EP1282499A1 - Composant composite profile et procede de fabrication - Google Patents
Composant composite profile et procede de fabricationInfo
- Publication number
- EP1282499A1 EP1282499A1 EP01980211A EP01980211A EP1282499A1 EP 1282499 A1 EP1282499 A1 EP 1282499A1 EP 01980211 A EP01980211 A EP 01980211A EP 01980211 A EP01980211 A EP 01980211A EP 1282499 A1 EP1282499 A1 EP 1282499A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- profiles
- reinforcing elements
- composite component
- thermoplastic
- component according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D29/00—Superstructures, understructures, or sub-units thereof, characterised by the material thereof
- B62D29/001—Superstructures, understructures, or sub-units thereof, characterised by the material thereof characterised by combining metal and synthetic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14467—Joining articles or parts of a single article
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/66—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by liberation of internal stresses, e.g. shrinking of one of the parts to be joined
- B29C65/68—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by liberation of internal stresses, e.g. shrinking of one of the parts to be joined using auxiliary shrinkable elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/70—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/112—Single lapped joints
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/114—Single butt joints
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/524—Joining profiled elements
- B29C66/5243—Joining profiled elements for forming corner connections, e.g. for making window frames or V-shaped pieces
- B29C66/52431—Joining profiled elements for forming corner connections, e.g. for making window frames or V-shaped pieces with a right angle, e.g. for making L-shaped pieces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/524—Joining profiled elements
- B29C66/5244—Joining profiled elements for forming fork-shaped connections, e.g. for making window frames or Y-shaped pieces
- B29C66/52441—Joining profiled elements for forming fork-shaped connections, e.g. for making window frames or Y-shaped pieces with two right angles, e.g. for making T-shaped pieces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/524—Joining profiled elements
- B29C66/5245—Joining profiled elements for forming cross-shaped connections, e.g. for making window frames or X-shaped pieces
- B29C66/52451—Joining profiled elements for forming cross-shaped connections, e.g. for making window frames or X-shaped pieces with four right angles, e.g. for making +-shaped pieces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/63—Internally supporting the article during joining
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J5/00—Doors
- B60J5/04—Doors arranged at the vehicle sides
- B60J5/0401—Upper door structure
- B60J5/0408—Upper door structure fastening window frame or parts of window frame to lower door structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J5/00—Doors
- B60J5/04—Doors arranged at the vehicle sides
- B60J5/0463—Conceptual assembling of door, i.e. how door frame parts should be fitted together to form door
- B60J5/0466—Conceptual assembling of door, i.e. how door frame parts should be fitted together to form door using cast parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J5/00—Doors
- B60J5/04—Doors arranged at the vehicle sides
- B60J5/048—Doors arranged at the vehicle sides characterised by the material
- B60J5/0484—Doors arranged at the vehicle sides characterised by the material hybrid, i.e. plastic moulded onto metal parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J5/00—Doors
- B60J5/10—Doors arranged at the vehicle rear
- B60J5/101—Doors arranged at the vehicle rear for non-load transporting vehicles, i.e. family cars including vans
- B60J5/107—Doors arranged at the vehicle rear for non-load transporting vehicles, i.e. family cars including vans constructional details, e.g. about door frame, panels, materials used, reinforcements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D25/00—Superstructure or monocoque structure sub-units; Parts or details thereof not otherwise provided for
- B62D25/08—Front or rear portions
- B62D25/14—Dashboards as superstructure sub-units
- B62D25/145—Dashboards as superstructure sub-units having a crossbeam incorporated therein
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D27/00—Connections between superstructure or understructure sub-units
- B62D27/02—Connections between superstructure or understructure sub-units rigid
- B62D27/023—Assembly of structural joints
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D29/00—Superstructures, understructures, or sub-units thereof, characterised by the material thereof
- B62D29/001—Superstructures, understructures, or sub-units thereof, characterised by the material thereof characterised by combining metal and synthetic material
- B62D29/004—Superstructures, understructures, or sub-units thereof, characterised by the material thereof characterised by combining metal and synthetic material the metal being over-moulded by the synthetic material, e.g. in a mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D29/00—Superstructures, understructures, or sub-units thereof, characterised by the material thereof
- B62D29/001—Superstructures, understructures, or sub-units thereof, characterised by the material thereof characterised by combining metal and synthetic material
- B62D29/005—Superstructures, understructures, or sub-units thereof, characterised by the material thereof characterised by combining metal and synthetic material preformed metal and synthetic material elements being joined together, e.g. by adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14836—Preventing damage of inserts during injection, e.g. collapse of hollow inserts, breakage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/26—Moulds
- B29C45/33—Moulds having transversely, e.g. radially, movable mould parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/72—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
- B29C66/721—Fibre-reinforced materials
- B29C66/7214—Fibre-reinforced materials characterised by the length of the fibres
- B29C66/72141—Fibres of continuous length
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7394—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoset
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3002—Superstructures characterized by combining metal and plastics, i.e. hybrid parts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24174—Structurally defined web or sheet [e.g., overall dimension, etc.] including sheet or component perpendicular to plane of web or sheet
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/2419—Fold at edge
- Y10T428/24198—Channel-shaped edge component [e.g., binding, etc.]
Definitions
- the invention relates to a composite component from two or more profiles and a method for its production, in which at least one profile with a free
- End adjoins the second profile or is immersed in the second profile, characterized in that reinforcing elements are attached in the area of the connection point of the profiles, which form a positive connection with the profiles, and that the profiles are joined together by thermoplastic material which is injection-molded or shrunk on in the area of the connection point are connected.
- the invention relates in particular to a method for joining profiles and plates by creating high-strength and highly rigid composite components, in particular in a plastic-metal hybrid construction, the joining of the semi-finished products and the production of the composite components being achieved simultaneously by a shaping process of thermoplastic molding compositions.
- the invention also relates to a method for connecting semi-finished products by creating highly resilient joining areas in hybrid construction.
- the process produces composite components that consist of high-strength and high-rigidity components such as Made of steel or composites, which are joined with the help of a thermoplastic, held in position and additionally supported in the form of ribs or solid walls.
- High-strength connections of heavy-duty beams, profiles, plates, etc. can often be found in vehicle or mechanical engineering. Beams made of steel or aluminum are predominantly used, which are welded or glued together in the joining areas. To further stiffen the connection points, also referred to below as nodes, struts are integrated or cast nodes, eg aluminum die-cast, are used. Another option is the use of semi- made of composite (long fiber reinforced plastic). These are usually connected to each other by laminating node elements, which also consist of composites.
- the invention is therefore based on the object of creating joining methods with nodes of the type mentioned at the outset, which both enable high-strength and highly rigid connections of supports and plates and also allow economical joining of semi-finished products and component components to components.
- the manufacture of the composite components should take place with high dimensional accuracy and reproducibility.
- a particular task is the collapse of thin-walled profiles with a wall thickness of 0.5 to, due to the injection pressure
- the invention relates to a composite component made of two or more profiles, in which at least one profile adjoins the second profile with a free end or immersed in a second profile, characterized in that reinforcement elements are attached in the area of the connection point of the profiles, which form a positive fit with the profiles, and that the profiles are connected to one another by thermoplastic material which is injection-molded or shrunk on in the area of the connection point.
- the reinforcing elements are e.g. Sheets or die-cast parts made of high-strength material.
- the high-strength materials can be steel, aluminum, magnesium, ceramics, thermosets or long-fiber reinforced plastics, composites or plastics reinforced with technical textiles.
- An unreinforced or reinforced or filled plastic e.g. based on polyamide (PA), polyester, especially polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyolefin, especially polypropylene (PP), polyethylene (PE), styrene-acrylonitrile copolymer, in particular
- PA polyamide
- PET polyethylene terephthalate
- PBT polybutylene terephthalate
- polyolefin especially polypropylene (PP), polyethylene (PE), styrene-acrylonitrile copolymer
- ABS Acrylonitrile-styrene-butadiene copolymer
- PC polycarbonate
- PPO polypropylene oxide
- PSO polyphenylene sulfide
- PPS polyimide
- PEEK polyketone syndiotactic polystyrene
- Profiles in the sense of the invention are, for example, open or closed profiles made of plastic or metal (preferably metal, e.g. steel, aluminum, magnesium) with any cross section. Closed profiles with a round or rectangular cross section or open U-profiles are preferred.
- the profiles preferably have a wall thickness of 0.3 to 1.5 mm, particularly preferably 0.5 to 1.2 mm.
- the reinforcement elements are used as highly rigid connecting components in the form of, for example, clips, rings and half-shells, the shape of which is adapted to the profiles (semi-finished products) and component components to be joined and in particular with the aid of struts and / or preferably with further support plates are additionally supported. You will see the profiles and profiles to be joined other component parts.
- the reinforcement elements serve to reinforce and stiffen the connection point and are designed so that they form-fit with the semi-finished products and component components to be joined.
- the reinforcement elements are provided with additional supporting walls, which make it more difficult, particularly in the case of an abutting profile, to kink the connection point.
- a composite component is particularly preferred in which a one-piece reinforcing element is provided at the connection point of the profiles, into which the profiles in front of the
- thermoplastic Injection molding of the thermoplastic is inserted or inserted.
- thermoplastic component is arranged as a connecting material with the aid of a shaping process in such a way that it holds the components (profiles and or plates) which are butting against one another in a form-fitting manner but which are otherwise loosely connected as well as the reinforcing elements themselves in position. This can be done by partially or completely enclosing the reinforcing elements.
- the power transmission from one component to the other takes place via the high-strength components of the reinforcing elements.
- optionally integrally formed ribs or by filling gaps - which e.g. are formed by individual support plates - with the thermoplastic component an additional increase in the strength of the composite components is achieved, since bulging or kinking of struts and support walls of the reinforcing elements only occurs with higher loads.
- a composite component has proven to be particularly advantageous in which openings and bores through which the thermoplastic is provided are provided in the profiles and / or in the reinforcing elements at points lying one above the other
- Plastic protrudes through and to which the thermoplastic is anchored. Additionally or alternatively, in a further preferred variant of the composite component in the profiles and / or in the reinforcing elements, deformations, in particular beads or beads, can be provided at which the thermoplastic is anchored.
- a preferred composite component is particularly advantageous, in which the reinforcing elements are formed in one piece with at least one of the profiles, and in which the profiles form a positive fit with one another.
- the interlocking profiles are pre-shaped so that they have matching tongue and groove combinations or projections that ensure a positive fit.
- a profile can additionally have a reinforcement in the area of the connection point in the form of the preferred materials for the reinforcement elements or have a higher wall thickness.
- Joining process which is made up of at least two different materials.
- One material component consists of a thermoplastic, while the other component is usually made of a high-strength material.
- Another object of the invention is therefore a method for producing a composite component according to the invention, characterized in that two or more profiles are inserted or inserted into reinforcing elements or clasped by reinforcing elements to form a detachable connection point, and then the connection point in an injection molding tool made of thermoplastic plastic is wholly or partially encapsulated, the profiles with the
- Reinforcing elements are connected.
- a method is preferred in which open profiles are used and reinforcing struts are produced in the open profiles when the thermoplastic is molded on.
- Composite component is characterized in that two or more profiles are inserted or inserted into reinforcing elements or clasped by reinforcing elements to form a detachable connection point, and that the connection point is then wholly or partially surrounded with one or more molded parts made of shrinkable thermoplastic, and the profiles with the reinforcing elements are then connected by heat treatment of the fittings.
- a particularly preferred method is characterized in that, in the profiles and / or in the reinforcing elements, deformations, in particular beads or beads, and / or openings or bores at certain points in the profiles and / or the reinforcing elements, before being folded or pushed in, are attached so that they lie one above the other when the profiles and / or the reinforcing elements are folded or pushed in before the thermoplastic is attached.
- thermoplastic component Since the joining process is achieved by thermally deforming the thermoplastic component, the shrinkage of the thermoplastic material can be used to build up stresses that ensure a permanent and firm bond in the area of the connection point of the profiles.
- further additional elements can be integrated into the composite component, which fulfill mechanical functions such as, for example, supporting additional plates or supports, attaching parts to be retrofitted or accommodating further components.
- these integrated elements can be made of high-strength elements with the help of form-fitting inserted
- thermoplastic component The production of the composite component and thus also the type of implementation of the joining process can take place in different ways.
- the component components to be joined profiles or profiles and plates and the reinforcing elements are first inserted into an injection molding tool.
- the injection mold is then closed and the thermoplastic is injected. Since the plastic material is poured into the injection mold in liquid form, it can enclose the inserts on all sides and thereby secure the form fit already achieved through the design of the reinforcing elements.
- a connection of the thermoplastic component in the form of rivet heads can also be achieved, in particular in the area of overlapping breakthroughs in the profiles and reinforcing elements. With this type of connection, it is not necessary to completely encase the node area.
- a cover e.g. with welding plate or with a sheet-reinforced plastic cap
- movable cores attached in the tool be closed. If high injection pressures are used in the injection molding process, collapse of the hollow profiles is prevented by also using moving cores in the injection molding tool or rib structures, double T-pieces or other reinforcements, eg made of metal foams, remaining in the hollow profile.
- the procedure for this method variant does not fundamentally differ from the previous method using injection molding.
- the semi-finished products or component components to be joined and the reinforcing elements are joined together in a form-fitting manner but in a loose bond.
- the cohesion of these individual parts is secured with a connecting element made of thermoplastic plastic, which is placed or snapped over the knot in the joining area.
- the thermoplastic connecting element used was previously stretched and is now shrunk onto the semi-finished products or component components and reinforcing elements in the node area to build up a non-positive support for the form-fitting reinforcing elements.
- clips, shells or the like made of thermoplastics with and without reinforcements are first plugged on and subsequently completed by means of injection molding, gluing or welding to form the connecting elements encompassing the node area on all sides.
- the manufacture of the reinforcement elements as well as the production of the connecting element and the joining process can be combined into one process step.
- the reinforcing elements consist, for example, of sheet metal, they can be shaped into their final shape during the injection molding process. For this purpose, flat or already to a certain extent preformed metal sheets with the components to be joined are placed in the injection mold. By moving the two halves of the tool together and applying the required closing force, the reinforcement plates are deformed in such a way that they form-fit around the components. Finally, the components to be joined and the reinforcing elements are connected by injecting and cooling the plastic melt.
- the invention enables the construction of permanently high strength and high stiff nodes and composite components using simply designed semi-finished products
- the manufacturing process ensures high dimensional accuracy and reproducibility in the
- the design of composite components can be optimized in terms of cost and weight
- Another object of the invention is the use of the composite components according to the invention in a corresponding design as a construction element for machines Vehicle and components of all kinds, in particular for motor vehicles, for electronic items, household items and for building supplies.
- Particularly suitable applications of the composite component are structural parts for motor vehicles, in particular doors, bumpers, beams, front and rear parts for cars,
- Fig.l a composite component with two reinforcing elements 3, 3 'for connecting two rectangular profiles connected by a molded thermoplastic
- Fig. 2 shows a composite component similar to Fig. 1 with an additional reinforcing edge
- FIG. 3 shows a composite component similar to FIG. 1 with a connection by shrink-fit thermoplastic molded parts 4, 5
- FIG. 4 shows a composite component similar to FIG. 1 but without lateral rib structures on the thermoplastic and with a one-piece reinforcing element 3
- FIG. 5 shows a composite component similar to FIG. 1 with fully encapsulated reinforcing elements 3, 3 '
- FIG. 6 shows the side view of a composite component with two reinforcing elements 3, 3 'with a flange 63 at the end of the profile 2 and fully with
- FIG. 7 shows the cross section through a composite component according to FIG. 6 along the line A-A in FIG. 6
- FIG. 8 shows the individual representation of the reinforcing elements 3, 3 'for a composite component according to FIG. 6
- FIG. 9 is a top view of the reinforcing elements 3, 3 'according to FIG. 8
- Fig. 11 is a composite component from three profiles 1, 2, 8 in which the profiles 1 and
- 15 shows a composite component made of thin-walled hollow profiles 1, 2 similar to FIG. 4 but with two reinforcing elements 3, 3 '
- FIG. 16 shows a composite component comprising a box section 161 and a U section 162 with reinforcing elements 21, 23, 25 integrated in the U section
- FIG. 17 individual representation of the U-profile from FIG. 16
- FIG. 19 shows a cross member for a motor vehicle instrument panel as an example of a complex composite component
- FIG. 20 shows the longitudinal section through the profile 9 of the cross member according to FIG. 19 along the line A-A in FIG. 19
- Fig. 21 is the view of the cross member according to Fig. 19 without extrusion molding of the profiles
- FIG. 22 shows the door frame structure of a motor vehicle as a further example of a complex composite component
- Fig. 23 shows the view of the door frame structure without plastic injection molding
- FIGS. 1 to 5 are the connection of two rectangular components (profiles) 1 and 2, which are held together in a form-fitting manner via high-strength and highly rigid reinforcing elements 3 and 3 'and with the aid of two connections 4 and 5 be firmly connected and supported from thermoplastic.
- FIGS. 6 and 7 show how the components and reinforcing elements to be connected are held together and supported by a thermoplastic plastic which surrounds the connection point 10
- Contour of profiles 1 and 2 is encompassed by walls 32 of reinforcing elements 3 and 3 ', respectively. This creates a positive connection between the profiles 1 and 2 to be joined and the reinforcing elements 3, 3 '.
- 1 shows a composite component with two reinforcing elements 3, 3 'for connecting two rectangular profiles 1, 2, which are formed by an injection-molded thermoplastic
- FIG. 2 shows a composite component similar to FIG. 1, in which the reinforcement elements are provided with an additional reinforcement edge in the region of the support wall.
- the reinforcing element 3 consists of one part.
- the profiles 1 and 2 to be joined are inserted or inserted into the reinforcing elements 3, 3 1 and inserted into an injection mold.
- the injection molding of the thermoplastic component 4 creates the connecting elements 4 and 5, which hold the reinforcing elements 3, 3 ′ together via the simultaneously created walls 42 and the rib structure 41 made of thermoplastic material.
- the connecting elements 4 and 5 can also be preformed separately. These are then stretched before the joining process and then attached to the support walls 31. Subsequent heating causes the thermoplastic parts 4, 5 to be firmly shrunk onto the reinforcing elements 3, 3 1 in this variant.
- the two slightly inwardly curved support walls 31 are supported by the rib structure 41. This prevents premature bulging or kinking of the support walls 31.
- this task is performed by the wall 43 made of thermoplastic material and arranged between the support walls 31.
- the thermoplastic 4 or 5 is positively anchored to the same reinforcing element 3, 3 1 via bores 34 which are provided in the reinforcing elements 3, 3 'and are penetrated by the thermoplastic.
- the reinforcement elements 3, 3 'in the area of the connection points 4 and 5 are surrounded by walls 42 by these.
- the reinforcing elements 3, 3 1 are divided along the longitudinal axis 21 of the profile 2 on the underside 22. The mode of operation is not impaired as compared to the embodiment according to FIG. 4 and the assembly of the two halves of the reinforcing element 3 is simplified.
- FIGS. 1 to 7 show connections of profiles with a rectangular cross section. Since the inner contour of the reinforcing elements 3,
- the composite component according to FIG. 6 is formed by profiles 1 and 2 and by two reinforcing elements 3 and 3 '(see also FIGS. 8 to 10), which are plugged onto the profiles 1 and 2 to be joined from both sides. Then the thermoplastic 4 is in the area of the connection point 10 on the to be connected
- Fig. 6 on the left side of the figure the positively joined profiles 1 and 2 and the reinforcing element 3 'are shown.
- the right-hand side shows the fully formed connection in which thermoplastic 4 is sprayed onto profiles 1 and 2 and reinforcing element 3.
- the reinforcing element 3 completely covered by connecting thermoplastics 4 and is therefore no longer visible.
- the composite components according to FIGS. 6 and 7 show how the profile 2 is connected to profile 1 via the additional flanges 63 and 24.
- the reinforcing elements 3 and 3 1 ensure a high torsional rigidity by means of the walls 32 which form-fit the profiles 1 and 2 and by means of the support walls 31 for a high bending rigidity between the profiles 1 and 2.
- Connection thermoplastic 4 which comprises all the individual parts 1, 2, 3, 3 'encloses, secures the cohesion of the connection through the material tension built up in the injection molding process in the thermoplastic.
- the inward arched support walls 31 support each other thermoplastic.
- a composite component is shown, which has an opening 35 on the back to allow the immersion of a core in the injection mold and thus the support of the hollow profiles 1, 2 and 8 during the injection molding process.
- the parts to be joined are first
- Components 1, 2 and 8 and the reinforcing elements 6, 6 'and 30 are placed in an injection mold.
- the thermoplastic component is then injected and the walls 42, the rib structure 41 and the fillings of the bores 34 are formed.
- the opening 35 can be closed with an after the thermoplastic component has been injected
- the profiles 1, 2 and 8 to be connected are mutually supported by the support walls 31 of the reinforcing elements 6, 6 'and 30 and held together by the rib structure 41, the fillings of the bores 34 and the walls 42.
- the reinforcing elements 6, 6 'and 30 can be in beads (not shown) of the components 1, 2 and 8 can be embedded in order to achieve an additional positive connection between the reinforcing elements 6, 6 'and 30 and the profiles 1, 2, and 8 to be joined.
- FIG. 13 Another possibility for reinforcing composite components is shown in FIG. 13.
- a reinforcement element 136 is shown for reinforcing a corner, which is formed by three rod-shaped components, similar to that in FIG. 11.
- the profiles to be joined lie against the walls 32 and are supported against one another by the supporting walls 31. Through the bores 34, a rivet connection between the profiles to be joined and the reinforcing element 136 can be realized.
- a solution is shown in the composite part according to FIG. 15, in which the effect of the injection pressure during the injection molding process is restricted to areas outside the hollow profiles to be joined.
- the hollow profiles 1 and 2 as well as the reinforcing elements 3 and 3 ' are placed in an injection molding tool and only extrusion-coated with the thermoplastic component in the area of the support walls 31.
- the thermoplastic component forms the connecting element 4, which is formed from the walls 42, the connecting webs 44 and the rivet heads 45.
- the connecting webs 44 it is achieved that the walls 42 and the rivet heads 45 can be formed by means of a sprue over each of the two supporting walls 31 through the thermoplastic component.
- a riveted connection of the reinforcing elements 3, 3 ' is produced via congruent bores (not shown) which are located in the supporting walls 31 of the reinforcing elements 3 and 3' in the area of the rivet heads 45.
- the connection of the reinforcing elements 3 and 3 ' is additionally reinforced by an extrusion coating in the area of the wall 42.
- the reinforcing elements 3 and 3 ' can be embedded in the components 1 and 2 via beads (not shown) in order to achieve an additional positive connection between the reinforcing elements 3 and 3' and the profiles 1 and 2 to be connected.
- the hollow profile 161 is connected directly to the U-profile 162. Both profiles are made of metal and are shown separately in FIGS. 17 and 18 in the non-connected state. U-profile 162 is deeper in the connection area, so that there is a retaining wall on the top and bottom
- the profile has an integration of the reinforcing element.
- the function of the reinforcing element is taken over by the interaction of the parts 21, 23 and 25.
- the hollow profile 161 is positively connected to the U-profile 162 by means of the interlocking beads 16 and 26.
- molded plastic rivets 45 can be formed on the connecting webs 44 of the rib structure 4, which secure the bond between the two profiles 161 and 162.
- the U-profile 162 is closed on the rear side via the wall 25 and flange 23.
- Flange 23 can also contain additional holes (not shown), which are also used to form riveted joints.
- the profile 161 is first in the profile
- the profile 161 is supported with the aid of a movable core in the injection molding tool, which dips into the hollow profile 161 through the opening 28 in the profile 162 in the connection area 10, in order to prevent the profile 161 from collapsing due to the high injection pressure during the injection molding process.
- connection shown in FIG. 16 can also be carried out with a U-profile rotated by 180 °.
- FIG. 19 shows an example of an instrument panel cross member for a motor vehicle, which is composed of the tube segments 1, 2 and 7.
- the cross member is on the fender banks, not shown, via the flanges 136 and
- the U-profile 9 is attached to pipe segment 1.
- the profile 9 is fastened to the body via the flanges 936 and the bores 934 (see FIG. 21).
- the passenger airbag is on the holes 334 of the two fasteners
- the individual profiles 1, 2, 3, 7, 8, 9 are plugged together and are held together by overmolding from thermoplastic 4. In order to be able to show the node areas of the connections between the profiles 1, 2, 3, 7, 8, 9, these are shown in FIG. 21 without thermoplastic overmolding.
- the profiles 1, 2, 7, 8, 9 are positively connected to one another via beads 126, 326 726, 826 and 926.
- a fixed connection of the individual components 1, 2, 7, 8 and 9 takes place via congruent bores 327, 827 and 927, which are filled by the thermoplastic overmoldings 4 (see FIG. 19). These connections are made by rivets 45 (see FIG. 20 ), which are formed as an integral part of the overmoldings 4 and 5.
- flanges 323, 823 and 923 With the help of flanges 323, 823 and 923, the torsional rigidity of the connections is further improved.
- a rib structure 41 To reinforce the U profiles 8 and 9, they are provided with a rib structure 41.
- the rib structure 41 is connected to the overmolding 4 in the multi-part connection area via the edge encapsulation 42 and 47.
- the rib structure 41 is at the rib cross gen 48 anchored to the U-profile 8 or 9 via rivets 45.
- the recess 46 in the rib structure 41 of the U-profile 9 allows the steering column to be received.
- the individual profiles 1, 2, 7, 8 and 9 are first put together.
- pipe segments 1, 2 and 7 from a pipe (by internal high-pressure forming (IHU)) or from two half-shells that are divided lengthways.
- IHU internal high-pressure forming
- the assembled profiles 1, 2, 7, 8 and 9 are placed in an injection mold.
- the mold is closed and a core, which is part of the injection molding tool, dips into the opening of profiles 1 and 7.
- the cores are designed so that they are in the retracted position
- thermoplastic Map the inner contour of pipe segments 1, 2 and 7.
- the thermoplastic is then injected and the thermoplastic overmoldings 4 and 5 with the molded-on rib structures 41, overmolding 42 and 47 are formed.
- the movable tool cores which are in the pipe segments 1, 2 and 7 during the injection molding process, prevent them from collapsing due to the high injection pressure.
- FIG. 22 shows the connection of the profiles 221, 222, 227, 228 and 229 to a door frame structure with thermoplastic overmolding 224.
- FIG. 23 again, only the profiles 221, 222, 227, 228 and 229 without thermoplastic overmolding are shown to illustrate the connection areas , Profiles 221, 228 and
- profile 228 consist of torsionally rigid closed box profiles.
- the profile 228 forms the window frame and is widened at the lower ends so that it can be plugged together with the profiles 221 and 229.
- the profiles 221, 228 and 229 can also be welded together from individual parts or consist of an IHU part.
- thermoplastic rib structure 41 are reinforced.
- a positive connection between the profiles 221, 222, 227, 228 and 229 is produced via congruent beads 226, 726 and 826.
- the thermoplastic overmoldings 224 hold the assembled individual parts 221, 222, 227, 228 and 229 firmly together.
- profiles 221 to 229 are put together and placed in an injection mold.
- the box profiles 221 and 229 are filled with movable tool cores in a manner similar to the previous application example and are thereby supported during the injection molding process.
- Connection areas and the rib structures 41 are formed.
- the structure shown in FIG. 24 consists of a torsionally rigid box profile 241, two side U-profiles 242, 242 ', which are predominantly subjected to bending, and for further stiffening the frame structure, a further U-profile 247 and a Z-profile 248.
- the profiles 247 and In other versions, 248 can also consist of U-profiles or closed box profiles.
- the U-profiles 242, 242 'and 247 are reinforced with a rib structure 41.
- the Z-Profile 248 can also be equipped with ribs or functional elements to hold windows, wiper motor, lock, etc. (not shown).
- the thermoplastic overmoldings 244 hold the individual profiles 241, 242, 242 ', 247 and
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- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Transportation (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Body Structure For Vehicles (AREA)
- Mutual Connection Of Rods And Tubes (AREA)
Abstract
L'invention concerne un composant composite constitué d'au moins deux profilés (1, 2), ainsi qu'un procédé de fabrication dudit composant. Selon l'invention, au moins un profilé (1) entre en contact avec le deuxième profilé (2) par l'intermédiaire d'une extrémité libre, ou pénètre dans ledit deuxième profilé (2). Ladite invention se caractérise en ce que des renforts (3, 3'; 6, 6'; 23; 25; 21) sont disposés au niveau de la zone d'assemblage (10) des profilés (1, 2), lesdits renforts étant spatialement complémentaires des profilés (1, 2), et en ce que les profilés (1, 2) sont reliés l'un à l'autre par l'intermédiaire de plastique thermoplastique pulvérisé ou emmanché à chaud au niveau de la zone d'assemblage (10).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10022360A DE10022360A1 (de) | 2000-05-08 | 2000-05-08 | Profilverbundbauteil und Verfahren zu seiner Herstellung |
DE10022360 | 2000-05-08 | ||
PCT/EP2001/004632 WO2002002292A1 (fr) | 2000-05-08 | 2001-04-25 | Composant composite profile et procede de fabrication |
Publications (1)
Publication Number | Publication Date |
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EP1282499A1 true EP1282499A1 (fr) | 2003-02-12 |
Family
ID=7641182
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP01980211A Withdrawn EP1282499A1 (fr) | 2000-05-08 | 2001-04-25 | Composant composite profile et procede de fabrication |
Country Status (15)
Country | Link |
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US (1) | US20030152745A1 (fr) |
EP (1) | EP1282499A1 (fr) |
JP (1) | JP2004501802A (fr) |
KR (1) | KR20020091276A (fr) |
CN (1) | CN1222400C (fr) |
AR (1) | AR028027A1 (fr) |
AU (1) | AU2002212112A1 (fr) |
BR (1) | BR0110640A (fr) |
CA (1) | CA2408241A1 (fr) |
CZ (1) | CZ20023702A3 (fr) |
DE (1) | DE10022360A1 (fr) |
MX (1) | MXPA02010963A (fr) |
PL (1) | PL358325A1 (fr) |
TW (1) | TW519561B (fr) |
WO (1) | WO2002002292A1 (fr) |
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2000
- 2000-05-08 DE DE10022360A patent/DE10022360A1/de not_active Withdrawn
-
2001
- 2001-04-23 AR ARP010101877A patent/AR028027A1/es unknown
- 2001-04-25 WO PCT/EP2001/004632 patent/WO2002002292A1/fr not_active Application Discontinuation
- 2001-04-25 JP JP2002506908A patent/JP2004501802A/ja active Pending
- 2001-04-25 US US10/275,456 patent/US20030152745A1/en not_active Abandoned
- 2001-04-25 PL PL01358325A patent/PL358325A1/xx not_active Application Discontinuation
- 2001-04-25 MX MXPA02010963A patent/MXPA02010963A/es unknown
- 2001-04-25 CA CA002408241A patent/CA2408241A1/fr not_active Abandoned
- 2001-04-25 AU AU2002212112A patent/AU2002212112A1/en not_active Abandoned
- 2001-04-25 BR BR0110640-6A patent/BR0110640A/pt not_active Application Discontinuation
- 2001-04-25 CN CNB018092365A patent/CN1222400C/zh not_active Expired - Fee Related
- 2001-04-25 CZ CZ20023702A patent/CZ20023702A3/cs unknown
- 2001-04-25 KR KR1020027014899A patent/KR20020091276A/ko not_active Application Discontinuation
- 2001-04-25 EP EP01980211A patent/EP1282499A1/fr not_active Withdrawn
- 2001-05-02 TW TW090110448A patent/TW519561B/zh active
Non-Patent Citations (1)
Title |
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See references of WO0202292A1 * |
Also Published As
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KR20020091276A (ko) | 2002-12-05 |
DE10022360A1 (de) | 2001-11-15 |
CZ20023702A3 (cs) | 2003-04-16 |
CN1222400C (zh) | 2005-10-12 |
AU2002212112A1 (en) | 2002-01-14 |
BR0110640A (pt) | 2003-03-18 |
US20030152745A1 (en) | 2003-08-14 |
AR028027A1 (es) | 2003-04-23 |
CN1427758A (zh) | 2003-07-02 |
WO2002002292A1 (fr) | 2002-01-10 |
MXPA02010963A (es) | 2003-05-27 |
JP2004501802A (ja) | 2004-01-22 |
CA2408241A1 (fr) | 2002-11-05 |
PL358325A1 (en) | 2004-08-09 |
TW519561B (en) | 2003-02-01 |
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