EP1802797B1 - Verfahren und anlage zum bedrucken von kettenfäden - Google Patents

Verfahren und anlage zum bedrucken von kettenfäden Download PDF

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Publication number
EP1802797B1
EP1802797B1 EP05761506A EP05761506A EP1802797B1 EP 1802797 B1 EP1802797 B1 EP 1802797B1 EP 05761506 A EP05761506 A EP 05761506A EP 05761506 A EP05761506 A EP 05761506A EP 1802797 B1 EP1802797 B1 EP 1802797B1
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EP
European Patent Office
Prior art keywords
chain
yarns
plant
ink
sensor
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP05761506A
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English (en)
French (fr)
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EP1802797A1 (de
Inventor
Claudio Gherardi
Francesco Azzimonti
Elisabetta Monti
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GHERTEX Srl
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GHERTEX Srl
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Priority to SI200530662T priority Critical patent/SI1802797T1/sl
Publication of EP1802797A1 publication Critical patent/EP1802797A1/de
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00—Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/0056—Treatment of selected parts of textile materials, e.g. partial dyeing of fabrics
    • D06B11/0059—Treatment of selected parts of textile materials, e.g. partial dyeing of fabrics by spraying
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00—Treatment of selected parts of textile materials, e.g. partial dyeing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00—Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/002—Treatment of selected parts of textile materials, e.g. partial dyeing of moving yarns
    • D06B11/0023—Treatment of selected parts of textile materials, e.g. partial dyeing of moving yarns by spraying or pouring

Definitions

  • the present invention relates to a method and plant for printing a chain of warp yarns, the method and plant of the invention in particular being arranged to form chine' fabrics.
  • Fabrics are composed of warp yarns woven with weft yarns; the totality of warp yarns (not yet woven with weft yarns) is known as a chain.
  • the chain i.e. the totality of warp yarns
  • the chain is previously fed to a loom to form a fabric presenting very few wefts per centimetre, to obtain a fabric presenting characteristics similar to those of a gauze.
  • This fabric is fed to a printing table of traditional type to form the desired decorative motifs thereon.
  • the weft yarns are extracted manually from the fabric in a discontinuous manner (usually 50 centimetres at a time), the released chain portions (i.e. The warp yarns) then being rewound on a warp beam.
  • the warp beam can then be fed to a loom to weave the previously printed chain yarns with new weft yarns (very densely) and form a fabric (by using the already printed chain and non-printed weft yarns).
  • This method is also discontinuous and manual (proceeding in about 50 centimetre steps), resulting in lengthy dead periods and consequent limited production.
  • the traditional method also requires the preparation of print frames or paper representing the motif to be transferred onto the chain by thermal transfer; the costs and commitment that this involves make the use of this method very uneconomical, especially for limited production.
  • the technical aim of the present invention is therefore to provide a method and plant for printing a chain of warp yarns which enable the stated drawbacks of the known art to be eliminated.
  • an object of the invention is to provide a method and plant with which chine' fabric can be produced more quickly and at lower cost than in the known art.
  • the method and plant of the invention do not require the formation of fabric to be printed by traditional methods, from which the weft yarns are then removed to obtain the printed chain.
  • Another object of the invention is to provide a method and plant which enable chine' fabric to be produced continuously and which present very high productivity.
  • a further object of the present invention is to provide a method and plant which do not require the provision of print frames or paper reproducing the motifs to be thermally transferred onto the chain.
  • the finished product obtained using the method and plant of the invention presents very high printing quality and, at the same time, high flexibility in producing the designs.
  • sampling can be organized easily and economically.
  • the method for printing a chain of warp yarns according to the invention consists of spraying ink onto the yarn chain by a plotter, to form a predetermined decorative motif thereon; "ink” means any colouring product which is sprayed onto the yarn chain.
  • the yarn chain After receiving the ink, the yarn chain is dried, whereas before spraying ink the yarn chain is impregnated with a product facilitating ink absorption.
  • the yarn chain is impregnated by immersion in a tank containing the impregnating product, after which the yarn chain is wrung out.
  • the yarn chain is dried.
  • the tension of the chain yarns is measured before their impregnation, their tensioning then being regulated to maintain it within a predetermined range.
  • Drying can also influence the chain yarn tension, consequently the method also includes measuring the tension of the chain yarns 3 after drying, and regulating their tensioning to maintain it within a predetermined range.
  • the tension is suitably regulated by monitoring the average of the tensions in the chain yarns, measured before impregnation and after drying.
  • the yarn chain is unwound from a support and sprayed with ink continuously.
  • the present invention also relates to a plant for printing a chain of warp yarns, which is indicated overall by the reference numeral 1.
  • the plant 1 comprises means 2 for feeding the yarn chain 3 to an ink application device 4 comprising an ink jet plotter as the ink spray means.
  • the plant 1 also comprises an adhesive belt 5 for carrying the yarn chain 3 to the plotter 4.
  • the adhesive belt 5 is operated by a first motor 6 connected to the plotter 4 which controls its operation, the plotter being connected to a plant operation control unit 7 and to a PC for transmitting all data relative to the printing (e.g. shapes and colours).
  • the plant also comprises a drying device 9, positioned downstream of the plotter 4, to dry the chain yarn portions leaving the plotter 4.
  • the product consists of a mixture prepared by mixing 100 grams/litre of urea with 20 grams/litre of liquid oxidol (anti-reducing agent) and 20 grams/litre of sodium bicarbonate. 10 litres of water are then prepared, to which there are added (by spray-mixing) 100 grams/litre of "alginate ALG 30 MB" produced by D.A.T.T. Chimica and 10 grams/litre of tersene hexaliquid sequestrant (in water) and 10 grams/litre of imbibing agent.
  • the product in a second embodiment (for acid dyes), consists of a mixture prepared by mixing 30 grams/litre of urea with 30 grams/litre of "acidat" produced by D.A.T.T. Chimica. 10 litres of water are then prepared, to which there are added (by spray-mixing) 100 grams/litre of "my program SN 12 AZ" and 10 grams/litre of "diaselin RB" imbibing agent.
  • the impregnation device 11 consists in the illustrated example of a tank containing the impregnating product into which the chain 3 is immersed.
  • the plant Downstream of the impregnation device 11 the plant presents a wringing device 12 for removing any excess of impregnating product from the yarns of the chain 3.
  • the wringing device 12 comprises a pair of rollers 13 rotatable by a second motor 14 connected to a unit 7 for controlling plant operation.
  • rollers 13 are mutually associated (at 15) along one of their generating lines, so that during operation the yarns of the chain 3 are pressed between the mutually associated rollers 13.
  • the plant To control the tension of the chain yarns the plant presents a first sensor 17 for measuring the tension of the yarns of the chain 3.
  • the sensor 17 is disposed upstream of the impregnation device 11 and is connected to the plant operation control unit 7.
  • the plant 1 also presents a drying device 19 positioned downstream of the wringing device 12; it dries the chain yarns after they have been immersed in the impregnating product, so that they are ready to receive the ink.
  • the plant 1 also presents a seconds sensor 20 for measuring the tension of the yarns of the chain 3; this second sensor 20 is positioned downstream of the drying device 19 and is connected to the plant operation control unit 7.
  • the feed means 2 comprise a support rotatable by a third motor 22; a beam 21 for feeding the chain yarns 3 to be processed can be housed on this support.
  • the third motor 22 is also connected to the plant operation control unit 7.
  • the plant also comprises a discharge support rotatable by a fourth motor 25, this discharge support housing a discharge beam on which the chain yarns 3 are rewound after processing.
  • the motor 25 is controlled by a sensor 26 disposed downstream of the plotter 4 (the motor 25 although independent presents friction deriving from the sensor 26 in the form of a feeler); the sensor 26 measures the tension of the chain yarns and regulates the speed of the motor 25 to maintain this tension within a predetermined range.
  • the chain yarns 3 are unwound from the beam 21 and pass by the first sensor 17 where their tension is measured; the chain yarns are then immersed in the tank 11 where they are impregnated with impregnating product.
  • the chain yarns 3 then pass between the rollers 13 where excess product is removed.
  • the chain yarns 3 then pass through the dryer 19 where they are perfectly dried and prepared to receive the ink.
  • the sensor 20 measures the tension of the chain yarns 3 and transmits it to the control unit to enable the control unit 7 to regulate the plant on the basis of the average of the tensions measured by the first and second sensor 17, 20.
  • the chain yarns 3 are then deposited on the adhesive belt 5 which guides them to the plotter 4 where they receive the ink, and after drying through the dryer 9 are rewound onto the beam 23.
  • the method of the invention enables just the chain yarns themselves to be printed continuously without the need to produce a fabric to be printed and from which the weft yarns have then to be removed to obtain the warp yarns (to be wound on a beam to obtain a printed chain).
  • the present invention also relates to software for controlling the plant printing the chain of warp yarns.
  • the software comprises means for controlling printing by the plotter 4 and regulator means for operating the first and second motor 6, 14 feeding the chain yarns 3 from the feed beam 21 to the plotter 4 in relation to the plotter printing speed.
  • the software also presents means for acquiring (from the first sensor 17 and from the second sensor 20) those values indicative of the tension of the chain yarns 3 and means for regulating the speed at least of the second motor 14, to maintain the tension measured by the first and second sensor 17, 20 within a predetermined range.
  • the software also comprises means for regulating the speed at least of the first motor 6 to maintain the tension measured by the second sensor 20 within a predetermined range.
  • Figure 2 shows an embodiment of the plant particularly suitable to be fed with pre-impregnated chain yarns. i.e. having undergone impregnation before being placed on the machine.
  • the plant comprises a yarn feeder composed of a yarn tension sensor 50 (for example equal to the sensor 20) connected to the motor 22 operating the beam 21, the adhesive belt 5, the plotter 4 and the dryer 9.
  • a yarn tension sensor 50 for example equal to the sensor 20
  • the second sensor 20 controls the chain yarns to ensure processing quality
  • the chain yarns 3 can be prepared by the device of Figure 3 , which comprises the impregnation device, the wringing device and the drying device, followed by rewinding the chain yarns on the discharge beam 23.
  • Figure 4 shows a different embodiment of the impregnation device; this comprises a roller over which the chain yarns slide; this roller is immersed in the impregnating product and entrains it during its rotation, to wet the chain yarns.
  • Figure 5 shows an embodiment of the impregnation device provided with fixed or movable spray nozzles which spray the impregnating product onto the chain yarns.
  • Figure 6 shows a beam about which the chain yarns are wound, and having a body provided with a plurality of through holes 28; this beam (with the chain yarns wound thereon)) is inserted into a suitable tank from which the impregnating product passes into the beam through the holes 28, then passes to the outside of the beam, so that in passing through the beam the impregnating product wets the chain yarns.
  • the method and plant of the invention can also be conveniently used together with the (known) delave' process.
  • the chain yarns are immersed in mixtures of cationic resins (of known type for the delave' process) and water.
  • the quantity of resin mixed with water can vary by ⁇ 50%; the utilization range is at least between 5 and 95 grams/litre (grams of resin per litre of water).
  • the impregnating product contained in the tank 11 is hence (in this case) the described cationic resin mixture.
  • the cationic resin mixture can also be used in the plant of Figure 3 to produce yarns to be wound on a beam.
  • the delave' impregnation enables particularly brilliant colours to be obtained on the yarns (and hence on the finished fabric), this being useful for forming particular decorative motifs (this is true especially for cotton and linen).
  • delave' treatment with cationic resins can be implemented on any type of fabric or yarn, as preparatory treatment allowing subsequent printing of fabrics or yarns by a plotter.
  • the delave' process can also be implemented directly during preparation of the yarn in dyeing machines to hence prepare a beam carrying chain yarns ready for printing (hence without the need to immerse the chain yarns in the bath containing the impregnation product).
  • the method and plant for printing a chain of warp yarns according to the invention are particularly advantageous because they enable chine' fabric to be produced very quickly at very low cost; they also enable a very limited production to be achieved quickly at low cost.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Coloring (AREA)
  • Apparatus For Radiation Diagnosis (AREA)

Claims (20)

  1. Verfahren zum Bedrucken einer Kette von Kettfäden (3), indem Druckfarbe auf die Kette der Fäden (3) gesprüht wird, um darauf ein vorbestimmtes dekoratives Motiv herzustellen, gekennzeichnet durch zumindest die folgenden Schritte:
    - Abwickeln der Kette von Kettfäden (3) von einem ersten Kettbaum (21),
    - Messen der Spannung der Kettenfäden (3) und Regulieren ihrer Spannung, um sie innerhalb eines vorbestimmten Bereichs zu halten, bevor die Kette bedruckt wird,
    - Absetzen der Kette von Kettfäden auf einem haftfähigen Band (5);
    - Führen der Kette von Kettfäden (3) zu einem Zeichengerät (4);
    - Sprühen der Druckfarbe mit dem Zeichengerät (4);
    - Wiederaufwickeln der Kette von Kettfäden (3) auf einen zweiten Kettbaum;
    - Führen des zweiten Kettbaums (23) zu einer Webmaschine, um die bedruckte Kette von Kettfäden (3) mit Schussfäden zu verweben, um ein Gewebe zu erhalten.
  2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass nach dem Aufnehmen der Druckfarbe die Fadenkette (3) getrocknet wird, und dass vor dem Sprühen der Druckfarbe die Fadenkette (3) mit einem Produkt imprägniert wird, welches eine Druckfarbeabsorption unterstützt.
  3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, dass die Fadenkette (3) durch Eintauchen in einen Behälter; welcher das Produkt enthält, imprägniert wird, dass die Fadenkette (3) nach dem Eintauchen ausgewrungen wird, und dass die Fadenkette (3) nach dem Wringen getrocknet wird.
  4. Verfahren nach Anspruch 3, dadurch gekennzeichnet, dass das Messen der Spannung der Kettenfäden vor ihrer Imprägnierung ausgeführt wird.
  5. Verfahren nach Anspruch 3, dadurch gekennzeichnet, dass das Messen der Spannung der Kettenfäden nach dem Trocknen durchgeführt wird.
  6. Anlage zum Bedrucken einer Kette von Kettfäden (3), umfassend ein Mittel zum Zuführen der Fadenkette (3) zu einer Druckfarbeaufbringungsvorrichtung, welche Mittel zum Sprühen von Druckfarbe auf die Kette umfasst, um ein vorbestimmtes Motiv abzudrucken, dadurch gekennzeichnet, dass sie umfasst:
    - einen ersten Kettbaum (21), wo die Kette von Kettfäden (3) aufgewickelt ist, wobei der erste Kettbaum (21) auf einer durch einen ersten Motor (22) drehbaren Halterung angeordnet ist,
    - einen ersten Sensor (20, 50), welcher dem ersten Kettbaum (21) nachgelagert und der Druckfarbenaufbringungsvorrichtung vorgelagert angeordnet ist, zum Messen der Spannung der Kettenfäden (3), um ihre Spannung zu steuern, um sie innerhalb eines vorbestimmten Bereichs zu halten,
    - ein haftfähiges Band (5) zum Befördern der Kette von Kettenfäden (3) zu dem Druckfarbensprühmittel, wobei das haftfähige Band durch mindestens einen zweiten Motor (6) antreibbar ist,
    - das Druckfarbensprühmittel, welches ein Zeichengerät (4) mit einer Art eines Druckfarbenstrahls umfasst,
    - einen zweiten Kettbaum (23), wo die Kette von Kettfäden (3) wieder aufgewickelt wird.
  7. Anlage nach Anspruch 6, dadurch gekennzeichnet, dass der erste Motor (22) und der zweite Motor (6) mit einer Anlagenbetriebssteuereinheit (7) verbunden sind.
  8. Anlage nach Anspruch 6, dadurch gekennzeichnet, dass der zweite Motor (6) mit dem Zeichengerät (4) verbunden ist, welches seinen Betrieb steuert, wobei das Zeichengerät mit einer Anlagenbetriebssteuereinheit (7) und mit einem PC zum Übertragen aller Daten bezüglich des Druckens verbunden ist.
  9. Anlage nach Anspruch 6, dadurch gekennzeichnet, dass sie eine Trockenvorrichtung (9) umfasst, welche dem Zeichengerät (4) nachgelagert angeordnet ist, um die Abschnitte der Kettenfäden (3) zu trocknen, welche das Zeichengerät (4) verlassen.
  10. Anlage nach Anspruch 6, weiterhin dadurch gekennzeichnet, dass sie dem Zeichengerät (4) vorgelagert eine Fadenkettenimprägniervorrichtung (11) zum Imprägnieren der Fäden mit einem Produkt, welches eine Druckfarbenabsorption unterstützt, umfasst, dass sie der Imprägniervorrichtung (11) nachgelagert eine Wringvorrichtung (12) zum Entfernen eines Überschusses des Produkts von den Kettenfäden (3) umfasst, und dass die Wringvorrichtung (12) ein Paar von Walzen (13) umfasst, welche durch mindestens einen dritten Motor (14) drehbar sind, welcher mit einer Anlagebetriebssteuereinheit (7) verbunden ist, wobei die Walzen (13) gegenseitig entlang einer ihrer bildenden Linien derart angeordnet sind, dass die Kettenfäden (3) während eines Betriebs zwischen den gegenseitig angeordneten Walzen (13) gepresst werden.
  11. Anlage nach Anspruch 10, dadurch gekennzeichnet, dass sie zum Messen der Spannung der Kettenfäden (3) einen zweiten Sensor (17) umfasst, welcher der Imprägniervorrichtung (11) vorgelagert angeordnet ist, wobei der zweite Sensor (17) mit einer Anlagenbetriebssteuereinheit (7) verbunden ist.
  12. Anlage nach Anspruch 10, dadurch gekennzeichnet, dass sie eine Trockenvorrichtung (19) umfasst, welche der Wringvorrichtung (12) nachgelagert angeordnet ist.
  13. Anlage nach Anspruch 12, dadurch gekennzeichnet, dass der erste Sensor (20) der Trockenvorrichtung (19) nachgelagert angeordnet ist.
  14. Anlage nach Anspruch 6, dadurch gekennzeichnet, dass der erste Sensor (20) mit der Anlagenbetriebssteuereinheit (7) verbunden ist.
  15. Anlage nach Anspruch 6, dadurch gekennzeichnet, dass der zweite Kettbaum (23) auf einer Halterung angeordnet ist, welche durch einen vierten Motor (25) drehbar ist, welcher mit einem Spannungsmesssensor (26) verbunden ist.
  16. Anlage nach Anspruch 10, dadurch gekennzeichnet, dass die Imprägniervorrichtung (11) eine Walze (13) umfasst, über welche die Kettenfäden (3) gleiten, wobei die Walze (13) in das Imprägnierprodukt eingetaucht wird und es bei einer Drehung mitnimmt, um die Kettenfäden (3) zu befeuchten.
  17. Anlage nach Anspruch 10, dadurch gekennzeichnet, dass die Imprägniervorrichtung (11) ortsfeste oder bewegliche Sprühdüsen umfasst, welche das Imprägnierprodukt auf die Kettenfäden (3) sprühen.
  18. Anlage nach Anspruch 6, dadurch gekennzeichnet, dass der erste Sensor (50) mit dem ersten Motor (22) verbunden ist.
  19. Anlage nach Anspruch 10, dadurch gekennzeichnet, dass sie eine Software zum Steuern der Anlage umfasst, welche Mittel zum Steuern eines Druckens mit dem Druckfarbensprühmittel und Reguliermittel zum Betreiben des ersten, des zweiten und des dritten Motors umfasst, welche die Kettenfäden (3) von dem ersten Kettbaum zu dem Druckfarbensprühmittel in Bezug auf die Druckgeschwindigkeit des Farbdrucksprühmittels führen, wobei die Anlage ferner einen zweiten Kettenfadenspannungssensor (17) umfasst, welcher der Imprägniervorrichtung (11) vorgelagert angeordnet ist, wobei die Software Mittel zum Erfassen von Werten von dem zweiten Sensor (17), welche die Spannung der Kettenfäden (3) anzeigen, und Mittel zum Regulieren der Geschwindigkeit von zumindest dem zweiten und dritten Motor darstellt, um die Spannung, welche von dem zweiten Sensor (17) gemessen wird, innerhalb eines vorbestimmten Bereichs zu halten.
  20. Anlage nach Anspruch 19, dadurch gekennzeichnet, dass die Software Mittel zum Erfassen von Werten von dem ersten Sensor (20), welche die Kettenfadenspannung anzeigen, und Mittel zum Regulieren der Geschwindigkeit von zumindest dem zweiten Motor umfasst, um die Spannung, welche von dem ersten Sensor gemessen wird, innerhalb eines vorbestimmten Bereichs zu halten.
EP05761506A 2005-05-19 2005-05-19 Verfahren und anlage zum bedrucken von kettenfäden Not-in-force EP1802797B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SI200530662T SI1802797T1 (sl) 2005-05-19 2005-05-19 Postopek in postrojenje za tiskanje niti vezne osnove

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IT2005/000283 WO2006123372A1 (en) 2005-05-19 2005-05-19 Method and plant for printing a chain of warp yarns

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Publication Number Publication Date
EP1802797A1 EP1802797A1 (de) 2007-07-04
EP1802797B1 true EP1802797B1 (de) 2009-01-28

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US (1) US20080314091A1 (de)
EP (1) EP1802797B1 (de)
JP (1) JP5265352B2 (de)
KR (1) KR101295391B1 (de)
CN (1) CN101203642A (de)
AT (1) ATE422001T1 (de)
CA (1) CA2608735A1 (de)
DE (1) DE602005012595D1 (de)
ES (1) ES2321635T3 (de)
PT (1) PT1802797E (de)
SI (1) SI1802797T1 (de)
WO (1) WO2006123372A1 (de)

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EP3070196B1 (de) * 2015-03-17 2019-05-08 Dyeberg S.p.A. Vorrichtung und verfahren zur veredelung von garnen
EP3633090A1 (de) * 2018-10-04 2020-04-08 Gitalia Jacquard S.r.l. Maschine und verfahren zur herstellung von bedruckten garnen
KR102434682B1 (ko) 2021-07-22 2022-08-23 한국기계연구원 파이버 기반 3d프린팅 연속 공정 장치 및 이를 이용한 기능성 원사 제조 방법
CN115139585B (zh) * 2022-06-23 2024-01-12 红豆集团无锡红豆童装有限公司 一种童装用亲肤面料及其制备工艺

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ATE422001T1 (de) 2009-02-15
KR101295391B1 (ko) 2013-08-09
WO2006123372A1 (en) 2006-11-23
US20080314091A1 (en) 2008-12-25
JP5265352B2 (ja) 2013-08-14
PT1802797E (pt) 2009-05-05
EP1802797A1 (de) 2007-07-04
ES2321635T3 (es) 2009-06-09
CN101203642A (zh) 2008-06-18
KR20080038277A (ko) 2008-05-06
CA2608735A1 (en) 2006-11-23
SI1802797T1 (sl) 2009-06-30
JP2008540867A (ja) 2008-11-20
DE602005012595D1 (de) 2009-03-19

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