EP2133756B1 - Zugfeder für Federhaus - Google Patents
Zugfeder für Federhaus Download PDFInfo
- Publication number
- EP2133756B1 EP2133756B1 EP09405089.5A EP09405089A EP2133756B1 EP 2133756 B1 EP2133756 B1 EP 2133756B1 EP 09405089 A EP09405089 A EP 09405089A EP 2133756 B1 EP2133756 B1 EP 2133756B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- spring
- radius
- nth turn
- max
- ribbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000005300 metallic glass Substances 0.000 claims description 6
- 238000005452 bending Methods 0.000 claims description 4
- 230000007246 mechanism Effects 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 description 17
- 239000000956 alloy Substances 0.000 description 17
- 238000010438 heat treatment Methods 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- 229920000297 Rayon Polymers 0.000 description 6
- 239000002964 rayon Substances 0.000 description 6
- 238000005266 casting Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 2
- 230000005489 elastic deformation Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 241001639412 Verres Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B1/00—Driving mechanisms
- G04B1/10—Driving mechanisms with mainspring
- G04B1/14—Mainsprings; Bridles therefor
- G04B1/145—Composition and manufacture of the springs
Definitions
- the present invention relates to a barrel spring for a mechanism driven by a motor spring, particularly for a timepiece, formed of a metal glass material.
- the mechanical properties of the alloy and the final shape are the result of the combination of these two steps. A single heat treatment would not achieve the desired mechanical properties for traditional alloys.
- the fixing of crystalline metal alloys involves a relatively long treatment time (several hours) at a temperature high enough to induce the desired modification of the crystalline structure.
- the mechanical properties of the material are intrinsically linked to its amorphous structure and are obtained immediately after solidification, unlike the mechanical properties of the traditional Nivaflex ® alloy springs, which are obtained by a series of heat treatments at different stages. of their manufacturing process. Therefore, and unlike the Nivaflex ® alloy, subsequent curing by heat treatment is not necessary.
- the object of the present invention is to overcome, at least in part, the aforementioned drawbacks.
- the present invention relates to a cylinder spring for a mechanism driven by a mainspring according to claim 1.
- the ribbons intended to form the barrel springs are made by the technique of quenching on a wheel (or Planar Flow Casting) which is a technique for producing metal ribbons by rapid cooling.
- a jet of molten metal is propelled on a cold wheel that rotates at high speed.
- the speed of the wheel, the width of the injection slot, the injection pressure are all parameters that will define the width and thickness of the ribbon produced.
- Other techniques for producing ribbons can also be used, such as Twin Roll Casting.
- the alloy used is Ni 53 Nb 20 Zr 8 Ti 10 Co 6 Cu 3 in this example. From 10 to 20 g of alloy are placed in a dispensing nozzle heated between 1050 and 1150 ° C. The slit width of the nozzle is between 0.2 and 0.8mm. The distance between the nozzle and the wheel is between 0.1 and 0.3mm. The wheel on which the molten alloy is deposited is a copper alloy wheel and driven at a speed of 5 to 20m / s. The pressure exerted to bring the molten alloy out through the nozzle is between 10 and 50kPa.
- the barrel spring releases its energy as it moves from the armed state to the disarmed state.
- the goal is to calculate the shape that the spring must have in its free state so that each section is subjected to the maximum bending moment in its armed state.
- the Figures 1 to 3 below describe respectively the three configurations of the barrel spring namely armed, disarmed and free.
- the spring in its armed state (see figure 1 ) is considered an Archimedean spiral with the turns tight against each other.
- the metallic glass ribbon is obtained by rapid solidification of the liquid metal on a copper wheel or alloy with high thermal conductivity rotating at high speed.
- a minimum critical cooling rate is required to vitrify the liquid metal. If the cooling is too slow, the metal solidifies by crystallization and loses its mechanical properties. It is important for a given thickness to guarantee the maximum cooling rate. The higher it is, the less the atoms will have time to relax and the higher the concentration of free volume will be important. The ductility of the ribbon is then improved.
- the plastic deformation of the metal glasses below about 0.7 x the glass transition temperature T g [K], is heterogeneous through the initiation and then the propagation of slip bands. Free volumes act as germination sites for slip bands and the higher their number, the less the deformation is localized and the greater the deformation before rupture is important.
- Planar Flow Casting stage is therefore crucial for the mechanical and thermodynamic properties of the ribbon.
- the viscosity decreases sharply with temperature, about an order of magnitude by 10K elevation.
- the viscosity at T g is generally equal to 10 12 Pa ⁇ s, independently of the alloy considered. It is then possible to model the viscous body, in this case the ribbon, to give it its desired shape, then cool it to freeze the shape permanently.
- thermal activation will allow the diffusion of free volumes and atoms within the material.
- the atoms will locally form denser domains, close to a crystalline structure at the expense of free volumes, which will be annihilated. This phenomenon is called relaxation.
- the decrease in free volume is accompanied by an increase in Young's modulus and a decrease in the subsequent ductility.
- the relaxation phenomenon can be likened to annealing.
- thermal agitation the diffusion of atoms is facilitated: the relaxation is accelerated and causes a drastic embrittlement of the glass by annihilation of the free volume. If the treatment time is too long, the amorphous material will crystallize and thus lose its exceptional properties.
- Hot forming is therefore a balance between sufficient relaxation to retain the desired shape and as little ductility as possible.
- the ribbons produced by the Planar Flow Casting (PFC) technique have a width of several millimeters and a thickness greater than 50 ⁇ m, typically between> 50 and 150 ⁇ m.
- ribbons with the width and length typical of a mainspring are machined by wire electroerosion technique. A sidewall grinding was performed, after which the spring was shaped from the theoretical form as previously calculated.
- the ribbon produced has the desired width.
- the spring in its setting was then introduced into a heated oven around T g (590 ° C) for a period of 3 to 5 minutes, depending on the setting used.
- heating modes such as Joule heating or a hot inert gas jet, for example.
- the figure 4 shows the torque variation as a function of the number of revolutions obtained with the spring calculated and shaped according to the method described in this document.
- This armor-disarming curve is quite characteristic of the behavior of a mainspring.
- the torque, the number of turns of development and the overall yield are fully satisfactory given the dimensions of the ribbon.
Landscapes
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Springs (AREA)
- Electromechanical Clocks (AREA)
Claims (2)
- Zugfeder für durch einen Federmotor angetriebenen Mechanismus, insbesondere für eine Uhr, die aus einem Band aus einem metallischen Glas hergestellt ist, dadurch gekennzeichnet, dass das Band monolithisch sowie von einer Dicke von mehr als 50 µm ist und dass die Dicke der Feder zwischen > 50 µm und 150 µm liegt.
- Zugfeder nach Anspruch 1, bei der die Gestalt im belastungsfreien Zustand durch den Radius im belasteten Zustand der n-ten Wicklung gemäß der folgenden Gleichung bestimmt ist:rn: Radius im belasteten Zustand der n-ten Wicklung [mm]rbonde: Radius des Federkerns [mm]n: Zahl der Aufzugsumdrehunge: Dicke des Bandes [mm],und mit der Länge der kurvilinearen Abszisse der n-ten Wicklung entsprechend der GleichungLn: Länge der kurvilinearen Abszisse der n-ten Wicklung [mm]rn: Radius im belasteten Zustand der n-ten Wicklung [mm]θ: überstrichener Winkel [rad],mit dem Radius im belastungsfreien Zustand der n-ten Wicklung entsprechend der Gleichung:Mmax: größtes Moment [N mm]E: Youngscher Modul [N/mm2]I: Trägheitsmoment [mm4],und mit dem Abschnittswinkel der n-ten Wicklung gemäß der Gleichung:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09405089.5A EP2133756B1 (de) | 2008-06-10 | 2009-05-27 | Zugfeder für Federhaus |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08405153 | 2008-06-10 | ||
EP08405192A EP2154581A1 (de) | 2008-08-04 | 2008-08-04 | Schließzylinderfeder und Verfahren zur ihrer Formgebung |
EP09405089.5A EP2133756B1 (de) | 2008-06-10 | 2009-05-27 | Zugfeder für Federhaus |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2133756A2 EP2133756A2 (de) | 2009-12-16 |
EP2133756A3 EP2133756A3 (de) | 2011-04-13 |
EP2133756B1 true EP2133756B1 (de) | 2016-07-20 |
Family
ID=41110579
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09405089.5A Revoked EP2133756B1 (de) | 2008-06-10 | 2009-05-27 | Zugfeder für Federhaus |
EP09771888.6A Active EP2286308B1 (de) | 2008-06-10 | 2009-06-09 | Feder von amorphem metall für federhaus und verfahren zur ihrer formgebung |
EP22170104.8A Withdrawn EP4092489A1 (de) | 2008-06-10 | 2009-06-09 | Verfahren zum umformen einer triebfeder aus metallischen glas |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09771888.6A Active EP2286308B1 (de) | 2008-06-10 | 2009-06-09 | Feder von amorphem metall für federhaus und verfahren zur ihrer formgebung |
EP22170104.8A Withdrawn EP4092489A1 (de) | 2008-06-10 | 2009-06-09 | Verfahren zum umformen einer triebfeder aus metallischen glas |
Country Status (6)
Country | Link |
---|---|
US (2) | US8348496B2 (de) |
EP (3) | EP2133756B1 (de) |
JP (2) | JP5656369B2 (de) |
CN (2) | CN101604141B (de) |
CH (1) | CH698962B1 (de) |
WO (1) | WO2010000081A1 (de) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH698962B1 (fr) * | 2008-06-10 | 2014-10-31 | Rolex Sa | Ressort de barillet et procédé pour sa mise en forme. |
EP2510405B1 (de) * | 2009-12-09 | 2016-03-30 | Rolex S.A. | Verfahren zur formung einer feder für eine uhr |
US20110156328A1 (en) * | 2009-12-31 | 2011-06-30 | Nicolio Curtis J | Integral retainer to retain a spring |
GB201001897D0 (en) * | 2010-02-05 | 2010-03-24 | Levingston Gideon | Non magnetic mateial additives and processes for controling the thermoelastic modulus and spring stiffness within springs for precision instruments |
EP2390732A1 (de) | 2010-05-27 | 2011-11-30 | Association Suisse pour la Recherche Horlogère | Zugfeder für Federhaus |
WO2011161139A1 (fr) * | 2010-06-22 | 2011-12-29 | The Swatch Group Research And Development Ltd | Systeme antichoc de piece d'horlogerie |
CN102339008A (zh) * | 2010-07-15 | 2012-02-01 | 慈溪市九菱电器有限公司 | 一种定时器s形发条 |
CN103052727B (zh) | 2010-07-21 | 2016-01-20 | 劳力士有限公司 | 包含非晶态金属合金的制表或制钟的部件 |
JP6346440B2 (ja) | 2010-07-21 | 2018-06-20 | ロレックス・ソシエテ・アノニムRolex Sa | アモルファス金属合金 |
US9298162B2 (en) * | 2010-10-01 | 2016-03-29 | Rolex Sa | Timepiece barrel with thin disks |
CH704236B1 (fr) | 2010-12-17 | 2015-09-30 | Manuf Et Fabrique De Montres Et Chronomètres Ulysse Nardin Le Locle Sa | Procédé de réalisation d'un timbre de sonnerie. |
DE102011001783B4 (de) | 2011-04-04 | 2022-11-24 | Vacuumschmelze Gmbh & Co. Kg | Feder für ein mechanisches Uhrwerk, mechanisches Uhrwerk, Uhr mit einem mechanischen Uhrwerk und Verfahren zur Herstellung einer Feder |
DE102011001784B4 (de) | 2011-04-04 | 2018-03-22 | Vacuumschmelze Gmbh & Co. Kg | Verfahren zur Herstellung einer Feder für ein mechanisches Uhrwerk und Feder für ein mechanisches Uhrwerk |
EP2590325A1 (de) * | 2011-11-04 | 2013-05-08 | The Swatch Group Research and Development Ltd. | Thermokompensierter Resonator aus Keramik |
WO2013138710A1 (en) * | 2012-03-16 | 2013-09-19 | Yale University | Multi step processing method for the fabrication of complex articles made of metallic glasses |
CN108196438B (zh) | 2012-04-04 | 2020-09-08 | 劳力士有限公司 | 轴、发条及包括轴和发条的发条盒、钟表机芯、腕表和表 |
EP2703911B1 (de) * | 2012-09-03 | 2018-04-11 | Blancpain SA. | Regulierorgan für kleinuhr |
EP2706415A3 (de) * | 2012-09-05 | 2017-06-14 | Seiko Epson Corporation | Verfahren zur Herstellung einer Uhrfeder, Vorrichtung zur Herstellung einer Uhrfeder, Uhrfeder und Uhr |
CH708231B1 (fr) * | 2013-06-27 | 2017-03-15 | Nivarox Far Sa | Ressort d'horlogerie en acier inoxydable austénitique. |
CH708660A1 (fr) * | 2013-10-04 | 2015-04-15 | Cartier Création Studio Sa | Ressort moteur pour barillet moteur minimisant l'usure du tambour. |
EP2924514B1 (de) | 2014-03-24 | 2017-09-13 | Nivarox-FAR S.A. | Uhrfeder aus austenitischem Edelstahl |
US10315241B2 (en) * | 2014-07-01 | 2019-06-11 | United Technologies Corporation | Cast components and manufacture and use methods |
DE102015002430A1 (de) | 2015-02-26 | 2016-09-01 | Gernot Hausch | CoNiCrMo-Legierung für Aufzugsfedern in einem mechanischen Uhrwerk |
US10317842B2 (en) | 2016-04-25 | 2019-06-11 | Seiko Epson Corporation | Timepiece mainspring, timepiece drive device, timepiece movement, timepiece, and manufacturing method of timepiece mainspring |
JP7133909B2 (ja) * | 2016-07-04 | 2022-09-09 | ロレックス・ソシエテ・アノニム | 時計用組立体の製造方法、及び該製造方法により得られる時計用組立体 |
EP3273305B1 (de) * | 2016-07-19 | 2023-07-19 | Nivarox-FAR S.A. | Bauteil für uhrwerk |
EP3557333B1 (de) | 2018-04-16 | 2020-11-04 | Patek Philippe SA Genève | Herstellungsverfahren einer zugfeder für eine uhr |
EP3575885B1 (de) * | 2018-06-01 | 2022-09-21 | Nivarox-FAR S.A. | Federhaus für uhren |
EP3882710A1 (de) | 2020-03-19 | 2021-09-22 | Patek Philippe SA Genève | Verfahren zur herstellung einer uhrenkomponente auf siliziumbasis |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0942337A1 (de) | 1997-08-28 | 1999-09-15 | Seiko Epson Corporation | Feder, zugfeder, spiralfeder, diese verwendenden antriebsmechanismus und uhr |
US20070133355A1 (en) | 2003-11-07 | 2007-06-14 | Seik Epson Corporation | Timepiece and spring thereof |
EP2154581A1 (de) | 2008-08-04 | 2010-02-17 | Rolex Sa | Schließzylinderfeder und Verfahren zur ihrer Formgebung |
WO2012010941A1 (fr) | 2010-07-21 | 2012-01-26 | Rolex S.A. | Composant horloger comprenant un alliage métallique amorphe |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH375685A (fr) | 1961-02-14 | 1963-10-15 | Tuetey Paul | Procédé de fabrication de spiraux d'horlogerie |
US3343573A (en) * | 1965-04-14 | 1967-09-26 | James Hill Mfg Company | Roving can spring |
GB1162296A (en) * | 1966-04-30 | 1969-08-20 | Citizen Watch Co Ltd | Improvements in and relating to Barrel Springs for Timepieces |
FR1533876A (fr) | 1967-08-09 | 1968-07-19 | Dispositif pour la fabrication des spiraux d'horlogerie et procédé pour la mise enaction de ce dispositif | |
CH506109A (fr) | 1968-02-08 | 1970-12-15 | Fabriques De Spiraux Reunies S | Procédé de fabrication et de fixation d'un spiral, dispositif de mise en oeuvre et spiral obtenu par l'application de ce procédé |
US4288901A (en) * | 1977-04-22 | 1981-09-15 | Babcock Clarence O | Method of manufacturing and calibrating a displacement measuring sensor |
DE3136303A1 (de) * | 1981-09-12 | 1983-04-14 | Vacuumschmelze Gmbh, 6450 Hanau | Vorrichtung fuer die herstellung von metallband aus einer schmelze |
DE3442009A1 (de) * | 1983-11-18 | 1985-06-05 | Nippon Steel Corp., Tokio/Tokyo | Amorphes legiertes band mit grosser dicke und verfahren zu dessen herstellung |
JPH082465B2 (ja) * | 1987-06-05 | 1996-01-17 | 中央発條株式会社 | S字型ぜんまいばねの成形方法 |
JPH02207935A (ja) * | 1989-02-08 | 1990-08-17 | Nishiki Sangyo Kk | コイルおよびその製造方法 |
FR2718380B3 (fr) * | 1994-04-12 | 1996-05-24 | Norton Sa | Meules abrasives. |
JP3863208B2 (ja) * | 1995-09-13 | 2006-12-27 | 中央発條株式会社 | ぜんまいばねの処理方法及びぜんまいばね |
US5772803A (en) | 1996-08-26 | 1998-06-30 | Amorphous Technologies International | Torsionally reacting spring made of a bulk-solidifying amorphous metallic alloy |
JPH10263739A (ja) * | 1997-03-27 | 1998-10-06 | Olympus Optical Co Ltd | 金属ガラスの成形方法および装置 |
JP3011904B2 (ja) * | 1997-06-10 | 2000-02-21 | 明久 井上 | 金属ガラスの製造方法および装置 |
EP0895823B1 (de) * | 1997-08-08 | 2002-10-16 | Sumitomo Rubber Industries, Ltd. | Verfahren zur Herstellung eines geformten Produktes aus amorphem Metall |
US6863435B2 (en) * | 1997-08-11 | 2005-03-08 | Seiko Epson Corporation | Spring, mainspring, hairspring, and driving mechanism and timepiece based thereon |
DE69939617D1 (de) * | 1998-01-22 | 2008-11-06 | Seiko Epson Corp | Elektronisches Uhrwerk mit einem Generator |
US20040267349A1 (en) * | 2003-06-27 | 2004-12-30 | Kobi Richter | Amorphous metal alloy medical devices |
CA2414099C (en) * | 2000-07-06 | 2009-12-29 | Trico Products Corporation | Method and apparatus for flexible manufacturing a discrete curved product from feed stock |
US6462575B1 (en) * | 2000-08-28 | 2002-10-08 | Micron Technology, Inc. | Method and system for wafer level testing and burning-in semiconductor components |
JP4317930B2 (ja) * | 2000-09-07 | 2009-08-19 | 明久 井上 | アモルファス合金粒子 |
JP4304897B2 (ja) | 2000-12-20 | 2009-07-29 | 株式会社豊田中央研究所 | 高弾性変形能を有するチタン合金およびその製造方法 |
DE60222651T2 (de) | 2001-04-13 | 2008-07-17 | Mitsui Chemicals, Inc. | Magnetkern und klebharzzusammensetzung für magnetkernbenutzung |
JP3596548B2 (ja) * | 2002-03-27 | 2004-12-02 | セイコーエプソン株式会社 | 電子時計および電子機器 |
JP2005062161A (ja) * | 2003-07-25 | 2005-03-10 | Seiko Epson Corp | アンテナ内蔵式電子時計 |
JP4320278B2 (ja) * | 2004-05-26 | 2009-08-26 | 国立大学法人東北大学 | Ti系金属ガラス |
US7082684B2 (en) * | 2004-08-04 | 2006-08-01 | Palo Alto Research Center Incorporated | Intermetallic spring structure |
US20090194205A1 (en) | 2005-10-03 | 2009-08-06 | Loffler Jorg F | Bulk Metallic Glass/Graphite Composites |
CH698962B1 (fr) * | 2008-06-10 | 2014-10-31 | Rolex Sa | Ressort de barillet et procédé pour sa mise en forme. |
EP2510405B1 (de) | 2009-12-09 | 2016-03-30 | Rolex S.A. | Verfahren zur formung einer feder für eine uhr |
-
2009
- 2009-05-26 CH CH00809/09A patent/CH698962B1/fr unknown
- 2009-05-27 EP EP09405089.5A patent/EP2133756B1/de not_active Revoked
- 2009-06-08 US US12/479,947 patent/US8348496B2/en active Active
- 2009-06-08 JP JP2009136880A patent/JP5656369B2/ja active Active
- 2009-06-09 WO PCT/CH2009/000191 patent/WO2010000081A1/fr active Application Filing
- 2009-06-09 EP EP09771888.6A patent/EP2286308B1/de active Active
- 2009-06-09 CN CN2009101595422A patent/CN101604141B/zh active Active
- 2009-06-09 CN CN2009801217412A patent/CN102057336B/zh active Active
- 2009-06-09 EP EP22170104.8A patent/EP4092489A1/de not_active Withdrawn
- 2009-06-09 US US12/996,542 patent/US8720246B2/en active Active
- 2009-06-09 JP JP2011512804A patent/JP5518852B2/ja active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0942337A1 (de) | 1997-08-28 | 1999-09-15 | Seiko Epson Corporation | Feder, zugfeder, spiralfeder, diese verwendenden antriebsmechanismus und uhr |
US20070133355A1 (en) | 2003-11-07 | 2007-06-14 | Seik Epson Corporation | Timepiece and spring thereof |
EP2154581A1 (de) | 2008-08-04 | 2010-02-17 | Rolex Sa | Schließzylinderfeder und Verfahren zur ihrer Formgebung |
WO2012010941A1 (fr) | 2010-07-21 | 2012-01-26 | Rolex S.A. | Composant horloger comprenant un alliage métallique amorphe |
Non-Patent Citations (7)
Title |
---|
"Dictionnaire professionnel ilustré de l'horlogerie", 1961, FÉDÉRATION DE L'INDUSTRIE HORLOGÈRE SUISSE FH, article "Ressort-moteur", XP055374931 |
A. MAIRE: "Etude énergétique de l'organe moteur d'une montre", ANNALES FRANÇAISES DE CHRONOMÉTRIE, vol. 1, 1957, pages 23 - 46, XP055374924 |
F.G. YOST: "On the use of Ti50Be40Zr10 as a spring material", JOURNAL OF MATERIALS SCIENCE, vol. 16, no. 11, November 1981 (1981-11-01), pages 3039 - 3044, XP055374882 |
R.E. NAPOLITANO ET AL.: "The role of melt pool behavior in free-jet melt spinning", METALLURGICAL AND MATERIALS TRANSACTIONS A, vol. 35, no. 5, May 2004 (2004-05-01), pages 1539 - 1553, XP019694832 |
S. ISHIHARA ET AL.: "Production of Glassy Coil Springs by Warm Coiling of Zr-based Glassy Alloy Wires", MATERIAL TRANSACTIONS, vol. 45, no. 8, 2004, pages 2788 - 2790, XP055374896 |
T. ZHANG ET AL.: "Thermal and Mechanical Properties of Ti-Ni-Cu-Sn Amorphous Alloys with a Wide suppercooled Liquid Region before Crytallization", MATERIALS TRANSACTIONS, JIM, vol. 39, no. 10, 1998, pages 1001 - 1006, XP055374892 |
X.H. LIN ET AL.: "Formation of Ti-Zr-Cu-Ni bulk metallic glasses", J. APPL. PHYS., vol. 78, no. 11, December 1995 (1995-12-01), pages 6514 - 6519, XP055374887 |
Also Published As
Publication number | Publication date |
---|---|
CN101604141B (zh) | 2012-06-27 |
CN102057336B (zh) | 2013-07-03 |
JP2009300439A (ja) | 2009-12-24 |
EP2133756A2 (de) | 2009-12-16 |
WO2010000081A1 (fr) | 2010-01-07 |
CN101604141A (zh) | 2009-12-16 |
EP4092489A1 (de) | 2022-11-23 |
EP2286308B1 (de) | 2022-05-04 |
JP2011523066A (ja) | 2011-08-04 |
US20110072873A1 (en) | 2011-03-31 |
CH698962A2 (fr) | 2009-12-15 |
JP5518852B2 (ja) | 2014-06-11 |
EP2286308A1 (de) | 2011-02-23 |
CH698962B1 (fr) | 2014-10-31 |
CN102057336A (zh) | 2011-05-11 |
EP2133756A3 (de) | 2011-04-13 |
US8348496B2 (en) | 2013-01-08 |
JP5656369B2 (ja) | 2015-01-21 |
US20090303842A1 (en) | 2009-12-10 |
US8720246B2 (en) | 2014-05-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2133756B1 (de) | Zugfeder für Federhaus | |
EP2510405B1 (de) | Verfahren zur formung einer feder für eine uhr | |
EP2596140B1 (de) | Uhrmacher- oder uhrenindustrie-komponente mit einer amorphen metalllegierung | |
EP2264553B1 (de) | Thermokompensierte Feder und ihr Herstellungsverfahren | |
EP0886195B1 (de) | Selbstkompensierende Spiralfeder für mechanische Uhrwerkunruhspiralfederoszillator und Verfahren zu deren Herstellung | |
FR2920890A1 (fr) | Ressort-moteur pour barillet de mouvement d'horlogerie presentant une duree de marche accrue | |
EP2400353A1 (de) | Uhrenzeiger | |
EP2154581A1 (de) | Schließzylinderfeder und Verfahren zur ihrer Formgebung | |
US9823624B2 (en) | Method for producing timepiece spring, device for producing timepiece spring, timepiece spring, and timepiece | |
WO2011161181A1 (fr) | Assemblage de pieces en materiau fragile | |
EP3267899B1 (de) | Verbesserungen an hyperelastischen nadeln | |
JP6024306B2 (ja) | 時計用バネの製造方法、時計用バネ、及び時計 | |
Jeong et al. | Micro-forming of thin film metallic glass by local laser heating | |
CH705173A2 (fr) | Composant horloger comprenant un alliage métallique amorphe. | |
EP2264552A1 (de) | Thermokompensierte Feder und ihr Herstellungsverfahren | |
CH701333A2 (fr) | Ressort thermocompensé et son procédé de fabrication. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA RS |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: G04B 1/14 20060101AFI20090930BHEP Ipc: G04D 3/00 20060101ALI20110304BHEP |
|
17P | Request for examination filed |
Effective date: 20111011 |
|
17Q | First examination report despatched |
Effective date: 20140826 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20160202 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: MOINAS AND SAVOYE SA, CH Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 814562 Country of ref document: AT Kind code of ref document: T Effective date: 20160815 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602009039809 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20160720 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 814562 Country of ref document: AT Kind code of ref document: T Effective date: 20160720 Ref country code: CH Ref legal event code: PFA Owner name: ROLEX SA, CH Free format text: FORMER OWNER: ROLEX SA, CH |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161120 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161020 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161021 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161121 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R026 Ref document number: 602009039809 Country of ref document: DE |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 |
|
26 | Opposition filed |
Opponent name: ICB INGENIEURS CONSEILS EN BREVETS SA Effective date: 20170419 |
|
PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161020 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170531 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 |
|
PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
PLAY | Examination report in opposition despatched + time limit |
Free format text: ORIGINAL CODE: EPIDOSNORE2 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170527 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20170531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170527 |
|
PLBC | Reply to examination report in opposition received |
Free format text: ORIGINAL CODE: EPIDOSNORE3 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20090527 |
|
RDAF | Communication despatched that patent is revoked |
Free format text: ORIGINAL CODE: EPIDOSNREV1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160720 |
|
APBM | Appeal reference recorded |
Free format text: ORIGINAL CODE: EPIDOSNREFNO |
|
APBP | Date of receipt of notice of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA2O |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 |
|
APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
APBQ | Date of receipt of statement of grounds of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA3O |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160720 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230528 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230523 Year of fee payment: 15 Ref country code: DE Payment date: 20230510 Year of fee payment: 15 Ref country code: CH Payment date: 20230602 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20230519 Year of fee payment: 15 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R103 Ref document number: 602009039809 Country of ref document: DE Ref country code: DE Ref legal event code: R064 Ref document number: 602009039809 Country of ref document: DE |
|
APBU | Appeal procedure closed |
Free format text: ORIGINAL CODE: EPIDOSNNOA9O |
|
RDAG | Patent revoked |
Free format text: ORIGINAL CODE: 0009271 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT REVOKED |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
27W | Patent revoked |
Effective date: 20231123 |
|
GBPR | Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state |
Effective date: 20231123 |