EP1270811A1 - Verfahren zum Imprägnieren von Dekorpapieren - Google Patents
Verfahren zum Imprägnieren von Dekorpapieren Download PDFInfo
- Publication number
- EP1270811A1 EP1270811A1 EP20020006502 EP02006502A EP1270811A1 EP 1270811 A1 EP1270811 A1 EP 1270811A1 EP 20020006502 EP20020006502 EP 20020006502 EP 02006502 A EP02006502 A EP 02006502A EP 1270811 A1 EP1270811 A1 EP 1270811A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- decorative paper
- parts
- abrasive substance
- amino resin
- grain size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0469—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
- B44C5/0476—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper with abrasion resistant properties
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/26—Aminoplasts
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/826—Paper comprising more than one coating superposed two superposed coatings, the first applied being pigmented and the second applied being non-pigmented
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
- Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
- Y10T428/277—Cellulosic substrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31993—Of paper
Definitions
- the invention relates to a method for impregnating for manufacturing highly abrasion-resistant laminate flooring materials used decorative paper, in which the decorative paper is first moistened with an amino resin and thereby impregnated as well as regulating the resin content.
- the mass is applied by spreading rollers in the wet phase directly after Impregnate or applied in an intermediate drying stage.
- the invention has for its object the disadvantages described above to avoid known manufacture of highly abrasion-resistant laminate flooring materials and to be able to produce highly abrasion-resistant decorative laminate flooring materials, whereby the decorative paper showing the surface structure evenly with particulate Corundum or aluminum oxide is coated without the surface of the so Floor materials produced has a graying.
- One of the main differences of the method according to the invention is that that for impregnating the decorative paper and for applying the abrasion bodies such as Corundum or alumina particles used mass or dispersion is sprayed or applied in the nozzle principle.
- the nozzle principle has the advantage over the roller application that the Abrasive bodies such as dispersion containing corundum particles constantly and before application completely circulated and thus moved more or less uniformly. Consequently There are no signs of sedimentation leading to irregularities. Therefore, the addition of viscosity-increasing substances or Substances are dispensed with. In fact, flow aids can even be used that cause a better distribution of the abrasion material like corundum, which in the press used to compress the material is advantageous.
- Corundum or aluminum oxide there is no particular fine grain of the Corundum or aluminum oxide must be respected, but that corundum or other particulate abrasion material with significantly larger or coarser grain size can be used. This in turn means that relatively small amounts Corundum or other particulate abrasion material is needed to make higher To achieve abrasion values.
- Another advantage of the invention is that you do not, as in the known Apply the mass or dispersion used for impregnation using Spreading rollers with relatively slow impregnation speeds of For example, 18 to 25 m / min must drive to a reasonably constant To ensure order, but that one with the inventive method, at to which the mass or dispersion is applied by means of nozzles, impregnation speeds can reach or realize between 40 to 50 m / min.
- a special dispersion is first placed in a storage container with an agitator premixed. 200 kg melamine resin (Kauramin impregnating resin 786 from the company BASF), 10 kg of water, 1.5 kg of a wetting agent, 0.4 kg of a release agent and 1.5 kg Hardener (H 527 from BASF) stirred. Then add 80 kg Corundum with an average grain size of 135 ⁇ m. After stirring for 10 min 25 kg of 6-caprolactam and 0.9 kg of a commercially available silane coupling agent were added.
- melamine resin Karl impregnating resin 786 from the company BASF
- a standard impregnation channel from VITS is provided after the impregnation plant, with a push-in unit consisting of a spreader roller, a deflection roller, a nozzle gap with a collecting trough, a pair of metering rollers and wire doctor rollers, is arranged.
- a decorative paper web with a basis weight of 70 g / m 2 is passed through the impregnation unit and the additional construction.
- a resin application of 75 g / m 2 (determined after drying) is first set. When this value is reached, the nozzle is started and the special dispersion is applied.
- a final mass of 155 g / m 2 is set via the second pair of metering rollers.
- the paper treated in this way is passed through a dryer at a speed of 45 m / min. The residual moisture is 6.1%.
- the decor paper is then placed on a HDF carrier board in a short-cycle press pressed (pressing temperature 180 ° C, pressing time 20 s). You get a brilliant surface, which meets the requirements of pr-EN 13329 and an abrasion value of IP Has 12,000.
- particulate silicon carbide is used with a average grain size of 125 microns used. It will be a dark colored decorative paper used.
Landscapes
- Laminated Bodies (AREA)
- Floor Finish (AREA)
- Paper (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Description
Claims (8)
- Verfahren zum Imprägnieren von zum Herstellen hochabriebfester Laminat-Fußbodenmaterialien verwendeter Dekorpapiere, bei dem das Dekorpapier zunächst mit einem Aminoharz angefeuchtet und dadurch imprägniert wird, wobei die Menge des Harzes mittels Dosierwalzen geregelt wird,
dadurch gekennzeichnet, dassauf das angefeuchtete nasse Dekorpapier zusätzlich eine Schicht aus einem Aminoharz in spezieller Dispersion aufgedüst wird, wobei die endgültige Flächenmasse - bezogen auf die Trockenmasse des Rohpapiers - 100 % bis 250 % beträgt,als abrasive Substanz Siliziumcarbid mit einer durchschnittlichen Korngröße von 60 bis 160 µm oder als abrasive Substanz Aluminiumoxid in Form von Korund oder aus der Schmelze mit einer Korngröße von 60 bis 160 µm in der Dispersion verwendet wird. - Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass Dispersion aus 100 Teilen eines Aminoharzes, 20 bis 95 Teilen abrasiver Substanz, 0,5 bis 2,5 Teilen eines
Silanhaftvermittlers, 5 bis 25 Teilen eines Fließhilfsstoffes, 0,1 bis 0,4 Teilen eines Netzmittels, 0,05 bis 0,4 Teilen eines Trennmittels und eines Aminoharzhärters verwendet wird. - Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass als Aminoharz ein Melaminharz verwendet wird.
- Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass als Fließhilfsstoff Polyglycolether, E-Caprolactam oder Butandiol verwendet wird.
- Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass ein Gemisch aus Silizlumcarbid und Aluminiumoxid als abrasive Substanz in beliebiger Mischung verwendet wird.
- Dekorpapier für die Verwendung bei hochabriebfesten Laminat-Fußbodenmaterialien, herstellbar nach einem Verfahren mit den Merkmalen nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass das Dekorpapier als abrasive Substanz Siliziumcarbid mit einer durchschnittlichen Korngröße von 60 bis 160 µm oder als abrasive Substanz Aluminiumoxid in Form von Korund oder aus der Schmelze mit einer Korngröße von 60 bis 160 µm umfasst.
- Dekorpapier nach Anspruch 6, dadurch gekennzeichnet, dass das Dekorpapier als Aminoharz ein Melaminharz aufweist.
- Laminat-Fußbodenmaterial mit einem Dekorpapier nach einem der Ansprüche 6 oder 7.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE59908146T DE59908146D1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum Imprägnieren von Dekorpapieren |
AT02006502T ATE256786T1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum imprägnieren von dekorpapieren |
SI9930502T SI1270811T1 (en) | 1999-01-26 | 1999-01-26 | Method for impregnating decorative papers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP1999/000604 WO2000044984A1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum imprägnieren von dekorpapieren |
EP99973654A EP1068394B1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum imprägnieren von dekorpapieren |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99973654A Division EP1068394B1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum imprägnieren von dekorpapieren |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1270811A1 true EP1270811A1 (de) | 2003-01-02 |
EP1270811B1 EP1270811B1 (de) | 2003-12-17 |
Family
ID=8167200
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20020006502 Revoked EP1270811B1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum Imprägnieren von Dekorpapieren |
EP99973654A Revoked EP1068394B1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum imprägnieren von dekorpapieren |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99973654A Revoked EP1068394B1 (de) | 1999-01-26 | 1999-01-26 | Verfahren zum imprägnieren von dekorpapieren |
Country Status (10)
Country | Link |
---|---|
US (2) | US6835421B1 (de) |
EP (2) | EP1270811B1 (de) |
CN (1) | CN100523375C (de) |
AT (1) | ATE254692T1 (de) |
AU (1) | AU3252099A (de) |
DE (2) | DE59907803D1 (de) |
HK (1) | HK1035219A1 (de) |
PT (2) | PT1068394E (de) |
SK (1) | SK286684B6 (de) |
WO (1) | WO2000044984A1 (de) |
Families Citing this family (46)
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ATE254692T1 (de) * | 1999-01-26 | 2003-12-15 | Kronospan Tech Co Ltd | Verfahren zum imprägnieren von dekorpapieren |
US7763345B2 (en) | 1999-12-14 | 2010-07-27 | Mannington Mills, Inc. | Thermoplastic planks and methods for making the same |
US8028486B2 (en) | 2001-07-27 | 2011-10-04 | Valinge Innovation Ab | Floor panel with sealing means |
ES2400939T3 (es) * | 2003-09-30 | 2013-04-15 | Kronoplus Technical Ag | Papel decorativo con corindón dispersado recubierto con un adhesivo |
DE20318290U1 (de) * | 2003-11-26 | 2004-04-01 | M. Kaindl | Antistatisches Papier nebst Paneel |
DE202004000084U1 (de) | 2004-01-06 | 2004-04-29 | M. Kaindl | Einschwenkprofil |
DE202004003061U1 (de) * | 2004-02-25 | 2005-07-14 | Kronospan Technical Company Ltd., Engomi | Dekorpapier mit elektrisch geladenen Fasern |
DE102004043355B4 (de) * | 2004-09-08 | 2006-09-21 | Kronotec Ag | Imprägnat |
DE102004063043B3 (de) * | 2004-12-22 | 2006-07-20 | Vits Systems Gmbh | Vorrichtung zum Auftragen einer Beschichtungsmasse auf eine Papierbahn |
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DE202005015978U1 (de) * | 2005-10-10 | 2007-02-15 | Kronospan Technical Co. Ltd., Engomi | Abriebfeste Platten mit dekorativer Oberfläche |
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DE102006054890A1 (de) | 2006-11-20 | 2008-05-21 | WKP Württembergische Kunststoffplatten-Werke GmbH & Co. KG | Beschichtungsmaterialien sowie Verfahren zum Herstellen solcher Beschichtungsmaterialien |
DE102007010483B4 (de) | 2007-03-03 | 2010-09-30 | Laminatepark Gmbh & Co. Kg | Verfahren zur Herstellung eines Paneels mit Kern und Dekorpapier |
ATE552124T1 (de) | 2007-05-15 | 2012-04-15 | Flooring Ind Ltd Sarl | Herstellungsverfahren für tafeln und dadurch gewonnene tafel |
DE102007025135B3 (de) * | 2007-05-30 | 2009-02-05 | Flooring Technologies Ltd. | Holzwerkstoffplatte und Verfahren zur Herstellung |
DE102007028603B4 (de) | 2007-06-19 | 2011-04-14 | Dakor Melamin Imprägnierungen Gmbh | Laminat mit einer abriebfesten Dekorfolie und dessen Herstellungsverfahren, insbesondere mit einem Overlay mit besonderem optischen Effekt |
DE102007047636A1 (de) * | 2007-10-04 | 2009-04-09 | Dakor Melamin Imprägnierungen Gmbh | Verfahren zum Herstellen einer abriebfesten Folie und nach diesem Verfahren herstellbare Finishfolie |
CA2705517A1 (en) * | 2007-11-16 | 2009-05-22 | Photocat A/S | Photocatalytic boards or panels and a method of manufacturing thereof |
PT2222922T (pt) * | 2007-12-17 | 2017-09-11 | Schoeller Technocell Gmbh & Co Kg | Impregnado de papel decorativo passível de compressão, que pode ser impresso pelo processo de jato de tinta |
EP2106903A1 (de) | 2008-02-22 | 2009-10-07 | Hermes Schleifkörper GmbH | Verfahren zum Aufstreuen abriebhemmender Werkstoffe und Vorrichtung hierzu |
WO2009117782A1 (en) | 2008-03-28 | 2009-10-01 | Depco-Trh Pty Ltd | Method for manufacturing an overlaying material |
CN102037082B (zh) | 2008-05-20 | 2014-05-28 | 日本化药株式会社 | 偶氮化合物及包含所述偶氮化合物的染料基偏振膜和偏振片 |
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DE3643742A1 (de) | 1986-12-20 | 1988-06-30 | Schwihag Gmbh | Unterlagsplatte fuer die befestigung der schienen von eisenbahngleisen und -weichen auf holzschwellen |
SE460274B (sv) | 1988-02-18 | 1989-09-25 | Perstorp Ab | Foerfarande foer framstaellning av ett noetningsbestaendigt, dekorativt haerdplastlaminat |
SE467150B (sv) * | 1988-08-25 | 1992-06-01 | Perstorp Ab | Dekorativt haerdplastlaminat med extremt foerhoejd slitstyrka |
JPH03136807A (ja) * | 1989-09-22 | 1991-06-11 | Noda Corp | 化粧板 |
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US5344704A (en) * | 1993-04-07 | 1994-09-06 | Nevamar Corporation | Abrasion-resistant, aesthetic surface layer laminate |
JPH071414A (ja) * | 1993-06-21 | 1995-01-06 | Ibiden Co Ltd | 抗菌性化粧板およびその製造方法 |
FR2743580B1 (fr) | 1996-01-11 | 1998-04-03 | Mead Corp | Procede pour fabriquer des recouvrements a resistance elevee a l'abrasion |
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-
1999
- 1999-01-26 AT AT99973654T patent/ATE254692T1/de not_active IP Right Cessation
- 1999-01-26 EP EP20020006502 patent/EP1270811B1/de not_active Revoked
- 1999-01-26 US US09/647,129 patent/US6835421B1/en not_active Expired - Lifetime
- 1999-01-26 EP EP99973654A patent/EP1068394B1/de not_active Revoked
- 1999-01-26 WO PCT/EP1999/000604 patent/WO2000044984A1/de not_active Application Discontinuation
- 1999-01-26 CN CNB998039306A patent/CN100523375C/zh not_active Expired - Lifetime
- 1999-01-26 PT PT99973654T patent/PT1068394E/pt unknown
- 1999-01-26 DE DE59907803T patent/DE59907803D1/de not_active Revoked
- 1999-01-26 AU AU32520/99A patent/AU3252099A/en not_active Abandoned
- 1999-01-26 PT PT02006502T patent/PT1270811E/pt unknown
- 1999-01-26 SK SK1400-2000A patent/SK286684B6/sk not_active IP Right Cessation
- 1999-10-12 DE DE29917947U patent/DE29917947U1/de not_active Expired - Lifetime
-
2001
- 2001-08-17 HK HK01105826A patent/HK1035219A1/xx not_active IP Right Cessation
-
2004
- 2004-12-21 US US11/018,325 patent/US7569270B2/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
US6835421B1 (en) | 2004-12-28 |
PT1270811E (pt) | 2004-04-30 |
DE29917947U1 (de) | 2000-03-09 |
CN100523375C (zh) | 2009-08-05 |
EP1068394B1 (de) | 2003-11-19 |
US20060134405A1 (en) | 2006-06-22 |
US7569270B2 (en) | 2009-08-04 |
HK1035219A1 (en) | 2001-11-16 |
DE59907803D1 (de) | 2003-12-24 |
AU3252099A (en) | 2000-08-18 |
ATE254692T1 (de) | 2003-12-15 |
WO2000044984A1 (de) | 2000-08-03 |
EP1270811B1 (de) | 2003-12-17 |
SK14002000A3 (sk) | 2001-06-11 |
EP1068394A1 (de) | 2001-01-17 |
CN1292840A (zh) | 2001-04-25 |
SK286684B6 (sk) | 2009-03-05 |
PT1068394E (pt) | 2004-03-31 |
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