EP1805342A1 - Verfahren zum herstellen eines korrosionsgeschützten stahlblechs - Google Patents
Verfahren zum herstellen eines korrosionsgeschützten stahlblechsInfo
- Publication number
- EP1805342A1 EP1805342A1 EP05796770A EP05796770A EP1805342A1 EP 1805342 A1 EP1805342 A1 EP 1805342A1 EP 05796770 A EP05796770 A EP 05796770A EP 05796770 A EP05796770 A EP 05796770A EP 1805342 A1 EP1805342 A1 EP 1805342A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling
- steel sheet
- cooling medium
- aqueous
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 48
- 239000010959 steel Substances 0.000 title claims abstract description 48
- 230000007797 corrosion Effects 0.000 title abstract description 14
- 238000005260 corrosion Methods 0.000 title abstract description 14
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 239000002826 coolant Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 40
- 239000011248 coating agent Substances 0.000 claims abstract description 28
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 claims abstract description 23
- 239000002184 metal Substances 0.000 claims abstract description 23
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 17
- 239000011701 zinc Substances 0.000 claims abstract description 17
- 238000009792 diffusion process Methods 0.000 claims abstract description 13
- 229910001297 Zn alloy Inorganic materials 0.000 claims abstract description 8
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 36
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 150000002739 metals Chemical class 0.000 claims description 7
- -1 hydroxide ions Chemical class 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000006172 buffering agent Substances 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000008199 coating composition Substances 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 2
- 229910021645 metal ion Inorganic materials 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 22
- 238000010438 heat treatment Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 229910001335 Galvanized steel Inorganic materials 0.000 description 5
- 239000008397 galvanized steel Substances 0.000 description 5
- 238000005246 galvanizing Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012928 buffer substance Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004532 chromating Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5806—Thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
- C23C2/29—Cooling or quenching
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
- C25D5/50—After-treatment of electroplated surfaces by heat-treatment
Definitions
- the invention relates to a method for producing a corrosion-protected steel sheet for coating with an organic coating agent, in which the coated with a coating of zinc or a zinc alloy corrosion-protected steel sheet in vacuum coated with at least one additional metal or metal alloy, then a thermal
- the galvanizing of steel body panels for the purpose of corrosion protection has largely prevailed in the last decades.
- the galvanized steel plates in the hot dip process or by means of electrolytic deposition are characterized by a good adhesion of the zinc layer to the steel sheet / and a good processability, in particular Umformbarköit from.
- DE 100 39 375 A1 describes a process for producing a corrosion-protected steel sheet, in which a layer of metals, in particular alkaline earth metals, magnesium or aluminum or their alloys, in a continuous steel sheet provided with a zinc or zinc alloy coating
- this heat treatment which consists of a heating and a holding phase, it comes in the areas of the surface in which in the vacuum coating multiphase alloys between the vapor-deposited layer and the zinc or zinc alloy layer with a melting temperature lower than that of the zinc or zinc alloy layer, locally to the welds, in which case the vapor-deposited metal or vapor-deposited alloy also penetrates into deeper layers of the zinc coating heat treatment is the steel sheet in cooled an unchanged oxygen-poor atmosphere, the fusions solidify.
- the corrosion resistance of the galvanized steel sheet is positively influenced by the dissolution of the Zinküberzmgs is slowed down by the stabilizing effect of the vapor deposited and penetrated by the melts ia the zinc coating metal greatly.
- DE 195 27 515 C1 describes another method for producing a corrosion-protected steel sheet.
- one or more of Zirxk different metals, in particular Fe, Mn, Cu, Ni and Mg, or their alloys by vacuum coating applied to a provided with a zinciferous steel sheet and then without intermediate exposure to oxidizing atmosphere of a thermal
- the invention is therefore based on the object of specifying a method for producing a corrosion-protected steel sheet for coating with an organic coating agent, which in comparison to the generic state of the art by excellent adhesion of the organic coating composition and by a high corrosion resistance in the coated state of the sheet distinguished.
- the object is achieved by a method according to the preamble of claim 1, characterized in that the cooling is carried out with an aqueous cooling medium under normal atmospheric conditions.
- a steel sheet is first provided in a known manner with a coating of zinc or a Zinklegieri ⁇ ng. This takes place in a known manner in the melt-dip process (hot-dip galvanizing) or by electrolytic deposition.
- the galvanized steel sheet is coated in vacuum with an additional metal.
- a thermal diffusion treatment in which atoms of the metal layer applied in a vacuum diffuse into the underlying zinc or zinc alloy. Due to the residual gas content in the vacuum and during the thermal diffusion treatment, a native oxide layer forms on the surface of the coated steel sheet, which passivates the surface and thus increases its corrosion resistance.
- the "finished steel sheet after the thermal diffusion treatment is cooled with an aqueous cooling medium.
- Another advantage of cooling by means of an aqueous cooling medium is that in subregions of the coated surface, in which no native oxide layer is formed, ie where the bare metallic coating is exposed, water molecules are decomposed from the coolant, with anti-corrosive, partially form sparingly soluble hydroxides. These hydroxides or: the resulting oxides in the subsequent drying improve significantly the adhesion of organic coatings on the surface of the steel sheet.
- the applied in vacuum on the galvanized sheet surface layer may be composed of one or more metals.
- those metals are used which form mixed phases with the zinc of the zinc or zinc alloy layer. This results in a good connection of both layers, and the corrosion resistance is increased.
- Particularly suitable are reactive metals, such as magnesium, aluminum, iron or manganese or their alloys.
- a predetermined temperature control in the sense of a defined starting temperature of the finished steel sheet zi ⁇ onset of cooling, a preset temperature of the cooling medium and a specified cooling time sowor ⁇ l shortening the treatment time and the quality of the corrosion protection layer can be improved in terms of higher corrosion resistance.
- the starting temperature of the steel sheet at the beginning of Abkühlumg is preferably 250 to 35O 0 C, in particular 290 to 310 0 C.
- the setting of the starting temperature can technically! done in different ways.
- the use of cooling rolls is just as possible as the use of gas cooling.
- the duration of the cooling is preferably 1 to LO s.
- the temperature of the cooling medium should not be set too high, since in this case the metal coating of the steel sheet by the coolant is strong is attacked.
- the temperature of the coolant should not exceed 42 ° C.
- the final temperature of the steel sheet after cooling is preferably 20 b> is 120 0 C, in particular 40 to 60 0 C. This results in a wide working range. An increase in the final temperature beyond 12O 0 C addition does not make sense, otherwise it can lead to damage of subsequent rubberized rollers for the removal of the cooling medium.
- the cooling can be carried out in a dip.
- the coated steel sheet can also be sprayed, wherein the spraying is preferably carried out under high pressure, since in this case a particularly rapid cooling and Passivierrung the surface can be achieved.
- hot sheet metal surfaces in this way are formed directly on the OberfLowne forming Wasserschampfschichit which greatly reduces the heat transfer between the steel sheet and the cooling medium (Leidenfrost effect).
- aqueous cooling medium should be removed immediately after cooling from the surface of the coated steel sheet.
- the removal of the cooling medium can be done by squeezing or durrch a gas jet.
- the corrosion resistance and the adhesion of the organic coating to be applied can be further improved by further measures.
- soluble salts can be added to the aqueous cooling medium. These set free suitable divalent metal ions or hydroxide ions and thus shift the solution equilibrium to the undissociated oxide according to the equation
- buffering substances in particular acetate, phosphate, borate, carbonate, or citrate ions, can be added to the aqueous cooling medium, by means of which an optimum pH in the sense of minimum hydrolysis of amphoteric native metal oxides can be set.
- the pH value should be neither in the weakly acidic range (pH ⁇ 5) nor in the strongly basic range (pH> 12.5).
- the drawing shows a plant for the continuous refining and subsequent painting of a steel strip.
- a substrate in the form of a steel strip 1 is first passed through one or more cells 2 and coated in a electrolytic deposition process with a zinc layer.
- galvanizing in the hot dip process is possible.
- the steel strip 1 enters a Vakuumkanxmer 3 a.
- the band 1 with one from the state coating technique known in the art, for example by means of PVD, with an additional metal, preferably magnesium coated.
- additional metal preferably magnesium coated.
- Further usable metals are, for example, aluminum and manganese.
- the coated galvanized steel strip 1 After leaving the vacuum chamber 3, the coated galvanized steel strip 1 enters a heating chamber 4 provided with a heating device 4a. In this heating chamber 4 then takes place a thermal diffusion treatment, which can be carried out in a normal atmosphere. In the course of the diffusion treatment, the magnesium layer applied in a vacuum partially diffuses into the underlying zinc layer, forming intermetallic phases consisting of zinc and magnesium.
- the steel strip 1 After emerging from the heating chamber 4, the steel strip 1 is deflected at least one cooling roller 5 and is thereby cooled to a defined temperature. This is at the same time the starting temperature of the subsequent cooling process and is preferably 250 to 350 0 C, in particular 290 to 31O 0 C.
- the steel strip 1 is passed into a further chamber 6.
- the diffusion-treated surface with an aqueous Spray cooling medium under high pressure.
- the cooling can also take place in a dipping bath.
- the aqueous cooling medium may be pure Wasserr act.
- salts which shift the solution equilibrium to the undissociated oxide can also be dissolved in the cooling medium.
- the cooling medium can contain buffering substances, for example acetate, phosphate, borate, carbonate, or citrate ions, by means of which an optimum pH value can be set in the sense of minimal hydrolysis of magnetic native metallic oxides.
- the spraying device is designed such that the coated steel sheet is completely wetted immediately at the beginning of the cooling by the aqueous cooling medium in order to avoid the formation of visible patterns on the surface.
- the cooling in the chamber 6 takes place with a predetermined temperature control. Daloei is the temperature of the cooling medium maximum 42 0 C-
- the exposure time of the cooling medium to the steel strip 1 is between 1 and 10 s.
- the cooling medium is removed by squeezing rollers 7 from the Bandoberiflache.
- the residual heat of the belt 1 supports the removal of the cooling medium by evaporation.
- the removal of the cooling medium can also be effected by a gas jet.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Electrochemistry (AREA)
- Coating With Molten Metal (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004052482A DE102004052482A1 (de) | 2004-10-28 | 2004-10-28 | Verfahren zum Herstellen eines korrosionsgeschützten Stahlblechs |
PCT/EP2005/011387 WO2006045570A1 (de) | 2004-10-28 | 2005-10-24 | Verfahren zum herstellen eines korrosionsgeschützten stahlblechs |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1805342A1 true EP1805342A1 (de) | 2007-07-11 |
Family
ID=35457276
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05796770A Withdrawn EP1805342A1 (de) | 2004-10-28 | 2005-10-24 | Verfahren zum herstellen eines korrosionsgeschützten stahlblechs |
Country Status (8)
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005036426B4 (de) * | 2005-08-03 | 2007-08-16 | Thyssenkrupp Steel Ag | Verfahren zum Beschichten von Stahlprodukten |
DE102006047060A1 (de) | 2006-05-18 | 2007-11-22 | Thyssenkrupp Steel Ag | Mit einem Korrosionsschutzsystem versehenes Stahlblech und Verfahren zum Beschichten eines Stahlblechs mit einem solchen Korrosionsschutzsystem |
DE102007026061A1 (de) * | 2007-06-01 | 2008-12-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verschleiß- und korrosionsbeständiges Bauteil und Verfahren zu seiner Herstellung |
ATE535631T1 (de) * | 2007-10-02 | 2011-12-15 | Thyssenkrupp Steel Europe Ag | Verfahren zum herstellen eines stahlbauteils durch warmformen und durch warmformen hergestelltes stahlbauteil |
KR100961371B1 (ko) * | 2007-12-28 | 2010-06-07 | 주식회사 포스코 | 실러 접착성 및 내식성이 우수한 아연계 합금도금강판과 그제조방법 |
ATE513938T1 (de) | 2008-02-25 | 2011-07-15 | Arcelormittal France | Beschichtungsverfahren eines metallstreifens und anlage zur ausführung dieses verfahrens |
EP2290133B1 (de) * | 2009-08-25 | 2012-04-18 | ThyssenKrupp Steel Europe AG | Verfahren zum Herstellen eines mit einem metallischen, vor Korrosion schützenden Überzug versehenen Stahlbauteils und Stahlbauteil |
DE102010030465B4 (de) * | 2010-06-24 | 2023-12-07 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Herstellen eines Blechformteils aus einem höherfesten Stahlblechmaterial mit einer elektrolytisch aufgebrachten Zink-Nickel-Beschichtung |
NZ706336A (en) * | 2012-10-17 | 2019-02-22 | Bluescope Steel Ltd | Method of producing metal-coated steel strip |
TWI653362B (zh) * | 2012-10-17 | 2019-03-11 | 澳大利亞商布魯史寇普鋼鐵有限公司 | 金屬被覆鋼帶的製造方法 |
NZ706324A (en) * | 2012-10-18 | 2019-02-22 | Bluescope Steel Ltd | Method of producing metal coated steel strip |
DE102012110972B3 (de) * | 2012-11-14 | 2014-03-06 | Muhr Und Bender Kg | Verfahren zum Herstellen eines Erzeugnisses aus flexibel gewalztem Bandmaterial und Erzeugnis aus flexibel gewalztem Bandmaterial |
WO2014104717A1 (ko) | 2012-12-26 | 2014-07-03 | 주식회사 포스코 | 알루미늄-마그네슘 코팅 강판 및 그 제조 방법 |
EP2824213A1 (de) * | 2013-07-12 | 2015-01-14 | Voestalpine Stahl GmbH | Verfahren zur Verbesserung der Haftfähigkeit auf einem schutzbeschichteten Stahlblech |
US9956576B2 (en) | 2014-04-22 | 2018-05-01 | Metokote Corporation | Zinc rich coating process |
CN104328370B (zh) * | 2014-11-11 | 2017-02-15 | 武汉钢铁(集团)公司 | 一种热镀锌镁合金钢板的生产方法 |
US10203232B2 (en) * | 2016-09-27 | 2019-02-12 | Cameron International Corporation | Flow meter with rotor assembly |
CN107354378A (zh) * | 2017-07-17 | 2017-11-17 | 承德市帝圣金属复合材料有限公司 | 一种复合金属材料及其制备方法 |
KR102031466B1 (ko) | 2017-12-26 | 2019-10-11 | 주식회사 포스코 | 표면품질 및 내식성이 우수한 아연합금도금강재 및 그 제조방법 |
CN111346803A (zh) * | 2020-03-10 | 2020-06-30 | 富阳双龙防火门有限公司 | 一种彩钢带的加工工艺及涂装装置 |
CN115433897B (zh) * | 2022-09-19 | 2025-02-28 | 平顶山市美伊厨炊具有限公司 | 一种钢铁基材料表面处理工艺 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1481120A (fr) * | 1966-03-09 | 1967-05-19 | Chiers Hauts Fourneaux | Perfectionnement au procédé et aux installations de galvanisation à chaud par immersion dans un bain métallique liquide de matériaux divers en acier |
DE2349236C2 (de) * | 1973-10-01 | 1982-05-13 | Bethlehem Steel Corp., Bethlehem, Pa. | Verfahren zum Herstellen eines eisenhaltigen Gegenstandes mit einem Aluminium/Zink-Überzug und seine Anwendung auf Bleche, Bänder und Drähte aus Stahl |
SE445470B (sv) * | 1979-03-02 | 1986-06-23 | Centre Rech Metallurgique | Forfarande for framstellning av ett belagt stalband |
BE874599A (fr) * | 1979-03-02 | 1979-09-03 | Centre Rech Metallurgique | Procede de fabrication d'une bande d'acier revetue |
US4361448A (en) * | 1981-05-27 | 1982-11-30 | Ra-Shipping Ltd. Oy | Method for producing dual-phase and zinc-aluminum coated steels from plain low carbon steels |
JPS6223977A (ja) * | 1985-07-22 | 1987-01-31 | Sumitomo Electric Ind Ltd | ブラスメツキ鋼線の製造方法 |
US4812371A (en) * | 1986-11-17 | 1989-03-14 | Nippon Steel Corporation | Zn-Al hot-dip galvanized steel sheet having improved resistance against secular peeling of coating |
JPS6421049A (en) * | 1987-07-15 | 1989-01-24 | Nippon Steel Corp | Hot dip plating method with zinc-iron alloy |
US5002837A (en) * | 1988-07-06 | 1991-03-26 | Kabushiki Kaisha Kobe Seiko Sho | Zn-Mg alloy vapor deposition plated metals of high corrosion resistance, as well as method of producing them |
JPH02194162A (ja) * | 1988-10-13 | 1990-07-31 | Kobe Steel Ltd | Zn―Mg合金めっき金属材料の製造方法 |
JPH02190463A (ja) * | 1989-01-20 | 1990-07-26 | Kawasaki Steel Corp | スポット溶接性に優れた溶融亜鉛系めっき鋼板の製造方法 |
US5284680A (en) * | 1992-04-27 | 1994-02-08 | Inland Steel Company | Method for producing a galvanized ultra-high strength steel strip |
US5439704A (en) * | 1993-10-27 | 1995-08-08 | Hunter Engineering Company, Inc. | Combined coil and blank powder coating |
DE10039375A1 (de) * | 2000-08-11 | 2002-03-28 | Fraunhofer Ges Forschung | Korrosionsgeschütztes Stahlblech und Verfahren zu seiner Herstellung |
JP2002241962A (ja) * | 2001-02-13 | 2002-08-28 | Sumitomo Metal Ind Ltd | 溶融Zn−Al−Mg合金めっき鋼板とその製造方法 |
JP3732141B2 (ja) * | 2001-11-09 | 2006-01-05 | 新日本製鐵株式会社 | 加工後の耐食性に優れた溶融亜鉛−Al系合金めっき鋼板及びその製造方法 |
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2004
- 2004-10-28 DE DE102004052482A patent/DE102004052482A1/de not_active Withdrawn
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2005
- 2005-10-24 BR BRPI0517630-1A patent/BRPI0517630A/pt not_active IP Right Cessation
- 2005-10-24 WO PCT/EP2005/011387 patent/WO2006045570A1/de active Application Filing
- 2005-10-24 JP JP2007538319A patent/JP2008518100A/ja active Pending
- 2005-10-24 CN CNA2005800371941A patent/CN101133178A/zh active Pending
- 2005-10-24 AU AU2005298896A patent/AU2005298896A1/en not_active Abandoned
- 2005-10-24 EP EP05796770A patent/EP1805342A1/de not_active Withdrawn
- 2005-10-24 US US11/577,981 patent/US20100040783A9/en not_active Abandoned
Non-Patent Citations (1)
Title |
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See references of WO2006045570A1 * |
Also Published As
Publication number | Publication date |
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CN101133178A (zh) | 2008-02-27 |
US20090098295A1 (en) | 2009-04-16 |
US20100040783A9 (en) | 2010-02-18 |
JP2008518100A (ja) | 2008-05-29 |
WO2006045570A1 (de) | 2006-05-04 |
BRPI0517630A (pt) | 2008-10-14 |
AU2005298896A1 (en) | 2006-05-04 |
DE102004052482A1 (de) | 2006-05-11 |
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