EP2656187A2 - Procédé de fabrication de composants durcis - Google Patents

Procédé de fabrication de composants durcis

Info

Publication number
EP2656187A2
EP2656187A2 EP11811026.1A EP11811026A EP2656187A2 EP 2656187 A2 EP2656187 A2 EP 2656187A2 EP 11811026 A EP11811026 A EP 11811026A EP 2656187 A2 EP2656187 A2 EP 2656187A2
Authority
EP
European Patent Office
Prior art keywords
zinc
coating
layer
steel
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11811026.1A
Other languages
German (de)
English (en)
Other versions
EP2656187B1 (fr
Inventor
Harald Schwinghammer
Thomas Kurz
Siegfried Kolnberger
Martin Rosner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Voestalpine Stahl GmbH
Original Assignee
Voestalpine Stahl GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102010056265.3A external-priority patent/DE102010056265C5/de
Priority claimed from DE102010056264.5A external-priority patent/DE102010056264C5/de
Priority claimed from DE102011053939.5A external-priority patent/DE102011053939B4/de
Priority claimed from DE102011053941.7A external-priority patent/DE102011053941B4/de
Application filed by Voestalpine Stahl GmbH filed Critical Voestalpine Stahl GmbH
Publication of EP2656187A2 publication Critical patent/EP2656187A2/fr
Application granted granted Critical
Publication of EP2656187B1 publication Critical patent/EP2656187B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/62—Quenching devices
    • C21D1/673—Quenching devices for die quenching
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C21D9/48—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C23C2/29—Cooling or quenching

Definitions

  • the invention relates to a method for producing hardened corrosion-protected components with the features of claim 1.
  • press-hardened components made of sheet steel are used.
  • These press-hardened components made of sheet steel are high-strength components that are used in particular as safety components of the bodywork sector.
  • the use of these high-strength steel components makes it possible to reduce the material thickness compared to a normal-strength steel and thus to achieve low body weights.
  • a sheet steel plate is heated above the so-called austenitizing temperature and, if appropriate, kept at this temperature until a desired degree of austenitization is achieved. Subsequently, this heated board is transferred to a mold and formed in this mold in a one-step forming step to the finished component and thereby simultaneously by the cooled mold at a speed over the critical hardness is, cooled. Thus, the hardened component is produced.
  • the component is first, if necessary, in a multi-stage forming process, the component formed almost completely finished. This formed component is then also heated to a temperature above the Austenitmaschinestempe- temperature and optionally held for a desired time required at this temperature.
  • this heated component is transferred to a mold and inserted, which already has the dimensions of the component or the final dimensions of the component, where appropriate, taking into account the thermal expansion of the preformed component.
  • the direct method is somewhat simpler to implement, but allows only shapes that are actually to be realized with a single forming step, i. relatively simple profile shapes.
  • the indirect process is a bit more complex, but it is also able to realize more complex shapes.
  • the corrosion protection layer used is only the aluminum or aluminum used to a lesser extent. alloys or the much more frequently requested coatings based on zinc.
  • Zinc has the advantage here that zinc not only provides a barrier protection layer such as aluminum, but cathodic corrosion protection.
  • zinc-coated press-hardened components fit better into the overall corrosion protection concept of vehicle bodies, since they are fully galvanized in today's common construction. In this respect, contact corrosion can be reduced or eliminated.
  • Zinc-coated steels are currently - with the exception of one component in the Asian region - in the direct process, i. the hot forming not used. Instead, steels with an aluminum-silicon coating are used here.
  • the zinc-iron phase diagram shows that above 782 ° C a large area is created containing liquid zinc as long as the iron content is less than 60%. However, this is also the temperature range in which the austenitized steel is thermoformed. It should also be noted, however, that if the forming takes place above 782 ° C, there is a great risk of stress corrosion by liquid zinc, which penetrates into the grain boundaries of the base steel, resulting in macrocracks in the base steel. In addition, with iron levels less than 30% in the coating, the maximum temperature for forming a safe product with no macrocracks is less than 782 ° C. This is the reason why hereby no direct forming process is operated, but that indirect forming process. This is intended to circumvent the problem described.
  • a method for hot forming a steel in which a component made of a given boron-manganese steel is heated to a temperature at the Ac 3 point or higher, kept at this temperature and then heated Steel sheet is formed into the finished component, wherein the molded component is quenched by cooling from the molding temperature during molding or after molding in such a manner that the cooling rate to MS point at least the critical cooling rate and that the average cooling rate of the molded component from the MS point to 200 ° C is in the range of 25 ° C / s to 150 ° C / s.
  • the object of the invention is to provide a method for producing provided with a corrosion protective layer sheet steel components, in which the cracking is reduced or eliminated and yet sufficient corrosion protection is achieved.
  • liquid metal embrittlement The above-described effect of liquid zinc cracking, which penetrates the steel in the vicinity of the grain boundaries, is also known as so-called "liquid metal embrittlement”.
  • the object is achieved by recognizing that the combination of the base material in the austenitized form, i. At high temperatures, the presence in this state of liquid zinc phases and the entry of stress by forming must be avoided in order to avoid the stresses induced thereby and thus cracks.
  • a barrier layer is disposed between the austenitized base material and the liquid zinc phases.
  • Such a barrier layer is, for example, a zinc ferritic barrier layer from the reaction between zinc and iron which dissolves pure zinc via a solid phase solution, the layer growing therefrom consuming zinc and forming a stable zinc ferrite mixed crystal.
  • zinc-nickel layers are possible as the first or sole corrosion protection layer because a zinc-nickel layer does not develop liquid zinc phases during the process.
  • the reduction of liquid zinc or the rapid construction of an effective barrier layer can be formed by rapidly closing the formation of the barrier layer by reducing the available amount of zinc and thus avoiding a residual liquid phase of zinc. This can i.a. be achieved by a reduction of the zinc coating thickness.
  • acceleration of the zinc-iron reaction and thus a faster and larger barrier layer thickness can also be achieved in this case if the zinc layer chemistry is interfered with.
  • Conventional zinc layers applied in the rapid dip galvanizing process have a certain amount of aluminum, which forms an inhibiting layer between the support material (steel) on the one hand and the zinc layer on the other hand, thereby preventing a strong reaction of substrate and coating.
  • the addition of aluminum can be purposefully reduced to promote precisely this rapid formation of a thick zinc-iron layer.
  • aluminum is reduced in the liquid zinc coating and optionally the coating before forming a Galvanealing reaction to form zinc-iron phases supplied to dissolve this inhibitor layer. Such a coating then does not cause any liquid zinc layers to directly interact with the austenite in detrimental interaction.
  • Figure 1 a table with the typical chemical composition of the examined steel samples
  • FIG. 2 is a graph showing the relationship between crack depth and furnace residence time in a pre-conversion annealing treatment
  • FIG. 3 shows a diagram showing the critical intervals of FIG
  • Figure 4 is a table showing the oven residence time along with images showing crack formation as a function of oven residence time
  • FIG. 5 shows samples according to FIG. 4 in a cross section showing the
  • FIG. 6 the ferrite layer formation through longer furnace residence time
  • FIG. 7 the zinc-iron state diagram.
  • a zinc ferrite layer can be formed with a longer furnace residence time and, consequently, a longer annealing treatment of a zinc coating, which effectively prevents the "liquid metal embrittlement" even if on the one hand austenite is present and stresses are introduced.
  • Figure 1 shows the analysis of a typical steel used in the method of the invention. It is understood that the remainder of the analysis consists of iron and unavoidable, unavoidable impurities.
  • the critical intervals of the furnace residence time for zinc-iron deposits of 80 g / m 2 , 100 g / m 2 and 120 g / m 2 are significantly lower, with the critical intervals, especially in a zinc-iron overlay of 80 g / m 2 between 45 s and 70 s and a zinc-iron overlay of 120 g / m 2 with 50 s to 105 s are also significantly narrower.
  • FIG. 5 cross sections of the different samples from FIG. 4 can be seen. Accordingly, not only the crack depth but also the crack width is significantly reduced with increasing furnace residence time. In addition, it can be seen that in the sample with the furnace residence time, the cracks are present only in the coating, while the cracks in the other samples reach into the base material.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Heat Treatment Of Articles (AREA)
  • Coating With Molten Metal (AREA)
  • Shaping Metal By Deep-Drawing, Or The Like (AREA)

Abstract

L'invention concerne un procédé de fabrication d'un composant en acier durci présentant un revêtement de zinc ou d'alliage de zinc, consistant à revêtir un matériau de zinc durcissable avec une couche de zinc ou une couche d'alliage de zinc, à matricer des platines à partir du matériau d'acier durcissable, à chauffer les platines à une température correspondant au point AC3 ou au-delà, et à les façonner à l'état chaud après une durée de séjour souhaitée dans un outil de façonnage, la platine de tôle d'acier façonnée étant refroidie par l'outil de façonnage à une vitesse supérieure à la vitesse de durcissage critique et ainsi durcie. Avant façonnage, la platine est maintenue à une température supérieure à 782 °C, indépendamment de l'épaisseur de la couche de zinc ou de l'épaisseur de la couche d'alliage de zinc, jusqu'à ce qu'une couche barrière en ferrite de zinc se forme entre l'acier et le revêtement de zinc ou d'alliage de zinc, et la couche de ferrite de zinc qui se forme absorbe du zinc liquide et est conçue si épaisse qu'aucune phase de zinc liquide ne réagit avec l'acier lors du façonnage.
EP11811026.1A 2010-12-24 2011-12-22 Procédé de fabrication de composants durcis Active EP2656187B1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE102010056265.3A DE102010056265C5 (de) 2010-12-24 2010-12-24 Verfahren zum Erzeugen gehärteter Bauteile
DE102010056264.5A DE102010056264C5 (de) 2010-12-24 2010-12-24 Verfahren zum Erzeugen gehärteter Bauteile
DE102011053939.5A DE102011053939B4 (de) 2011-09-26 2011-09-26 Verfahren zum Erzeugen gehärteter Bauteile
DE102011053941.7A DE102011053941B4 (de) 2011-09-26 2011-09-26 Verfahren zum Erzeugen gehärteter Bauteile mit Bereichen unterschiedlicher Härte und/oder Duktilität
PCT/EP2011/073892 WO2012085256A2 (fr) 2010-12-24 2011-12-22 Procédé de fabrication de composants durcis

Publications (2)

Publication Number Publication Date
EP2656187A2 true EP2656187A2 (fr) 2013-10-30
EP2656187B1 EP2656187B1 (fr) 2020-09-09

Family

ID=45470542

Family Applications (5)

Application Number Title Priority Date Filing Date
EP11811025.3A Active EP2655675B1 (fr) 2010-12-24 2011-12-22 Procédé pour produire des éléments de construction durcis pourvus de zones de différentes duretés et/ou ductilités
EP11808211.4A Active EP2655673B1 (fr) 2010-12-24 2011-12-22 Procédé de fabrication de composants durcis
EP11811026.1A Active EP2656187B1 (fr) 2010-12-24 2011-12-22 Procédé de fabrication de composants durcis
EP11808645.3A Active EP2655674B1 (fr) 2010-12-24 2011-12-22 Procédé de formage et de durcissement de tôles d'acier revêtues
EP11807691.8A Active EP2655672B1 (fr) 2010-12-24 2011-12-22 Procédé pour produire des éléments de construction durcis pourvus de zones de différentes duretés et/ou ductilités

Family Applications Before (2)

Application Number Title Priority Date Filing Date
EP11811025.3A Active EP2655675B1 (fr) 2010-12-24 2011-12-22 Procédé pour produire des éléments de construction durcis pourvus de zones de différentes duretés et/ou ductilités
EP11808211.4A Active EP2655673B1 (fr) 2010-12-24 2011-12-22 Procédé de fabrication de composants durcis

Family Applications After (2)

Application Number Title Priority Date Filing Date
EP11808645.3A Active EP2655674B1 (fr) 2010-12-24 2011-12-22 Procédé de formage et de durcissement de tôles d'acier revêtues
EP11807691.8A Active EP2655672B1 (fr) 2010-12-24 2011-12-22 Procédé pour produire des éléments de construction durcis pourvus de zones de différentes duretés et/ou ductilités

Country Status (8)

Country Link
US (2) US20140020795A1 (fr)
EP (5) EP2655675B1 (fr)
JP (2) JP2014507556A (fr)
KR (3) KR20130132566A (fr)
CN (5) CN103547687A (fr)
ES (5) ES2848159T3 (fr)
HU (5) HUE054867T2 (fr)
WO (5) WO2012085256A2 (fr)

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WO2012085256A2 (fr) 2012-06-28
HUE052381T2 (hu) 2021-04-28
EP2655672A2 (fr) 2013-10-30
CN103384726B (zh) 2016-11-23
WO2012085256A3 (fr) 2012-08-16
EP2655675B1 (fr) 2021-03-10
WO2012085248A3 (fr) 2012-08-16
CN103384726A (zh) 2013-11-06
ES2829950T8 (es) 2021-06-10
WO2012085247A2 (fr) 2012-06-28
HUE055049T2 (hu) 2021-10-28
ES2858225T3 (es) 2021-09-29
WO2012085247A3 (fr) 2012-08-16
WO2012085253A2 (fr) 2012-06-28
JP2014505791A (ja) 2014-03-06
KR20130126962A (ko) 2013-11-21
KR20130132566A (ko) 2013-12-04
ES2858225T8 (es) 2022-01-05
EP2656187B1 (fr) 2020-09-09
CN103392014A (zh) 2013-11-13
CN103547686B (zh) 2016-11-23
CN103415630B (zh) 2015-09-23
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CN103547686A (zh) 2014-01-29
CN103392014B (zh) 2016-01-27
ES2851176T3 (es) 2021-09-03
CN103415630A (zh) 2013-11-27
KR101582922B1 (ko) 2016-01-07
EP2655674B1 (fr) 2021-02-03
HUE054867T2 (hu) 2021-10-28
EP2655673B1 (fr) 2021-02-03
JP2014507556A (ja) 2014-03-27
JP5727037B2 (ja) 2015-06-03
ES2853207T3 (es) 2021-09-15
WO2012085253A3 (fr) 2012-08-16
US20140020795A1 (en) 2014-01-23
EP2655674A2 (fr) 2013-10-30
EP2655675A2 (fr) 2013-10-30
ES2848159T3 (es) 2021-08-05
HUE054465T2 (hu) 2021-09-28
EP2655672B1 (fr) 2020-12-16
US20140027026A1 (en) 2014-01-30
KR20130132565A (ko) 2013-12-04
US10640838B2 (en) 2020-05-05
CN103547687A (zh) 2014-01-29
WO2012085251A3 (fr) 2012-08-16

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