EP2137359B2 - Fassadendämmplatte für die dämmung von aussenfassaden von gebäuden, wärmedämm-verbundsystem mit derartigen fassadendämmplatten sowie verfahren zur herstellung einer fassadendämmplatte - Google Patents

Fassadendämmplatte für die dämmung von aussenfassaden von gebäuden, wärmedämm-verbundsystem mit derartigen fassadendämmplatten sowie verfahren zur herstellung einer fassadendämmplatte Download PDF

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Publication number
EP2137359B2
EP2137359B2 EP08749004.1A EP08749004A EP2137359B2 EP 2137359 B2 EP2137359 B2 EP 2137359B2 EP 08749004 A EP08749004 A EP 08749004A EP 2137359 B2 EP2137359 B2 EP 2137359B2
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EP
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Prior art keywords
layer
facade
thermal insulation
top layer
mineral wool
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German (de)
English (en)
French (fr)
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EP2137359A1 (de
EP2137359B1 (de
Inventor
Carsten Wigge
Lothar Bihy
Helmut Hornung
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Saint Gobain Isover SA France
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Saint Gobain Isover SA France
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/762—Exterior insulation of exterior walls
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/762—Exterior insulation of exterior walls
    • E04B1/7629—Details of the mechanical connection of the insulation to the wall
    • E04B1/7633—Dowels with enlarged insulation retaining head
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78—Heat insulating elements
    • E04B1/80—Heat insulating elements slab-shaped
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
    • E04F13/04—Bases for plaster
    • E04F13/045—Means for fastening plaster-bases to a supporting structure

Definitions

  • the invention relates to a composite thermal insulation system according to the preamble of claim 1 and to the use of a facade insulation panel according to claim 15.
  • facade insulation panels are mostly used in thermal insulation composite systems in which they form an insulating layer arranged side by side on a facade.
  • the facade insulation panels are typically glued to the building facade and fixed by means of plate dowel. These penetrate the façade insulation panels and, with their large dowel plates, secure the position of the facade insulation panels on the façade.
  • an external plaster is attached to a thermal insulation composite system, which usually has a flush with an embedded reinforcing layer and a finishing coat as the outer edge.
  • the facade insulation panels in such a thermal insulation composite system are exposed to loads due to their own weight, by hygrothermal effects and in particular by wind suction.
  • the interaction of the adhesive mortar with the plate anchors causes the power dissipation and thus the stability of the thermal insulation composite system.
  • the greatest mechanical load of the thermal insulation composite system is generally due to the wind suction forces. These lead perpendicular to the ground on the cross section of the thermal insulation composite system acting tensile forces in this and thus also in the facade insulation panels that are absorbed by the dowels and discharged into the ground.
  • the adhesive mortar remains out of consideration here in the stability tests. In tear tests for experimental determination of the required number of anchors no adhesive mortar is used.
  • facade insulation elements or thermal insulation composite systems go by way of example from the EP 1 088 945 A2 , the EP 1 408 168 A1 and the DE 103 36 795 A1 out.
  • the facade insulation panels used for this purpose are formed as a homogeneous, single-layered mineral wool body, in particular rock wool is used.
  • a two-layer facade insulation board with a compacted covering layer on the plaster side and an insulating layer with a lower density on the facade side is conventionally used for an insulation system according to WLG 035.
  • Such multi-layer insulation boards can be, for example, from one according to DE 37 01 592 A1 or.
  • This has a compressed cover layer, which consists of the same material as the lower layer and also has a laminar fiber orientation.
  • a prefabricated facade insulation board can be due to the hard outer layer good power transfer from the anchor plate to the adjacent areas and thus achieve an advantageous fixation of the insulation board on the facade.
  • the product "Sillatherm” is also known, which also uses a two-layer facade insulation board to achieve the thruleitrios 035.
  • This insulation board has a lower layer of laminar mineral wool, which especially due to their fiber orientation unfolds a good insulation effect.
  • a cover layer with mineral wool in three-dimensional isotropic orientation of the fibers is arranged, which has significantly better strength properties than the lower layer with slightly poorer insulating properties.
  • Such a mineral wool layer with three-dimensional isotropic fiber orientation can be, for example, by the method according to the DE 103 59 902 A1 achieve.
  • a primary non-woven with a laminar fiber structure so largely parallel to the large surfaces aligned fibers, digested, ie isolated with the formation of mineral wool flakes, which can be done for example by means of combing rollers or carding machines. Subsequently, the respectively obtained mineral wool flakes or individual fibers are re-combined to form a secondary nonwoven, whereby this results in a quasi-isotropic fiber orientation in all three dimensions directions.
  • the document DE 102 41 231 A1 discloses a thermal insulation composite system with the features of the preamble of claim 1.
  • a basket-shaped insert is used as a force-distributing element.
  • the invention is therefore based on the object, a thermal insulation composite system with an insulating layer of Fassadendämmplatten for the insulation of external facades of buildings in such a way that such Fassadendämmplatte with recessed plate dowels for systems with a design value of thermal conductivity ⁇ ⁇ 0.040 W / mK according to DIN EN 13162 can be used without an increased number of plate anchors over the prior art for their attachment to the facade is required.
  • the invention provides an inhomogeneous binder distribution over the thickness of a facade insulation board.
  • the combinatorial interaction of the advantageous in terms of thermal insulation laminar undercoat with the cover layer which combines the advantage of a further good thermal insulation behavior with the other advantage of good inherent stability of the layer, as well as an integral in the Boundary layer between this cover layer and the laminar lower layer present situation with increased binder content can achieve a facade insulation board, which is characterized by a particularly reliable stability.
  • the interaction with the plate anchors an essential role, as the through the dowel plate on the facade insulation board applied holding force is transmitted through this inner layer with increased binder content in a particularly suitable manner to adjacent areas.
  • the inventively chosen special design of a facade insulation board brings despite significant improvement of their inherent stability and strength properties no relevant deterioration of the thermal insulation properties. Therefore, with the facade insulation board a design value of the thermal conductivity ⁇ ⁇ 0.040 W / mK can be achieved according to DIN EN 13162, which is very advantageous in terms of energy savings associated therewith.
  • the improved strength properties of the facade insulation board used in the invention compared to the prior art that can be worked with the substantially same number of plate anchors in the attachment of the facade insulation board to an outer wall of a building in the context of a thermal insulation composite system. It thus accounts according to the invention labor-intensive, time-consuming and costly additional work for the attachment of additional plate dowels.
  • plate anchors with a diameter of the dowel plate of less than 90 mm can be used to attach the facade insulation board.
  • the properties of the facade insulation board on their large surfaces be it on the outer facade facing surface of the lower layer or the plaster base layer on the outer layer, not affected in the least, so that here from the prior art such as the product "Sillatherm” obtained known excellent properties.
  • an advantageous composite thermal insulation system can be achieved which, in view of the facade insulation panels used according to the invention, is suitable even for insulation systems with a design value of the thermal conductivity of ⁇ ⁇ 0.040 W / mK.
  • thermal insulation composite system according to the invention can achieve a dowel image on the finished facade, which optically substantially similar to the appearance of a system according to the prior art with plate anchors with a plate diameter of 90 mm and with a ⁇ ⁇ 0.036 W / mK is designed while avoiding the thermal bridges of the prior art.
  • the cover layer may be formed from a mineral wool with a three-dimensional isotropic arrangement of the fibers.
  • the cover layer may consist of compressed mineral wool.
  • a three-dimensional compression of the mineral wool is preferred, as for example in the DE 198 60 040 A1 which is referred to for technical details.
  • the cover layer can also be formed as a laminar mineral wool layer with an increased density compared to the laminar lower layer. In this case, the bulk density of this laminar cover layer is more than 150 kg / m 3 , in particular more than 180 kg / m 3 .
  • the region with a relatively large proportion of binder it is also possible for the region with a relatively large proportion of binder to essentially contain an outer layer facing the outer layer of the laminar lower layer. It has been found that the added binder in this section allows a particularly effective increase in the strength properties of the facade insulation board. This is due to the orientation of the fibers in a largely parallel manner to the large surfaces of the lower layer. On the one hand, the stiffening of the structure and thus an increase in the transverse tensile strength is achieved here by the increased binder content, and on the other hand, the prevailing orientation of the individual fibers is permitted a particularly good transfer of compressive and tensile forces on adjacent areas in the same plane, so that there is a particularly favorable distribution of forces over a larger area.
  • the mean binder content in the cover layer is greater than the average binder content in the laminar lower layer. It has been shown that this can be improved in a particularly effective manner, the inherent stability of the facade insulation board without this would go to the detriment of the thermal insulation ability to a considerable extent.
  • the additional binder brings about a particularly effective connection of the individual fibers and thus an advantageous stiffening of the structure.
  • the fibers in the cover layer have a larger average diameter than those in the laminar underlayer. It has been shown in experiments that this measure leads to a further stabilization of the outer layer and thus the improvement of the stability of the facade insulation board.
  • the larger diameter fibers in the top layer provide improved distribution of induced forces to adjacent areas, so that transverse tensile loads can be particularly well absorbed by, for example, wind suction forces.
  • the layer thickness of the cover layer is designed so that after sinking a plate dowel in the cover layer plus possibly deeper outcrops or incisions in the course of dowel insertion remains sufficient for the load transfer residual layer of the cover layer. Due to the comparatively poorer thermal conductivity of the cover layer, it is preferable not to make this layer thicker than necessary. In practical experiments With products of nominal thicknesses of 100 and 120 mm, a ratio of layer thicknesses of about 60% underlayer to 40% top layer has proven to be particularly suitable for achieving a system with a thermal conductivity ⁇ of less than 0.040 W / mK. If the laminar underlayer is thicker than the cover layer, its particularly advantageous properties with regard to thermal insulation can be used effectively for the facade insulation board. As a result of these relationships, the thickness ratio of the outer layer and the lower layer preferably decreases with increasing thicknesses of the facade insulation elements.
  • the facade insulation board satisfies a design value of thermal conductivity ⁇ ⁇ 0.036 W / mK in accordance with DIN EN 13162, which is possible by the measures according to the invention, it can be used advantageously even for a system of heat conduction group 035 and therefore meets the highest requirements with regard to the regulations for energy saving.
  • the facade insulation board preferably has a design value of the thermal conductivity ⁇ ⁇ 0.035 W / mK in accordance with DIN EN 13162.
  • the effective diameter of the anchor plate may be less than 70 mm, in particular about 60 mm, which can reduce the workload as well as the costs on.
  • Another advantage is when the facade insulation panels have a recess in the support area of the anchor plate, in which the dowel plate is sunk. Then the dowel plate can sink with proven in practice resources in the facade insulation board, without causing an impairment of adjacent to the sinking fiber structure.
  • the facade insulation panels have an incision in the support region of the anchor plate whose shape substantially corresponds to the peripheral line of the anchor plate, wherein the anchor plate is recessed in this area in the facade insulation board.
  • the incision removes the structural relationship between the mineral wool material covered by the dowel plate and the adjacent areas; At the same time, however, the material present here is compressed when tightening the plate dowel and acts as an improved counter bearing for the tightening force of the dowel.
  • the plate dowel sits therefore particularly stable in the facade insulation board and allows an even more reliable fastening the same on the facade.
  • this compressed mineral wool material under the dowel plate combinatorially cooperates in a particularly advantageous manner with the given in the present invention used facade insulation board layer with increased binder content, so that there is a further improvement in the stability of the system.
  • the depth of the incision is less than the thickness of the cover layer, wherein the residual thickness of the cover layer remaining at the incision is preferably at least 5%, in particular at least 10%, and particularly preferably at least 20% of the total thickness of the cover layer.
  • the remaining thickness remaining an advantageous distribution of the loads on adjacent areas within the outer layer is possible. As a result, the stability of the thermal insulation composite system according to the invention can be further improved.
  • the recessed dowel plate When the recessed dowel plate is covered by a plug, advantageously results in a substantially continuous surface on the outside of the insulating layer.
  • the plug consists of mineral wool material, since then there is a uniform material on the outside of the insulating layer throughout. The associated elimination of the thermal bridge then the risk is less, that the points of the plate dowels are visible over the years on the facade.
  • a facade insulation board for the insulation of exterior facades of buildings is proposed as part of a thermal insulation composite system according to the invention according to claim 15.
  • a thermal insulation composite system 1 which is applied to a facade 2, an adhesive mortar 3, by means of which an insulation layer formed from facade insulation panels 4 is selectively bonded to the facade 2. Furthermore, the thermal insulation composite system 1 on an external plaster 5. How out Fig. 1 it can be seen, the facade insulation panels are 4th also anchored by means of dowels 6 in the facade 2, wherein the plate dowel 6 sunk in the facade insulation board 4 are arranged and the space between the plate dowel 6 and the outer plaster 5 is closed by a plug 7.
  • the thermal insulation composite system 1 is used in the old building renovation.
  • the facade 2 here contains an outer wall 21 and an old plaster 22, which forms a level and stable ground for the thermal insulation composite system 1.
  • a dowel hole 23 is formed in the facade 2 in a conventional manner, in which the plate dowel 6 is anchored.
  • the plate anchor 6 includes a dowel plate 61, which has a diameter of 60 mm in the present example. This is integrally formed with a dowel shaft 62, which passes through the facade insulation board 4 and in a conventional manner in cooperation with a dowel screw 63 allows anchoring in the facade 2.
  • the outer plaster 5 has a flush 51, in which wet in wet a reinforcing fabric 52 is embedded. On the outside, an outer plaster 53 is also arranged.
  • the facade insulation board 4 has a lower layer 41 and a cover layer 42, which in the present example are integrally connected to each other by mineral wool nonwoven webs with uncured binder over each other and then cured together in a curing oven.
  • the lower layer 41 in this case has a laminar fiber orientation, ie the The vast majority of the mineral fibers are oriented essentially parallel to the large surfaces of the lower layer 41.
  • the cover layer 42 has mineral wool in three-dimensional isotropic fiber orientation, i. the fibers contained in this layer are aligned substantially equally in the three spatial dimensions.
  • the facade insulation board 4 has an incision 43 which protrudes from the plaster base side of the cover layer 42 by a measure T in the cover layer 42, while leaving a residual thickness of the cover layer 42 of about 15% of the total thickness of this layer unprocessed.
  • the incision 43 can be produced with a so-called can drill, and consequently, in the present exemplary embodiment, the mineral wool material lying within the cut edges is not removed.
  • the dowel plate 61 compresses this material within the notch 43 in the course of fastening the facade insulation panel 4 to the facade 2.
  • the lower layer 41 has an edge layer 41a, which is present in the region of the large surface facing the cover layer 42 on the lower layer 41.
  • the boundary layer between the underlayer 41 and the cover layer 42 is hereby clarified in FIG Fig. 1 schematically indicated by a dashed line.
  • this edge layer 41a has a higher binder content than the other areas of the facade insulation board 4.
  • the binder content in the topcoat is chosen to be about 5%.
  • the Binder content in the underlayer is in the range of about 3.7% over a wide range, but increased to more than 6% in the surface layer in the example shown. Since this increased amount of binder in the region of the boundary layer, due to process engineering, also penetrates into the edge region of the cover layer 42 in the course of the production of the facade insulation board 4, the result is also close to that in FIG Fig. 2 also indicated by dashed lines boundary layer between the cover layer and the lower layer a slightly increased binder content.
  • the facade insulation board 4 can be made in a Zerhotelsstation like a jet blowing device with, for example, ten consecutively lined blowing nozzles.
  • six tuyeres can form the mineral wool of the lower layer 41 and four downstream tuyeres form the cover layer 42, wherein in the area of the sixth tuyere for the lower layer 41 a greater amount of binder is added than in the other regions.
  • a primary nonwoven with laminar fiber orientation thus formed is then separated into a first mineral wool raw nonwoven and the second mineral wool raw nonwoven fabric in such a way that the zone with higher binder concentration in an outer layer of the first mineral wool raw nonwoven is present.
  • the second mineral wool raw nonwoven is digested and re-combined, resulting in a quasi-isotropic fiber orientation herein. Subsequently, these nonwovens are guided together in such a way that the edge layer is present with a larger proportion of binder in the interior of the combined nonwoven.
  • the facade insulation panel 4 can then be made up of it with its outer layer 41 formed by the second mineral wool raw non-woven fabric and the lower layer 41 formed by the first mineral wool non-woven fabric by separating cuts.
  • the facade insulation board 4 in this case has a total thickness of 100 mm, wherein the cover layer 42 is about 40 mm thick and the lower layer 41 is designed about 60 mm thick.
  • the edge layer 41a is about 10 mm thick in the example shown.
  • binder proportions results for the entire facade insulation board 4, an average binder content of about 4.5%.
  • the bulk density of the cover layer 42 is in the example shown at about 120 kg / m 3 and in the lower layer 41 at about 100 kg / m 3 .
  • the facade insulation board 4 thus reaches a design value of the thermal conductivity ⁇ of about 0.035 W / mK according to DIN EN 13162.
  • the facade insulation panel 4 can also be provided with the following parameters:
  • the top layer is a three-dimensionally compressed mineral wool according to the procedure of DE 198 60 040 A1 with a bulk density of about 130 kg / m 3 and a binder content of about 4% with a layer thickness provided by about 60 mm.
  • the underlayer with a layer thickness of about 140 mm has a bulk density of about 100 kg / m 3 and a binder content of about 3.5%.
  • the binder content of the boundary layer is adjusted to about 5%, so that there is an average binder content of about 3.9% for the Fassadendämmelement.
  • the cover layer is provided in the form of a laminar mineral wool layer increased density of about 200 kg / m 3 with a binder content of about 4% with a layer thickness of about 50 mm.
  • the underlayer with a layer thickness of about 110 mm has a bulk density of about 100 kg / m 3 and a binder content of about 3.5%.
  • the binder content of the boundary layer is adjusted to about 5%, so that there is an average binder content of about 3.8% for the Fassadendämmelement.
  • these two variants can be produced by bonding the hardened layers provided with the parameters mentioned, or the hardened covering layer is fed to a hardening process together with the uncured laminar sublayer.
  • the mean binder content in the cover layer 42 is greater than the average binder content in the underlayer 41; Rather, these binder proportions can be about the same. It is also possible that the binder content in the entire Fassadendämmplattenquerites with the exception of an edge layer 41a is set at the same level.
  • the fibers in the cover layer 42 are inventively formed with a larger diameter than those of the lower layer 41; However, this is not absolutely necessary, but also identically configured fibers can be used.
  • facade insulation board 4 rock wool As a material for the facade insulation board 4 rock wool is used in the illustrated embodiment; however, it is also possible to form, for example, the underlayer 41 and / or the cover layer 42 of glass wool.
  • the ratio of the layer thicknesses of the underlayer 41 to the cover layer 42 is not limited to the factor 60:40 explained and can be varied in both directions, depending on the application.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Physics & Mathematics (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Acoustics & Sound (AREA)
  • Electromagnetism (AREA)
  • Building Environments (AREA)
EP08749004.1A 2007-04-20 2008-04-18 Fassadendämmplatte für die dämmung von aussenfassaden von gebäuden, wärmedämm-verbundsystem mit derartigen fassadendämmplatten sowie verfahren zur herstellung einer fassadendämmplatte Active EP2137359B2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL08749004T PL2137359T5 (pl) 2007-04-20 2008-04-18 Płyta izolacyjna do fasad do izolowania zewnętrznych fasad budynków, zespolony system termoizolacji z tego rodzaju płytami izolacyjnymi do fasad, jak również sposób wytwarzania płyty izolacyjnej do fasad

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007018774A DE102007018774A1 (de) 2007-04-20 2007-04-20 Fassadendämmplatte für die Dämmung von Außenfassaden von Gebäuden, Wärmedamm-Verbundsystem mit derartigen Fassadendämmplatten sowie Verfahren zur Herstellung einer Fassadendämmplatte
PCT/EP2008/003160 WO2008128733A1 (de) 2007-04-20 2008-04-18 Fassadendämmplatte für die dämmung von aussenfassaden von gebäuden, wärmedämm-verbundsystem mit derartigen fassadendämmplatten sowie verfahren zur herstellung einer fassadendämmplatte

Publications (3)

Publication Number Publication Date
EP2137359A1 EP2137359A1 (de) 2009-12-30
EP2137359B1 EP2137359B1 (de) 2012-06-20
EP2137359B2 true EP2137359B2 (de) 2019-05-08

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EP08749004.1A Active EP2137359B2 (de) 2007-04-20 2008-04-18 Fassadendämmplatte für die dämmung von aussenfassaden von gebäuden, wärmedämm-verbundsystem mit derartigen fassadendämmplatten sowie verfahren zur herstellung einer fassadendämmplatte

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EP (1) EP2137359B2 (ru)
JP (1) JP5290275B2 (ru)
CN (1) CN101680221B (ru)
DE (1) DE102007018774A1 (ru)
DK (1) DK2137359T4 (ru)
EA (1) EA018261B1 (ru)
ES (1) ES2390522T5 (ru)
PL (1) PL2137359T5 (ru)
UA (1) UA99130C2 (ru)
WO (1) WO2008128733A1 (ru)

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DE102010061539A1 (de) 2010-12-23 2012-06-28 Saint-Gobain Isover G+H Ag Wärmedämmverbundsystem sowie Fassadendämmplatte hierfür und Verfahren zur Herstellung der Fassadendämmplatte
WO2017217147A1 (ja) * 2016-06-14 2017-12-21 旭ファイバーグラス株式会社 グラスウール保温帯
RU2756192C1 (ru) 2018-07-12 2021-09-28 Ксило Текнолоджиз АГ Плита из минеральной ваты с наполнителями
US20220347206A1 (en) * 2021-04-30 2022-11-03 Npo Petrovax Pharm, Llc Methods of prophylaxis and treatment of covid-19 using azoximer bromide

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EA200970986A1 (ru) 2010-06-30
DK2137359T3 (da) 2012-10-08
EA018261B1 (ru) 2013-06-28
EP2137359A1 (de) 2009-12-30
UA99130C2 (ru) 2012-07-25
WO2008128733A1 (de) 2008-10-30
EP2137359B1 (de) 2012-06-20
ES2390522T3 (es) 2012-11-13
DK2137359T4 (da) 2019-08-19
CN101680221B (zh) 2013-03-06
CN101680221A (zh) 2010-03-24
ES2390522T5 (es) 2020-02-04
PL2137359T3 (pl) 2013-01-31
JP2010525191A (ja) 2010-07-22
JP5290275B2 (ja) 2013-09-18
PL2137359T5 (pl) 2020-09-21

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