EP1027477A1 - METALLBEHANDLUNGSFLÜSSIGKEIT FÜR DEN NEUTRALEN pH-BEREICH - Google Patents

METALLBEHANDLUNGSFLÜSSIGKEIT FÜR DEN NEUTRALEN pH-BEREICH

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Publication number
EP1027477A1
EP1027477A1 EP98956861A EP98956861A EP1027477A1 EP 1027477 A1 EP1027477 A1 EP 1027477A1 EP 98956861 A EP98956861 A EP 98956861A EP 98956861 A EP98956861 A EP 98956861A EP 1027477 A1 EP1027477 A1 EP 1027477A1
Authority
EP
European Patent Office
Prior art keywords
acid
range
carboxylic acids
metal treatment
nitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98956861A
Other languages
German (de)
English (en)
French (fr)
Inventor
Andreas Rathjens
Sigrid Friese
Wiltrud Klose
Jürgen Geke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1027477A1 publication Critical patent/EP1027477A1/de
Withdrawn legal-status Critical Current

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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
    • C10M129/36—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms containing hydroxy groups
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles

Definitions

  • the invention relates to metal treatment fluids such as cooling lubricants, cleaners and corrosion protection emulsions. which can be used due to a new corrosion inhibitor combination in the pH range from about 6 to about 9, in particular up to about 8.5.
  • the corrosion inhibitor combination of carboxylic acids and nitrogen compounds has a good buffering effect in addition to the good corrosion protection effect.
  • the pH value of the metal treatment liquid which is in the neutral range, can be maintained for a longer period of time despite possible acid entry and / or microbiological acid development.
  • corrosion-prone metals such as iron, aluminum, zinc. Copper or its alloys against corrosion is a wide-ranging technical task. It arises particularly when the metal parts are not or not yet covered with a permanently corrosion-protecting coating, such as a varnish, for example, due to their processing condition or their area of application. Examples of this are metal parts during technical processing stages such as cutting or non-cutting shaping or cleaning as well as finished metal components such as Heat exchangers or pipelines that come into contact with corrosive aqueous media during their operation. In order to prevent or contain corrosion during or between the individual processing steps or during the intended use, the metal surfaces are brought into contact with corrosion inhibitors, which provide temporary protection against corrosion.
  • corrosion inhibitors It is often necessary for technical reasons, for example in aqueous cooling or heating circuits, or for reasons of environmental protection, for example during or after an aqueous cleaning of the metal surfaces. that the corrosion inhibitors can be brought into contact with the metal surfaces in the aqueous phase. Therefore, it is a desirable property of corrosion inhibitors to be water soluble or at least water dispersible.
  • inorganic corrosion inhibitors can be based, for example, on chromates, nitrites or phosphates, which are more or less disadvantageous for toxicological and ecological reasons.
  • Organic corrosion inhibitors are often based on carboxylates. Amines. Amides or on nitrogen-containing heterocyclic compounds. In practice, however, carboxylic acids do not prove to be sufficiently long-term effective if the pH value, which is usually in the alkaline region, is lowered by an acid input into the inhibitor baths or by microbiological processes to such an extent that the carboxylic acids are present in the less effective acid form instead of in the salt form .
  • carboxylic acids as anticorrosive agents in cooling lubricants, for example. Cleaners and corrosion protection emulsions are common in the prior art.
  • DE-A-42 29 848 describes a cooling lubricant emulsion whose corrosion protection system is based on a combination of long-chain fatty acids, short-chain fatty acids, dimer fatty acids and aromatic carboxylic acids such as benzoic acid or salicylic acid.
  • the carboxylic acids are neutralized with potassium hydroxide.
  • DE-A-43 23 909 teaches two-component agents for cleaning and / or passivating metal surfaces. one component containing the anti-corrosion agents.
  • the corrosion inhibitor active ingredients are selected from
  • R is a straight-chain or branched, saturated or unsaturated alkyl or alkenyl radical having 5 to 21 carbon atoms or a radical of the general formula (II)
  • R ' saturated, straight-chain or branched alkyl radical having 6 to 18 carbon atoms and N represents hydrogen, an alkali metal ion equivalent or an ammonium ion,
  • EP-A-556 087 reveals the knowledge that monocarboxylic acids with an odd number of carbon atoms, in particular heptanoic acid, nonanoic acid and undecanoic acid. represent particularly effective corrosion inhibitors.
  • nitrogen-free corrosion protection agents with a good buffer effect which have a pH in the application concentration of 7 to 11. They contain as a corrosion protection component carboxylic acid anions having 6 to 44 C atoms and, as buffer component aromatic hydroxy compounds with a pK s value for the hydroxy group in the range 7-1. 1
  • conventional corrosion protection agents usually have an alkaline pH in the application concentration in the range from about 9 to about 10.
  • the alkaline agents can also endanger the user, for example by splashing in the eyes.
  • There is therefore a need for effective corrosion protection agents which can be used in the neutral pH range between about 6 and about 9, preferably between about 6 and about 8.5 and in particular between about 6 and about 8. These agents are safer to use and easier to dispose of than conventional agents. They should also have a certain buffer capacity so that the approximately neutral pH value can be maintained for a longer period of time despite possible acid entry and / or microbiological acid development.
  • neutral corrosion inhibitors for aerosol spray cans consist of certain ammonium salts of carboxylic acids. These cause corrosion inhibition in the approximately neutral pH range. Since such aerosol spray cans are closed systems, decomposition of the corrosion-inhibiting liquid by microorganisms is not to be expected. Therefore, in this closed system, there can be no pH shift due to biological processes, so that the liquid does not have to be stabilized against a shift in pH. Accordingly, the corrosion inhibitor combination need not have a buffering effect and the pK $ values of the nitrogen compounds can be in any range. In fact, the pK a values are in accordance with EP 520 108 to be used nitrogen compounds all above. 9
  • the present invention has for its object to provide a corrosion protection system for the pH range between about 6 and about 9, which is stabilized against acidification due to biological decomposition processes.
  • the corrosion protection system must therefore have a certain buffer effect in this pH range.
  • a metal treatment liquid having a pH in the range 6 to 9 comprising a combination of one or more carboxylic acids and one or several nitrogen compounds selected from organic amines or nitrogen-containing heterocycles, wherein the nitrogen compounds have a pK a value for at least one Protolysis level in the range of 6 to 9, in a weight ratio of 10: 1 to 10: 20.
  • the pH is preferably in the range from 6 to 8.5 and in particular in the range from 6 to 8. Accordingly, the nitrogen compounds also have preferred as a pK a value in the range of 6 to 8.5 and especially in the range of 6 to 8.
  • carboxylic acids When this is referred to as carboxylic acids, this means that the acids can be used as such or in the form of their salts which are water-soluble in the use concentration. Depending on the pK s value of the acids, a pH-dependent balance of acid anions and undissociated acid is established. This applies accordingly to the equilibrium between the free nitrogen base and its protonated form.
  • the weight ratio of carboxylic acids: nitrogen compounds is preferably in the range from about 10: 2 to about 10:10.
  • the carboxylic acid is preferably selected from mono- or polybasic, saturated or unsaturated, linear or branched aliphatic carboxylic acids with 6 to 14 carbon atoms and from carboxylic acids with heteroatoms inserted into the carbon chain. which have between 6 and 26 atoms in the carbon heteroatom chain.
  • Examples of such carboxylic acids are the unbranched saturated carboxylic acids n-hexanoic acid. n-octanoic acid.
  • An example of a dicarboxylic acid is 1.8-octanedicarboxylic acid.
  • a preferred example of an unsaturated short-chain carboxylic acid is 1,4-hexadienoic acid (sorbic acid).
  • the preferred carboxylic acids with heteroatoms inserted into the carbon chain are preferably ether carboxylic acids of the general formula R - (0-C 2 H 4 ) n - OCH 2 COOH, where R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 16 carbon atoms, n is a number in the range from 1 to 5 and R and n are to be coordinated with one another such that the sum of the C-- and O atoms, neglecting the carboxyl group, is not greater than 25.
  • the ether carboxylic acids can be technical mixtures of molecules with different radicals R and different values for n. An example of this is the technical lauryl ether carboxylic acid, in which R stands for a mixture of linear, saturated alkyl groups with 12 and 14 C atoms and n is about 2.5.
  • Aromatic carboxylic acids containing nitro groups are also suitable as carboxylic acids.
  • An example of such an acid is 3-nitrobenzoic acid.
  • the nitrogen compound which additionally acts as a buffer is of particular importance. in order to stabilize the metal treatment liquid against acid input or acid formation and thus keep it usable for a longer period of time compared to unbuffered systems without further maintenance measures. It is preferred to choose those nitrogen compounds which have a buffering capacity of about 1 to about 4. To determine this value, dilute 50 mg of the nitrogen compound with 50 ml of deionized water. If the nitrogen compound is not sufficiently water-soluble for this. it is first dissolved in 10 ml of isopropanol and then diluted to 50 ml with deionized water.
  • pH of this solution is below 6.0, titrate with 0.1 N sodium hydroxide solution. If the aqueous solution of the nitrogen compound has a pH of above 7.5, it is tritrated with 0.1 N hydrochloric acid. The consumption of 0.1 N alkali or acid in ml to change the pH from 6.0 to 7.5 or from 7.5 to 6.0 is defined as the buffer capacity. If the pH of the solution is in the range between 6.0 and 7.5, it is first adjusted to a value of with lye above 7.5 and then titrate with 0.1 N acid until the pH is lowered from 7.5 to 6.0.
  • the pK ⁇ value is known to be the negative decimal logarithm of the
  • Acid constants Kg which is generally known as a thermodynamic variable and is a measure of the completeness of the proton transfer reaction from the acid to water and thus of the acid strength. Details on this can be found in general chemistry textbooks. HRChristen may be mentioned as an example: “Fundamentals of General and Inorganic Chemistry", Verlag Sauerators. Aarau and Disterweg.Salle, Frankfurt. 4th edition 1973, pp. 353-372.
  • the pK s value refers to the conjugate acid of the nitrogenous base, ie to the protonated nitrogen compound. So you choose the acid constant for the equilibrium reaction of the protonated nitrogen base with water to the free nitrogen base and an oxonium cation.
  • the nitrogen compounds have multiple nitrogen atoms. it is according to the invention sufficient for the pK s value for the protolysis in the desired range.
  • the pKs values for a number of nitrogen compounds can be found, for example, in DD Perrin: "Dissociation Constants of Organic Bases in Aqueous Solutions". International Union of Pure and Applied Chemistry, Butterworths (London), 1965.
  • the nitrogen compounds can be selected, for example, from linear or cyclic alkylenediamines, alkylenetriamines and alkylenetetraamines.
  • alkylenetriamines examples of such compounds are ethylenediamine, propylenediamine (in particular 1,2-propylenediamine), butylenediamine. Diethylene triamine. Dipropylenetriamine. Triethylene tetraamine and tripropylene tetraamine. Ethylene diamine is preferred.
  • Another example are guanidinium salts with suitable anions. especially guanidinium carbonate.
  • Such nitrogen compounds are also very suitable. which are selected from 5- or 6-membered aromatic organic heterocycles with 1 or 2 nitrogen atoms, which can also be present as parts of benzo-fused ring systems.
  • a preferred example of such heterocycles is imidazole, having a pK s value of about. 7
  • Metal treatment fluids according to the present invention which can be used, for example, as water-soluble cooling lubricants, as water-mixed cooling lubricant emulsions, as cleaners or as corrosion protection emulsions, are usually commercially available as concentrates and are diluted by the user on site with water to the application concentration.
  • Such concentrates of the metal treatment liquids are used in amounts of about 5 to about 30% by weight of the carboxylic acid. preferably about 8 to about 20% by weight, the nitrogen compound in amounts between about 0.5 to about 40% by weight. preferably about 2 to about 10% by weight.
  • Ready-to-use solutions or oil-in-water emulsions are prepared from such concentrates by dilution with water. These ready-to-use metal treatment fluids are usually adjusted in this way. that they contain about 2 to about 10% by weight of the concentrate in water. Of course, such metal treatment liquids can also be prepared by dissolving or dispersing the individual components in the desired concentration in water. Here, one is independent of the manufacturability of the concentrates and has a greater freedom of formulation. Such a method is not common in practice, however, individual components in an otherwise ready-to-use Metal treatment liquid can be added if necessary.
  • the metal treatment fluids in the form of a ready-to-use aqueous solution or a ready-to-use oil-in-water emulsion thus they contain about 0.1 to about 3% by weight, preferably about 0.2 to about 2% by weight of the carboxylic acid and about 0.01 to about 6% by weight. preferably about 0.04 to 2% by weight of the nitrogen compound.
  • the invention relates to the use of a combination of one or more carboxylic acids and one or more nitrogen compounds selected from organic amines or nitrogen-containing heterocycles in a weight ratio of 10: 1 to 10:20 as corrosion inhibitors in metal treatment liquids with a pH in the range of 6 to 9.
  • the nitrogen compounds have a pKa value for at least one protolysis stage in the range from 6 to 9.
  • the pH is of the metal treatment liquid in the range of about 6 to about 8.5 and especially from about 6 to about 8.
  • the nitrogen compounds have a pK a - value for at least a protolysis in the range of 6 to 8.5 and in particular have in the range of 6 to 8.
  • the weight ratio of carboxylic acids: nitrogen compounds is preferably from about 10: 2 to about 10:10.
  • the above detailed explanations apply to the carboxylic acids and nitrogen compounds which are preferably used in this use.
  • Typical metal treatment fluids for the pH range between about 6 and about 9, which contain the combination of carboxylic acids and nitrogen compounds according to the invention are cooling lubricants or cooling lubricant emulsions and neutral cleaners or their concentrates.
  • the metal treatment liquid can be an oil-in-water emulsion with an oil content of about 0.2 to 4% by weight, which contains nonionic surfactants as emulsifiers. Suitable nonionic surfactants are, for example, ethoxylates or propoxylates of fatty alcohols.
  • Such oil-in-water emulsions are usually prepared by adding concentrates with water.
  • these concentrates generally contain about 30 to 50% by weight of an oil component such as mineral oil, about 10 to 20% by weight of emulsifiers, about 20 to 50% by weight of the combination of carboxylic acids and nitrogen compounds according to the invention and as Remainder water and / or other auxiliary substances.
  • an oil component such as mineral oil
  • emulsifiers emulsifiers
  • the combination of carboxylic acids and nitrogen compounds according to the invention can be added to oil-free cooling lubricant solutions such as grinding water.
  • oil-free cooling lubricant solutions such as grinding water.
  • grinding water is usually marketed as a concentrate and diluted by the user with water to the application concentration.
  • the application concentration is usually about 2 to about 8, in particular about 4 to about 6,% by weight of concentrate in water.
  • These concentrates usually contain about 6 to about 30% by weight of the combination of carboxylic acids and nitrogen compounds according to the invention.
  • the grinding water concentrates usually contain non-ferrous metal inhibitors in amounts between about 0.05 and about 0.3% by weight.
  • non-ferrous metal inhibitors are triazines, triazoles or thiazoles.
  • examples include benzotriazole, tolyltriazole or benzothiazole derivatives.
  • Optional components of grinding water concentrates are, for example, boric acid in amounts of about 5 to about 15% by weight and complexing agents such as nitrilotriacetic acid in amounts of about 0.01 to about 0.2% by weight.
  • the concentrates of the grinding water are advantageously used with polyhydric alcohols. such as glycerin. For example, a concentrate between about
  • 1,2-diaminoethane ethylenediamine
  • a buffer capacity determined as described above, of 4.4
  • imidazole with a buffer capacity of 2.0
  • guanidinium carbonate with a buffer capacity of 2.4.
  • Diaminoethane has protolysis in the second at 20 ° C has a pKa of 7
  • imidazole at 20 ° C has a pK a of 7.2.
  • suitable examples are 1, 2-diaminopropane with a pK a value in the second protolysis stage at 25 ° C of 7, 1, 1,3-diaminopropane with a pK a value at 20 ° C of 8.6 or diethylenetriamine with a pK s value of 8.9 in the second protolysis stage at 20 ° C.
  • suitable examples of nitrogen compounds having pK s values in accordance with the invention the desired range can be the above-cited work of Table DD Perrin be removed.
  • Enepar 301 (paraffinic mineral oil) 609.3 g
  • the concentrate was additionally mixed with the amounts of corrosion inhibitor combination given in Table 1.
  • The% data of the components given in Table 1 relate to the total amount of concentrate after adding the inhibitor combination.
  • water-mixed cooling lubricant emulsions with the percentages of concentrate given in Table 1 were produced from the concentrates.
  • the corrosion protection properties of the ready-to-use water-mixed cooling lubricant emulsions were determined using the shavings / filter paper method in accordance with German standard DIN 51 360, part 2. For this test, cast iron shavings are wetted with the cooling lubricant emulsion on a round filter, exposed to room temperature for 2 hours in a petri dish and then visually assessed the circular filter on corrosion marks.
  • a degree of corrosion 0 means no signs of corrosion. a degree of corrosion 4 strong signs of corrosion.
  • the test results for application concentrations of 5 to 8% by weight of concentrate in water according to DIN 51360 are given in Table 1.
  • the Water according to DIN 51360 is prepared in the following way: A solution is prepared by dissolving 39 g of calcium chloride hexahydrate with deionized water to a volume of one liter. Solution B is also prepared by dissolving 44 g of magnesium sulfate heptahydrate with deionized water to a volume of one liter.
  • the table contains the pH of the 5% cooling lubricant emulsion, which, if necessary, was adjusted to the stated value with alkali or acid.
  • the corrosion protection effect was additionally carried out after a plate climate test.
  • steel sheets of the quality ST 1405 with the dimensions 5 cm x 10 cm were brushed with an aqueous surfactant solution, rinsed with water and alcohol and dried. The sheets were then immersed in the application solution, drained and stored in a climatic chamber at 22 ° C. and a relative air humidity of 76%.
  • concentrates were first prepared which contained 20% by weight of heptanoic acid, 5% by weight of nitrogen compound and 75% of completely demineralized water. Ethylene diamine, imidazole and guanidinium carbonate were selected as nitrogen compounds.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Removal Of Specific Substances (AREA)
EP98956861A 1997-10-30 1998-10-21 METALLBEHANDLUNGSFLÜSSIGKEIT FÜR DEN NEUTRALEN pH-BEREICH Withdrawn EP1027477A1 (de)

Applications Claiming Priority (3)

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DE19747895 1997-10-30
DE19747895A DE19747895A1 (de) 1997-10-30 1997-10-30 Metallbehandlungsflüssigkeit für den neutralen pH-Bereich
PCT/EP1998/006693 WO1999023281A1 (de) 1997-10-30 1998-10-21 METALLBEHANDLUNGSFLÜSSIGKEIT FÜR DEN NEUTRALEN pH-BEREICH

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DE19833894A1 (de) 1998-07-28 2000-02-03 Fuchs Dea Schmierstoffe Gmbh & Wassermischbares Kühlschmierstoff-Konzentrat
DE10217208B4 (de) * 2002-04-18 2004-09-16 Clariant Gmbh Verwendung von Ethercarbonsäuren mit niedrigem Stockpunkt
DE102007004292A1 (de) * 2007-01-23 2008-07-24 Henkel Ag & Co. Kgaa Kühlschmierstoff für die wässrige Zerspanung von Leichtmetallen mit hohem Dispergiervermögen
US8802606B2 (en) 2010-08-06 2014-08-12 Basf Se Lubricant composition having improved antiwear properties
AR078234A1 (es) 2009-08-07 2011-10-26 Basf Se Composicion lubricante
DE102012204683A1 (de) 2012-03-23 2013-09-26 Henkel Ag & Co. Kgaa Korrosionsschutzsystem für die Behandlung von Metalloberflächen

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DE1769769B2 (de) * 1968-06-15 1973-05-03 Fuji Iron & Steel Co Ltd , Tokio Schmier- und korrosionsschutzmittel fuer die spanlose stahlbearbeitung, insbesondere fuer tiefziehbleche
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ZA989884B (en) 1999-04-30
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NO20002246L (no) 2000-04-28
NO20002246D0 (no) 2000-04-28
WO1999023281A1 (de) 1999-05-14

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