EP2158076A1 - Trennprodukt - Google Patents
TrennproduktInfo
- Publication number
- EP2158076A1 EP2158076A1 EP07788748A EP07788748A EP2158076A1 EP 2158076 A1 EP2158076 A1 EP 2158076A1 EP 07788748 A EP07788748 A EP 07788748A EP 07788748 A EP07788748 A EP 07788748A EP 2158076 A1 EP2158076 A1 EP 2158076A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- basic substrate
- release product
- release
- coating
- coating layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000011247 coating layer Substances 0.000 claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 20
- 239000010410 layer Substances 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 10
- 229920002472 Starch Polymers 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229920005615 natural polymer Polymers 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000000123 paper Substances 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000008199 coating composition Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000010954 inorganic particle Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 239000004447 silicone coating Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 239000011086 glassine Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- -1 curtain coating Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/001—Release paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
Definitions
- the present invention relates to a release product comprising a basic substrate and a siliconized release layer.
- the basic substrate has a first side and a second side.
- the siliconized release layer has been applied on the first side of the basic substrate.
- a release product usually comprises a paper provided with a silicone coating.
- plastic material can also be used instead of paper.
- the release product is used as a backing paper for self-adhesive labels which are either paper, or plastic material.
- the release product and the face material attached to the release product form a self-adhesive laminate web.
- a problem related to this product is that the silicone coating tend to migrate through the basic substrate.
- the face material of the laminate web may be contaminated with silicone. This causes problems e.g. in printing, or with metallised layers. In order to avoid such problems, the release product of the invention has been developed.
- the release product is characterized in that the release product comprises a coating layer which has been applied directly on either the first side of the release product, or on the second side of the release product, the coating layer comprising silica particles and a binder.
- the coating layer absorbs the problematic silicone before it causes harmful effects. Thus, printing problems are avoided.
- the coating layer comprises inorganic particles and a binder.
- the inorganic particles contain silica (SiO 2 ) particles.
- the silica particles may be a silica gel, a colloidal silica, a precipitated silica, or a fumed silica.
- the silica gel is a highly absorbent form of silicon dioxide. Instead, or in addition to silica particles it is possible to use aluminium hydroxide particles (AI(OH) 3 ).
- the preferred silica particles are porous amorphous silicic anhydride particles, i.e. silica gel.
- the particles may have an average particle size from 0.3 to 20 ⁇ m, preferably from 0.3 to 10 ⁇ m, more preferably the average particle size is from 0.3 to 8 ⁇ m.
- the surface area may be at least 200 m 2 /g, preferably at least 300 m 2 /g, and the bulk density at least 0.15 g/cm 3 , preferably at least 0.30 g/cm 3 .
- a product having an average particle size of 4 ⁇ m, a surface area of 340 m 2 /g and a bulk density of 1.77 g/cm 3 was well suitable for this purpose.
- the binder forms a medium to the silica particles.
- the binder preferably comprises natural polymers or their derivatives, such as starch, carboxymethyl cellulose (CMC), or mixtures of those. Starch is rather cheap material to be used whereas CMC makes the runnability of the coating line better.
- the coating composition may comprise other inorganic particles, such as kaolin or talc, to add impermeability to the coating layer.
- the coating composition may also comprise a medium which brings impermeability to the coating layer for its part.
- a medium may be e.g. polyvinyl alcohol, or styrene/butadiene copolymer.
- the coating composition may comprise a cross-linking agent whose amount is relative to the total amount of the binder comprising the natural polymers and their derivatives.
- the purpose of the cross- linking agent in the coating composition is to prevent dusting and sticking to calender rolls.
- the coating layer is applied directly on the basic substrate, i.e. there is not e.g. plastic layers between the basic substrate, i.e. the base paper or another suitable base material, and the coating layer. However, there may be surface sizing layers, or other coated layers between the basic substrate and the coating layer.
- the coating layer is usually a one layer coating, but a multilayer coating is also possible.
- the base paper may be a glassine paper, or a calendered paper.
- a silicone layer is applied on the first side of the paper and cured.
- the coating layer is applied to the second side of the release paper by methods which are known as such, for example blade coating, airbrush coating, curtain coating, or coating in a film or size press.
- the coating may also be applied on the first side of the release paper under the silicone coating, i.e. between the silicone layer and the basic substrate. Preferably, however, the coating is applied on the second side of the release paper.
- the grammage of the coating layer may be from 0.7 to 1.4 g/m 2 .
- the typical composition of the coating composition comprises at least silica particles and a binder comprising starch or its derivatives, cmc, or their mixtures. There is usually also a cross-linking agent in order to prevent dusting and sticking to calender rolls.
- the coating composition may also comprise inorganic particles different from the silica particles, such as kaolin. Table 1. Coating compositions.
- the base paper was a glassine paper having a grammage of 64 g/m 2 .
- the grammage of the coating layer was 1.1 g/m 2 .
- the used silica particles had an average particle size of about 4 ⁇ m, a surface area of about 340 m 2 /g, and a bulk density of about 1.77 g/cm 3 .
- the coating compositions were applied on the second side of the release paper. All the coating layers showed desired properties, i.e. the coating layers were efficient to absorb contaminants.
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
- Adhesive Tapes (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/FI2007/050363 WO2008152182A1 (en) | 2007-06-15 | 2007-06-15 | A release product |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2158076A1 true EP2158076A1 (de) | 2010-03-03 |
EP2158076A4 EP2158076A4 (de) | 2011-06-01 |
EP2158076B1 EP2158076B1 (de) | 2013-03-06 |
Family
ID=40129284
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07788748A Active EP2158076B1 (de) | 2007-06-15 | 2007-06-15 | Trennprodukt |
Country Status (5)
Country | Link |
---|---|
US (1) | US10428462B2 (de) |
EP (1) | EP2158076B1 (de) |
CN (1) | CN101720278B (de) |
BR (1) | BRPI0721814B1 (de) |
WO (1) | WO2008152182A1 (de) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011117831A1 (de) | 2011-02-15 | 2012-08-16 | Huhtamaki Forchheim Zweigniederlassung Der Huhtamaki Deutschland Gmbh & Co. Kg | Trennfolie mit rauher Oberflächenstruktur |
DE102011089565A1 (de) * | 2011-12-22 | 2013-06-27 | Tesa Se | Liner zum Schutz von Klebemassen |
DE102011089566A1 (de) | 2011-12-22 | 2013-06-27 | Tesa Se | Liner zum Schutz von Klebemassen |
DE102014200948A1 (de) * | 2014-01-20 | 2015-07-23 | Tesa Se | Verfahren zum Entfernen von Permeaten aus Flächengebilden |
CN105109156A (zh) * | 2015-08-17 | 2015-12-02 | 浙江欧仁新材料有限公司 | 一种可根据需要调节离型力的离型膜及其制作方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0276048A1 (de) * | 1987-01-06 | 1988-07-27 | The Wiggins Teape Group Limited | Trennpapier |
EP0605840A2 (de) * | 1992-12-25 | 1994-07-13 | Mitsubishi Paper Mills, Ltd. | Tintenstrahl-Aufzeichnungsblatt |
EP1249533A1 (de) * | 2001-04-14 | 2002-10-16 | The Dow Chemical Company | Verfahren zur Herstellung von mehrschichtig beschichtetem Papier oder Pappe |
US20040062913A1 (en) * | 2002-09-27 | 2004-04-01 | Dai Nippon Print. Co., Ltd. | Composition for matte layer formation, release sheet using the same, and synthetic leather produced using said release sheet |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1072664A (en) * | 1913-09-09 | A R Silverston | Airship. | |
US4074000A (en) * | 1976-10-27 | 1978-02-14 | Xerox Corporation | Pressure sensitive adhesive drafting films for use in electrostatographic copiers |
JPS5769091A (en) * | 1980-10-17 | 1982-04-27 | Ricoh Co Ltd | Peel-off type heatsensitive recording paper |
US4622566A (en) * | 1984-04-26 | 1986-11-11 | Sanyo-Kokusaku Pulp Co., Ltd. | Heat-sensitive recording material |
US4577204A (en) * | 1984-05-25 | 1986-03-18 | Ricoh Electronics, Inc. | Thermosensitive recording label |
JP2995637B2 (ja) | 1990-12-28 | 1999-12-27 | 王子製紙株式会社 | 粘着シート |
JPH07290818A (ja) * | 1994-03-04 | 1995-11-07 | Mitsubishi Paper Mills Ltd | インクジェット記録用タックシート |
US6632488B2 (en) * | 1998-02-26 | 2003-10-14 | Oji Paper Co., Ltd | Ink jet recording material |
JP4480814B2 (ja) * | 1999-07-29 | 2010-06-16 | 日東電工株式会社 | 接着シート類 |
EP1088789A3 (de) * | 1999-09-28 | 2002-03-27 | Heraeus Quarzglas GmbH & Co. KG | Poröse Granulate aus Siliciumdioxid, deren Herstellungsverfahren und deren Verwendung bei einem Verfahren zur Herstellung von Quarzglas |
US6545543B2 (en) * | 2001-07-06 | 2003-04-08 | Remec, Inc. | Small aspect ratio MMIC power amplifier layout |
US6846538B2 (en) | 2001-12-27 | 2005-01-25 | Ricoh Company, Ltd. | Composite sheet, method of preparing same, and adhesive label sheet assembly having same |
FI20020521A0 (fi) | 2002-03-19 | 2002-03-19 | Raisio Chem Oy | Paperin pintakäsittelykoostumus ja sen käyttö |
CN1330559C (zh) * | 2002-06-12 | 2007-08-08 | 日本板硝子株式会社 | 薄片形式的多孔金属氧化物材料、其生产方法和包含它的化妆品、涂布材料、树脂组合物、油墨组合物和纸张 |
JP4234473B2 (ja) | 2003-03-26 | 2009-03-04 | シャープ株式会社 | 液晶パネルおよびその製造方法 |
FI20030976A (fi) * | 2003-06-30 | 2004-12-31 | M Real Oyj | Päällystetty pohjapaperi ja menetelmä päällystetyn pohjapaperin valmistamiseksi |
US8582125B2 (en) * | 2003-07-22 | 2013-11-12 | Hewlett-Packard Development Company, L.P. | Variable support structure and media sheet separator |
EP1721662A4 (de) * | 2004-02-05 | 2012-11-07 | Taiyo Kagaku Kk | Adsorptionsvermögen verleihendes mittel, enthaltend poröses siliciumdioxid |
JP4655533B2 (ja) * | 2004-08-02 | 2011-03-23 | ソニー株式会社 | 画像処理装置および方法、記録媒体、並びにプログラム |
JP2006116797A (ja) * | 2004-10-21 | 2006-05-11 | Mitsubishi Paper Mills Ltd | 水性顔料インク用インクジェット記録材料 |
JP4954519B2 (ja) * | 2004-11-12 | 2012-06-20 | 富士フイルム株式会社 | インクジェット記録用媒体、及びインクジェット記録用媒体の製造方法 |
US20100189993A1 (en) * | 2005-06-24 | 2010-07-29 | Nippon Kasei Chemical Company Limited | Coating composition, method for making the same, resin forming product, and method for making the resin forming product |
-
2007
- 2007-06-15 EP EP07788748A patent/EP2158076B1/de active Active
- 2007-06-15 US US12/664,693 patent/US10428462B2/en active Active
- 2007-06-15 CN CN200780053355.5A patent/CN101720278B/zh active Active
- 2007-06-15 WO PCT/FI2007/050363 patent/WO2008152182A1/en active Application Filing
- 2007-06-15 BR BRPI0721814-1A patent/BRPI0721814B1/pt active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0276048A1 (de) * | 1987-01-06 | 1988-07-27 | The Wiggins Teape Group Limited | Trennpapier |
EP0605840A2 (de) * | 1992-12-25 | 1994-07-13 | Mitsubishi Paper Mills, Ltd. | Tintenstrahl-Aufzeichnungsblatt |
EP1249533A1 (de) * | 2001-04-14 | 2002-10-16 | The Dow Chemical Company | Verfahren zur Herstellung von mehrschichtig beschichtetem Papier oder Pappe |
US20040062913A1 (en) * | 2002-09-27 | 2004-04-01 | Dai Nippon Print. Co., Ltd. | Composition for matte layer formation, release sheet using the same, and synthetic leather produced using said release sheet |
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Week 199240 Thomson Scientific, London, GB; AN 1992-327522 XP002615033, & JP 4 234473 A (KANZAKI PAPER MFG CO LTD) 24 August 1992 (1992-08-24) * |
See also references of WO2008152182A1 * |
Also Published As
Publication number | Publication date |
---|---|
BRPI0721814B1 (pt) | 2017-12-26 |
EP2158076B1 (de) | 2013-03-06 |
US10428462B2 (en) | 2019-10-01 |
US20100261006A1 (en) | 2010-10-14 |
EP2158076A4 (de) | 2011-06-01 |
CN101720278B (zh) | 2015-11-25 |
WO2008152182A1 (en) | 2008-12-18 |
CN101720278A (zh) | 2010-06-02 |
BRPI0721814A2 (pt) | 2013-02-13 |
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