EP0995781B1 - Beschichtungszusammensetzung - Google Patents

Beschichtungszusammensetzung Download PDF

Info

Publication number
EP0995781B1
EP0995781B1 EP99917073A EP99917073A EP0995781B1 EP 0995781 B1 EP0995781 B1 EP 0995781B1 EP 99917073 A EP99917073 A EP 99917073A EP 99917073 A EP99917073 A EP 99917073A EP 0995781 B1 EP0995781 B1 EP 0995781B1
Authority
EP
European Patent Office
Prior art keywords
resin
soluble
water
coating material
beads
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99917073A
Other languages
English (en)
French (fr)
Other versions
EP0995781A4 (de
EP0995781A1 (de
Inventor
Takaharu Yasue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Petrochemical Co Ltd
Original Assignee
Idemitsu Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Petrochemical Co Ltd filed Critical Idemitsu Petrochemical Co Ltd
Publication of EP0995781A1 publication Critical patent/EP0995781A1/de
Publication of EP0995781A4 publication Critical patent/EP0995781A4/de
Application granted granted Critical
Publication of EP0995781B1 publication Critical patent/EP0995781B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18—Spheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L89/00—Compositions of proteins; Compositions of derivatives thereof

Definitions

  • the present invention relates to a coating material to be coated on a resin sheet etc. for preventing blocking or the like caused when the resin sheet etc. are superposed.
  • resin sheets (or films) having flat surface generally have no surface lubricity and are likely to cause blocking (a phenomenon where solid surfaces are stuck together to form continuity of mutual materials), which results in following problems.
  • the blocking when the blocking is caused to a raw fabric (wound sheet in roll shape) of a sheet, the sheet cannot be unrolled from the raw fabric. Further, when the sheet is cut while being superposed, the blocking is caused between the sheets by being pressed during cutting process, so that the sheets are bonded with each other and are unable to peel off.
  • starch powder etc. is conventionally sprayed onto the sheet surface or an appropriate coating material is coated thereon.
  • a coating material having good adhesive properties is inferior in heat sealability.
  • a coating material having good heat sealability is inferior in adhesive properties to the sheet.
  • inorganic filler is generally added to the conventional coating material for avoiding blocking and deterioration of surface lubricity, which results in inferior transparency thereof.
  • Silicone is sometimes blended to the coating material for imparting surface lubricity.
  • a sheet coated by a coating material blended with silicone is inferior in printability thereof.
  • polyolefin type sheet is inferior in adhesive properties with the coating material, thereby impairing applicability.
  • Japanese Patent Publication No. Sho 59-47991 Japanese Patent Publication No. Sho 59-47991
  • film coating compounds composed of acrylic copolymer and slipping agent Japanese Patent Laid-Open Publication No. Hei 2-3433
  • a heat sealable covering film coated with a coating fluid made of emulsion composed of particular wax and inorganic lubricant added to polyvinyl chloride vinylidene emulsion Japanese Patent Publication No. Hei 3-63586
  • a sheet applied with the above-described coating material is bonded as necessary in assembling as a wrapping box etc.
  • the primer coating before bonding increases steps in fabrication, which result in higher production cost.
  • US-A-2970365 describes coating the surface of fleece fibres with an adhesive binder to form a thin surface of bonded fibres, which is then dried and subjected to needling.
  • a wide range of adhesive binders are contemplated, with one of the exemplified binders consisting of 100 parts by weight of an acrylic resin emulsion (46% total solids) and 20 parts by weight of an ammonia casein solution (20% total solids).
  • US-A-3250638 describes fibrous products, such' as highly specular glazed papers, having adhered thereto a metallic film.
  • the examples describe coating compositions coated on to a base paper to form a glazed paper, and which comprise amongst other ingredients a waxy emulsion and casein.
  • US-A-5238736 describes polymeric microspheres which can optionally be mixed with resin and then coated on to a substrate.
  • the polymeric microspheres are composed of short-chain diol diacrylate homopolymers or copolymers of diol diacrylates and long-chain acrylate esters.
  • a primary object of the present invention is to provide a coating material capable of enhancing anti-blocking property and surface lubricity without deteriorating adhesive properties with the sheet, heat sealability, transparency and printability thereof.
  • Another object of the present invention is to provide a coating material capable of enhancing adhesivity of the sheet itself as well as being capable of improving the above anti-blocking properties.
  • a coating material according to first aspect of the present invention includes at least one substance selected from the group consisting of water-soluble resin, resin emulsion and solvent resin (A) and resin beads (B); and a water-soluble amine additive (D) selected from an aminosilane and a polyoxyethyleneallylaminoether, wherein: the resin beads (B) are composed of polyethylene, acyrl, nylon, polyester or polypropylene; the content of the resin beads (B) is 0.01 to 20.0wt%; and the average particle size of the resin beads (B) is not more than 20 ⁇ m.
  • (A) is a low-molecular-weight resin for enhancing adhesion with a base member.
  • water-soluble resin is water-soluble acryl resin, water-soluble polyurethane resin, water-soluble polyester and the like.
  • resin emulsion is acryl emulsion, polyurethane emulsion, polyester emulsion and the like.
  • the solvent resin is a solution of urethane resin, acryl resin polyvinyl chloride resin etc. into a solvent composed of at least one substance selected from dimetylformamide (DMF), methyl ethyl ketone (MEK), toluene, cyclohexane, butyl acetate etc.
  • DMF dimetylformamide
  • MEK methyl ethyl ketone
  • Content of the (A) component is preferably 0.1 to 50.0wt%. When the content is less than 0.1wt%, stable coating is difficult. When the content exceeds 50.0wt%, fabrication can be deteriorated.
  • the resin beads (B) are contained for improving heat sealability.
  • Average particle size of the beads is more preferably, not more than 10 ⁇ m. When the average particle size exceeds 20 ⁇ m, roughness is felt to deteriorate touch, which may also cause dropout of beads.
  • a coating material according to second aspect of the present invention includes at least one substance selected from a group consisting of water-soluble resin, resin emulsion and solvent resin (A) and at least one substance selected from the group consisting of soluble protein and resin emulsion incompatible with the (A) component (C) and a water-soluble amine additive (D) selected from an aminosilane and a polyoxyethyleneallylaminoether.
  • the component (C) is contained for improving surface lubricity and anti-blocking properties of the base member.
  • soluble protein is whey (serum lactis), egg white, silk (fibroin), collagen, casein, gelatin, sericin, serum protein etc.
  • egg white is an albumen of egg of chicken, quail, duck, goose and the like.
  • the "soluble” means water-soluble and solvent-soluble.
  • resin emulsion incompatible with above (A) is ethylene-acryl copolymer, ethylene-vinyl acetate copolymer etc.
  • Content of the (C) component is preferably from 0.01wt% to 10wt%. Sufficient improving effect of the surface lubricity and the anti-blocking properties cannot be obtained below 0.01wt%. And transparency is lowered over 10.0wt%.
  • the water-soluble amine additive (D) is added for improving adhesion with the base member and improving antiblocking properties.
  • adhesion of the sheet is improved by the coating.
  • water-soluble amine additive examples include aminosilanes, such as N-.(aminoetyl).-aminopropylmetyldimethoxysilane, N-(aminoetyl)-aminopropylmetyltrimethoxysilane, .-aminopropylmetyltrimethoxysilane, aminopropylmetyltriethoxysilane, and polyoxyethyleneallylaminoethers such as polyoxyethylenelaurylaminoether and polyoxyethylenestearylaminoether.
  • aminosilanes such as N-.(aminoetyl).-aminopropylmetyldimethoxysilane, N-(aminoetyl)-aminopropylmetyltrimethoxysilane, .-aminopropylmetyltrimethoxysilane, aminopropylmetyltriethoxysilane, and polyoxyethyleneallylamino
  • the content of the water-soluble amine additive is 0.01 to 20% (solid content ratio) relative to the above-described components (A to C).
  • Any coating method can be used for the coating material added with the water-soluble amine additive, which may be general methods such as gravure, offset, and comma coater.
  • the sheet processed with the coating material added with the water-soluble amine additive may be bonded by general adhesive (cyanoacrylate adhesive).
  • a coating material according to third aspect of the present invention includes at least one substance selected from a group consisting of water-soluble resin, resin emulsion and solvent resin (A); resin beads (B); at least one substance selected from the group consisting of soluble protein and resin emulsion incompatible with the (A) component (C); and a water-soluble amine additive (D) selected from an aminosilane and a polyoxyethyleneallylaminoether, wherein the resin beads (B) are composed of polyethylene, acryl, nylon, polyester or polypropylene, the content of resin beads is 0.01 to 20.0 weight % and their average size is no more than 20 ⁇ m.
  • coating material superior in adhesion with the sheets etc, heat sealability, surface lubricity of the base member and anti-blocking properties can be obtained.
  • the coating material of the present invention can be coated on any specific base member, which is, for example, transparent soft resin (such as polyvinyl chloride and olefin resin) sheet, enamel coated fabric.
  • transparent soft resin such as polyvinyl chloride and olefin resin
  • the coating material of the present invention may be coated in any manner and general process such as use of gravure, offset, and comma coater etc may be used.
  • Coating material of the Experiment 1 included 1.0wt% of water-soluble acryl resin (solid content 30%) as the water-soluble resin (A), 0.25wt% of polyethylene beads as the resin beads (B), and 98.75wt% of water.
  • the coating material of Experiment 2 included 0.5% of N- ⁇ (aminoetyl) ⁇ -aminopropylmethyltrimethoxysilane as a water-soluble amine additive in addition to the coating material of Experiment 1 (including 1.0wt% of water-soluble acryl resin (solid content 30%) as a water-soluble resin (A), 0.25wt% of acryl beads as resin beads (B) and 98.75wt% of water).
  • the coating material was coated onto a polypropylene sheet using a gravure coater (150 mesh) and dried at 100°C for 10 seconds.
  • the coating material according to the present invention is suitable for coating for improving anti-blocking properties when a resin sheet having flat surface is cut while being wound to a roller or being superposed.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Claims (3)

  1. Beschichtungszusammensetzung, welche umfasst: zumindest eine Substanz, welche ausgewählt ist aus der Gruppe, die wasserlösliches Harz, Harzemulsion und Lösungsmittelharz (A) umfasst, Harzkügelchen (B), und einen wasserlöslichen Aminzusatz (D), der ausgewählt ist aus einem Aminosilan und einem Polyoxiethylenallylaminoether, wobei:
    die Harzkügelchen (B) zusammengesetzt sind aus Polyethylen, Acryl, Nylon, Polyester oder Polypropylen;
    der Gehalt der Harzkügelchen (B) zwischen 0,01 bis 20,0 Gew.-% liegt; und
    die durchschnittliche Teilchengröße der Harzkügelchen (B) nicht mehr als 20 µm beträgt.
  2. Beschichtungszusammensetzung, welche umfasst: zumindest eine Substanz, die ausgewählt ist aus einer Gruppe, die wasserlösliches Harz, Harzemulsion und Lösungsmittelharz umfasst (A); zumindest eine Substanz (C), die ausgewählt ist aus der Gruppe, die ein lösliches Eiweiß und Harzemulsion umfasst, die inkompatibel ist mit der Komponente (A); und einem wasserlöslichen Aminzusatz (D), der ausgewählt ist aus einem Aminosilan und einem Polyoxiethylenallylaminoether.
  3. Beschichtungszusammensetzung, welche umfasst: zumindest eine Substanz, die ausgewählt ist aus einer Gruppe, die wasserlösliches Harz, Harzemulsion und Lösungsmittelharz umfasst (A); Harzkügelchen (B); zumindest eine Substanz (C), die ausgewählt ist aus der Gruppe, die ein lösliches Eiweiß umfasst und eine Harzemulsion, die inkompatibel ist mit der (A)-Komponente; und einem wasserlöslichen Aminzusatz (D), der ausgewählt ist aus einem Aminosilan und einem Polyoxiethylenallylaminoether, wobei:
    die Harzkügelchen (B) zusammengesetzt sind aus Polyethylen, Acryl, Nylon, Polyester oder Polypropylen;
    der Gehalt der Harzkügelchen (B) zwischen 0,01 bis 20,0 Gew.-% liegt; und
    die durchschnittliche Teilchengröße der Harzkügelchen (B) nicht mehr als 20 µm beträgt.
EP99917073A 1998-04-23 1999-04-21 Beschichtungszusammensetzung Expired - Lifetime EP0995781B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP11355698 1998-04-23
JP11355698 1998-04-23
PCT/JP1999/002112 WO1999054419A1 (fr) 1998-04-23 1999-04-21 Materiau de revetement

Publications (3)

Publication Number Publication Date
EP0995781A1 EP0995781A1 (de) 2000-04-26
EP0995781A4 EP0995781A4 (de) 2001-07-25
EP0995781B1 true EP0995781B1 (de) 2004-08-18

Family

ID=14615293

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99917073A Expired - Lifetime EP0995781B1 (de) 1998-04-23 1999-04-21 Beschichtungszusammensetzung

Country Status (5)

Country Link
US (1) US6545082B2 (de)
EP (1) EP0995781B1 (de)
KR (1) KR100605785B1 (de)
DE (1) DE69919480T2 (de)
WO (1) WO1999054419A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE384524T1 (de) * 1999-07-16 2008-02-15 Shoei Co Ltd Nitroimidazolpräparationen zur äusseren anwendung zur behandlung von atopischer dermatitis
DE20119233U1 (de) * 2001-11-26 2002-02-07 Boewing Gmbh Chem Fab L Beschichtungsmasse und damit hergestellte funktionelle Beschichtung auf Formteilen aus Kautschuk
DE10208039A1 (de) * 2002-02-26 2003-09-04 Basf Ag Haftklebstoffe, enthaltend Polyethylen
US6723916B2 (en) * 2002-03-15 2004-04-20 Parker-Hannifin Corporation Combination EMI shielding and environmental seal gasket construction
CA2492098A1 (en) * 2002-07-10 2004-01-22 Akzo Nobel Nv Depolymerization of water soluble polysaccharides
DE10360610A1 (de) * 2003-12-19 2005-07-14 Kalle Gmbh & Co. Kg Proteinhaltige, schlauchförmige Nahrungsmittelhülle mit Innenverstärkung
KR100604984B1 (ko) * 2004-06-10 2006-07-31 한국생산기술연구원 나노점토가 포함된 부식방지 코팅제 및 그 제법
US20060246302A1 (en) * 2005-04-29 2006-11-02 Brady Michael D Methods for protecting glass
US20060246299A1 (en) * 2005-04-29 2006-11-02 Brady Michael D Methods for protecting glass
GB0521585D0 (en) * 2005-10-22 2005-11-30 Depuy Int Ltd A spinal support rod
KR101267766B1 (ko) 2006-07-20 2013-05-27 현대모비스 주식회사 자동차 플라스틱 내장재용 박막형 질감도료 조성물
US20080242822A1 (en) * 2007-04-02 2008-10-02 West Richard A Polyurethane formulation using protein-based material
MX2011009084A (es) 2009-03-06 2012-01-25 Biopolymer Technologies Ltd Espumas que contienen proteinas, su produccion y sus usos.
US8519031B2 (en) 2009-03-06 2013-08-27 Biopolymer Technologies, Ltd. Protein-containing emulsions and adhesives, and manufacture and use thereof
US8821970B2 (en) 2009-05-22 2014-09-02 Corning Incorporated Slip agent for protecting glass
WO2011156380A2 (en) 2010-06-07 2011-12-15 Biopolymer Technologies, Ltd. Protein-containing adhesives, and manufacture and use thereof
ES2777941T3 (es) * 2011-07-22 2020-08-06 Pimec Películas recubiertas de proteínas del suero de la leche
CN102399460A (zh) * 2011-09-08 2012-04-04 皆爱西(上海)节能环保工程有限公司 盈速粒涂料
WO2013036739A1 (en) 2011-09-09 2013-03-14 Biopolymer Technologies, Ltd. Protein-containing adhesives, and manufacture and use thereof
WO2013036744A1 (en) 2011-09-09 2013-03-14 Biopolymer Technologies, Ltd. Protein-containing adhesives, and manufacture and use thereof
EP3666845A1 (de) 2012-07-30 2020-06-17 Evertree Proteinklebstoffe mit einer anhydrid-, carbonsäure- und/oder carboxylatsalzverbindung und deren verwendung
CN102911573A (zh) * 2012-10-30 2013-02-06 广东华兹卜化学工业有限公司 鱼胶原抗冲击木器漆

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL235456A (de) * 1958-08-04 1900-01-01
US3250638A (en) 1962-01-17 1966-05-10 Frederic H Lassiter Metal coated paper employing irradiated subbing layer
BE631317A (de) 1962-04-24 1900-01-01
DE1669156A1 (de) 1967-09-01 1971-05-13 Bayer Ag Binderfarben
JPS487254B1 (de) * 1968-09-06 1973-03-03
US4124548A (en) 1974-05-01 1978-11-07 Dulux Australia Ltd. Mar-resistant paints
JPS51109032A (ja) * 1975-03-22 1976-09-27 Japan Synthetic Rubber Co Ltd Kamihifukusoseibutsu
JPS529030A (en) * 1975-07-11 1977-01-24 Dainippon Toryo Co Ltd Water-based resin composition for tentative corrosionproofing
GB2099444B (en) * 1981-05-29 1984-08-01 Berger Jenson & Nicholson Ltd Anti-fouling compositions
US4590022A (en) * 1981-10-26 1986-05-20 Seton Company Method of forming a moisture permeable polymeric sheet material
US4494052A (en) 1982-08-05 1985-01-15 Rca Corporation DC Motor servo system
US4543106A (en) * 1984-06-25 1985-09-24 Carborundum Abrasives Company Coated abrasive product containing hollow microspheres beneath the abrasive grain
JPS61111374A (ja) * 1984-11-05 1986-05-29 Nippon Erasutoran Kk 塗料組成物
US5800861A (en) * 1985-08-15 1998-09-01 The Sherwin-Williams Company High solid infrared absorbing compositions
DE3620165A1 (de) * 1986-06-14 1987-12-17 Wolff Walsrode Ag Innenausruestung von schlauchfoermigen nahrungsmittelhuellen
JPH0794623B2 (ja) * 1986-06-20 1995-10-11 新星鋼業株式会社 水溶性熱硬化型樹脂塗料
US4981758A (en) 1988-01-29 1991-01-01 Mobil Oil Corporation Thermoplastic films coated with acrylic polymer
JPH0243271A (ja) * 1988-08-04 1990-02-13 Toshiba Corp 冷凍サイクル用断熱塗料
JP2864543B2 (ja) 1989-08-01 1999-03-03 株式会社デンソー 移動体識別装置用応答器
JPH03134071A (ja) * 1989-10-18 1991-06-07 Nippon Paint Co Ltd ロールコート用水性塗料組成物
JPH03269065A (ja) * 1990-03-16 1991-11-29 Kao Corp カバーシート用塗料
US5064868A (en) * 1990-11-28 1991-11-12 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Sprayable lightweight ablative coating
JP2993159B2 (ja) * 1991-03-29 1999-12-20 藤倉化成株式会社 塗料組成物
JPH0565429A (ja) * 1991-07-05 1993-03-19 Nippon Paint Co Ltd 塗料の艶下げ方法、塗料および塗装品
JP2623043B2 (ja) * 1991-12-27 1997-06-25 東海ゴム工業株式会社 異音防止塗料
US5387463A (en) * 1992-01-24 1995-02-07 Dai Nippon Printing Co., Ltd. Transparent protective substrate provided with hard coating having glare reducing property, method for producing the same and polarizing plate
JP3092640B2 (ja) 1992-08-12 2000-09-25 株式会社アルファ技研 ２−シアノアクリレート系瞬間接着剤用プライマー
US5238736A (en) * 1992-09-18 1993-08-24 Minnesota Mining And Manufacturing Company Polymeric microspheres for low-friction surfaces
JPH0853635A (ja) * 1994-08-10 1996-02-27 Sekisui Chem Co Ltd 粗面仕上げ用塗料
US6051106A (en) 1996-03-22 2000-04-18 Nippon Paper Industries Co., Ltd. Cast-coated paper and production method thereof
US5691410A (en) * 1996-06-21 1997-11-25 The United States Of America As Represented By The Secretary Of The Army Water dispersible low-reflectance chemical resistance coating compostion
US6395356B1 (en) * 1997-05-14 2002-05-28 Teepak Properties, Llc Food casings having modified release properties and methods of manufacture
JP4101339B2 (ja) * 1997-09-25 2008-06-18 大日本印刷株式会社 光拡散フィルム、その製造方法、拡散層付偏光板及び液晶表示装置
US6083581A (en) * 1997-11-12 2000-07-04 Viskase Corporation Cellulase resistant cellulose casing and process
US6133342A (en) * 1999-01-21 2000-10-17 Marconi Data Systems Inc. Coating composition

Also Published As

Publication number Publication date
DE69919480D1 (de) 2004-09-23
WO1999054419A1 (fr) 1999-10-28
US20020010233A1 (en) 2002-01-24
EP0995781A4 (de) 2001-07-25
US6545082B2 (en) 2003-04-08
DE69919480T2 (de) 2005-08-18
EP0995781A1 (de) 2000-04-26
KR20010020477A (ko) 2001-03-15
KR100605785B1 (ko) 2006-07-31

Similar Documents

Publication Publication Date Title
EP0995781B1 (de) Beschichtungszusammensetzung
CN1070416C (zh) 组合膜和其在溶剂存在下的使用
US5427851A (en) Pressure sensitive adhesive and adhesive coated product
MXPA01010128A (es) Composicion de apresto de baja adhesion.
US5154974A (en) Adhesive composition having improved cutting properties
EP1370623B1 (de) Verfahren zur entklebung des randes einer klebebandrolle
EP0927752B1 (de) Druckempfindliches Klebeband mit antistatischer Beschichtung
EP1275684A1 (de) Auf polyolefin basierende folie, diese enthaltende anzeigefläche, verpackungsfolie, aufzeichnungsfolie, kosmetische folie, emblemfolie, dekorfolie sowie beschichtungsmaterial für polyolefinharze zur verwendung in diesen
US2599576A (en) Adhesive sheet or tape
JP4340050B2 (ja) ガスバリア性フィルム
US6306497B1 (en) Pressure-sensitive adhesive articles for use on transparent imaging films
JP3920972B2 (ja) 紙粘着テープ基材
JP2016141789A (ja) 塗工用剥離層形成組成物、及び、剥離層を有する壁紙
GB2344061A (en) Repositionable/slippable self-adhesive articles
JP3622940B2 (ja) 再剥離可能な情報記録用感圧接着シート
JP4307859B2 (ja) 感圧接着シート
JP2002120477A (ja) カット紙用疑似接着用紙
JP3537823B6 (ja) 静電トナー受理層を含むグラフィック物品
JP3537823B2 (ja) ゴム改質熱可塑性樹脂の静電トナー受理層
JPH10324079A (ja) プリント用シート
JPH11116933A (ja) 感圧接着剤および感圧接着性シート
JP2003072265A (ja) 疑似接着用紙
JPH05311135A (ja) 感圧粘着剤及びそれを使用した帳票
US20050053766A1 (en) Primer to enhance adhesion to irregular surfaces
JP2002023643A (ja) 疑似接着用紙

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): BE DE FR GB IT

17P Request for examination filed

Effective date: 20000403

A4 Supplementary search report drawn up and despatched

Effective date: 20010608

AK Designated contracting states

Kind code of ref document: A4

Designated state(s): BE DE FR GB IT

17Q First examination report despatched

Effective date: 20021121

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE DE FR GB IT

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 69919480

Country of ref document: DE

Date of ref document: 20040923

Kind code of ref document: P

ET Fr: translation filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

BECA Be: change of holder's address

Owner name: *IDEMITSU KOSAN CO. LTD1-1, MARUNOUCHI 3-CHOME, CH

Effective date: 20050706

26N No opposition filed

Effective date: 20050519

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

BECA Be: change of holder's address

Owner name: *IDEMITSU KOSAN CO. LTD1-1, MARUNOUCHI 3-CHOME, CH

Effective date: 20050706

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20080312

Year of fee payment: 10

Ref country code: DE

Payment date: 20080424

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20080616

Year of fee payment: 10

Ref country code: IT

Payment date: 20080429

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20080423

Year of fee payment: 10

BERE Be: lapsed

Owner name: *IDEMITSU KOSAN CO. LTD

Effective date: 20090430

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20090421

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20091231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091103

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090421

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091222

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090421