EP2473587B1 - Schmierstoffe auf wasserbasis - Google Patents

Schmierstoffe auf wasserbasis Download PDF

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Publication number
EP2473587B1
EP2473587B1 EP10747591.5A EP10747591A EP2473587B1 EP 2473587 B1 EP2473587 B1 EP 2473587B1 EP 10747591 A EP10747591 A EP 10747591A EP 2473587 B1 EP2473587 B1 EP 2473587B1
Authority
EP
European Patent Office
Prior art keywords
weight
water
lubricant
chosen
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP10747591.5A
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German (de)
English (en)
French (fr)
Other versions
EP2473587A1 (de
Inventor
Martin Schmid-Amelunxen
Martin Schweigkofler
Thomas Kilthau
Jochen MÜHLEMEIER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Klueber Lubrication Muenchen GmbH and Co KG
Original Assignee
Klueber Lubrication Muenchen GmbH and Co KG
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Publication of EP2473587A1 publication Critical patent/EP2473587A1/de
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Publication of EP2473587B1 publication Critical patent/EP2473587B1/de
Not-in-force legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34—Polyoxyalkylenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
    • C10M2207/1285—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof used as thickening agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/081—Biodegradable compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/02—Bearings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/04—Aerosols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Definitions

  • the present invention relates to water-based lubricants.
  • the invention relates to the use of water-based lubricants for the lubrication of friction partners in drive elements, as well as their use.
  • the WO 2005/113640 A1 discloses formulations of low pulmonary toxicity functional fluids containing low unsaturation alkylene oxide copolymers. More particularly, this document relates to low inhalation toxicity water-glycol hydraulic fluids containing from 30 to 60% of a water-soluble polyglycol, from 0 to 40% antifreeze, such as ethylene glycol, from 20 to 45% water, from 0 to 15% thickener, from 0 to 5% corrosion additives, 0 to 5% defoamers and dyes, as well as 0 to 5% fatty acid amides included.
  • a water-soluble polyglycol from 0 to 40% antifreeze, such as ethylene glycol, from 20 to 45% water, from 0 to 15% thickener, from 0 to 5% corrosion additives, 0 to 5% defoamers and dyes, as well as 0 to 5% fatty acid amides included.
  • the WO 97/15643 A1 relates to a water-soluble lubricant composition consisting of a mixture of polyethylene glycol and an amine to which further additives are added, inter alia optionally biocides are added.
  • the operating fluid consists of a mixture of water and an aliphatic hydrocarbon in which graphite particles are suspended as a solid lubricant.
  • This solid lubricant is in the form of flaky graphite particles having a particle size of less than 50 microns.
  • Further components of this lubricant and coolant are dispersing additives, defoamers, Corrosion inhibitors. Disadvantages of this operating fluid are the graphite particles present in solid or flaky form, which on the one hand can settle out of the suspension and thus adhere the operating parts to be lubricated.
  • Another disadvantage is the persistent contamination of components that come into contact with graphite-containing lubricants. If a filtration of the lubricating oil is required during operation, the graphite may lead to a clogging of the filter pores. In addition, the operating fluid has a very low viscosity, which can lead to failure of the lubricating film at high loads.
  • the present invention was therefore based on the object to provide a water-based lubricant that meets the above requirements, in particular is biodegradable and that helps to significantly reduce the production of carbon dioxide.
  • a lubricant consisting of water, water-soluble polyalkylene glycols, water-soluble emulsifiers and lubricant-compatible additives.
  • the water-soluble polyalkylene glycols are selected from the group of randomly distributing polyoxyethylene and polyoxypropylene units and / or other polyoxyalkylene units having one or more hydroxyl end groups, from a block polymer of polyoxyethylene and / or polyoxypropylene units and / or other polyoxyalkylene units.
  • anionic surfactants e.g. Sulfonates
  • nonionic surfactants e.g. Fatty alcohol ethoxylates or NPE
  • cationic surfactants e.g. quaternary ammonium compounds, water-soluble or water-emulsifiable carboxylic acid esters used.
  • the low-temperature behavior of water-based lubricants by the addition of antifreeze e.g. low molecular weight glycols, glycerol, salts or ionic liquids can be significantly improved.
  • additives can be added to influence the properties of the lubricant targeted. These may be in soluble or dispersed, colloidal or nanoscale form.
  • water-based lubricants can also be formulated foaming.
  • the application as a spray foam is of particular interest here, because it allows a visual control of the lubricant application. In the case of contamination of textiles or machine parts with water-based lubricating fluids, these are easy to clean.
  • stain lubricants based on mineral oil or synthetic oil are usually harmful and / or ecotoxicological dyes required.
  • water-based lubricants a variety of toxicologically harmless water-soluble dyes to food colors can be used.
  • the "base oil” according to the invention can also be converted into a lubricating grease or a lubricating paste by mixing with soap or urea powders, layered silicates or other common lubricant thickeners.
  • the lubricant composition 0.5 to 40 wt .-% lubricant thickener selected from the group consisting of metal soaps of mono- and / or dicarboxylic acids, ureas, phyllosilicates, solid lubricants and Aerosil contain.
  • Examples 1 and 3 to 5 are comparative examples.
  • Table 1 shows properties of Example Formulation 1 compared to a mineral oil based product. ⁇ b> Table 1 ⁇ / b> example 1 petroleum product Viscosity at 40 ° C ISO VG 32 ISO VG 32 pour Point -35 ° C -10 ° C Friction coefficient, SRV test 0.058 0,100 Hazen color number 35 140
  • Table 2 shows properties of Example Formulation 2 compared to a mineral oil based product. Despite its clearly low viscosity, the aqueous formulation has significantly improved wear protection (higher achievable surface coverage), according to Reichert. ⁇ b> Table 2 ⁇ / b> Example 2 petroleum product Viscosity at 40 ° C 110 mm 2 / s 460 mm 2 / s pour Point -35 ° C -10 ° C Surface pressure according to Reichert wear scale according to VKIS worksheet 3500 N / cm 2 2800 N / cm 2 Hazen color number 130 230
  • An oil foam consists of Water dist. 50.0% by weight propylene glycol 15.0% by weight Polyethylene glycol high molecular weight 25.0% by weight Foaming fatty alcohol ethoxylate 5.0% by weight Alkanolamine and boric acid derivative 2.0% by weight Sulfurized fatty acid 3.0% by weight
  • the pour point of the formulation is -20 ° C.
  • This composition has a high foam formation, which allows the application by means of spray / pump spray as a foam.
  • Such an application has the advantage that the lubricant on the surface can be detected well visually, even with minimum quantity lubrication immediately after application, for example with the focus quality assurance.
  • a further advantage of the application as foam is the improved wetting of the entire surface of the tribosystem, which allows a shortened run-in time and an improved run-in behavior.
  • illustration 1 shows a significantly lower torque of foamed (not water-based) lubricant bearing within the first 120 minutes running time.
  • a bb. 1 Current consumption of a lubricated with lubricant A bearing. Gray curve: standard application. Black curve: application as a foam.
  • Table 3 shows properties of Example Formulation 4. ⁇ b> ⁇ u> Table 3 ⁇ / u> ⁇ /b> Walkpenetration DIN ISO 2137 NLGI 2 Base oil viscosity, DIN 51562 90 cst Flow pressure at -30 ° C, DIN 51805 ⁇ 1400 mbar
  • Lubricant consisting of: Water dist. 27.5% by weight Polyalkylene glycol high molecular weight 50.0% by weight alkylene 10.0% by weight Carboxylic acid derivative M-528, Cortec 2.0% by weight Water-soluble carboxylic acid ester 10.0% by weight acrylic copolymer 0.5% by weight
  • This lubricant is suitable for the lubrication of seals on rotating shafts and, in contrast to the known lubricants of mineral oils or synthetic hydrocarbons well biodegradable and therefore environmentally friendly to dispose of. It is characterized by a low friction, good cooling effect, good compatibility with rubber-elastic materials and has a low Geissesserverschmutzungspotential. Advantageously, it changes the viscosity when diluted with water only slightly and therefore allows the formation of an effective lubricating film.
  • the water-based lubricant according to the invention can be used for lubricating drive elements in chains, gears, rolling and sliding bearings or for lubricating seals on rotating shafts in the form of a foam, spray or emulsion by means of spray or pump spray devices with the focus of better surface wetting and the better Detectability of thin lubricating films is applied, can be used.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)
EP10747591.5A 2009-09-01 2010-08-23 Schmierstoffe auf wasserbasis Not-in-force EP2473587B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009039626A DE102009039626A1 (de) 2009-09-01 2009-09-01 Schmierstoffe auf Wasserbasis
PCT/EP2010/005157 WO2011026576A1 (de) 2009-09-01 2010-08-23 Schmierstoffe auf wasserbasis

Publications (2)

Publication Number Publication Date
EP2473587A1 EP2473587A1 (de) 2012-07-11
EP2473587B1 true EP2473587B1 (de) 2015-10-07

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP10747591.5A Not-in-force EP2473587B1 (de) 2009-09-01 2010-08-23 Schmierstoffe auf wasserbasis

Country Status (14)

Country Link
US (1) US8809243B2 (zh)
EP (1) EP2473587B1 (zh)
JP (1) JP5698240B2 (zh)
KR (1) KR101439832B1 (zh)
CN (1) CN102482603A (zh)
AU (1) AU2010291521B2 (zh)
BR (1) BR112012004662A2 (zh)
CA (1) CA2769029C (zh)
DE (1) DE102009039626A1 (zh)
DK (1) DK2473587T3 (zh)
ES (1) ES2552791T3 (zh)
MX (1) MX2012002029A (zh)
RU (1) RU2550498C2 (zh)
WO (1) WO2011026576A1 (zh)

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EP3901291A1 (de) 2020-04-24 2021-10-27 Schaeffler Technologies AG & Co. KG Maschinenelement mit einer wälzkontaktfläche und verfahren zur wärmebehandlung eines maschinenelementes

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2365037T3 (pl) * 2010-03-10 2013-10-31 Ppg Ind Ohio Inc Sposób usuwania mgły malarskiej z malarskiej komory natryskowej
DE102010015757A1 (de) * 2010-04-21 2011-10-27 KLüBER LUBRICATION MüNCHEN KG Schmierstoffe für Textilmaschinen auf Wasserbasis
ES2708388T3 (es) 2014-09-10 2019-04-09 Ppg Ind Ohio Inc Líquido de separación acuoso y proceso para retirar el exceso de pintura pulverizada de una cabina de pulverización de pintura
JP6159373B2 (ja) * 2015-10-07 2017-07-05 出光興産株式会社 冷凍機油、冷凍機用組成物、冷凍機及び冷凍機油の選定方法
CN106151279A (zh) * 2016-08-17 2016-11-23 常州市武进长江滚针轴承有限公司 防冻型滚针轴承
US20180298306A1 (en) * 2017-04-06 2018-10-18 Wd-40 Company Non-flammable aerosol multiuse invert emulsion lubricant
JP2018199743A (ja) * 2017-05-25 2018-12-20 三菱重工業株式会社 加工機用液剤
EP3431574A1 (de) * 2017-07-21 2019-01-23 Carl Bechem Gmbh Schmiermittelzusammensetzung
DE102017215713A1 (de) 2017-09-06 2019-03-07 Sms Group Gmbh Verfahren zum Betrieb einer walz- oder hüttentechnischen Anlage
CN107574001B (zh) * 2017-10-11 2018-10-12 天津农学院 用于食品灌装生产线的水基润滑剂
DE102018207442A1 (de) 2018-05-15 2019-11-21 Bayerische Motoren Werke Aktiengesellschaft Mit einem wasserhaltigen Schmierstoff geschmierte Kraftfahrzeugvorrichtung
JP7246683B2 (ja) * 2018-10-02 2023-03-28 株式会社ユーテック 液圧駆動装置のための水系作動液
JP7179322B2 (ja) * 2018-10-25 2022-11-29 株式会社ユーテック 減速装置のための水系潤滑液
JP2020067151A (ja) 2018-10-25 2020-04-30 株式会社ユーテック 歯車装置
CN109777014B (zh) * 2018-12-29 2020-10-27 西安交通大学 一种高强度抗冻导电聚吡咯水凝胶及其制备方法
WO2020160802A1 (en) 2019-02-08 2020-08-13 Evonik Operations Gmbh Polymer-modified metal oxides, manufacturing process thereof and their use for obtaining mineral oil
DE102019117288A1 (de) 2019-06-27 2020-06-04 Schaeffler Technologies AG & Co. KG Maschinenelement und Verwendung eines Maschinenelements
CN110982605B (zh) * 2019-12-19 2022-04-19 广州市硅涂新材料有限公司 一种线缆润滑剂及其制备方法
CN111206423B (zh) * 2020-03-13 2022-07-26 诸暨富鸿绣花机制造有限公司 纺织润滑助剂和纱线润滑方法
CN115702231A (zh) * 2020-06-16 2023-02-14 三吉油脂株式会社 赋予润滑性的添加剂或组合物
FR3111639B1 (fr) 2020-06-22 2022-08-19 Total Marketing Services Composition aqueuse pour la lubrification des systèmes mécaniques
FR3111640B1 (fr) 2020-06-22 2022-07-22 Total Marketing Services Composition aqueuse pour la lubrification des systèmes mécaniques
CN113403131B (zh) * 2021-06-16 2022-06-10 中国科学院兰州化学物理研究所 一种超润滑水基切削液
EP4112705A1 (en) * 2021-07-01 2023-01-04 TotalEnergies OneTech Aqueous lubricating composition comprising mos2 nanosheet
EP4112704A1 (en) * 2021-07-01 2023-01-04 TotalEnergies OneTech Aqueous lubricating composition comprising mos2 nanosheet
CN113527149B (zh) * 2021-08-22 2023-05-09 宝鸡文理学院 一种离子液体水基润滑添加剂及其制备方法和应用
FR3134815A1 (fr) * 2022-04-20 2023-10-27 Totalenergies Onetech Composition aqueuse pour la lubrification et/ou le refroidissement d’un système de propulsion d’un véhicule électrique ou hybride
FR3134814A1 (fr) 2022-04-20 2023-10-27 Totalenergies Onetech Composition lubrifiante aqueuse comprenant un ester de l’acide gallique
FR3134813A1 (fr) 2022-04-20 2023-10-27 Totalenergies Onetech Composition lubrifiante aqueuse comprenant un ester de l’acide ascorbique
CN115404119B (zh) * 2022-08-23 2023-08-22 煤炭科学技术研究院有限公司 一种液压支架防冻液复合添加剂及其制备方法与应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2854308B2 (ja) * 1988-12-15 1999-02-03 出光興産株式会社 防錆・防食性不凍液用基材、防錆・防食性合成潤滑剤及び防錆・防食性含水液
BR9306004A (pt) * 1992-03-02 1997-10-21 Henkel Kommanditengesellschaft Lubrificantes para correias transportadoras de corrente e sua aplicação
US5801128A (en) * 1995-10-23 1998-09-01 International Refining And Manufacturing Company Hot melt lubricant and method of application
EP1148076A1 (de) * 2000-04-17 2001-10-24 Clariant GmbH Wasserlösliche Polyalkylenglykolöle mit hohem Viskositätsindex und niedriger Aeorosoltoxizität
DE10049175A1 (de) * 2000-09-22 2002-04-25 Tea Gmbh Biologisch abbaubare Funktionsflüssigkeit für mechanische Antriebe
US6436883B1 (en) * 2001-04-06 2002-08-20 Huntsman Petrochemical Corporation Hydraulic and gear lubricants
MX221601B (en) 2004-05-14 2004-07-22 Basf Ag Functional fluids containing alkylene oxide copolymers having low pulmonary toxicity
JP2006045350A (ja) 2004-08-04 2006-02-16 Toyota Motor Corp 流体組成物及びその利用
US7612024B2 (en) * 2004-12-22 2009-11-03 Ecolab Inc. Polyalkylene glycol based solutions with enhanced high temperature stability
US20060270569A1 (en) * 2005-05-27 2006-11-30 James Athans Emulsions and products thereof
US20070027037A1 (en) * 2005-07-27 2007-02-01 Nissan Technical Center North America, Inc. Lubricant aerosol dispensing container
AT9168U1 (de) 2006-03-03 2007-05-15 Magna Steyr Fahrzeugtechnik Ag Betriebsbereites getriebe, betriebsflüssigkeit für ein solches und verfahren zu dessen erstinbetriebnahme
US8258086B2 (en) * 2006-12-01 2012-09-04 Henkel Corporation Anti-seize composition with nano-sized lubricating solid particles
US8222190B2 (en) * 2009-08-19 2012-07-17 Nanotek Instruments, Inc. Nano graphene-modified lubricant

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3401358A1 (de) 2017-05-08 2018-11-14 Carl Freudenberg KG Plasma-beschichtetes dichtelement
WO2018206248A1 (de) 2017-05-08 2018-11-15 Carl Freudenberg Kg Plasma-beschichtetes dichtelement
US11371614B2 (en) 2017-05-08 2022-06-28 Carl Freudenberg Kg Plasma-coated sealing element
EP3901291A1 (de) 2020-04-24 2021-10-27 Schaeffler Technologies AG & Co. KG Maschinenelement mit einer wälzkontaktfläche und verfahren zur wärmebehandlung eines maschinenelementes

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DE102009039626A1 (de) 2011-03-03
US8809243B2 (en) 2014-08-19
AU2010291521A1 (en) 2012-02-02
WO2011026576A1 (de) 2011-03-10
KR101439832B1 (ko) 2014-09-12
CA2769029A1 (en) 2011-03-10
CN102482603A (zh) 2012-05-30
RU2012112337A (ru) 2013-10-10
KR20120027498A (ko) 2012-03-21
JP2013503922A (ja) 2013-02-04
DK2473587T3 (en) 2016-01-18
CA2769029C (en) 2017-07-04
AU2010291521B2 (en) 2013-09-19
RU2550498C2 (ru) 2015-05-10
ES2552791T3 (es) 2015-12-02
JP5698240B2 (ja) 2015-04-08
BR112012004662A2 (pt) 2017-05-23
DE102009039626A8 (de) 2011-06-01
EP2473587A1 (de) 2012-07-11
MX2012002029A (es) 2012-03-26

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