EP1356863B1 - Verfahren zur reinigung von methanhaltigem abgas - Google Patents

Verfahren zur reinigung von methanhaltigem abgas Download PDF

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Publication number
EP1356863B1
EP1356863B1 EP01983804A EP01983804A EP1356863B1 EP 1356863 B1 EP1356863 B1 EP 1356863B1 EP 01983804 A EP01983804 A EP 01983804A EP 01983804 A EP01983804 A EP 01983804A EP 1356863 B1 EP1356863 B1 EP 1356863B1
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Prior art keywords
catalyst
methane
exhaust gas
zirconia
iridium
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EP01983804A
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English (en)
French (fr)
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EP1356863A4 (de
EP1356863A1 (de
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Hirofumi c/o OSAKA GAS COMPANY LIMITED OHTSUKA
Takenori Hirano
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Osaka Gas Co Ltd
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Osaka Gas Co Ltd
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Priority to EP06025079A priority patent/EP1790412B1/de
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/864—Removing carbon monoxide or hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1028—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof

Definitions

  • the present invention relates to a method for removing hydrocarbons from a combustion exhaust gas containing methane and containing an excess of oxygen.
  • the term "containing an excess of oxygen” means that the gas (exhaust gas) to be treated by being contacted with the catalyst of the present invention contains oxygen, nitrogen oxides and like oxidizing components in excess of the amount required for complete oxidation of hydrocarbons, carbon monoxide and like reducing components contained therein.
  • Catalysts comprising supported platinum group metals (e.g., platinum, palladium,.) are known to have a high capability for removing hydrocarbons from an exhaust gas by oxidation.
  • platinum group metals e.g., platinum, palladium,.
  • Japanese Unexamined Patent Publication No. 1976-106691 discloses an exhaust-gas-purifying catalyst that comprises platinum and palladium supported on an alumina carrier.
  • an exhaust gas comprising hydrocarbons mainly composed of methane such as an exhaust gas generated by the combustion of natural gas
  • the use of such a catalyst still poses the problem of failing to achieve sufficient oxidative decomposition of the hydrocarbons (methane conversion) since methane has high chemical stability.
  • a combustion exhaust gas generated by the combustion of kerosene, light oil or like petroleum fuels inevitably contains a reaction inhibitor, such as sulfur oxides derived from the sulfur compounds contained in the fuel. Therefore, it is unavoidable that the deposition of the reaction inhibitor onto the surface of the catalyst significantly reduces the activity of the catalyst with time.
  • a reaction inhibitor such as sulfur oxides derived from the sulfur compounds contained in the fuel. Therefore, it is unavoidable that the deposition of the reaction inhibitor onto the surface of the catalyst significantly reduces the activity of the catalyst with time.
  • the same problem described above arises, since sulfur compounds are added thereto as odorants.
  • Lampert et al. reported that in methane oxidation with a palladium catalyst, the presence of sulfur dioxide therein even in such a slight amount as 0.1 ppm causes the catalyst to substantially lose its activity within several hours, and concluded that the presence of sulfur oxides adversely affects the activity of the catalyst ( Applied Catalysis B: Environmental, vol. 14: pp. 211-223(1997 )).
  • Yamamoto et al. reported the results of an experiment in which hydrocarbons were oxidatively removed from an exhaust gas generated by the combustion of city gas using a catalyst comprising platinum and palladium both supported on alumina. According to this report, the catalytic activity markedly declines after a short time of about 100 hours (Abstracts of the Catalysis Society of Japan Meeting, 1996, published on September 13, 1996).
  • Japanese Unexamined Patent Publication No. 1996-332392 discloses a catalyst for oxidizing low-concentration hydrocarbons from an exhaust gas containing an excess of oxygen, the catalyst comprising at least 7 g/l of palladium and 3 to 20 g/l of platinum both supported on a honeycomb substrate through an alumina carrier.
  • this catalyst does not achieve sufficient long-term durability and unavoidably entails time-dependent degradation of catalytic activity.
  • Japanese Unexamined Patent Publication No. 1999-319559 discloses that a catalyst comprising palladium, or palladium and platinum, supported on a zirconia carrier maintains high activity for methane oxidation even in the presence of sulfur oxides.
  • this catalyst exhibits low activity for methane oxidation at lower temperatures, particularly below about 400°C. Therefore, in order to obtain high methane conversion according to this technique, a large amount of catalyst must be used, increasing the exhaust gas treatment costs, thus making it impractical.
  • Japanese Unexamined Patent Publication No. 1991-98644 discloses a method for manufacturing a catalyst for purifying an exhaust gas, wherein, by employing a specific method using citric acid, at least one of platinum and rhodium and at least one of iridium and ruthenium are jointly supported on an inorganic carrier such as activated alumina, etc.
  • iridium and/or ruthenium and platinum and/or rhodium form a solid solution having a high melting point, and therefore the heat resistance of the resulting catalyst can be improved.
  • this publication merely discloses that the NO x conversion of the obtained catalyst is improved and it nowhere teaches the oxidative decomposition of methane, which is particularly difficult to decompose among the hydrocarbons contained in exhaust gases.
  • Japanese Unexamined Patent Publication No. 1999-207182 discloses "a catalyst for catalytic reduction of nitrogen oxides, in which (a) iridium and (b) at least one of indium and gallium are supported on an oxide carrier.” It is disclosed that when nitrogen oxides are reduced using the catalyst disclosed in this publication, various kinds of hydrocarbons in the gas state or liquid state can be used as a reducing agent. Among these hydrocarbons, ethylene, propylene, isobutylene, 1-butene, 2-butene, and like lower alkenes; propane, butane, and like lower alkanes; light oil, kerosene, etc., are recommended. However, this publication also does not disclose a means for oxidative decomposition of methane, which is particularly difficult to decompose among the hydrocarbons contained in exhaust gases.
  • Japanese Unexamined Patent Publication No. 1995-80315 discloses a de-NOx catalyst for an exhaust gas emitted from a lean-burning engine and a method for treating an exhaust gas emitted from a lean-burning engine.
  • This publication discloses that a catalyst comprising iridium supported on various kinds of inorganic carriers can efficiently remove harmful substances contained in exhaust gases, particularly NO x , even in the lean-burning range.
  • this publication also does not indicate that among the various hydrocarbons contained in exhaust gas, methane is particularly difficult to decompose. Therefore, it nowhere teaches the means for efficiently decomposing methane by oxidation.
  • US-A-4 016 241 describes a process for reducing nitrogen oxides from flue gas
  • the main object of the present invention is to involve a catalyst that can exhibit a high activity for methane decomposition even at low temperatures with respect to removing hydrocarbons from a combustion gas containing methane and containing an excess of oxygen in a method for purifying an exhaust gas using this catalyst.
  • the present inventors conducted intensive research in view of the above status of the prior art, and found that a catalyst comprising iridium as a catalytically active component supported on zirconium oxide as a carrier is highly resistant to the activity inhibition caused by sulfur oxides and therefore maintains a high activity for methane oxidation even when used under the conditions for purifying a combustion exhaust gas containing sulfur oxides, and exhibits excellent activity at low temperatures as well.
  • the present inventors found that when iridium and additionally at least one member selected from the group consisting of platinum, palladium, rhodium and ruthenium are supported on zirconium oxide, the durability and ability to oxidize methane of the resultant catalyst are further improved.
  • the present invention involves a catalyst for purifying exhaust gas in a method for purifying exhaust gas as described in the appended claims.
  • the catalyst used in the present invention is a catalyst for removing hydrocarbons from a combustion exhaust gas containing methane and containing an excess of oxygen, and is characterized in that iridium as a catalytically active component is supported on zirconium oxide as a carrier.
  • the catalyst used in the present invention may further comprise, as a supplemental component, at least one member selected from the group consisting of platinum, palladium, rhodium and ruthenium supported thereon. The use of such a supplemental component will further increase the performance of the catalyst.
  • zirconium oxide functioning as a carrier
  • high dispersion of iridium cannot be maintained.
  • zirconium oxide tends to have insufficient thermal stability and is likely to be sintered during the use of the catalyst.
  • the specific surface area of the zirconium oxide is not particularly limited, it is generally about 2 to 60 m 2 /g and preferably about 5 to 30 m 2 /g.
  • the zirconium oxide can be obtained by known methods, e.g., by calcining zirconium hydroxide in an oxidizing atmosphere such as air at a temperature of about 600 to 1,000°C.
  • the amount of the supported iridium relative to the zirconium oxide is too small, the catalytic activity will be lowered. On the other hand, if its amount becomes excessively large, the grain size of the supported iridium becomes too large with the result that the iridium supported will not be effectively used.
  • the amount of the supported iridium is generally about 0.5 to 20% by weight, preferably about 1 to 5% by weight, relative to the zirconium oxide.
  • the catalyst used in the present invention it is possible to additionally use at least one member selected from the group consisting of platinum, palladium, rhodium, and ruthenium as a component for supplementing catalytic activity.
  • a component for supplementing catalytic activity it is possible to additionally use at least one member selected from the group consisting of platinum, palladium, rhodium, and ruthenium as a component for supplementing catalytic activity.
  • platinum is more preferable.
  • the amount of platinum is preferably about 2 to 100%, more preferably about 5 to 50%, relative to the weight of iridium.
  • the amount of said at least one member selected from the group consisting of palladium, rhodium and ruthenium is preferably about 0.5 to 10%, more preferably about 1 to 5%, relative to the weight of iridium.
  • the amount of said at least one member selected from the group consisting of palladium, rhodium and ruthenium is preferably about 0.5 to 10%, more preferably about 1 to 5%, relative to the weight of iridium.
  • the catalyst used in the present invention is prepared, for example, by impregnating zirconium oxide with a solution containing iridium ions and optionally ions of at least one metal selected from the group consisting of platinum, palladium, rhodium and ruthenium, followed by drying and calcination.
  • Impregnation may be conducted using an aqueous solution system prepared by dissolving a water-soluble compound such as a chloro complex, an ammine complex, a nitrate, for example in pure water, or using an organic solvent solution system prepared by dissolving an organometallic compound such as an acetylacetonato complex, for example in a solvent such as acetone.
  • a water-soluble compound such as a chloro complex, an ammine complex, a nitrate
  • an organic solvent solution system prepared by dissolving an organometallic compound such as an acetylacetonato complex, for example in a solvent such as acetone.
  • water-soluble compounds examples include chloroiridic acid, chloroplatinic acid, chlororhodic acid, chloropalladic acid, ruthenium chloride, tetraammineplatinum nitrate, tetraamminepalladium nitrate, rhodium nitrate, palladium nitrate or tri-nitrato-nitrosyl ruthenium, etc.
  • organometallic compounds include tris(acetylacetonato)iridium, bis(aoetylaoetonato)platinum, tris(acetylacetonato)ruthenium, tris(acetylacetonato)rhodium.
  • the use of two or more kinds of metal compounds in the impregnation step may cause precipitation.
  • different metals may be supported on a zirconium oxide carrier sequentially.
  • iridium may be deposited on the carrier, and, if necessary, after drying or after drying and calcination, the operation for depositing platinum may be conducted.
  • the impregnation time is not limited as far as the metal is supported in the prescribed amount. However, it is generally about 1 to 50 hours and preferably about 3 to 20 hours.
  • the zirconium oxide having the prescribed metal component supported thereon is subjected to drying or evaporation to dryness if so desired, and then calcined.
  • Calcination may be conducted in a stream of air.
  • calcinations may be conducted in a stream of an oxidizing gas, such as a mixed gas obtained by suitably mixing air or oxygen with an inert gas such as nitrogen.
  • the calcination temperature be about 450 to 650°C and more preferably about 500 to 600°C. While the calcination time is not particularly limited, it is generally about 1 to 50 hours and preferably about 3 to 20 hours.
  • the catalyst used in the present invention may be formed into pellets, a honeycomb shape or the like, or may be washcoated onto a fire-resistant honeycomb substrate. It is preferable that the catalyst of the present invention be washcoated onto a fire-resistant honeycomb substrate.
  • the catalyst prepared by the above-mentioned method may be formulated into a slurry and used for washcoating.
  • the specific surface area of the catalyst used in the present invention is not limited. However, it is generally about 2 to 60 m 2 /g and preferably about 5 to 30 m 2 /g.
  • the present invention intends to purify an exhaust gas that contains methane and containing an excess of oxygen.
  • the exhaust gas may contain ethane, propane and like lower hydrocarbons in addition to methane. With the present invention, these hydrocarbons can be decomposed more easily than methane, and therefore they can be readily removed together with methane by oxidation.
  • the concentration of the hydrocarbons contained in exhaust gas is not limited. However, if it is too high, an extreme temperature rise occurs in the catalyst beds, and might adversely affect the durability of the catalyst. Therefore, it is preferable that the concentration thereof be about 5,000 ppm or less, calculated as methane on carbon basis.
  • the method for removing hydrocarbons from a methane-containing exhaust gas according to the present invention is characterized in that the catalyst obtained as mentioned above is used.
  • the catalyst be used in an amount such that the gas hourly space velocity (GHSV) is 200,000h -1 or less.
  • GHSV gas hourly space velocity
  • the lower limit of GHSV be about 1,000 h -1 and more preferably about 5,000 h -1 .
  • the oxygen concentration in the exhaust gas to be treated is not limited as long as the exhaust gas contains an excess of oxygen. However, it is preferable that the exhaust gas contain oxygen in an amount of about 2% or greater (more preferably about 5% or greater) by volume, and at least about 5 times (more preferably at least about 10 times) the stoichiometric amount of the reducing components including hydrocarbons and the like. If the oxygen concentration of the exhaust gas is extremely low, the reaction speed might be reduced, and therefore, a predetermined amount of air or an exhaust gas containing an excess of oxygen may be added in advance.
  • the catalyst for removing hydrocarbons from a methane-containing exhaust gas according to the present invention has high activity. However, when the temperature for treating the exhaust gas is too low, activity of the catalyst is lowered, and this makes it impossible to achieve the desired methane conversion. On the other hand, if the treatment temperature is too high, durability of the catalyst may be adversely affected. While the temperature of the catalyst bed may be suitably selected depending on the type of catalytically active metal and its amount, it is generally about 300 to 600°C and preferably about 350 to 500°C.
  • the catalyst be used under the condition that the temperature elevation in the catalyst bed is generally about 150°C or less and preferably about 100°C or less.
  • combustion exhaust gases contain about 5 to 15% of water vapor. According to the present invention, a significant hydrocarbon conversion is attained even in treating exhaust gases containing water vapor.
  • exhaust gases generally contain, in addition to water vapor, a small amount of sulfur oxides, which are known to greatly reduce the catalytic activity.
  • the catalyst of the present invention is highly resistant to catalytic activity degradation due to sulfur components, and therefore, high hydrocarbon conversion is maintained even when an ordinary amount of sulfur oxides are contained.
  • the catalyst used in the present invention exhibits high methane oxidation activity even for an exhaust gas that contains a large amount of water vapor, such as combustion exhaust gas.
  • the catalyst used in the present invention also exhibits extremely excellent resistance to the activity inhibition caused by sulfur oxides, and therefore maintains high methane conversion for a long period of time. Especially, the catalyst used in the present invention achieves high conversion, even when used under low temperature conditions or under relatively high sulfur oxides concentration conditions in which known catalysts could not achieve a sufficient conversion.
  • the present invention makes it possible to achieve high conversion of lower saturated hydrocarbons, such as methane, which are difficult to decompose by known catalysts even with use of a large amount of expensive noble metal, and also to maintain such high conversion for a long period of time.
  • Chloroiridic acid, cis-diamminedinitroplatinum and 0.5 ml of 69% nitric acid were dissolved with stirring, giving 11 ml of an impregnation solution containing 0.07 g of iridium and 0.0175 g of platinum.
  • Chloroiridic acid, cis-diamminedinitroplatinum and tri-nitrato-nitrosyl ruthenium [Ru(NO)(NO 3 ) 3 ] were mixed with and dissolved in 0.5 ml of 69% nitric acid with heating, giving 11 ml of an aqueous impregnation solution containing 0.07 g of iridium, 0.0175 g of platinum and 0.0035 g of ruthenium.
  • the mixture was then evaporated to dryness, and the solid was calcined in air at 600°C for 4 hours, giving a 2% Ir-0.5% Pt-0.1% Ru/zirconia catalyst.
  • a 2% Ir-0.5% Pt/alumina catalyst was obtained in the same manner as in Example 4 except that alumina (manufactured by Sumitomo Chemical Industry Co., Ltd. "NK-124") was used as a carrier.
  • alumina manufactured by Sumitomo Chemical Industry Co., Ltd. "NK-124"
  • the catalysts prepared in Examples 1 to 6 and Comparative Examples 1 and 4 were pressed into pellets. Then, 1 ml of each catalyst was packed in each reaction tube. The methane conversion (%) was measured over time by passing a gas through the reaction tube at a gas hourly space velocity (GHSV) of 40,000 h -1 while maintaining the catalyst bed at 400°C, the gas being composed of 1,000 ppm methane, 10% oxygen, 10% water vapor, 8 ppm sulfur dioxide, with the balance being nitrogen.
  • the gas compositions before and after passing through the reaction bed were measured with a gas chromatograph equipped with a hydrogen flame ionization detector.
  • Table 1 shows the methane conversion (%) achieved 1, 5, 10 and 30 hours after the start of the test with respect to the catalysts prepared in Examples 1 to 6 and Comparative Examples 1 and 4.
  • CH 4 conversion ( % ) 100 ⁇ x ( 1 - CH 4 - out / CH 4 - in )
  • CH 4-out represents the methane concentration at the catalyst bed outlet
  • CH 4-in represents the methane concentration at the catalyst bed inlet.
  • Table 1 Composition of Catalyst Elapsed time 1 hour our 5 hours ours 10 hours 30 hours
  • Example 1 2% Ir/zirconia 25% 22% 21% 19%
  • Example 2 5% Ir-1% Pt/zirconia 72% 71% 66% 59%
  • Example 3 2% Ir-1% Pt/zirconia 77% 79% 76% 73%
  • Example 4 2% Ir-0.5% Pt/zirconia (1) 66% 63% 66% 60%
  • Example 5 2% Ir-0.5% Pt/zirconia (2) 42% 56% 60% 58%
  • Example 6 2% Ir-0.5% Pt-0.1% Ru/zirconia 49% 59% 63% 58%
  • Comp.Ex.1 5%
  • Pd/zirconia 84% 70% 56% 28%
  • Comp.Ex.4 2% Pd/zirconia 63% 34% 24%
  • 10% Composition of Catalyst Elapsed time 1 hour our 5 hours ours 10 hours 30 hours
  • Example 1
  • the catalysts of the present invention exhibit a stable catalytic activity for a long period of time.
  • the catalysts obtained in Examples 2 to 6 exhibit high catalytic activity over a long period of time even in the presence of sulfur dioxides, which markedly reduce catalytic activity, even at a temperature of as low as 400°C.
  • the catalysts prepared in Comparative Examples 1 and 4 in which palladium is used as its catalytically active component, exhibit extremely excellent methane decomposition ability in the beginning. However, their activity sharply declined after 5 to 10 hours.
  • a 0.61 g quantity of tris(acetylacetonato)iridium and 0.12 g of bis(acetylacetonato)platinum were dissolve in acetone so as to give a solution having a volume of 35 ml.
  • To the resultant solution was added 12 g of zirconia (manufactured by Tosoh Corporation, TZ-O, specific surface area: 14 m 2 /g). The resultant mixture was stirred at room temperature for 2 hours. The mixture subjected to the stirring treatment was then evaporated to dryness using an evaporator, and the solid was calcined in air at 550°C for 2 hours, giving 2% Ir-0.5% Pt/zirconia catalyst (3).
  • Chloroiridic acid and chloroplatinic acid were dissolved with stirring, giving 25 ml of an aqueous solution for impregnation containing 0.50 g of iridium and 0.10 g of platinum.
  • the 2% Ir-0.5% Pt/zirconia catalyst (3) obtained in Example 8 was pressed into pellets, and 1.5 ml of the pellets was packed in a reaction tube.
  • the methane conversion (%) was measured over time by passing a gas through the reaction tube at a gas hourly space velocity (GHSV) of 80,000 h -1 while maintaining the catalyst bed at 400°C, the gas being composed of 1,000 ppm methane, 80 ppm nitrogen monoxide, 10% oxygen, 6% carbon dioxide, 10% water vapor, 3 ppm sulfur dioxide, with the balance being nitrogen.
  • the gas compositions before and after passing through the reaction bed were measured with a gas chromatograph equipped with a hydrogen flame ionization detector. Fig. 1 shows the results.
  • Example 8 maintains an extremely high methane conversion for a long period of time even when used for purifying an exhaust gas comprising water vapor, sulfur oxides, for example.
  • Example 9 The catalyst durability test using the 2.5% Ir-0.5% Pt/zirconia catalyst obtained in Example 9 was conducted in the same manner as in Example 10. The results are shown in Fig. 3 .

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Claims (3)

  1. Verfahren zum Entfernen von Kohlenwasserstoffen aus einem Verbrennungsabgas, das Methan enthält und das mehr Sauerstoff enthält als die Menge, die für eine vollständige Oxidation der reduzierenden Substanzen benötigt wird, wobei das Verfahren das Inkontaktbringen des Verbrennungsabgases mit einem Katalysator, der Iridium, getragen auf Zirconiumoxid, umfaßt, bei einer Temperatur von 300 bis 600°C umfaßt.
  2. Verfahren nach Anspruch 1, umfassend das Inkontaktbringen des Verbrennungsabgases mit einem Katalysator, der Iridium und Platin, getragen auf Zirconiumoxid, umfaßt, bei einer Temperatur von 300 bis 600°C.
  3. Verfahren nach Anspruch 1, umfassend das Inkontaktbringen des Verbrennungsabgases mit einem Katalysator, der Iridium und mindestens einen Vertreter, ausgewählt aus der Gruppe, bestehend aus Platin, Palladium, Rhodium und Ruthenium, getragen auf Zirconiumoxid, umfaßt, bei einer Temperatur von 300 bis 600°C.
EP01983804A 2000-11-17 2001-11-15 Verfahren zur reinigung von methanhaltigem abgas Expired - Lifetime EP1356863B1 (de)

Priority Applications (2)

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DK06025079.2T DK1790412T3 (da) 2000-11-17 2001-11-15 Katalysator til at oprense methan-holdig røggas
EP06025079A EP1790412B1 (de) 2000-11-17 2001-11-15 Katalysator zur reinigung von Methanhaltigem Abgas

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JP2000351654 2000-11-17
JP2000351654 2000-11-17
PCT/JP2001/009979 WO2002040152A1 (fr) 2000-11-17 2001-11-15 Catalyseur utile pour purifier des gaz residuaires contenant du methane et procede de purification de gaz residuaires contenant du methane

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EP1356863A1 EP1356863A1 (de) 2003-10-29
EP1356863A4 EP1356863A4 (de) 2004-12-29
EP1356863B1 true EP1356863B1 (de) 2009-03-18

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US (1) US7364712B2 (de)
EP (2) EP1356863B1 (de)
JP (1) JP4096176B2 (de)
DE (1) DE60138046D1 (de)
DK (2) DK1790412T3 (de)
WO (1) WO2002040152A1 (de)

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DE10340653B4 (de) * 2003-09-03 2006-04-27 Hte Ag The High Throughput Experimentation Company Katalysator für die Entfernung von Schadstoffen aus Abgasen von Mager-Motoren mit Ruthenium als Aktiv-Metall
US7309480B2 (en) * 2004-04-16 2007-12-18 H2Gen Innovations, Inc. Catalyst for hydrogen generation through steam reforming of hydrocarbons
US7601671B2 (en) * 2004-10-28 2009-10-13 Umicore Ag & Co. Kg Drying method for exhaust gas catalyst
JP4688646B2 (ja) * 2004-12-01 2011-05-25 大阪瓦斯株式会社 三元触媒及びこれを用いたメタン含有ガスの浄化方法
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EP1356863A1 (de) 2003-10-29
US20040013591A1 (en) 2004-01-22
JPWO2002040152A1 (ja) 2004-03-18
DK1790412T3 (da) 2013-03-25
DK1356863T3 (da) 2009-06-02
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EP1790412B1 (de) 2013-03-06
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