EP1516911A1 - Additif pour huile de graissage, composition d'huile de graissage le renfermant et procede de fabrication dudit additif - Google Patents

Additif pour huile de graissage, composition d'huile de graissage le renfermant et procede de fabrication dudit additif Download PDF

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Publication number
EP1516911A1
EP1516911A1 EP03736321A EP03736321A EP1516911A1 EP 1516911 A1 EP1516911 A1 EP 1516911A1 EP 03736321 A EP03736321 A EP 03736321A EP 03736321 A EP03736321 A EP 03736321A EP 1516911 A1 EP1516911 A1 EP 1516911A1
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EP
European Patent Office
Prior art keywords
lubricating oil
oil additive
mass
additive
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP03736321A
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German (de)
English (en)
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EP1516911A4 (fr
Inventor
Kazuhiro c/o Nippon Oil Corporation YAGISHITA
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Eneos Corp
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Nippon Oil Corp
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Publication of EP1516911A1 publication Critical patent/EP1516911A1/fr
Publication of EP1516911A4 publication Critical patent/EP1516911A4/fr
Ceased legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
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    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/06Metal salts
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    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/10Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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    • C10M159/12Reaction products
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    • C10M159/12Reaction products
    • C10M159/123Reaction products obtained by phosphorus or phosphorus-containing compounds, e.g. P x S x with organic compounds
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    • C10M2207/02Hydroxy compounds
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    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/043Ammonium or amine salts thereof
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
    • CCHEMISTRY; METALLURGY
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/063Ammonium or amine salts
    • CCHEMISTRY; METALLURGY
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/14Group 7
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/16Groups 8, 9, or 10
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/70Soluble oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/02Bearings
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • CCHEMISTRY; METALLURGY
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    • C10N2070/00Specific manufacturing methods for lubricant compositions

Definitions

  • the present invention relates to lubricating oil additives and more specifically to those which are obtained by making metal salts of phosphorus compounds insoluble or less soluble in lubricating base oils, soluble therein, lubricating oil compositions containing such additives, and a process for producing the additives and compositions.
  • the total aromatic content of mineral base oils is preferably 15 percent by mass or less, more preferably 10 percent by mass or less, further more preferably 5 percent by mass or less, and particularly preferably 2 percent by mass or less.
  • a base oil of a total aromatic content exceeding 15 percent by mass is not preferably because the oxidation stability of the resulting lubricating oil composition would be poor.
  • metal ratio used herein is represented by "valence of metal element x metal element content (mol%) / soap group content (mol%) in a metallic detergent" wherein the metal element is calcium, magnesium, or the like and the soap group is a sulfonic acid group, a salicylic acid group, or the like.
  • a lubricating oil composition containing 0.3 percent by mass or less, preferably 0.1 percent by mass or less, and more preferably 0.01 percent by mass or less of sulfur or containing substantially no sulfur can be obtained by decreasing the amount of a sulfur-containing additive or not using such an additive.
  • lubricating oil additives of the present invention were obtained using polybutenylsuccinimide-based ashless dispersant SA not modified with boric acid (molecular weight of polybutenyl group: 1300, nitrogen content: 1.6 mass%, boron content: 0 mass%, base number (hydrochloric acid method): 24 mgKOH/g) instead of the commercially available polybutenylsuccinimide-based ashless dispersant SB used in Examples 5 to 13 (additives E to M of the present invention). Lubricating oil compositions containing such additives had similar results to those achieved by the present invention as described above.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
EP03736321A 2002-06-28 2003-06-30 Additif pour huile de graissage, composition d'huile de graissage le renfermant et procede de fabrication dudit additif Ceased EP1516911A4 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2002191089 2002-06-28
JP2002191089 2002-06-28
PCT/JP2003/008337 WO2004003118A1 (fr) 2002-06-28 2003-06-30 Additif pour huile de graissage, composition d'huile de graissage le renfermant et procede de fabrication dudit additif

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EP1516911A1 true EP1516911A1 (fr) 2005-03-23
EP1516911A4 EP1516911A4 (fr) 2005-09-14

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EP03736321A Ceased EP1516911A4 (fr) 2002-06-28 2003-06-30 Additif pour huile de graissage, composition d'huile de graissage le renfermant et procede de fabrication dudit additif

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EP (1) EP1516911A4 (fr)
JP (1) JP4532268B2 (fr)
CN (2) CN102268317B (fr)
AU (1) AU2003244023A1 (fr)
WO (1) WO2004003118A1 (fr)

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WO2004020557A1 (fr) 2002-08-27 2004-03-11 Nippon Oil Corporation Composition lubrifiante
EP1686168A1 (fr) * 2003-10-09 2006-08-02 Idemitsu Kosan Co., Ltd. Additif pour huile lubrifiante et composition d'huile lubrifiante
EP1736529A4 (fr) * 2004-03-19 2010-02-24 Nippon Oil Corp Composition d'huile de graissage pour moteur diesel
RU2492217C2 (ru) * 2008-01-16 2013-09-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения смазывающей композиции

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US7563752B2 (en) 2002-08-05 2009-07-21 Nippon Oil Corporation Lubricating oil compositions
US7625847B2 (en) 2002-08-05 2009-12-01 Nippon Oil Corporation Lubricating oil compositions
US7645726B2 (en) * 2004-12-10 2010-01-12 Afton Chemical Corporation Dispersant reaction product with antioxidant capability
TWI423995B (zh) * 2005-06-22 2014-01-21 Nippon Polyurethane Kogyo Kk A reaction catalyst for forming a isocyanurate link, and a method for producing the modified polyisocyanate mixture containing the isocyanurate link thereof
JP5255220B2 (ja) * 2007-03-19 2013-08-07 Jx日鉱日石エネルギー株式会社 潤滑油組成物
CN101323809B (zh) * 2008-08-12 2010-12-22 上海海联润滑材料科技有限公司 盾构专用抗磨液压油
JP5537179B2 (ja) 2010-02-12 2014-07-02 Jx日鉱日石エネルギー株式会社 潤滑油用添加剤組成物
EP2714856A1 (fr) * 2011-05-26 2014-04-09 The Lubrizol Corporation Mélanges stabilisés contenant des modificateurs de frottement
JP5843406B2 (ja) * 2014-02-19 2016-01-13 株式会社オートネットワーク技術研究所 金属表面コーティング用組成物およびこれを用いた端子付き被覆電線
CN104194896A (zh) * 2014-08-30 2014-12-10 广西大学 一种蓖麻基高速齿轮泵油的组合物
CN104194895A (zh) * 2014-08-31 2014-12-10 广西大学 一种燃用油焦浆发动机油组合物
US9944879B2 (en) * 2014-10-08 2018-04-17 Afton Chemical Corporation Phosphorous-containing compounds and uses thereof
WO2016199567A1 (fr) * 2015-06-11 2016-12-15 株式会社オートネットワーク技術研究所 Composition de revêtement de surface métallique et fil électrique recouvert pourvu d'une borne
CN111032836A (zh) * 2017-07-14 2020-04-17 雪佛龙奥伦耐有限责任公司 含有不含硫-磷的锌化合物的润滑油组合物和用于防止或减少直喷式火花点火发动机中低速提前点火的方法
JP2023004315A (ja) * 2021-06-25 2023-01-17 Eneos株式会社 内燃機関用潤滑油組成物
CN116042288A (zh) * 2021-10-28 2023-05-02 中国石油化工股份有限公司 润滑脂组合物及其制备方法和嘧啶类化合物和脂肪醇的应用

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004020557A1 (fr) 2002-08-27 2004-03-11 Nippon Oil Corporation Composition lubrifiante
EP1544279A1 (fr) * 2002-08-27 2005-06-22 Nippon Oil Corporation Composition lubrifiante
EP1544279A4 (fr) * 2002-08-27 2007-03-07 Nippon Oil Corp Composition lubrifiante
US7696137B2 (en) 2002-08-27 2010-04-13 Nippon Oil Corporation Lubricating oil compositions
EP1686168A1 (fr) * 2003-10-09 2006-08-02 Idemitsu Kosan Co., Ltd. Additif pour huile lubrifiante et composition d'huile lubrifiante
EP1686168A4 (fr) * 2003-10-09 2008-06-04 Idemitsu Kosan Co Additif pour huile lubrifiante et composition d'huile lubrifiante
EP1736529A4 (fr) * 2004-03-19 2010-02-24 Nippon Oil Corp Composition d'huile de graissage pour moteur diesel
RU2492217C2 (ru) * 2008-01-16 2013-09-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения смазывающей композиции

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CN102268317A (zh) 2011-12-07
AU2003244023A1 (en) 2004-01-19
JPWO2004003118A1 (ja) 2005-10-27
JP4532268B2 (ja) 2010-08-25
WO2004003118A1 (fr) 2004-01-08
EP1516911A4 (fr) 2005-09-14
CN1671828A (zh) 2005-09-21
CN1671828B (zh) 2012-05-30
CN102268317B (zh) 2013-09-18

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