * 2015-03-31 2016-06-16 Thyssenkrupp Ag Verfahren und Auftragsvorrichtung zum Auftragen einer wässrigen Behandlungslösung auf die Oberfläche eines bewegten Bands sowie Vorrichtung zur Durchführung des Verfahrens
KR101613426B1 (ko) * 2015-10-02 2016-04-21 주식회사 유진테크놀로지 이차전지 전극단자용 표면처리 장치
KR102593063B1 (ko) * 2015-10-12 2023-10-25 쓰리엠 이노베이티브 프로퍼티즈 캄파니 층상 코팅 장치 및 방법
JP6227749B2 (ja) * 2016-03-29 2017-11-08 株式会社神戸製鋼所 アルミニウム材の表面処理方法および表面処理アルミニウム材
WO2017170015A1 (ja) * 2016-03-29 2017-10-05 株式会社神戸製鋼所 アルミニウム材の表面処理方法、表面処理装置および表面処理アルミニウム材
CN110373661B (zh) * 2019-07-31 2021-05-28 首钢京唐钢铁联合有限责任公司 一种镀锡板钝化液及钝化工艺
CN111346803A (zh) * 2020-03-10 2020-06-30 富阳双龙防火门有限公司 一种彩钢带的加工工艺及涂装装置
CN112201826B (zh) * 2020-09-27 2022-05-17 江苏氢导智能装备有限公司 浸泡池组件及膜材浸泡设备
CN115505917A (zh) * 2021-06-23 2022-12-23 上海梅山钢铁股份有限公司 一种镀锡板无铬钝化装置及工艺
CN114985221B (zh) * 2022-06-02 2024-05-14 黄山市天马科技有限公司 一种胶带生产的余胶处理方法及余胶回收装置

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JP6391279B2 (ja) 2018-09-19
RU2651545C2 (ru) 2018-04-20
BR102014015410B1 (pt) 2021-10-26
RU2014127434A (ru) 2016-02-10
CA2851472C (en) 2016-06-07
ES2572562T3 (es) 2016-06-01
EP2826887A1 (de) 2015-01-21
CN104289394B (zh) 2019-06-18
CA2851472A1 (en) 2015-01-16
US20150024137A1 (en) 2015-01-22
CN104289394A (zh) 2015-01-21
JP2015027662A (ja) 2015-02-12
BR102014015410A2 (pt) 2015-10-06
DE102013107505A1 (de) 2015-01-22

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