EP2286308B1 - Feder von amorphem metall für federhaus und verfahren zur ihrer formgebung - Google Patents
Feder von amorphem metall für federhaus und verfahren zur ihrer formgebung Download PDFInfo
- Publication number
- EP2286308B1 EP2286308B1 EP09771888.6A EP09771888A EP2286308B1 EP 2286308 B1 EP2286308 B1 EP 2286308B1 EP 09771888 A EP09771888 A EP 09771888A EP 2286308 B1 EP2286308 B1 EP 2286308B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ribbon
- curvatures
- spring
- shape
- mainspring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims description 18
- 238000007493 shaping process Methods 0.000 title claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 14
- 239000005300 metallic glass Substances 0.000 claims description 13
- 238000005452 bending Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 230000009477 glass transition Effects 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 description 16
- 239000000956 alloy Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 9
- 229920000297 Rayon Polymers 0.000 description 6
- 239000002964 rayon Substances 0.000 description 6
- 238000005266 casting Methods 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000005489 elastic deformation Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 241001639412 Verres Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B1/00—Driving mechanisms
- G04B1/10—Driving mechanisms with mainspring
- G04B1/14—Mainsprings; Bridles therefor
- G04B1/145—Composition and manufacture of the springs
Definitions
- the present invention relates to a method for shaping a barrel spring for a mechanism driven by a mainspring, in particular for a timepiece, formed from a metallic glass material.
- the mechanical properties of the alloy and the final shape are the result of the combination of these two steps. A single heat treatment would not achieve the mechanical properties desired for traditional alloys.
- the fixing of crystalline metal alloys involves a relatively long treatment time (several hours) at a temperature high enough to induce the desired modification of the crystalline structure.
- the mechanical properties of the material are intrinsically linked to its amorphous structure and are obtained immediately after solidification, unlike the mechanical properties of traditional Nivaflex ® alloy springs which are obtained by a series of heat treatments at different stages of their manufacturing process. Therefore, and unlike Nivaflex ® alloy, further hardening by heat treatment is not necessary.
- the object of the present invention is to remedy, at least in part, the above-mentioned drawbacks.
- the subject of the present invention is a method for shaping the barrel spring according to claim 1.
- the strips intended to form the barrel springs are produced by the wheel quenching technique (or Planar Flow Casting) which is a technique for producing metal strips by rapid cooling.
- a jet of molten metal is propelled onto a cold wheel which spins at high speed.
- the speed of the wheel, the width of the injection slot, the injection pressure are all parameters which will define the width and the thickness of the ribbon produced.
- Other tape-making techniques can also be used, such as Twin Roll Casting, for example.
- the alloy used is Ni 53 Nb 20 Zr 8 Ti 10 Co 6 Cu 3 in this example. From 10 to 20g of alloy are placed in a distribution nozzle heated between 1050 and 1150°C. The slit width of the nozzle is between 0.2 and 0.8mm. The distance between the nozzle and the wheel is between 0.1 and 0.3mm. The wheel on which the molten alloy is deposited is a copper alloy wheel and driven at a speed of 5 to 20m/s. The pressure exerted to force the molten alloy out through the nozzle is between 10 and 50 kPa.
- the barrel spring releases its energy when it passes from the armed state to the disarmed state.
- the goal is to calculate the shape that the spring must have in its free state so that each section is subjected to the maximum bending moment in its armed state.
- the figures 1 to 3 below respectively describe the three mainspring configurations, namely armed, disarmed and free.
- the spring in its charged state (see figure 1 ) is considered to be a spiral with the turns tight against each other.
- the metallic glass ribbon is obtained by rapid solidification of the liquid metal on a copper or alloy wheel with high thermal conductivity rotating at high speed.
- a minimum critical cooling rate is required to vitrify liquid metal. If the cooling is too slow, the metal solidifies by crystallization and loses its mechanical properties. It is important, for a given thickness, to guarantee the maximum cooling rate. The higher this will be, the less the atoms will have time to relax and the greater the concentration of free volume will be. The ductility of the ribbon is then improved.
- the Planar Flow Casting step is therefore decisive for the mechanical and thermodynamic properties of the tape.
- the viscosity decreases sharply with the temperature, that is to say approximately one order of magnitude per rise of 10K.
- the viscosity at T g is generally equal to 10 12 Pa ⁇ s, independently of the alloy considered. It is then possible to shape the viscous body, in this case the ribbon, to give it its desired shape, then cool it to permanently fix the shape.
- thermal activation will allow the diffusion of free volumes and atoms within the material.
- the atoms will locally form denser domains, close to a crystalline structure at the expense of the free volumes, which will be annihilated. This phenomenon is called relaxation.
- the decrease in free volume is accompanied by an increase in Young's modulus and a decrease in subsequent ductility.
- the relaxation phenomenon can be similar to annealing.
- the thermal agitation the relaxation is accelerated and causes a drastic embrittlement of the glass by annihilation of the free volume. If the treatment time is too long, the amorphous material will crystallize and thus lose its exceptional properties.
- Hot forming is therefore a balance between sufficient relaxation to retain the desired shape and as little reduction in ductility as possible.
- the ribbons produced by the Planar Flow Casting (PFC) technique have a width of several millimeters and a thickness of between 40 and 150 ⁇ m. Strips have been machined, using the wire EDM technique, to the typical width and length of a mainspring. The flanks were ground, after which the spring was shaped, based on the theoretical shape as calculated previously.
- PFC Planar Flow Casting
- a laying of the type generally used is used, on which the spring is wound to give it its free shape, determined by the theoretical shape as calculated previously, taking account of a variation between the shape imposed by the laying and the free shape actually obtained.
- the curvatures being defined as the inverse of the radius of curvature
- the laying curvatures must therefore be increased accordingly so that the free shape obtained corresponds to the theoretical shape.
- the ratio between the curvatures of the shaped ribbon before the relaxation heating and the curvatures of the theoretical free form depends on the heating parameters, the alloy and its initial state of relaxation, and is between 100% and 140%, typically 130% under the conditions used below.
- the spring in its setting was then introduced into an oven heated to around T g (590° C.) for a period of 3 to 5 minutes, depending on the setting used.
- heating modes can be used, such as heating by Joule effect or a jet of hot inert gas for example.
- a sliding flange for a self-winding watch spring in Nivaflex ® alloy was riveted to its outer end, to enable winding and unwinding tests to be carried out.
- the sliding flange is necessary to ensure the function of such a spring, however its method of assembly to the blade as well as the material of the flange may vary.
- the figure 4 shows the variation in torque as a function of the number of turns obtained with the spring calculated and shaped according to the method described in this document.
- This winding-unwinding curve is entirely characteristic of the behavior of a mainspring.
- the torque, the number of turns of development and the overall efficiency are fully satisfactory given the dimensions of the tape.
Landscapes
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Springs (AREA)
- Electromechanical Clocks (AREA)
Claims (6)
- Verfahren zur Formgebung für eine Feder eines Federhauses einer Uhr, die aus einem monolithischen Band aus amorphem Metall gebildet ist, gekennzeichnet durch:- Berechnen einer freien theoretischen Form, die diesem monolithischen Band aus amorphem Metall zu geben ist, damit jedes Segment, wenn die Feder in dem Federhaus gespannt ist, dem maximalen Biegemoment ausgesetzt ist,- Formen dieses Bands, indem ihm Biegungen verliehen werden, die für diese freie theoretische Form charakteristisch sind, um eine Verringerung dieser Biegungen bei Freigabe des Bands zu berücksichtigen,- Durchführen der Relaxation des Bands, um seine Form zu fixieren, indem es ungefähr auf die Glasübergangstemperatur oder auf einen Bereich zwischen Tx+50K und Tg-50K erhitzt wird, wobei Tg die Glasübergangstemperatur ist und Tx die Kristallisationstemperatur ist,- Abkühlen dieses Bands.
- Verfahren nach Anspruch 1, wobei die freie theoretische Form der Feder des Federhauses aus dem monolithischem Band erhalten wird, indem sie auf einem geeigneten Gestell angeordnet wird.
- Verfahren nach einem der Ansprüche 1 bis 2, wobei die Fixierung des in Form gebrachten Bands durchgeführt wird, indem es innerhalb einer Zeitspanne, die kleiner als 6 Minuten ist, erhitzt und dann abgekühlt wird.
- Verfahren nach Anspruch 1, wobei das Verhältnis zwischen den Biegungen des in Form gebrachten Bands vor dem Relaxationserhitzen und den Biegungen der freien theoretischen Form zwischen 100 % und 140 % liegt.
- Verfahren nach Anspruch 4, wobei das Verhältnis zwischen den Biegungen des in Form gebrachten Bands vor dem Relaxationserhitzen und den Biegungen der freien theoretischen Form typischerweise bei 130 % liegt.
- Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass ein Gleitzaum an die Feder montiert wird, insbesondere durch Vernieten.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22170104.8A EP4092489A1 (de) | 2008-06-10 | 2009-06-09 | Verfahren zum umformen einer triebfeder aus metallischen glas |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08405153 | 2008-06-10 | ||
EP08405192A EP2154581A1 (de) | 2008-08-04 | 2008-08-04 | Schließzylinderfeder und Verfahren zur ihrer Formgebung |
PCT/CH2009/000191 WO2010000081A1 (fr) | 2008-06-10 | 2009-06-09 | Procede pour la mise en forme d'un ressort de barillet en verre metallique |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP22170104.8A Division EP4092489A1 (de) | 2008-06-10 | 2009-06-09 | Verfahren zum umformen einer triebfeder aus metallischen glas |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2286308A1 EP2286308A1 (de) | 2011-02-23 |
EP2286308B1 true EP2286308B1 (de) | 2022-05-04 |
Family
ID=41110579
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09405089.5A Revoked EP2133756B1 (de) | 2008-06-10 | 2009-05-27 | Zugfeder für Federhaus |
EP22170104.8A Withdrawn EP4092489A1 (de) | 2008-06-10 | 2009-06-09 | Verfahren zum umformen einer triebfeder aus metallischen glas |
EP09771888.6A Active EP2286308B1 (de) | 2008-06-10 | 2009-06-09 | Feder von amorphem metall für federhaus und verfahren zur ihrer formgebung |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09405089.5A Revoked EP2133756B1 (de) | 2008-06-10 | 2009-05-27 | Zugfeder für Federhaus |
EP22170104.8A Withdrawn EP4092489A1 (de) | 2008-06-10 | 2009-06-09 | Verfahren zum umformen einer triebfeder aus metallischen glas |
Country Status (6)
Country | Link |
---|---|
US (2) | US8348496B2 (de) |
EP (3) | EP2133756B1 (de) |
JP (2) | JP5656369B2 (de) |
CN (2) | CN101604141B (de) |
CH (1) | CH698962B1 (de) |
WO (1) | WO2010000081A1 (de) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH698962B1 (fr) * | 2008-06-10 | 2014-10-31 | Rolex Sa | Ressort de barillet et procédé pour sa mise en forme. |
CN102713770B (zh) * | 2009-12-09 | 2015-11-25 | 劳力士有限公司 | 用于制造钟表用弹簧的方法 |
US20110156328A1 (en) * | 2009-12-31 | 2011-06-30 | Nicolio Curtis J | Integral retainer to retain a spring |
GB201001897D0 (en) * | 2010-02-05 | 2010-03-24 | Levingston Gideon | Non magnetic mateial additives and processes for controling the thermoelastic modulus and spring stiffness within springs for precision instruments |
EP2390732A1 (de) | 2010-05-27 | 2011-11-30 | Association Suisse pour la Recherche Horlogère | Zugfeder für Federhaus |
EP2585882B1 (de) * | 2010-06-22 | 2021-02-24 | The Swatch Group Research and Development Ltd. | Stossdämpfungssystem für eine uhr |
CN102339008A (zh) * | 2010-07-15 | 2012-02-01 | 慈溪市九菱电器有限公司 | 一种定时器s形发条 |
WO2012010941A1 (fr) | 2010-07-21 | 2012-01-26 | Rolex S.A. | Composant horloger comprenant un alliage métallique amorphe |
JP6346440B2 (ja) | 2010-07-21 | 2018-06-20 | ロレックス・ソシエテ・アノニムRolex Sa | アモルファス金属合金 |
US9298162B2 (en) * | 2010-10-01 | 2016-03-29 | Rolex Sa | Timepiece barrel with thin disks |
CH704236B1 (fr) | 2010-12-17 | 2015-09-30 | Manuf Et Fabrique De Montres Et Chronomètres Ulysse Nardin Le Locle Sa | Procédé de réalisation d'un timbre de sonnerie. |
DE102011001783B4 (de) | 2011-04-04 | 2022-11-24 | Vacuumschmelze Gmbh & Co. Kg | Feder für ein mechanisches Uhrwerk, mechanisches Uhrwerk, Uhr mit einem mechanischen Uhrwerk und Verfahren zur Herstellung einer Feder |
DE102011001784B4 (de) | 2011-04-04 | 2018-03-22 | Vacuumschmelze Gmbh & Co. Kg | Verfahren zur Herstellung einer Feder für ein mechanisches Uhrwerk und Feder für ein mechanisches Uhrwerk |
EP2590325A1 (de) * | 2011-11-04 | 2013-05-08 | The Swatch Group Research and Development Ltd. | Thermokompensierter Resonator aus Keramik |
SG10201607483TA (en) * | 2012-03-16 | 2016-10-28 | Univ Yale | Multi step processing method for the fabrication of complex articles made of metallic glasses |
US9448533B2 (en) | 2012-04-04 | 2016-09-20 | Rolex Sa | Barrel shaft for a clock movement, barrel spring and barrel including such a spring and/or such a shaft |
EP2703911B1 (de) * | 2012-09-03 | 2018-04-11 | Blancpain SA. | Regulierorgan für kleinuhr |
EP2706415A3 (de) * | 2012-09-05 | 2017-06-14 | Seiko Epson Corporation | Verfahren zur Herstellung einer Uhrfeder, Vorrichtung zur Herstellung einer Uhrfeder, Uhrfeder und Uhr |
CH708231B1 (fr) * | 2013-06-27 | 2017-03-15 | Nivarox Far Sa | Ressort d'horlogerie en acier inoxydable austénitique. |
CH708660A1 (fr) * | 2013-10-04 | 2015-04-15 | Cartier Création Studio Sa | Ressort moteur pour barillet moteur minimisant l'usure du tambour. |
EP2924514B1 (de) | 2014-03-24 | 2017-09-13 | Nivarox-FAR S.A. | Uhrfeder aus austenitischem Edelstahl |
US10315241B2 (en) | 2014-07-01 | 2019-06-11 | United Technologies Corporation | Cast components and manufacture and use methods |
DE102015002430A1 (de) | 2015-02-26 | 2016-09-01 | Gernot Hausch | CoNiCrMo-Legierung für Aufzugsfedern in einem mechanischen Uhrwerk |
US10317842B2 (en) | 2016-04-25 | 2019-06-11 | Seiko Epson Corporation | Timepiece mainspring, timepiece drive device, timepiece movement, timepiece, and manufacturing method of timepiece mainspring |
EP3273305B1 (de) * | 2016-07-19 | 2023-07-19 | Nivarox-FAR S.A. | Bauteil für uhrwerk |
EP3557333B1 (de) | 2018-04-16 | 2020-11-04 | Patek Philippe SA Genève | Herstellungsverfahren einer zugfeder für eine uhr |
EP3575885B1 (de) * | 2018-06-01 | 2022-09-21 | Nivarox-FAR S.A. | Federhaus für uhren |
EP3882710A1 (de) | 2020-03-19 | 2021-09-22 | Patek Philippe SA Genève | Verfahren zur herstellung einer uhrenkomponente auf siliziumbasis |
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US3343573A (en) * | 1965-04-14 | 1967-09-26 | James Hill Mfg Company | Roving can spring |
CH510283A (de) * | 1966-04-30 | 1971-03-31 | Citizen Watch Co Ltd | Uhrenzugfeder |
EP1296798A1 (de) * | 2000-07-06 | 2003-04-02 | Trico Products Company | Verfahren und vorrichtung zur flexiblen fertigung von gekrümmten einzelartikeln |
US20070133355A1 (en) * | 2003-11-07 | 2007-06-14 | Seik Epson Corporation | Timepiece and spring thereof |
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CH698962B1 (fr) * | 2008-06-10 | 2014-10-31 | Rolex Sa | Ressort de barillet et procédé pour sa mise en forme. |
EP2154581A1 (de) | 2008-08-04 | 2010-02-17 | Rolex Sa | Schließzylinderfeder und Verfahren zur ihrer Formgebung |
CN102713770B (zh) * | 2009-12-09 | 2015-11-25 | 劳力士有限公司 | 用于制造钟表用弹簧的方法 |
WO2012010941A1 (fr) | 2010-07-21 | 2012-01-26 | Rolex S.A. | Composant horloger comprenant un alliage métallique amorphe |
-
2009
- 2009-05-26 CH CH00809/09A patent/CH698962B1/fr unknown
- 2009-05-27 EP EP09405089.5A patent/EP2133756B1/de not_active Revoked
- 2009-06-08 US US12/479,947 patent/US8348496B2/en active Active
- 2009-06-08 JP JP2009136880A patent/JP5656369B2/ja active Active
- 2009-06-09 EP EP22170104.8A patent/EP4092489A1/de not_active Withdrawn
- 2009-06-09 US US12/996,542 patent/US8720246B2/en active Active
- 2009-06-09 CN CN2009101595422A patent/CN101604141B/zh active Active
- 2009-06-09 CN CN2009801217412A patent/CN102057336B/zh active Active
- 2009-06-09 JP JP2011512804A patent/JP5518852B2/ja active Active
- 2009-06-09 WO PCT/CH2009/000191 patent/WO2010000081A1/fr active Application Filing
- 2009-06-09 EP EP09771888.6A patent/EP2286308B1/de active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3343573A (en) * | 1965-04-14 | 1967-09-26 | James Hill Mfg Company | Roving can spring |
CH510283A (de) * | 1966-04-30 | 1971-03-31 | Citizen Watch Co Ltd | Uhrenzugfeder |
EP1296798A1 (de) * | 2000-07-06 | 2003-04-02 | Trico Products Company | Verfahren und vorrichtung zur flexiblen fertigung von gekrümmten einzelartikeln |
US20070133355A1 (en) * | 2003-11-07 | 2007-06-14 | Seik Epson Corporation | Timepiece and spring thereof |
Also Published As
Publication number | Publication date |
---|---|
EP2286308A1 (de) | 2011-02-23 |
CN101604141B (zh) | 2012-06-27 |
EP4092489A1 (de) | 2022-11-23 |
WO2010000081A1 (fr) | 2010-01-07 |
CH698962A2 (fr) | 2009-12-15 |
US20110072873A1 (en) | 2011-03-31 |
US8720246B2 (en) | 2014-05-13 |
CH698962B1 (fr) | 2014-10-31 |
US8348496B2 (en) | 2013-01-08 |
JP2011523066A (ja) | 2011-08-04 |
US20090303842A1 (en) | 2009-12-10 |
EP2133756A2 (de) | 2009-12-16 |
CN101604141A (zh) | 2009-12-16 |
CN102057336A (zh) | 2011-05-11 |
JP5518852B2 (ja) | 2014-06-11 |
JP5656369B2 (ja) | 2015-01-21 |
EP2133756A3 (de) | 2011-04-13 |
EP2133756B1 (de) | 2016-07-20 |
JP2009300439A (ja) | 2009-12-24 |
CN102057336B (zh) | 2013-07-03 |
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