Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
  • B01D71/06—Organic material
  • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
  • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
  • C08G8/28—Chemically modified polycondensates
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
  • B01D71/06—Organic material
  • B01D71/52—Polyethers
  • B01D71/522—Aromatic polyethers
  • B01D71/5222—Polyetherketone, polyetheretherketone, or polyaryletherketone
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
  • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
  • C08G65/48—Polymers modified by chemical after-treatment
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
  • C08J5/20—Manufacture of shaped structures of ion-exchange resins
  • C08J5/22—Films, membranes or diaphragms
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/10—Fuel cells with solid electrolytes
  • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
  • H01M8/1018—Polymeric electrolyte materials
  • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
  • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/10—Fuel cells with solid electrolytes
  • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
  • H01M8/1018—Polymeric electrolyte materials
  • H01M8/1041—Polymer electrolyte composites, mixtures or blends
  • H01M8/1044—Mixtures of polymers, of which at least one is ionically conductive
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/10—Fuel cells with solid electrolytes
  • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
  • H01M8/1018—Polymeric electrolyte materials
  • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
  • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/10—Fuel cells with solid electrolytes
  • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
  • H01M8/1018—Polymeric electrolyte materials
  • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
  • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
  • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

• the present invention relates to a process for the preparation of sulfonated polyaryl ether ketones, sulfur-containing polyaryl ether ketones which can be prepared by reaction with at least one alkanesulfonic acid, sulfonated polyaryl ether ketones which can be prepared by reaction of the sulfur-containing polyaryl ether ketones, crosslinked sulfonated polyaryl ether ketones, polymer blends containing the sulfonated polyaryl ether ketones and polymer electrolyte Fuel cell containing at least one polymer electrolyte membrane according to the invention, and generally the use of alkanesulfonic acids for the treatment of polyaryl ether ketones.
• Polyaryl ether ketones and their use are known in the prior art.
• polyether ether ketones from the group of polyaryl ether ketones are used as or in polymer electrolyte membranes.
• These polyether ether ketones are functionalized in such a way that they are capable of ion exchange and preferably of taking up and releasing protons.
• the - COOH and -SO 3 H groups in particular should be mentioned as functional groups.
• the prior art describes, for example, oleum, concentrated sulfuric acid or sulfur trioxide in a suitable organic solvent as sulfonation reagents for polyaryl ether ketones.
• Lithography using butyllithium, reaction with sulfur dioxide and subsequent oxidation with, for example, potassium permanganate is also known.
• DE 100 47 551 A1 discloses the use of sulfonated polyether ether ketones as proton-exchanging membranes, the use of the membranes preferably being described in direct methanol fuel cells.
• the sulfonation of the polyether ether ketone is carried out using sulfur trioxide, sulfuric acid or trimethylsilylsulfonyl chloride.
• EP 574 791 A2 describes the sulfonation of polyaryl ether ketones using sulfonic acid.
• the sulfonated polymer is used, among other things, in fuel cells as an electrolyte membrane.
• Nafion® is functionalized using gas phase sulfonation.
• JP 2001233974 A2 describes the sulfonation of films which in turn are produced from heat-resistant and imide bond-containing polymers and which are used as ion exchange membranes in fuel cells, for example.
• the sulfonation is achieved by immersing the film in sulfuric acid.
• JP 2001325970 A2 describes the use of alkanesulfonic acids such as, for example, methanesulfonic acid in electrolyte membranes which are used in fuel cells. There it is described that an already sulfonated polymer matrix is impregnated with methanesulfonic acid, phosphoric acid or sulfuric acid, which act as a liquid electrolyte, to produce the membranes.
• alkanesulfonic acids such as, for example, methanesulfonic acid in electrolyte membranes which are used in fuel cells.
• JP 2000294033 A2 discloses the production of proton-conducting DNA membranes which can be used in fuel cells, DNA membranes in polar organic solvents containing strong acids such as methanesulfonic acid, ethanesulfonic acid, phosphoric acid or sulfuric acid are immersed. This immersion loads the strong acid in the DNA membrane.
• DE-A 101 16 391 discloses sulfonated amorphous polyether ketone ketones (see PEKK). The sulfonation is carried out using diphenyl ether and benzenedicarboxylic acid derivative, preferably benzenedicarboxylic acid dichloride. According to DE-A 101 16 391, the degree of sulfonation of the amorphous polyether ketone ketones used is adjustable.
• the term “low degrees of sulfonation” means degrees of sulfonation of less than 60% and in particular less than or equal to 55%.
• the term “degree of sulfonation” relates to the number of sulfonic acid groups per repeating unit of the polyaryl ether ketone calculated from the sulfur content determined by means of elemental analysis.
• a “degree of sulfonation” of 100% here denotes a sulfur-containing polyaryl ether ketone, which has a “sulfonic acid group” per statistical unit on average.
• An exact setting of the “degree of sulfonation” means a setting which generally deviates from the desired degree of sulfonation by a maximum of +/- 5%, preferably a maximum of +/- 2%.
• One object of the present invention is to provide a method by which it is possible to achieve degrees of sulfonation over a wide range, for example in the range from 10 to 90%, and for example preferably also low degrees of sulfonation while maintaining simple parameters such as temperature, reaction time and Targeted concentration of sulfonation reagent.
• a targeted adjustment of the degree of sulfonation of polyaryl ether ketones is important, since polyaryl ether ketones with a very high degree of sulfonation are water-soluble and polyaryl ether ketones with a very low degree of sulfonation are poorly ion-conducting. For preferred use as membranes in fuel cells, however, it is desirable to provide water-insoluble but good ion-conducting polyaryl ether ketones. These can be obtained by a specific degree of sulfonation.
• the present invention relates to a process for the preparation of sulfonated polyaryl ether ketones, comprising the step (i):
• polyaryl ether ketones are used together in the process according to the invention, it is conceivable that only one of the polyaryl ether ketones is sulfonated. Two or more can also be sulfonated. In principle, all polyaryl ether ketones that are accessible to sulfonation via alkanesulfonic acids can be used as polyaryl ether ketones.
• Suitable polyaryl ether ketones are the polyaryl ether ketones of the formula I mentioned in EP-A 0 574 791, and polyaryl ether ketones of the formulas IV, V and VI which are preferably used in EP-A 0 574 791.
• the preferred polyaryl ether ketones used in the context of the present invention are polyether ether ketones, polyether ketones, polyether ketone ketones. Suitable compounds of these groups are known to the person skilled in the art. Polyether ether ketones and polyether ketones are further preferred.
• the PEEK TM and PEK TM polymer types (from Victrex plc), in particular PEEK TM 450P, PEEK TM 150P and PEK TM P22, are very particularly preferably used.
• Aliphatic sulfonic acids are generally suitable as alkane sulfonic acid in step (i). Alkanesulfonic acids of the general formula are preferred
• R is a hydrocarbon radical which can be branched or unbranched, having 1 to 12 carbon atoms, preferably having 1 to 6 carbon atoms, particularly preferably an unbranched hydrocarbon radical having 1 to 3 carbon atoms, very particularly preferably having 1 carbon atom, that is to say methanesulfonic acid
• the present invention also relates to a method as described above, which is characterized in that the alkanesulfonic acid Methanesulfonic acid and the at least one polyaryl ether ketone is a polyether ether ketone.
• At least one alkanesulfonic acid or a mixture of different alkanesulfonic acids is used as the solvent.
• the alkanesulfonic acid used in step (i) for the reaction with the polyaryl ether ketone is preferably used, particularly preferably methanesulfonic acid. This means that preferably the at least one alkanesulfonic acid itself acts as a solvent. Suitable alkanesulfonic acids are mentioned above.
• the at least one polyaryl ether ketone can be introduced into the reaction in all suitable forms.
• the polyether ether ketone is preferably used as a powder. If step (i) is carried out in one or more solvents, the polyaryl ether ketone can be dissolved or suspended in at least one alkanesulfonic acid before the reaction with the at least one alkanesulfonic acid and reacted with the at least one alkanesulfonic acid.
• the reaction according to (i) is preferably carried out at temperatures in the range from 15 to 120 ° C., particularly preferably 15 to 90 ° C., more preferably in the range from 25 to 70 ° C. and very particularly preferably in the range from 30 to 50 ° C. , Basically, it is conceivable to keep the temperature constant during the course of the reaction or to change it continuously or in discrete steps. The temperature is preferably kept constant in the course of the reaction.
• the reaction according to (i) is preferably carried out in a period in the range from 1 to 25 h, more preferably in the range from 2 to 20 h and particularly preferably in a period from 4 to 16 h. Accordingly, the present invention also relates to a process as described above, which is characterized in that the reaction according to (i) at temperatures in the range from 15 to 120 ° C., preferably from 15 to 90 ° C. in a period of from 2 to 20 hours is carried out.
• the reaction according to (i) will preferably be carried out under atmospheric pressure. In principle, it is also conceivable to set a pressure other than atmospheric pressure during the reaction. During the reaction, the pressure can be kept constant or change continuously or discretely.
• the molar ratio of the reactants according to (i) is essentially arbitrary.
• a molar ratio of polyaryl ether ketone to alkanesulfonic acid to be sulfonated is in the range from generally 1: 1 to 1: 1000, preferably from 1: 2 to 1: 500 and particularly preferably from 1:10 to 1: 300 chosen.
• the at least one alkanesulfonic acid is used in excess.
• alkanesulfonic acid is used simultaneously as a solvent, it is in a molar excess in relation to the polyaryl ether ketone.
• the reaction in step (i) is carried out in such a way that the alkanesulfonic acid, which is preferably used simultaneously as the solvent, is mixed with the polyaryl ether ketone in a reactor with stirring. It is stirred further under the reaction conditions mentioned above over the period mentioned above.
• the resulting sulfur-containing polyaryl ether ketone can be isolated by methods known to those skilled in the art. In a preferred embodiment of the process according to the invention, however, the sulfur-containing polyaryl ether ketone is not isolated, but rather is reacted with at least one further sulfonating agent to give sulfonated polyaryl ether ketones (II) in a further process step (ii).
• Process step (ii) can be carried out in a different reactor than process step (i) or - which is preferred - in the same reactor as process step (i).
• the present invention further relates to a sulfur-containing polyaryl ether ketone which can be produced by a process as described above.
• a “sulfur-containing polyaryl ether ketone” is understood to mean a polyaryl ether ketone that contains bound sulfur. This does not have to be present, or not exclusively, in the form of sulfonic acid groups.
• the sulfur content of the sulfur-containing polyaryl ether ketones is generally 0.10 to 8.7% by weight, preferably 4 to 5.7% by weight through elemental analysis.
• step (i) is followed by a sulfonation step (ii) in which the degree of sulfonation of the sulfur-containing polyaryl ether ketones obtained in (i) is adjusted.
• the present invention relates to a method as described above, which is characterized in that it comprises the additional step (ii):
• the present invention thus describes a process in which a polyaryl ether ketone and preferably a polyether ether ketone is functionalized with sulfur and sulfonated in at least two steps, the treatment with alkanesulfonic acid being a pretreatment step followed by a sulfonation step by means of which the step to be finally achieved Degree of sulfonation of the polyaryl ether ketone is achieved.
• the solution obtained according to (i) is preferably used directly in (ii). In a particularly preferred embodiment, this solution is brought into contact according to (ii) with oleum with an SO 3 content of 25% or highly concentrated (98% strength) sulfuric acid as the sulfonating agent.
• the present invention also relates to a process as described above, which is characterized in that oleum is used as the at least one sulfonating agent.
• reaction parameters of step (ii) can be adapted.
• a particular advantage of the process described in the context of the present invention can be seen in the fact that after pretreatment using alkanesulfonic acid according to (i), setting the reaction parameters which can be influenced comparatively easily, such as temperature, reaction time and concentration of the sulfonating agent, preferably oleum and highly concentrated (98% ige) sulfuric acid, the "degree of sulfonation" of the sulfonated polyaryl ether ketones is reproducibly adjustable in a wide range, in particular in the range from 10 to 90%.
• the different "degrees of sulfonation" of the polyaryl ether ketones are controlled in particular by the concentration of the sulfonating agent.
• sulfonated polyaryl ether ketones can be obtained which have a “degree of sulfonation” have in the range of 10 to 90%. Be further preferred
• the process according to the invention particularly preferably comprises steps (i) and (ii) sulfonated polyaryl ether ketones with low "degrees of sulfonation", particularly preferably with "degrees of sulfonation” of generally 10 to 55%, preferably 35 to 55%, particularly preferably 48 to 55 % or 35 to 40%.
• the temperature is preferably kept constant in the course of the reaction.
• the sulfonation according to (ii) is preferably carried out under atmospheric pressure.
• the sulfonating agent used is generally highly concentrated (98% strength) sulfuric acid, preferably used in a weight ratio with respect to the sulfur-containing polyaryl ether ketone obtained in (i) in the range from 2 to 10 and particularly preferably from 6 to 10, very particularly preferably from 8 to 9.
• the present invention therefore also relates to sulfonated polyaryl ether ketones, preferably sulfonated polyether ether ketones, which can be prepared by the process according to the invention comprising steps (i) and (ii). Preferred embodiments of the method according to the invention are mentioned above.
• the sulfonated polyaryl ether ketones according to the invention preferably sulfonated
• Polyetheretherketones have a polydispersity M / M n of generally ⁇ 3, preferably ⁇ 2.9, particularly preferably ⁇ 2.6.
• M w means that weight average molecular weight and M n the number average molecular weight.
• M w and M n were determined using size exclusion chromatography (SEC).
• polyaryl ether ketones according to the invention show reduced swelling behavior in water.
• the sulfonated polyaryl ether ketones according to the invention are distinguished by excellent stability of membranes containing the sulfonated polyaryl ether ketones according to the invention with respect to methanol.
• the sulfonated polyaryl ether ketones according to the invention are particularly suitable for use in methanol fuel cells.
• the sulfonated polyaryl ether ketone obtained in (ii) is obtained in solution, particularly preferably in the at least one alkanesulfonic acid used in step (i). It is basically conceivable, depending on
• Scope of the sulfonated polyaryl ether ketone to use this in solution A solvent exchange using a suitable method is also conceivable.
• the sulfonated polyaryl ether ketone can also be isolated from the solution by a suitable process known to the person skilled in the art and used in its field of application. This is preferably done
• the sulfonated polyaryl ether ketone generally being obtained in the form of powder, granules or fibers, depending on the isolation step.
• the present invention therefore furthermore relates to a process for the preparation of sulfonated polyaryl ether ketones, comprising the steps (i) and (ii):
• step (iii) adding sulfuric acid to the solution of the sulfonated polyaryl ether ketone obtained in step (ii), whereby a reaction mixture is formed which contains precipitated sulfonated polyaryl ether ketone;
• the precipitation generally takes place with 65 to 85% by weight, preferably 65 to 75% by weight, very particularly preferably 70% by weight sulfuric acid.
• the temperature during the precipitation in step (iii) is 0 to 40 ° C., preferably 0 to 30 ° C., particularly preferably 5 to 20 ° C. That means that Reaction mixture obtained in step (ii) is generally first cooled before adding the sulfuric acid according to step (iii).
• the sulfuric acid is generally slow, for example dropwise or by slow continuous feed or
• portionwise feed added, generally over a period of 20 to 120 minutes, preferably 20 to 100 minutes, particularly preferably 30 to 100 minutes.
• Sulfuric acid is preferably added until essentially no more product precipitates.
• step (iv) there is a further treatment of the sulfonated polyaryl ether ketone with water, preferably fully demineralized (VE) water.
• the temperature in step (iv) is generally 0 to 50 ° C, preferably 10 to 40 ° C, particularly preferably 20 to 40 ° C.
• the water is generally slow, e.g. added dropwise or by slow continuous feed or portionwise feed. In general, the water is added over a period of 10 to 120 minutes, preferably 20 to 90 minutes, particularly preferably 30 to 60 minutes. It has been found that sulfonated polyaryl ether ketone can be obtained by the two-stage treatment and can be processed further better than polyaryl ether ketone produced according to the prior art.
• the sulfonated polyaryl ether ketone obtained is separated from the supernatant solution by processes known to those skilled in the art, for example by filtration or decanation or centrifugation, washed, preferably with hot water and dried by processes known to those skilled in the art, for example at elevated temperature in vacuo.
• the sulfonated polyaryl ether ketones, preferably sulfonated polyether ether ketones, prepared according to the process according to the invention comprising a two-stage treatment are distinguished from the polyether ether ketones known in the prior art by a significantly improved swelling behavior in water.
• the sulfonated polyaryl ether ketones have a polydispersity index M w / M n of generally ⁇ 2.6. Mw and M n are determined as indicated above.
• the particle sizes of the polyaryl ether ketone produced by the process according to the invention comprising a two-stage treatment are smaller than the particle sizes of polyaryl ether ketone produced according to
• the present invention thus furthermore relates to sulfonated polyaryl ether ketones which can be prepared by the process according to the invention, comprising a two-stage treatment.
• Suitable starting materials for the preparation of the sulfonated polyaryl ether ketones according to the invention are mentioned above.
• sulfonated polyaryl ether ketones according to the present invention is, among others, use as a polymer electrolyte membrane, the sulfonated polyaryl ether ketone being able to be used as an ion-exchanging, preferably proton-exchanging polymer system in membranes for fuel cells in a preferred application.
• sulfonated polyaryl ether ketones according to the invention are to be understood as meaning all sulfonated polyaryl ether ketones mentioned above.
• the sulfonated polyaryl ether ketones isolated as described in (ii) above are dissolved in at least one suitable solvent and crosslinked using at least one suitable crosslinking reagent.
• Another subject of the present application is therefore a method for crosslinking sulfonated polyaryl ether ketones according to the present invention by reacting the sulfonated polyaryl ether ketones with at least one crosslinking reagent.
• Preferred polyaryl ether ketones are mentioned above.
• crosslinking reagents examples include epoxy crosslinking agents, such as, for example, the commercially available Denacole®.
• Suitable solvents in which the crosslinking can be carried out can be selected, inter alia, depending on the crosslinking reagent and the sulfonated polyaryl ether ketone.
• Preferred among others are polar aprotic solvents such as DMAc (N, N-dimethylacetamide), DMF (dimethylformamide), NMP (N-methylpyrrolidone) or mixtures thereof.
• the sulfonated polyaryl ether ketones produced according to the invention are preferably crosslinked with “degrees of sulfonation” in the range from 55 to 90% in order to be able to be used as swell-resistant and powerful fuel cell membranes.
• Sulfonated polyaryl ether ketones with “degrees of sulfonation” in the range of less than 60%, preferably less than 55% and particularly preferably less than 50%, with a decreasing “degree of sulfonation” in the uncrosslinked state have controllable swelling behavior when used as fuel cell membranes. However, the proton conductivity decreases. Above all, however, the sulfonated polyether ether ketones produced according to the invention surprisingly also have “degrees of sulfonation” of less than 50% especially in the range from 45% to less than 50%, as well as in the range from 35 to 40%, still outstanding performance as a fuel cell membrane.
• the present invention describes a method for producing a crosslinked sulfonated polyaryl ether ketone, preferably a polyether ether ketone, comprising the steps
• Another object of the present application is a crosslinked sulfonated polyaryl ether ketone which can be prepared according to the invention
• the sulfonated polyaryl ether ketones according to the present invention can be blended with one or more polymers. These polymers can also - like the polyaryl ether ketones themselves - are capable of proton exchange or generally of ion exchange. However, it is also possible to use polymers - optionally together with the abovementioned polymers - which have no functional groups which enable these polymers to ion exchange. Likewise, other inorganic and / or organic compounds, which can be liquid or solid, for example, can be used together with the sulfonated polyaryl ether ketones or the mixtures of the sulfonated polyaryl ether ketones with the polymers.
• At least one sulfonated polyaryl ether ketone with at least one polymer selected from polyether sulfones and polysulfones is preferably used.
• the present application therefore also relates to polymer blends comprising at least one sulfonated polyaryl ether ketone according to the present invention and further polymers, preferably at least one polyether sulfone, and, if appropriate, further inorganic and / or organic compounds.
• Sulfonated polyaryl ether ketones which are preferably used have already been mentioned above.
• the weight ratio between the at least one sulfonated polyaryl ether ketone and the at least one polymer, preferably at least one polyether sulfone or polysulfone, is generally 1:99 to 99: 1, preferably 2: 1 to 20: 1.
• the “degree of sulfonation” of the polyaryl ether ketone in the polymer blends according to the invention is preferably 45 to 80%, particularly preferably 45 to 55% or 35 to 40%.
• the inorganic and / or organic compounds used as further constituents are generally low molecular weight or polymeric solids, it being possible, for example, for them to be able to accept or release protons.
• Examples of these compounds which are capable of accepting or releasing protons are:
• Alumosilicates such as zeolites.
• Non-water-soluble organic carboxylic acids such as those with 5 to 30, preferably with 8 to 22, particularly preferably with 12 to 18 carbon atoms, with a linear or branched alkyl radical, which may have one or more further functional groups, the functional groups in particular being hydroxyl groups , CC double bonds or carbonyl groups are to be mentioned.
• carboxylic acids can be mentioned: valeric acid, isovaleric acid, 2-methyl butyric acid, pivalic, caproic, enanthic, caprylic, Pelergonklare, capric acid, undecanoic acid, lauric acid, tridecanoic acid, pentadecanoic, margaric acid, stearic acid, nonadecanoic, arachidic 5 behenic, lignoceric,
• Docosahexanoic acid or mixtures of two or more of them Docosahexanoic acid or mixtures of two or more of them.
• Polyphosphoric acids as described for example in Hollemann-Wiberg, op. Cit., Pp. 659 ff.
• crosslinking reagents can be selected which either crosslink only the sulfonated polyaryl ether ketones produced according to the invention with one another or only crosslink the other compounds with one another or at least one of the sulfonated polyaryl ether ketones produced according to the invention and at least one of the crosslinkable further compounds with one another network.
• non-functionalized polymer is understood to mean those polymers which are neither perfluorinated and sulfonated (ionomeric) polymers such as Nafion® or Flemion® nor to obtain adequate proton conductivity with suitable groups such as -SO 3 H, for example -Groups or -COOH groups are functionalized polymers.
• suitable groups such as -SO 3 H, for example -Groups or -COOH groups are functionalized polymers.
• these non-functionalized polymers which can be used in the context of the present invention, as long as they are stable within the scope of the fields of application in which the polymer systems according to the invention are used. If, according to a preferred use, these are used in fuel cells, then polymers are to be used which are thermally stable up to 100 ° C. and preferably up to 200 ° C. or higher and have the highest possible chemical stability. The following are preferably used:
• Aromatic backbone polymers such as polyimides, polysulfones, polyether sulfones such as Ultrason®, polybenzimidazoles.
• Polymers with a fluorinated backbone such as Teflon® or PVDF.
• Thermoplastic polymers or copolymers such as polycarbonates such as polyethylene carbonate,
• Phenol-formaldehyde resins polytrifluorostyrene, poly-2,6-diphenyl-l, 4-phenylene oxide, polyaryl ether sulfones, polyarylene ether sulfones, phosphonated
• Olefinic hydrocarbons such as ethylene, propylene, butylene, isobutene, propene, hexene or higher homologues, butadiene, cyclopentene, cyclohexene, norbornene,
• Acrylic acid or methacrylic acid esters such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, hexyl, octyl, decyl, dodecyl, 2-ethylhexyl, cyclohexyl, benzyl, trifluoromethyl, or hexafluoropropyl ester or tetrafluoropropyl acrylate or tetrafluoropropyl methacrylate.
• Vinyl ethers such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, hexyl, octyl, decyl, dodecyl, 2-ethylhexyl, cyclohexyl, benzyl, trifluoromethyl or hexafluoropropyl or
• non-functionalized polymers can be used in crosslinked or uncrosslinked form.
• the present invention also relates to a polymer system, as described above, which is characterized in that it comprises at least one non-functionalized polymer, preferably a polyether sulfone, other than sulfonated polyaryl ether ketones.
• sulfonated polyaryl ether ketone produced according to the invention can in principle be used in all suitable technical fields of application, use as an ion-exchanging polymer system in fuel cells, for example as an ionomer or polymer electrolyte membrane, is particularly preferred.
• use as a polymer electrolyte membrane is to be mentioned as a particularly preferred area of use.
• Such a membrane can generally be produced according to all suitable methods from the sulfonated polyaryl ether ketone according to the invention, the crosslinked sulfonated polyaryl ether ketone according to the invention or the polymer blends according to the invention.
• the polymer electrolyte membranes are preferably produced by one of the processes listed below.
• a preferably homogeneous casting solution or casting dispersion is prepared from the optionally crosslinked polyaryl ether ketones prepared according to the invention and, if appropriate, the further added compounds, and this casting solution is applied to at least one suitable carrier.
• suitable diluents for example by dipping, spincoating, roller coating, spray coating, printing in high, low, flat or screen printing processes or by extrusion, if appropriate, should this be necessary to apply to a carrier material. Further processing can be carried out in a conventional manner, for example by removing the diluent and curing the materials.
• Membranes are preferably produced which generally have a thickness of 5 to 500 ⁇ m, preferably 10 to 500 ⁇ m and particularly preferably a thickness of 10 to 200 ⁇ m.
• the present application therefore also relates to a polymer electrolyte membrane comprising at least one sulfonated polyaryl ether ketone according to the invention, at least one crosslinked polyaryl ether ketone according to the invention or a polymer blend according to the invention.
• Preferred embodiments of the sulfonated polyaryl ether ketone, the crosslinked sulfonated polyaryl ether ketone, the crosslinked sulfonated polyaryl ether ketone and the polymer blend have already been mentioned above.
• the present invention also describes a composite body which contains at least a first layer which contains a sulfonated polyaryl ether ketone according to the invention, a crosslinked sulfonated polyaryl ether ketone according to the invention or a polymer blend according to the invention, and also a composite body of this type which further comprises an electrically conductive catalyst layer (membrane-electrode unit) , Furthermore, this composite body can comprise one or more bipolar electrodes.
• the composite body can have one or more gas distribution layers, such as a carbon fleece, between the bipolar electrode and the electrically conductive catalyst layer.
• gas distribution layers such as a carbon fleece
• the present invention also relates to the use of a sulfonated polyaryl ether ketone according to the invention, a crosslinked sulfonated polyaryl ether ketone according to the invention or a polymer blend according to the invention as described above, as a polymer electrolyte membrane or as an ionomer, preferably as a polymer electrolyte membrane or as an ionomer in a fuel cell.
• Another object of the present application is a fuel cell containing at least one polymer electrolyte membrane according to the invention or an ionomer composed of a sulfonated according to the invention Polyaryl ether ketone, a crosslinked sulfonated polyaryl ether ketone according to the invention or a polymer blend according to the invention.
• Preferred components of the polymer electrolyte membrane, the ionomer and the fuel cell have already been mentioned above.
• the present invention also relates to the use of at least one alkanesulfonic acid, preferably methanesulfonic acid, for treating at least one polyaryl ether ketone, preferably polyether ether ketone, in a process for producing at least one polyaryl ether ketone, preferably sulfonated polyether ether ketone.
• at least one alkanesulfonic acid preferably methanesulfonic acid
• Polyaryl ether ketones are used to produce three different types of polymer electrolyte membranes.
• sulfonated PEEK was obtained by precipitation in ice water, subsequent washing with demineralized water and drying at 50 ° C. (48 h / water jet pump vacuum). Depending on the dropping height, the sulfur-containing PEEK was obtained in the form of needles, fibers, granules or powder. The sulfur content was determined by elemental analysis and gave a value of 5% sulfur, which corresponds to a calculated degree of sulfonation of 51.4%.
• This membrane showed a good performance in terms of current density voltage (FIG. 1) and current density performance (FIG. 2) in laboratory fuel cells.
• Example 3 Preparation of a sulfonated polyether ether ketone with a degree of sulfonation of 45 to 47%
• Example 3 7.5 g of the powder obtained according to Example 3 was dissolved in 42.5 g of N, N-dimethylacetamide at 150 ° C. and filtered. A clear solution of sulfonated polyether ether ketone in N, N-dimethylacetamide was obtained. The hot one Solution was poured onto a carrier material (for example PET film) in a uniform layer thickness using a doctor blade and flashed off at 40 ° C. for 3 hours.
• a carrier material for example PET film
• the membrane After drying overnight at 50 ° C. under vacuum (water jet pump), the membrane was detached from the carrier film and treated at 80 ° C. for 2 hours with one-molar sulfuric acid. After rinsing with demineralized water, a fuel cell test was carried out.
• the solution 2 obtained was cooled to 20 ° C. with ice water, and a precipitation solution 1 containing 1719.92 g of 70% strength by weight sulfuric acid was added dropwise over the course of 90 minutes, the temperature of the reaction mixture being ⁇ 20 ° C. , A precipitation solution 2, which contained 985.04 g of demineralized water, was then added dropwise over a period of 45 minutes, the temperature being kept at ⁇ 40.degree.
• the precipitated product was separated from the supernatant solution and washed with hot deionized water to a pH of 5. After drying at 80 ° C (12 h / water jet pump vacuum), the sulfonated polyether ether ketone was obtained in the form of powder.
• the sulfur content was determined by elemental analysis and gave a value of 5.1% sulfur, which corresponds to a calculated degree of sulfonation of 52.6%.

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