EP1929059A1 - Tole d'acier pour galvanisation a excellente usinabilite, et procede de fabrication - Google Patents
Tole d'acier pour galvanisation a excellente usinabilite, et procede de fabricationInfo
- Publication number
- EP1929059A1 EP1929059A1 EP06783735A EP06783735A EP1929059A1 EP 1929059 A1 EP1929059 A1 EP 1929059A1 EP 06783735 A EP06783735 A EP 06783735A EP 06783735 A EP06783735 A EP 06783735A EP 1929059 A1 EP1929059 A1 EP 1929059A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- less
- steel sheet
- steel
- temperature
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 107
- 239000010959 steel Substances 0.000 title claims abstract description 107
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000005246 galvanizing Methods 0.000 title claims description 11
- 229910052718 tin Inorganic materials 0.000 claims abstract description 17
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 14
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 13
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 238000000137 annealing Methods 0.000 claims description 34
- 238000001816 cooling Methods 0.000 claims description 13
- 238000005097 cold rolling Methods 0.000 claims description 11
- 229910052748 manganese Inorganic materials 0.000 claims description 10
- 238000005096 rolling process Methods 0.000 claims description 9
- 239000010960 cold rolled steel Substances 0.000 claims description 8
- 238000005098 hot rolling Methods 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 238000003303 reheating Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 4
- 229910001566 austenite Inorganic materials 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 11
- 238000007747 plating Methods 0.000 description 7
- 239000006104 solid solution Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000001953 recrystallisation Methods 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0426—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
- C21D8/0473—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/004—Dispersions; Precipitations
Definitions
- the present invention generally relates to a high strength ductile steel sheet for extra deep drawing for interior or exterior plates of automobile bodies and the like, and to a method for manufacturing the same. More particularly, the present invention relates to a steel sheet for galvanizing with excellent workability, which has a tensile strength of 28 ⁇ 50 Df/D, and has excellent properties in terms of formability, secondary work embrittlement resistance, fatigue properties of welded joints and surface quality, and to a method for manufacturing the same.
- steel sheets for the automobile body have been required to have further enhanced formability.
- the steel sheets for the automobile body also have been required to have excellent secondary work embrittlement and fatigue properties of welded joints in terms of using conditions of the automobiles, and to have an appealing plated surface.
- the added elements described as above have a higher affinity to oxygen than Fe, the added elements are grown to surface agglomerates, such as MnO, SiO Al O , TiO and the like, in singular or composite forms during the cold annealing process.
- JP2002-146477, JP2001-64750 and JP2002-155317 disclose techniques aiming to enhance plating properties by adding specific elements such as Cr, Sb and the like to a steel sheet
- JP2001-288550 discloses a technique aiming to suppress formation of the surface agglomerates during cold annealing through pre-oxidation of hot coil before cold rolling.
- the present invention has been made to solve the above problems, and it is an object of the present invention to provide a steel sheet for galvanizing with excellent workability, which has a tensile strength of 28 ⁇ 50 Df/D, and has excellent properties in terms of formability, secondary work embrittlement resistance, fatigue properties of welded joints and surface quality.
- a steel sheet for galvanizing with excellent workability comprising, by weight%: C: 0.010% or less, Si: 0.1% or less, Mn: 0.06 ⁇ 1.5%, P: 0.15% or less, S: 0.020% or less, Sol.
- Al 0.10 ⁇ 0.40%, N: 0.010% or less, Ti: 0.003 ⁇ 0.010%, Nb: 0.003 ⁇ 0.040%, B: 0.0002 ⁇ 0.0020%, Mo: 0.05% or less, one or both of Sb: 0.005 ⁇ 0.05% and Sn: 0.005 ⁇ 0.05%, a total amount of Sb and Sn being in the range of 0.005 - 0.1% when both of Sb and Sn are added to the steel sheet, and the balance of Fe and other unavoidable impurities, wherein the steel sheet has surface agglomerates having an average diameter of 1 D or less, and a tensile strength of 28 ⁇ 50 Df/D.
- the average diameter of the surface agglomerates is suppressed in growth by 10% or less for an increase in annealing temperature of 10 °C.
- a method for manufacturing a steel sheet for galvanizing with excellent workability comprises: reheating a steel slab comprising by weight%: C: 0.010% or less, Si: 0.1% or less, Mn: 0.06 ⁇ 1.5%, P: 0.15% or less, S: 0.020% or less, Sol.
- the present invention provides a steel sheet for galvanizing with excellent workability, which has a tensile strength of 28 ⁇ 50 Df/D, and excellent properties in terms of formability, secondary work embrittlement resistance, fatigue properties of welded joints and surface quality.
- Fig. 1 is a graph depicting change in amount of surface agglomerates according to kinds of steel and annealing temperature
- Fig. 2 is micrographs showing distribution of surface agglomerates on surfaces of air cooled steel sheets and water cooled steel sheets according to kinds of steel and after hot coiling
- Fig. 3 is micrographs showing distribution of surface agglomerates on steel sheets according to kinds of steel and annealing temperatures.
- the texture which is advantageous in terms of workability in the course of forming the texture in a steel sheet upon cold rolling and annealing.
- An excessive content of carbon requires an increase in contents of Ti and Nb which are carbide and nitride formation elements, causing a disadvantage of increased manufacturing costs.
- the carbon content is preferably 0.010% or less.
- Si is an element which causes temper color upon annealing, and non-plated regions upon plating as well as surface scale.
- the silicon content is preferably 0.1% or less.
- Mn is added as a substitutional solid solution strengthening element for ensuring strength of steel.
- the Mn content is preferably in the range of 0.06 - 1.5%.
- P is also a representative solid solution strengthening element which is added to the steel along with Mn for increasing the strength.
- P is added to Ti-Nb steel as in the steel of the present invention, it results in growth of the 111 texture, advantageous in terms of the r- value, through grain refinement, grain boundary segregation, and the like.
- P content exceeds 0.15%, the steel suffers from rapid reduction in elongation along with significant increase in brittleness.
- the P content is preferably in the range of 0.03 - 0.15%.
- S content in the steel is generally restricted to a low degree of 0.005% or less. According to the present invention, however, since the steel contains Mn, all amounts of S in the steel are precipitated as MnS, thereby making it possible to avoid deterioration in formability due to solid solution of S.
- S content is preferably 0.020% or less, which can deviate from a region causing edge cracks during rolling.
- a Sol. Al content of the steel is generally controlled to be in the range of 0.02 - 0.07% while dissolved oxygen in the steel is maintained at a sufficiently low amount in consideration of manufacturing costs.
- Sol. Al serves to allow deep drawability to be stably secured at a lower annealing temperature.
- the Sol. Al content is 0.10%or more in the steel, it coarsens the precipitates in the steel, remarkably obstructs effect of suppressing recrystallization by P, thereby activating the recrystallization, and aids in development of the 111 texture. If the Sol. Al content exceeds 0.40%, it causes an increase of the manufacturing costs, and deterioration in efficiency of continuous casting operation. Thus, the Sol. Al content is preferably in the range of 0.10 - 0.40%.
- the Sol. Al content influences formation of Ti or Nb-based precipitates as the carbide and nitride to coarsen the precipitates, it serves as a critical component which provides further enhanced workability of the steel with small added amounts of Ti and Nb in comparison to the conventional IF steel.
- N deteriorates the workability of the steel if it exists in a solid solution state in the steel. Furthermore, if an excessive content of N resides in the steel, it is necessary to increase added amounts of Ti and Nb for fixing N as precipitates in the steel. Thus, the N content is preferably 0.010% or less.
- B is a grain boundary strengthening element, and effective to enhance fatigue properties of spot welded joints while preventing grain boundary embrittlement by P.
- B content In order to obtain the effect by addition of B, it is necessary to have B content of 0.0002% or more. However, if the B content exceeds 0.0020%, the steel suffers from rapid deterioration of the workability and surface properties of the plated steel sheet.
- the B content is preferably 0.0002 ⁇ 0.0020%.
- Mo is added to enhance the secondary work embrittlement resistance and the plating properties. If Mo content exceeds 0.05%, the effect of enhancing the secondary work embrittlement resistance and the plating properties is significantly reduced, and it is disadvantageous in terms of the manufacturing costs. Thus, the Mo content is preferably 0.05% or less.
- Ti and Nb are very important elements in view of the workability. Ti and Nb must be added to the steel in an amount of 0.003 ⁇ 0.010%, and an amount of 0.003 ⁇ 0.040%, respectively, in consideration of a minimum and optimum amount for securing the workability (in particular, r- value) enhancing effect.
- Sb is a very important element, and exhibits remarkable effects to suppress generation of surface agglomerates such as MnO, SiO , Al O , and the like, and to suppress coarsening of the surface agglomerates by a temperature increase and other variations in hot processing.
- the Sb content must be 0.005% or more.
- Sb is added exceeding a specific content, the above effects cannot be obtained, and thus the Sb content has an upper limit of 0.05%.
- Sn exhibits similar effects to those of Sb in the steel. In order to obtain these effects, the Sn content must be 0.005% or more, but if Sn is added above a specific content, the above effects cannot be obtained, and thus the Sb content has an upper limit of 0.05%.
- a total content of Sb and Sn is preferably in the range of 0.005 - 0.1%.
- the steel slab After reheating a steel slab having the composition as described above, the steel slab is subjected to hot rolling with finish rolling at a finish hot rolling temperature of a single phase austenite region, coiling, and cold rolling, thereby providing a cold rolled steel sheet. Then, continuous annealing is performed at a temperature of 700 °C or more.
- the surface agglomerates (singular or composite oxides of Si, Al, Mn and the like) on the steel sheet increase in amount, exhibiting a remarkable tendency of coarsening. As a result, it is likely to generate surface defects such as non-plate regions or surface dents.
- growth of the surface agglomerates can be suppressed in the annealing temperature region, thereby ensuring excellent surface quality of the steel sheet.
- the reheating of the steel slab is performed at a temperature in the range of 1,100 ⁇ 1,300 °C
- the finish rolling is performed at a temperature in the range of 830
- the hot rolled steel sheet may be subjected to air cooling or water cooling after hot coiling.
- a reduction ratio is preferably 65% or more upon the cold rolling in order to obtain a high r- value of 1.9 or more.
- the annealing temperature is 700 °C or more, and preferably in the range of 780 ⁇ 860
- annealing temperature of 10 °C in the annealing temperature range described as above is suppressed by 10% or less for an increase in annealing temperature of 10 °C in the annealing temperature range described as above.
- continuous annealing of the cold rolled steel sheet is performed at a temperature in the range of 880 - 930 °C.
- the continuous annealing temperature of the present invention is lower than the annealing temperature applied to manufacturing of the typical extra deep drawing, the present invention is more economic and has superior operability.
- a steel sheet for galvanizing with excellent workability, which has surface agglomerates having an average diameter of 1 D or less, and a tensile strength of 28 ⁇ 50 Df/D.
- the surface agglomerates mainly comprise singular or composite oxides of Si, Al,
- the surface agglomerates are preferably suppressed in growth of the average diameter by 10% or less for an increase in annealing temperature of 10 °C.
- the Steel Kind 5 satisfying the conditions of the present invention has a lower amount and a smaller size of surface agglomerates than those of the Steel Kind 5 which does not satisfy the conditions of the present invention.
- the steel sheet of the Steel Kind 4 subjected to air cooling after hot coiling has surface agglomerates remarkably increased in size compared with the steel sheet subjected to water-cooling after coiling.
- the steel sheet of the Steel Kind 5 subjected to water-cooling after hot coiling has surface agglomerates which have substantially the same size as that of surface agglomerates on the steel sheet subjected to air cooling after coiling.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020050078433A KR100711356B1 (ko) | 2005-08-25 | 2005-08-25 | 가공성이 우수한 아연도금용 강판 및 그 제조방법 |
PCT/KR2006/003348 WO2007024114A1 (fr) | 2005-08-25 | 2006-08-24 | Tole d'acier pour galvanisation a excellente usinabilite, et procede de fabrication |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1929059A1 true EP1929059A1 (fr) | 2008-06-11 |
EP1929059A4 EP1929059A4 (fr) | 2012-06-13 |
Family
ID=37771816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06783735A Withdrawn EP1929059A4 (fr) | 2005-08-25 | 2006-08-24 | Tole d'acier pour galvanisation a excellente usinabilite, et procede de fabrication |
Country Status (6)
Country | Link |
---|---|
US (1) | US20110073223A1 (fr) |
EP (1) | EP1929059A4 (fr) |
JP (1) | JP5388577B2 (fr) |
KR (1) | KR100711356B1 (fr) |
CN (1) | CN101243198B (fr) |
WO (1) | WO2007024114A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5042232B2 (ja) * | 2005-12-09 | 2012-10-03 | ポスコ | 成形性及びメッキ特性に優れた高強度冷延鋼板、これを用いた亜鉛系メッキ鋼板及びその製造方法 |
KR100797238B1 (ko) * | 2006-12-26 | 2008-01-23 | 주식회사 포스코 | 가공성이 우수한 심가공용 박강판의 제조방법 |
CN102791895B (zh) * | 2009-12-04 | 2014-12-24 | Posco公司 | 具有优异耐热性的加工用冷轧钢板及其制造方法 |
JP4998757B2 (ja) * | 2010-03-26 | 2012-08-15 | Jfeスチール株式会社 | 深絞り性に優れた高強度鋼板の製造方法 |
KR20120127095A (ko) * | 2011-05-13 | 2012-11-21 | 주식회사 포스코 | 표면특성이 우수한 고강도 고인성 선재 및 그 제조방법 |
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CN112654723B (zh) * | 2018-11-02 | 2023-04-04 | 日本制铁株式会社 | 无取向电磁钢板 |
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- 2006-08-24 JP JP2008527851A patent/JP5388577B2/ja not_active Expired - Fee Related
- 2006-08-24 WO PCT/KR2006/003348 patent/WO2007024114A1/fr active Application Filing
- 2006-08-24 US US12/064,653 patent/US20110073223A1/en not_active Abandoned
- 2006-08-24 CN CN2006800305520A patent/CN101243198B/zh not_active Expired - Fee Related
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Title |
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See also references of WO2007024114A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2007024114A9 (fr) | 2009-12-03 |
CN101243198B (zh) | 2010-12-29 |
JP5388577B2 (ja) | 2014-01-15 |
EP1929059A4 (fr) | 2012-06-13 |
US20110073223A1 (en) | 2011-03-31 |
KR20070023995A (ko) | 2007-03-02 |
KR100711356B1 (ko) | 2007-04-27 |
JP2009506208A (ja) | 2009-02-12 |
CN101243198A (zh) | 2008-08-13 |
WO2007024114A1 (fr) | 2007-03-01 |
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