EP1490917A4 - BATTERIES COMPRISING ALKALI TRANSITION METAL PHOSPHATES AND PREFERRED ELECTROLYTES - Google Patents

BATTERIES COMPRISING ALKALI TRANSITION METAL PHOSPHATES AND PREFERRED ELECTROLYTES

Info

Publication number
EP1490917A4
EP1490917A4 EP03721492A EP03721492A EP1490917A4 EP 1490917 A4 EP1490917 A4 EP 1490917A4 EP 03721492 A EP03721492 A EP 03721492A EP 03721492 A EP03721492 A EP 03721492A EP 1490917 A4 EP1490917 A4 EP 1490917A4
Authority
EP
European Patent Office
Prior art keywords
transition metal
mixtures
batteries
alkali
metal phosphates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03721492A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1490917A1 (en
Inventor
James Pugh
M Yazid Saidi
Haitao Huang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valence Technology Inc
Original Assignee
Valence Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=28673938&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1490917(A4) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Valence Technology Inc filed Critical Valence Technology Inc
Publication of EP1490917A1 publication Critical patent/EP1490917A1/en
Publication of EP1490917A4 publication Critical patent/EP1490917A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/582—Halogenides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/56—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
EP03721492A 2002-04-03 2003-03-27 BATTERIES COMPRISING ALKALI TRANSITION METAL PHOSPHATES AND PREFERRED ELECTROLYTES Withdrawn EP1490917A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US116276 2002-04-03
US10/116,276 US20030190527A1 (en) 2002-04-03 2002-04-03 Batteries comprising alkali-transition metal phosphates and preferred electrolytes
PCT/US2003/009634 WO2003085757A1 (en) 2002-04-03 2003-03-27 Batteries comprising alkali-transition metal phosphates and preferred electrolytes

Publications (2)

Publication Number Publication Date
EP1490917A1 EP1490917A1 (en) 2004-12-29
EP1490917A4 true EP1490917A4 (en) 2008-12-03

Family

ID=28673938

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03721492A Withdrawn EP1490917A4 (en) 2002-04-03 2003-03-27 BATTERIES COMPRISING ALKALI TRANSITION METAL PHOSPHATES AND PREFERRED ELECTROLYTES

Country Status (8)

Country Link
US (2) US20030190527A1 (ko)
EP (1) EP1490917A4 (ko)
JP (1) JP4758610B2 (ko)
KR (1) KR101107423B1 (ko)
CN (1) CN1650450B (ko)
AU (1) AU2003224801A1 (ko)
CA (1) CA2479790C (ko)
WO (1) WO2003085757A1 (ko)

Families Citing this family (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7524584B2 (en) * 2000-04-27 2009-04-28 Valence Technology, Inc. Electrode active material for a secondary electrochemical cell
US8057769B2 (en) * 2000-04-27 2011-11-15 Valence Technology, Inc. Method for making phosphate-based electrode active materials
US8367036B2 (en) * 2000-04-27 2013-02-05 Valence Technology, Inc. Alkali/transition metal halo-and hydroxy-phosphates and related electrode active materials
US6964827B2 (en) * 2000-04-27 2005-11-15 Valence Technology, Inc. Alkali/transition metal halo- and hydroxy-phosphates and related electrode active materials
US6777132B2 (en) * 2000-04-27 2004-08-17 Valence Technology, Inc. Alkali/transition metal halo—and hydroxy-phosphates and related electrode active materials
CA2455540C (en) * 2002-12-19 2012-08-28 Valence Technology, Inc. Electrode active material and method of making the same
JP4192635B2 (ja) * 2003-03-04 2008-12-10 ソニー株式会社 リチウムイオン二次電池用電解質およびそれを用いたリチウムイオン二次電池
US7041239B2 (en) * 2003-04-03 2006-05-09 Valence Technology, Inc. Electrodes comprising mixed active particles
US20070141468A1 (en) * 2003-04-03 2007-06-21 Jeremy Barker Electrodes Comprising Mixed Active Particles
WO2005031954A2 (en) 2003-09-22 2005-04-07 Valence Technology, Inc. Electrical systems, power supply apparatuses, and power supply operations methods
CA2543851C (en) * 2003-10-27 2014-05-06 Mitsui Engineering & Shipbuilding Co., Ltd. Cathode material for secondary battery and method for producing the material for secondary battery
FR2864348B1 (fr) * 2003-12-18 2006-03-10 Commissariat Energie Atomique Accumulateur au lithium presentant a la fois un potentiel electrique et une capacite d'insertion du lthium eleves.
US7008726B2 (en) * 2004-01-22 2006-03-07 Valence Technology, Inc. Secondary battery electrode active materials and methods for making the same
US20050163699A1 (en) * 2004-01-23 2005-07-28 Jeremy Barker Fluorosulfate-based electrode active materials and method of making the same
US7719227B2 (en) 2004-02-13 2010-05-18 Valence Technology, Inc. Electrical energy supply methods and electrical energy power supplies
JP5043290B2 (ja) * 2004-06-08 2012-10-10 パナソニック株式会社 非水電解質二次電池用正極活物質、その製造方法、およびそれを用いた非水電解質二次電池
JP4703985B2 (ja) * 2004-08-02 2011-06-15 住友大阪セメント株式会社 リチウム電池用正極活物質の製造方法
US7205067B2 (en) * 2005-02-08 2007-04-17 Valence Technology, Inc. Method and apparatus for dissipation of heat generated by a secondary electrochemical cell
US7700236B2 (en) * 2005-09-09 2010-04-20 Aquire Energy Co., Ltd. Cathode material for manufacturing a rechargeable battery
US8323832B2 (en) 2005-08-08 2012-12-04 A123 Systems, Inc. Nanoscale ion storage materials
US8158090B2 (en) 2005-08-08 2012-04-17 A123 Systems, Inc. Amorphous and partially amorphous nanoscale ion storage materials
US7939201B2 (en) 2005-08-08 2011-05-10 A123 Systems, Inc. Nanoscale ion storage materials including co-existing phases or solid solutions
KR100901535B1 (ko) * 2005-10-26 2009-06-08 주식회사 엘지화학 수명 특성이 향상된 이차전지
US7906238B2 (en) * 2005-12-23 2011-03-15 3M Innovative Properties Company Silicon-containing alloys useful as electrodes for lithium-ion batteries
US7723958B2 (en) 2006-03-31 2010-05-25 Valence Technology, Inc. Battery charge indication methods, battery charge monitoring devices, rechargeable batteries, and articles of manufacture
US20070298317A1 (en) * 2006-05-09 2007-12-27 Ralph Brodd Secondary electrochemical cell with increased current collecting efficiency
WO2008013315A1 (fr) * 2006-07-28 2008-01-31 Sumitomo Chemical Company, Limited Phosphate métallique et sa méthode de production
JP5127179B2 (ja) * 2006-07-31 2013-01-23 古河電池株式会社 リチウム二次電池正極活物質の製造方法
EP2266160A4 (en) 2006-10-17 2010-12-29 Valence Technology Inc METHOD AND DEVICE FOR MONITORING AND CONTROLLING AN ELECTROCHEMICAL CELL
US20080261113A1 (en) * 2006-11-15 2008-10-23 Haitao Huang Secondary electrochemical cell with high rate capability
US8324868B2 (en) * 2007-08-24 2012-12-04 Valence Technology, Inc. Power source with temperature sensing
TWI466370B (zh) * 2008-01-17 2014-12-21 A123 Systems Inc 鋰離子電池的混合式金屬橄欖石電極材料
CN101489351B (zh) * 2008-01-18 2012-10-31 郑州泰达电子材料科技有限公司 线路板埋入型固体电解电容器以及使用该线路板埋入型固体电解电容器的线路板
JP5370937B2 (ja) * 2008-01-28 2013-12-18 シャープ株式会社 正極活物質、正極及び非水二次電池
CA2720600C (en) * 2008-04-07 2017-09-12 Jay Whitacre Sodium ion based aqueous electrolyte electrochemical secondary energy storage device
CN101339992B (zh) * 2008-08-04 2010-06-16 清华大学 锂离子电池正极材料硅酸钒锂的制备方法
JP5107213B2 (ja) * 2008-11-18 2012-12-26 シャープ株式会社 正極活物質、正極及び非水二次電池
ATE543227T1 (de) * 2008-12-30 2012-02-15 Hengdian Group Dmegc Magnetic Ltd Company Lithium-eisen-phosphatbatterieelektrode und herstellungsverfahren dafür
JP5234862B2 (ja) 2009-05-22 2013-07-10 シャープ株式会社 正極活物質、正極及び非水二次電池
WO2011025823A1 (en) 2009-08-25 2011-03-03 A123 Systems, Inc. Mixed metal olivine electrode materials for lithium ion batteries having improved specific capacity and energy density
JP2011071114A (ja) * 2009-08-28 2011-04-07 Equos Research Co Ltd リチウムイオン電池用正極活物質及びそれを用いたリチウムイオン電池
JP5551019B2 (ja) * 2009-09-02 2014-07-16 シャープ株式会社 正極活物質、正極及び非水二次電池
WO2011035235A1 (en) 2009-09-18 2011-03-24 A123 Systems, Inc. Ferric phosphate and methods of preparation thereof
CN102246333A (zh) * 2009-09-18 2011-11-16 松下电器产业株式会社 非水电解质二次电池用电极及其制造方法以及非水电解质二次电池
US9660267B2 (en) 2009-09-18 2017-05-23 A123 Systems, LLC High power electrode materials
US8603367B2 (en) * 2009-09-24 2013-12-10 Valence Technology, Inc. Manganese phosphates and related electrode active materials
WO2011038499A1 (en) * 2009-10-02 2011-04-07 Linda Faye Nazar Sodium metal phosphate olivines for sodium-ion batteries
CN106099039A (zh) * 2010-04-01 2016-11-09 株式会社Lg化学 二次电池用正极、锂二次电池以及中型和/或大型电池组
US9373844B2 (en) 2010-07-01 2016-06-21 Sharp Kabushiki Kaisha Positive electrode active substance containing lithium-containing metal oxide
JP5271975B2 (ja) 2010-07-01 2013-08-21 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
CN103069624B (zh) 2010-07-01 2016-06-22 夏普株式会社 正极活性材料、正极和非水二次电池
JP5132727B2 (ja) 2010-07-12 2013-01-30 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
KR101219395B1 (ko) * 2010-07-15 2013-01-11 전자부품연구원 리튬이차전지용 양극재료 및 그의 제조방법
US20120138867A1 (en) * 2010-11-11 2012-06-07 Phostech Lithium Inc. Carbon-deposited alkali metal oxyanion electrode material and process for preparing same
WO2012088509A1 (en) 2010-12-23 2012-06-28 Wildcat Discovery Technologies, Inc. Lithium-ion battery materials with improved properties
WO2012148569A2 (en) 2011-03-01 2012-11-01 Aquion Energy Inc. Profile responsive electrode ensemble
US8298701B2 (en) 2011-03-09 2012-10-30 Aquion Energy Inc. Aqueous electrolyte energy storage device
JP5451671B2 (ja) 2011-03-23 2014-03-26 シャープ株式会社 正極活物質、正極及び非水系二次電池
JP5451681B2 (ja) 2011-05-09 2014-03-26 シャープ株式会社 正極活物質、正極及び非水系二次電池
JP5731278B2 (ja) * 2011-05-24 2015-06-10 株式会社オハラ 全固体リチウムイオン電池
US8137830B2 (en) 2011-07-19 2012-03-20 Aquion Energy, Inc. High voltage battery composed of anode limited electrochemical cells
US8945751B2 (en) 2011-07-19 2015-02-03 Aquion Energy, Inc. High voltage battery composed of anode limited electrochemical cells
KR101316066B1 (ko) * 2011-09-27 2013-10-11 전자부품연구원 이차전지용 양극재료 및 이의 제조방법
JP5818086B2 (ja) * 2011-10-14 2015-11-18 トヨタ自動車株式会社 二次電池およびその製造方法
WO2013108570A1 (ja) * 2012-01-17 2013-07-25 シャープ株式会社 正極活物質、正極及び非水系二次電池
CN102569889A (zh) * 2012-02-06 2012-07-11 深圳新宙邦科技股份有限公司 锂离子电池非水电解液与锂离子电池
US8652672B2 (en) 2012-03-15 2014-02-18 Aquion Energy, Inc. Large format electrochemical energy storage device housing and module
CN102664267B (zh) * 2012-04-13 2015-04-22 浙江工业大学 共掺杂的磷酸钒锂正极材料及其应用
KR101946012B1 (ko) * 2012-07-11 2019-02-08 삼성전자주식회사 리튬 이온 전도체, 이를 포함한 고체 전해질, 이를 포함한 활물질 및 상기 리튬 이온 전도체를 포함한 리튬 전지
US8945756B2 (en) 2012-12-12 2015-02-03 Aquion Energy Inc. Composite anode structure for aqueous electrolyte energy storage and device containing same
US9356291B2 (en) 2013-12-04 2016-05-31 The United States Of America, As Represented By The Secretary Of The Army High voltage lithium ion positive electrode material
WO2015153485A1 (en) 2014-04-01 2015-10-08 The Research Foundation For The State University Of New York Electrode materials for group ii cation-based batteries
KR102393748B1 (ko) * 2014-05-20 2022-05-03 가번먼트 오브 더 유나이티드 스테이츠, 에즈 리프리젠티드 바이 더 시크리터리 오브 더 아미 고전압 리튬 이온 양극 물질
CN105742698B (zh) * 2014-12-12 2018-02-13 中国科学院物理研究所 Nasicon 型钠离子固体电解质材料及其制备方法
US10326164B2 (en) 2015-03-03 2019-06-18 Ut-Battelle, Llc High-conduction GE substituted LiAsS4 solid electrolyte
CN106058250A (zh) * 2016-07-22 2016-10-26 天津巴莫科技股份有限公司 一种氟化富锂磷酸钒锂正极材料
US10826145B2 (en) 2017-02-10 2020-11-03 General Electric Company Electrochemical cell for use in high temperature metal-air battery
CN108390026B (zh) * 2018-01-22 2020-07-14 李慧 一种笼式正极材料及其制备方法和应用
US11251430B2 (en) 2018-03-05 2022-02-15 The Research Foundation For The State University Of New York ϵ-VOPO4 cathode for lithium ion batteries
US12040446B2 (en) * 2018-03-26 2024-07-16 Toyota Motor Europe Solid electrolyte material for solid state batteries, solid electrolyte and solid state battery
US11862797B2 (en) 2020-02-19 2024-01-02 Ningde Amperex Technology Limited Cathode, electrochemical device and electronic device including same
US12062781B2 (en) 2020-02-21 2024-08-13 Ningde Amperex Technology Limited Cathode material and electrochemical device including the same
US11515566B2 (en) 2020-04-26 2022-11-29 International Business Machines Corporation Liquid cathode formulation for rechargeable metal halide battery
WO2021219320A1 (en) * 2020-04-26 2021-11-04 International Business Machines Corporation Liquid cathode formulation for rechargeable metal halide battery
WO2023206397A1 (zh) * 2022-04-29 2023-11-02 宁德时代新能源科技股份有限公司 二次电池、电池模块、电池包和用电装置

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998012761A1 (en) * 1996-09-23 1998-03-26 Valence Technology, Inc. Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery
US5908716A (en) * 1997-04-15 1999-06-01 Valence Technology, Inc. Lithium--containing sulfates, method of preparation and uses thereof
US5910382A (en) * 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
WO2000001024A1 (en) * 1998-06-26 2000-01-06 Valence Technology, Inc. Lithium-containing silicon/phosphates, method of preparation, and uses thereof
US6085015A (en) * 1997-03-25 2000-07-04 Hydro-Quebec Lithium insertion electrode materials based on orthosilicate derivatives
WO2000057505A1 (en) * 1999-03-23 2000-09-28 Valence Technology, Inc. Lithium-containing phosphate active materials
US6203946B1 (en) * 1998-12-03 2001-03-20 Valence Technology, Inc. Lithium-containing phosphates, method of preparation, and uses thereof
WO2001084655A1 (en) * 2000-04-27 2001-11-08 Valence Technology, Inc. Lithium metal fluorophosphate materials and preparation thereof
US6447951B1 (en) * 1996-09-23 2002-09-10 Valence Technology, Inc. Lithium based phosphates, method of preparation, and uses thereof

Family Cites Families (97)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049891A (en) * 1976-06-21 1977-09-20 Massachusetts Institute Of Technology Compositions for fast alkali-metal-ion transport
US4194062A (en) * 1978-07-27 1980-03-18 Bell Telephone Laboratories, Incorporated Rechargeable dichalcogenide cell
IT1131478B (it) * 1980-05-13 1986-06-25 Consiglio Nazionale Ricerche Pile ricaricabili ad elevata energia specifica con anodo e catodo a intercalazione
US4477541A (en) * 1982-12-22 1984-10-16 The United States Of America As Represented By The United States Department Of Energy Solid electrolyte structure
CA1265580A (en) * 1985-05-10 1990-02-06 Akira Yoshino Secondary battery
US4840858A (en) * 1987-06-12 1989-06-20 Sanyo Electric Co., Ltd. Secondary cell
US4792504A (en) * 1987-09-18 1988-12-20 Mhb Joint Venture Liquid containing polymer networks as solid electrolytes
US4830939B1 (en) * 1987-10-30 1996-10-08 Mhb Joint Venture Radiation cured solid electrolytes and electrochemical devices employing the same
US5037712A (en) * 1987-10-30 1991-08-06 Ultracell, Inc. Preparation of radiation cured solid electrolytes and electrochemical devices employing the same
US4990413A (en) * 1989-01-18 1991-02-05 Mhb Joint Venture Composite solid electrolytes and electrochemical devices employing the same
US4925752A (en) * 1989-03-03 1990-05-15 Fauteux Denis G Solid state electrochemical cell having porous cathode current collector
US5011501A (en) * 1989-04-26 1991-04-30 Shackle Dale R Process for making a solid state cell
US5028500A (en) * 1989-05-11 1991-07-02 Moli Energy Limited Carbonaceous electrodes for lithium cells
US4935317A (en) * 1989-06-21 1990-06-19 Mhb Joint Venture Method for producing solid state electrochemical laminar cell utilizing cathode rolling step
CA2052317C (en) * 1990-09-28 1995-09-26 Norio Takami Nonaqueous electrolyte secondary battery
US5130211A (en) * 1990-10-24 1992-07-14 Her Majesty The Queen In Right Of The Provence Of British Columbia Electrolyte solution sequestering agents for electrochemical cells having carbonaceous electrodes
US5686138A (en) * 1991-11-12 1997-11-11 Sanyo Electric Co., Ltd. Lithium secondary battery
US5252413A (en) * 1992-04-07 1993-10-12 Eic Laboratories, Inc. Solid polymer electrolyte lithium batteries
CA2096386A1 (en) * 1992-05-18 1993-11-19 Masahiro Kamauchi Lithium secondary battery
EP0573266B1 (en) * 1992-06-01 1999-12-08 Kabushiki Kaisha Toshiba Lithium secondary battery and method of manufacturing carbonaceous material for negative electrode of the battery
US5262253A (en) * 1992-07-22 1993-11-16 Valence Technology, Inc. Solid electrolytes derived by polymerization of vinyl sulfonate polyalkylene oxides
US5508130A (en) * 1992-07-22 1996-04-16 Golovin; Milton N. Solid electrolytes containing LiN(SO2 CF3)2 and a triglyme-carbonate solvent, and electrochemical cells produced therefrom
US5620810A (en) * 1992-07-22 1997-04-15 Valence Technology, Inc. Solid, solvent-containing electrolytes and electrolytic cells produced therefrom
US5538811A (en) * 1992-07-23 1996-07-23 Matsushita Electric Industrial Co., Ltd. Ionic conductive polymer electrolyte
US5300373A (en) * 1992-09-11 1994-04-05 Valence Technology, Inc. Electrochemical cell stack and method of making an electrochemical cell stack
US5326653A (en) * 1992-10-29 1994-07-05 Valence Technology, Inc. Battery unit with reinforced current collector tabs and method of making a battery unit having strengthened current collector tabs
US5418090A (en) * 1993-02-17 1995-05-23 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
US5460904A (en) * 1993-08-23 1995-10-24 Bell Communications Research, Inc. Electrolyte activatable lithium-ion rechargeable battery cell
US5540741A (en) * 1993-03-05 1996-07-30 Bell Communications Research, Inc. Lithium secondary battery extraction method
US5418091A (en) * 1993-03-05 1995-05-23 Bell Communications Research, Inc. Polymeric electrolytic cell separator membrane
US5240790A (en) * 1993-03-10 1993-08-31 Alliant Techsystems Inc. Lithium-based polymer electrolyte electrochemical cell
US5411820A (en) * 1993-06-08 1995-05-02 Valence Technology, Inc. Solid, glyme-containing electrolytes including ion salt derivatives and electrolytic cells produced therefrom
US5541020A (en) * 1993-07-22 1996-07-30 Golovin; Milton N. Compositions and methods for improving the cumulative capacity of solid, secondary electrolytic cells
US5435054A (en) * 1993-11-15 1995-07-25 Valence Technology, Inc. Method for producing electrochemical cell
US5399447A (en) * 1993-12-06 1995-03-21 Valence Technology, Inc. Acidity reduction of adhesion promoter layer and electrolytic cells produced therefrom
US5463179A (en) * 1993-12-06 1995-10-31 Chaloner-Gill; Benjamin Solid electrolyte obtained by the polymerization of diacrylate monomer having a rigid alkane segment
US5482795A (en) * 1994-05-25 1996-01-09 Chaloner-Gill; Benjamin Solid electrolyte utilizing a polymeric matrix obtained by the polymerization of a substituted allylic chloroformate
US5514490A (en) * 1994-08-30 1996-05-07 Industrial Technology Research Institute Secondary lithium battery using a new layered anode material
JPH08153541A (ja) * 1994-11-28 1996-06-11 Mitsubishi Cable Ind Ltd リチウム二次電池
US5721070A (en) * 1995-04-13 1998-02-24 Shackle; Dale R. Alkali metal ion battery electrode material
US5695893A (en) * 1995-05-18 1997-12-09 Nippon Telegraph And Telephone Corporation Material for use in the positive electrodes of lithium batteries, its manufacture, and lithium batteries incorporating this material
US5712059A (en) * 1995-09-26 1998-01-27 Valence Technology, Inc. Carbonaceous electrode and compatible electrolyte solvent
US5660948A (en) * 1995-09-26 1997-08-26 Valence Technology, Inc. Lithium ion electrochemical cell
US5643695A (en) * 1995-09-26 1997-07-01 Valence Technology, Inc. Carbonaceous electrode and compatible electrolyte
JP3460407B2 (ja) * 1995-09-27 2003-10-27 ソニー株式会社 非水電解液二次電池
JP3484003B2 (ja) 1995-11-07 2004-01-06 日本電信電話株式会社 非水電解質二次電池
JP3523397B2 (ja) 1995-11-07 2004-04-26 日本電信電話株式会社 非水電解質二次電池
MY123761A (en) * 1995-11-15 2006-06-30 Asahi Kasei Emd Corp Hybrid polymeric electrolyte and non-aqueous electrochemical device comprising the same
EP1124158A1 (en) * 1996-02-26 2001-08-16 Matsushita Electric Industrial Co., Ltd. Pattern forming material and pattern forming method
US5700298A (en) * 1996-03-15 1997-12-23 Valence Technology, Inc. Carbon anode for lithium ion electrochemical cell
US6514640B1 (en) * 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
US6103419A (en) * 1996-09-06 2000-08-15 Valence Technology, Inc. Solid secondary lithium cell based on lithiated zirconium, titanium or hafnium oxide cathode material
US5851504A (en) * 1996-09-23 1998-12-22 Valence Technology, Inc. Carbon based electrodes
US6183718B1 (en) * 1996-12-09 2001-02-06 Valence Technology, Inc. Method of making stabilized electrochemical cell active material of lithium manganese oxide
US5869207A (en) * 1996-12-09 1999-02-09 Valence Technology, Inc. Stabilized electrochemical cell
EP0890192A1 (fr) * 1997-01-17 1999-01-13 Hydro-Quebec Composition electrolytique a base de polymeres pour generateur electrochimique
US6096234A (en) * 1997-01-23 2000-08-01 Shin-Etsu Chemical Co., Ltd. Cross-linked polymer solid electrolyte, method of manufacturing cross-linked solid polymer electrolyte, composite solid electrolyte, and thin solid cell employing composite solid electrolyte
US5830602A (en) * 1997-02-20 1998-11-03 Valence Technology, Inc. Carbonaceous active material and method of making same
CA2200998A1 (en) 1997-03-25 1998-09-25 Hydro-Quebec New lithium insertion electrode materials based on tetraoxyanions derivatives with olivine structure
US6268088B1 (en) * 1997-05-15 2001-07-31 Cheil Industries Gel polymer electrolyte of vinyl acetate
US20010055719A1 (en) * 1997-06-20 2001-12-27 Hiroyuki Akashi Cell
CA2215849A1 (en) * 1997-09-11 1999-03-11 Christophe Michot New solvent and electrolytic composition with high conductivity and wide stability range
US6077897A (en) * 1997-12-01 2000-06-20 Wen; Ten-Chin Polymeric composite electrolyte and process for producing same
JP4005192B2 (ja) * 1997-12-09 2007-11-07 第一工業製薬株式会社 固体電池
US6235433B1 (en) * 1997-12-19 2001-05-22 Nec Corporation High molecular gel electrolyte and secondary battery using the same
US6020087A (en) * 1998-01-30 2000-02-01 Valence Technology, Inc. Polymer electrolytes containing lithiated fillers
JP3932653B2 (ja) * 1998-03-10 2007-06-20 ソニー株式会社 非水電解液二次電池
US6306215B1 (en) * 1998-03-10 2001-10-23 Valence Technology, Inc. Apparatus for coating current collectors
TW431009B (en) * 1998-05-22 2001-04-21 Teijin Ltd Electrolytic-solution-supporting polymer film and secondary battery
US6110622A (en) * 1998-07-22 2000-08-29 Wilson Greatbatch Ltd. Chemically machined current collector design
JP3951039B2 (ja) * 1998-09-22 2007-08-01 第一工業製薬株式会社 固体電解質及びその製造方法
EP1094533A1 (en) 1999-04-06 2001-04-25 Sony Corporation Active material of positive plate, nonaqueous electrolyte secondary cell, method for producing active material of positive material
CA2270771A1 (fr) 1999-04-30 2000-10-30 Hydro-Quebec Nouveaux materiaux d'electrode presentant une conductivite de surface elevee
US6468695B1 (en) 1999-08-18 2002-10-22 Valence Technology Inc. Active material having extended cycle life
JP3504195B2 (ja) * 1999-09-16 2004-03-08 日本電信電話株式会社 リチウム二次電池正極活物質およびリチウム二次電池
US20020039688A1 (en) * 1999-09-29 2002-04-04 Jeremy Barker Lactone solvents for electrochemical cells
JP2001110414A (ja) * 1999-10-04 2001-04-20 Nippon Telegr & Teleph Corp <Ntt> リチウム二次電池正極活物質およびリチウム二次電池
US7001690B2 (en) * 2000-01-18 2006-02-21 Valence Technology, Inc. Lithium-based active materials and preparation thereof
US6528033B1 (en) 2000-01-18 2003-03-04 Valence Technology, Inc. Method of making lithium-containing materials
US6627337B2 (en) * 2000-02-16 2003-09-30 Wilson Greatbatch Ltd. Conversion of low rate energy into high rate energy by parallel discharging
JP3952491B2 (ja) * 2000-04-24 2007-08-01 株式会社ジーエス・ユアサコーポレーション 電極材料及びそれを用いた電池
CA2344903C (en) * 2000-04-25 2013-03-05 Sony Corporation Positive electrode active material and non-aqueous electrolyte cell
JP3959929B2 (ja) * 2000-04-25 2007-08-15 ソニー株式会社 正極及び非水電解質電池
US6964827B2 (en) * 2000-04-27 2005-11-15 Valence Technology, Inc. Alkali/transition metal halo- and hydroxy-phosphates and related electrode active materials
US6777132B2 (en) * 2000-04-27 2004-08-17 Valence Technology, Inc. Alkali/transition metal halo—and hydroxy-phosphates and related electrode active materials
US6645670B2 (en) * 2000-05-16 2003-11-11 Wilson Greatbatch Ltd. Efficient cell stack for cells with double current collectors sandwich cathodes
JP2002042778A (ja) * 2000-07-27 2002-02-08 Gs-Melcotec Co Ltd 電池の製造方法及び電池
CA2320661A1 (fr) 2000-09-26 2002-03-26 Hydro-Quebec Nouveau procede de synthese de materiaux limpo4 a structure olivine
JP2002117908A (ja) * 2000-10-06 2002-04-19 Sony Corp 非水電解液電池
JP4686852B2 (ja) * 2000-12-04 2011-05-25 ソニー株式会社 非水電解液電池
JP2002246025A (ja) * 2001-02-22 2002-08-30 Mitsubishi Chemicals Corp 非水電解質二次電池用電極活物質、それを含む電極及び電池
JP3615196B2 (ja) * 2001-03-26 2005-01-26 株式会社東芝 正極活物質及び非水電解質二次電池
KR100469163B1 (ko) * 2001-03-26 2005-02-02 가부시끼가이샤 도시바 양극활성물질 및 비수전해질 이차전지
CA2750707A1 (en) * 2001-04-06 2002-12-05 Valence Technology, Inc. Sodium ion batteries
JP2003157850A (ja) * 2001-11-22 2003-05-30 Kyushu Univ ２次電池用正極材料、および２次電池
JP4120860B2 (ja) * 2001-11-22 2008-07-16 国立大学法人九州大学 ２次電池用正極材料の製造方法、および２次電池
US7422823B2 (en) * 2002-04-03 2008-09-09 Valence Technology, Inc. Alkali-iron-cobalt phosphates and related electrode active materials

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5910382A (en) * 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
WO1998012761A1 (en) * 1996-09-23 1998-03-26 Valence Technology, Inc. Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery
US6447951B1 (en) * 1996-09-23 2002-09-10 Valence Technology, Inc. Lithium based phosphates, method of preparation, and uses thereof
US6085015A (en) * 1997-03-25 2000-07-04 Hydro-Quebec Lithium insertion electrode materials based on orthosilicate derivatives
US5908716A (en) * 1997-04-15 1999-06-01 Valence Technology, Inc. Lithium--containing sulfates, method of preparation and uses thereof
WO2000001024A1 (en) * 1998-06-26 2000-01-06 Valence Technology, Inc. Lithium-containing silicon/phosphates, method of preparation, and uses thereof
US6203946B1 (en) * 1998-12-03 2001-03-20 Valence Technology, Inc. Lithium-containing phosphates, method of preparation, and uses thereof
WO2000057505A1 (en) * 1999-03-23 2000-09-28 Valence Technology, Inc. Lithium-containing phosphate active materials
WO2001084655A1 (en) * 2000-04-27 2001-11-08 Valence Technology, Inc. Lithium metal fluorophosphate materials and preparation thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DELMAS C ET AL: "A NASICON-TYPE PHASE AS INTERCALATION ELECTRODE: NATI2(PO4)3", MATERIALS RESEARCH BULLETIN, ELSEVIER, KIDLINGTON, GB, vol. 22, 1 January 1987 (1987-01-01), pages 631 - 639, XP009017293, ISSN: 0025-5408 *
DELMAS C ET AL: "THE NASICON-TYPE TITANIUM PHOSPHATES ATI2(PO4)3 (A=LI, NA) AS ELECTRODE MATERIALS", SOLID STATE IONICS, NORTH HOLLAND PUB. COMPANY. AMSTERDAM, NL, vol. 28 - 30, no. PART 01, 1 September 1988 (1988-09-01), pages 419 - 423, XP000126384, ISSN: 0167-2738 *

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