EP0535311A1 - Lampe à décharge à haute pression de faible puissance - Google Patents

Lampe à décharge à haute pression de faible puissance Download PDF

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Publication number
EP0535311A1
EP0535311A1 EP92109933A EP92109933A EP0535311A1 EP 0535311 A1 EP0535311 A1 EP 0535311A1 EP 92109933 A EP92109933 A EP 92109933A EP 92109933 A EP92109933 A EP 92109933A EP 0535311 A1 EP0535311 A1 EP 0535311A1
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EP
European Patent Office
Prior art keywords
discharge lamp
lamp according
pressure discharge
filling
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92109933A
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German (de)
English (en)
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EP0535311B1 (fr
Inventor
Dietrich Dr. Fromm
Andreas Dr. Hohlfeld
Günter Söhring
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osram GmbH
Original Assignee
Patent Treuhand Gesellschaft fuer Elektrische Gluehlampen mbH
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Publication of EP0535311A1 publication Critical patent/EP0535311A1/fr
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Publication of EP0535311B1 publication Critical patent/EP0535311B1/fr
Anticipated expiration legal-status Critical
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/12Selection of substances for gas fillings; Specified operating pressure or temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/82Lamps with high-pressure unconstricted discharge having a cold pressure > 400 Torr
    • H01J61/827Metal halide arc lamps
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/12Selection of substances for gas fillings; Specified operating pressure or temperature
    • H01J61/125Selection of substances for gas fillings; Specified operating pressure or temperature having an halogenide as principal component
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/30Vessels; Containers
    • H01J61/35Vessels; Containers provided with coatings on the walls thereof; Selection of materials for the coatings

Definitions

  • the invention relates to a high-pressure discharge lamp of low power. This means the range of around 35 - 200 W.
  • metal halide lamps for general lighting which are essentially characterized by a warm white light color (WDL) or neutral light color (NDL) corresponding to a color temperature of approximately 2600-4600 K.
  • WDL warm white light color
  • NNL neutral light color
  • Criteria for the suitability in general lighting are in particular a long lifespan of ⁇ 6000 hours and the best possible color rendering, which is expressed in a high Ra index.
  • a minimum value of Ra8 80 is sought for the overall color rendering index.
  • the individual index R9 which forms a yardstick for the reproduction in the red spectral range, is of particular importance. So far it has not been possible to find a satisfactory compromise between long service life and good color rendering.
  • From DE-PS 2 106 447 is one for the NDL light color developed filling from halides of sodium and various rare earth metals (SE) known.
  • SE rare earth metals
  • this filling is not suitable for the WDL light color, since too high a wall load would be required to achieve this light color, which, in connection with the fact that the majority of the rare earth material is present in the lamp as condensate, quickly becomes one chemical reaction of the filling substances with the quartz glass leads (devitrification), which significantly affects the service life.
  • EP-OS 215 524 Special efforts are made in EP-OS 215 524 to achieve a satisfactory lamp with good color rendering and low color temperature (corresponding to WDL).
  • the lamp is based on a Na-Tl system, possibly with the help of rare earth additives (including Sc).
  • the lamp must be operated with such a high wall load (> 25 W / cm2, typically 60 W / cm2) that a ceramic discharge vessel must be used.
  • a ceramic discharge vessel must be used.
  • several geometric relationships with regard to the discharge volume and the electrode arrangement must be maintained. This solution is theoretically interesting, but in practice unsatisfactory because the use of ceramic material is a completely new technology requires, which is associated with considerable additional costs and problems. This relates in particular to the permanent tightness of the implementation and the development of halogen-resistant glass solders.
  • An important aspect of the invention is the consideration that, with careful selection of the filling components, the wall load of a discharge vessel made of quartz glass can be chosen to be higher than the experts have hitherto assumed.
  • a limit of 20 W / cm2 has generally been regarded as the limit value, which can be seen, for example, in the "Technical-Scientific Treatments of the OSRAM Society” (TWAOG), Volume 12, Springer Verlag, Heidelberg 1986, page 11 ff (in particular Table 3 on page 15), is expressed.
  • Another document is DE-OS 40 13 039, page 3 (A. 54 (3) EPC).
  • the wall load increases with decreasing power level. This compensates for the heat losses that increase with the correspondingly small lamp dimensions. It is particularly critical for power levels below 100 W, which are particularly preferred for interior lighting.
  • a molar ratio of Na-H.:Sc-H. from 5 ... 24: 1 (preferably from 5 ... 22: 1, particularly preferably from 5 ... 19: 1) and Na-H.:Tl-H. from 25 ... 73: 1 used.
  • the sodium content is therefore reduced.
  • the present invention is therefore essentially based on the knowledge of the different roles of these two sodium compounds in relation to the filling / wall reaction and on the consequences drawn from them.
  • the result is a partially saturated lamp which is designed to be saturated with respect to the Na halides but unsaturated with respect to the complex compound and the Sc and Tl halides. If the Na-Sc ratio is below 5: 1, the desired color temperature cannot be achieved.
  • the reduction in the amount of sodium is compensated for by two measures: the first is a corresponding increase in the cold spot temperature in order to achieve the same warm white light color. This is done using a reflective coating. In particular, it is heat accumulation at the two ends of the two-sided squeezed discharge vessel.
  • the heat accumulation behavior must be optimized so that the cold spot temperature Tc exceeds 800 ° C; Previously common Tc values were around 600-800 ° C for quartz glass, whereas higher Tc values were previously only possible with ceramic discharge tubes.
  • This temperature is achieved particularly elegantly by a layer thickness of the heat accumulation covering which is considerably increased in comparison to previous versions. This effect can be intensified by evacuating the outer bulb.
  • the second measure is the use of Tl in the dosage according to the invention.
  • the task of the Tl is not so much in its direct contribution to improving color rendering. Rather, the focus is on the fact that it partially takes on the function of Na as an electron supplier. As a result, the degree of ionization of the Na vapor phase is reduced accordingly. A large part of the sodium is thus present as a neutral atom, which supports the broadening of the Na resonance line.
  • the thallium additive is dimensioned so that the lamp, when baked (after approx. 100 hours), lies almost exactly on the Planck curve and thus harmonises well with other light sources.
  • a Na-Tl ratio below 25: 1 would give the lamp a green tinge.
  • a ratio above 73: 1 would have an unfavorable effect on the burning voltage and the reignition behavior.
  • a Na / Tl ratio of between 25: 1 and 50: 1 if iodine is used exclusively as the halide.
  • the heat accumulation behavior can be influenced favorably by carefully designing the heat accumulation coating in the form of two calottes.
  • the decisive factor here is the thickness of the covering, its purity and the distance between the two covering domes. Zirconium oxide or aluminum oxide with a purity of at least 97% according to DE-OS 38 32 643 is advantageously used. With regard to the layer thickness, the dimensioning of which has so far been given no particular attention, care must be taken that it is sufficiently large, namely optically thick.
  • the thickness of an aluminum or zirconium oxide layer must be at least 0.15 mm.
  • the distance between the two domes of the covering should advantageously be chosen so that it is approximately 90 to 105% of the electrode distance.
  • the absolute dosage of the Na-Sc-Tl system is preferably 2.5 to 5.5 mg / cm3, based on the internal volume of the discharge vessel, so that the system is just at the limit of saturation.
  • Iodine possibly with a certain proportion of bromine, can be used as halogen.
  • bromine as a halide
  • Typical values are 30%, regardless of the light color.
  • the use of bromine is already known as a theoretical alternative to pure iodine fillings from US Pat. No. 4,866,342, but it has not yet been used in the lamps according to the invention. Only now has the behavior of a mixed filling of iodine and bromine been clarified to such an extent that their use seems particularly advantageous.
  • bromine causes the decrease in luminous flux (previously up to 30%), the decrease in color temperature (previously up to 600 K) and the drift of the color locus (decrease in the y coordinate up to 10 hundredths of a point) during the first 100 to 500 Operating hours is improved by more than 50%.
  • Na-Sc ratio 5 ... 13: 1 (based on the halides) is preferred for the exclusive addition of iodine as halide, in the case of a J / Br mixed filling a higher value, in particular up to 22: 1 , possibly even up to 24: 1, recommended.
  • the reason is that the addition of bromine causes a higher color temperature due to the partial elimination of the iodine-related absorption in the blue spectral range. This must be compensated for by increasing the Na-Sc ratio.
  • zirconium and / or hafnium halides can also be used in a total amount of up to 4 mol% of the metal halide filling.
  • Zr is also suitable for improving the R9 index because it also emits in the red spectral range.
  • Another essential dimensioning is the ratio of the maximum inside diameter of the Discharge vessel to the electrode gap. It is advantageously about 1.1 to 1.4 and is therefore significantly higher than the previously usual values of typically 0.9.
  • the term maximum inner diameter also indicates that the discharge vessel should preferably be bulged in the middle. In particular, a barrel body has proven itself. Another option is an ellipsoid. The degree of bulging is chosen in particular so that the so-called effective average inner diameter is approximately 0.9 to 1.2 times the electrode spacing.
  • the effective mean inner diameter is defined by the root of the inner volume, which has been divided by the electrode distance (cf. EP-PS 215 524).
  • a particular advantage of the lamp according to the invention is that the operating voltage of 100 V remains constant over a good approximation.
  • the spread of the color temperature is also reduced.
  • the lamp can be operated in any burning position without any significant change in the color values. This makes the lamp particularly suitable for illuminating large areas (e.g. halls), since the individual lamps have only slightly different color values.
  • the invention creates high-pressure discharge lamps of low power which are suitable for interior lighting. With a lifespan of 6000 hours, a color rendering index Ra8 ⁇ 80 and an R9 of ⁇ -30 are created. The proportion of red increases from 15% to more than 20%.
  • a getter material 14 applied to a metal plate is additionally melted in a potential-free manner via a piece of wire.
  • the ends of the discharge vessel 2 are provided with a heat-reflecting coating 15, 16 made of zirconium dioxide with a layer thickness of provided about 0.2 mm, so that the cold spot temperature is kept well above 800 ° C.
  • the coating forms two domes, the inner edges of which are arranged at the level of the electrode tips.
  • the electrode distance of 7 mm also corresponds to the distance between the inner edges.
  • the discharge vessel 2 is bulged in a barrel shape.
  • the generatrix of the barrel body is a circular arc with a radius of 11.1 mm.
  • the inside length of the discharge vessel is 14 mm, its inside volume is 0.69 m3 with a wall load of up to 22 W / cm2.
  • the quartz glass is about 1.3 mm thick.
  • the discharge vessel 2 contains a total of 2 mg of the following metal halides (molar fraction in% of the total metal halides): 89% NaJ, 8.3 in order to achieve a warm white light color (WDL) with a color temperature of 3000 K in addition to 16 mg of mercury and 120 mbar argon % ScJ3 and 2.7% TlJ.
  • WDL warm white light color
  • the luminous flux (100 hour value) increases by 20% to 6000 lm compared to a lamp with a known filling with the halides of sodium, tin, thallium, indium and lithium.
  • the luminous efficacy is 77 lm / W instead of 67 lm / W (15% increase).
  • the index R9 improves from -90 to -20, with the red component increasing from 15 to 21%.
  • the service life is 6000 hours.
  • the color scatter is reduced from ⁇ 300 K to ⁇ 130 K.
  • FIG. 2 shows a comparison of the spectrum of a 75 W lamp with the known sodium-tin filling (dashed line) with a structurally identical lamp which contains the above sodium-scandium-thallium filling.
  • the color temperature is set to 3300 K.
  • the spectrum has additional individual lines (a) that contribute to the improved color rendering index. They are caused by the addition of scandium.
  • the uniformity of the spectrum is significantly improved. Strong single lines in the spectrum of the conventional lamp, such as the lines of sodium (b), lithium (c), indium (d), mercury (e) and thallium (f) are more or less leveled (lithium is still present as an impurity).
  • Another embodiment is a similarly constructed 150 W lamp with warm white light color (WDL), the filling of which, in addition to mercury and argon, has a total of 4 mg of the same metal halide component as in the previous embodiment.
  • WDL warm white light color
  • This lamp also has a lifespan of at least 6000 hours.
  • the color scatter decreases from ⁇ 300 K to ⁇ 130 K.
  • the older comparison values relate to a filling that contains the iodides of dysprosium, holmium, thulium, sodium and thallium as metal halides.
  • the NaJ content can be partially (typically 30%) replaced by NaBr.
  • elemental Sc in an amount of 0.03 mg can be added to the Na-Sc-Tl filling of the first exemplary embodiment. This compensates for the inevitable loss of filling quantity in the first 100 hours, so that the constancy of the color values and also the burning voltage is improved.
  • Another scandium compound that releases Sc in substoichiometric amounts is suitable for this, e.g. ScJ2.
  • the above-mentioned dimensions of the discharge vessels are particularly advantageous because they avoid acoustic resonances when operating on high-frequency ballasts.
  • HPS filling color temperature 4000 K
  • metal halide component proportions in mol%): 81.9% NaJ, 14% ScJ3, 2.7% HfJ4 and 1 , 4% TlJ.
  • the molar ratio NaJ / ScJ3 is 6: 1 and the ratio NaJ / TlJ is 58: 1.
  • the invention has its main advantages in those of particular interest for interior lighting Color temperatures in the range of about 3000 K unfolded, corresponding to a light color WDL.
  • the addition of thallium is very important here, corresponding to a halide ratio Na / Tl of 25 ... 50: 1 for pure iodine fillings or up to 73: 1 for mixed fillings.
  • the principle of the invention can also be applied to color temperatures of approximately 4300 K (corresponding to the light color NDL).
  • the influence of the thallium naturally decreases, so that in this case a halide ratio Na / Tl up to 70: 1 is recommended for pure iodine fillings; a ratio of 50: 1 ... 65: 1 is particularly advantageous.
  • a ratio of 50: 1 ... 73: 1 is particularly suitable for mixed fillings.

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  • Discharge Lamp (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)
EP92109933A 1991-09-30 1992-06-12 Lampe à décharge à haute pression de faible puissance Expired - Lifetime EP0535311B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4132530A DE4132530A1 (de) 1991-09-30 1991-09-30 Hochdruckentladungslampe kleiner leistung
DE4132530 1991-09-30

Publications (2)

Publication Number Publication Date
EP0535311A1 true EP0535311A1 (fr) 1993-04-07
EP0535311B1 EP0535311B1 (fr) 1994-03-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP92109933A Expired - Lifetime EP0535311B1 (fr) 1991-09-30 1992-06-12 Lampe à décharge à haute pression de faible puissance

Country Status (8)

Country Link
US (1) US5363007A (fr)
EP (1) EP0535311B1 (fr)
JP (1) JPH05205697A (fr)
KR (1) KR100232590B1 (fr)
CN (1) CN1047689C (fr)
CA (1) CA2079438A1 (fr)
DE (2) DE4132530A1 (fr)
HU (1) HU214135B (fr)

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Publication number Priority date Publication date Assignee Title
DE4322115A1 (de) * 1993-07-02 1995-01-12 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Metallhalogenid-Hochruckentladungslampe
DE4325679A1 (de) * 1993-07-30 1995-02-02 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Elektrische Lampe mit Halogenfüllung
DE9401436U1 (de) * 1994-01-28 1994-03-31 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH, 81543 München Metallhalogenidentladungslampe für Projektionszwecke
CN1089481C (zh) * 1994-11-10 2002-08-21 皇家菲利浦电子有限公司 电灯
RU2071619C1 (ru) * 1995-03-22 1997-01-10 Акционерное общество закрытого типа Научно-техническое агентство "Интеллект" Способ получения оптического излучения и разрядная лампа для его осуществления
US5576598A (en) * 1995-08-31 1996-11-19 Osram Sylvania Inc. Lamp with glass sleeve and method of making same
US5714839A (en) * 1996-03-01 1998-02-03 Osram Sylvania Inc. Metal halide lamp with reduced quartz devitrification comprising sodium, scandium, lithium and cesium iodides
US5694002A (en) * 1996-05-08 1997-12-02 Osram Sylvania Inc. Metal halide lamp with improved color characteristics
CN1149628C (zh) * 1997-04-25 2004-05-12 皇家菲利浦电子有限公司 高压气体放电灯
DE19727430A1 (de) * 1997-06-27 1999-01-07 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Metallhalogenidlampe mit keramischem Entladungsgefäß
DE19731168A1 (de) * 1997-07-21 1999-01-28 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Beleuchtungssystem
KR20000075542A (ko) * 1998-02-20 2000-12-15 모리시타 요이찌 무수은 메탈 할라이드 램프
US6376988B1 (en) 1998-08-28 2002-04-23 Matsushita Electric Industrial Co., Ltd. Discharge lamp for automobile headlight and the automobile headlight
JP3603723B2 (ja) * 1999-03-26 2004-12-22 松下電工株式会社 メタルハライドランプ及び放電灯点灯装置
DE29905662U1 (de) * 1999-03-26 2000-08-10 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Metallhalogenid-Entladungslampe mit langer Lebensdauer
JP3655126B2 (ja) * 1999-06-14 2005-06-02 株式会社小糸製作所 メタルハライドランプ
CN1171283C (zh) * 1999-08-25 2004-10-13 皇家菲利浦电子有限公司 金属卤化物灯
WO2002082490A1 (fr) * 2001-03-30 2002-10-17 Advanced Lighting Technologies, Inc. Lampe a plasma amelioree et procede associe
JP3907041B2 (ja) * 2001-10-11 2007-04-18 日本碍子株式会社 高圧放電灯用放電管および高圧放電灯
DE10163584C1 (de) * 2001-11-26 2003-04-17 Philips Corp Intellectual Pty Verfahren und Vorrichtung zur Herstellung von Lampenkolben mit nicht-rotationssymmetrischer und/oder konkaver innerer und/oder äußerer Form
DE10204691C1 (de) * 2002-02-06 2003-04-24 Philips Corp Intellectual Pty Quecksilberfreie Hochdruckgasentladungslampe und Beleuchtungseinheit mit einer solchen Hochdruckgasentladungslampe
US7105989B2 (en) 2002-04-01 2006-09-12 Advanced Lighting Techniques, Inc. Plasma lamp and method
DE10222954A1 (de) * 2002-05-24 2003-12-04 Philips Intellectual Property Hochdruckgasentladungslampe
JP4036039B2 (ja) * 2002-06-19 2008-01-23 ウシオ電機株式会社 ショートアーク型放電ランプ
DE10234758B4 (de) * 2002-07-30 2006-02-16 Sli Lichtsysteme Gmbh Metall-Halogendampflampe niedriger Leistung
US6888312B2 (en) * 2002-12-13 2005-05-03 Welch Allyn, Inc. Metal halide lamp for curing adhesives
JP4295700B2 (ja) * 2003-08-29 2009-07-15 パナソニック株式会社 メタルハライドランプの点灯方法及び照明装置
WO2006025027A2 (fr) 2004-09-02 2006-03-09 Philips Intellectual Property & Standards Gmbh Lampe a decharge avec remplissage aux sels optimise
JP2008293912A (ja) * 2007-05-28 2008-12-04 Phoenix Denki Kk 高圧放電灯およびこれを用いた光源装置
JP5023959B2 (ja) * 2007-10-22 2012-09-12 ウシオ電機株式会社 高圧放電ランプおよび高圧放電ランプ装置
WO2012063205A2 (fr) * 2010-11-10 2012-05-18 Koninklijke Philips Electronics N.V. Lampes aux halogénures métalliques à quartz ne contenant pas de thorium
CN103839751B (zh) * 2013-12-20 2016-08-03 广西南宁智翠科技咨询有限公司 一种金属卤化物灯药丸
US9875886B1 (en) * 2016-12-04 2018-01-23 Robert Su Double-ended ceramic metal halide lamp

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EP0173235A2 (fr) * 1984-08-20 1986-03-05 GTE Products Corporation Lampe à halogénure métallique à basse puissance
EP0276514A1 (fr) * 1986-12-29 1988-08-03 North American Philips Corporation Lampe à halogénures métalliques
EP0215524B1 (fr) * 1985-09-13 1989-07-26 Koninklijke Philips Electronics N.V. Lampe à décharge à vapeur de mercure à haute pression
FR2627627A1 (fr) * 1988-02-18 1989-08-25 Gen Electric Lampe a halogene-metal-xenon convenant particulierement pour les applications automobiles
EP0399288A2 (fr) * 1989-05-15 1990-11-28 General Electric Company Lampe à décharge utilisant des oscillations, résonantes acoustiques pour assurer une grande efficacité

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DE3680070D1 (de) * 1985-10-25 1991-08-08 Gen Electric Asymmetrische bogenkammer fuer eine entladungslampe.
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DE3832643A1 (de) * 1988-09-26 1990-03-29 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Verfahren zur herstellung einer reflexionsbeschichtung bei hochdruckentladungslampen
DE4013039A1 (de) * 1990-04-24 1991-10-31 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Hochdruckentladungslampe
JPH04292848A (ja) * 1991-03-20 1992-10-16 Toshiba Lighting & Technol Corp 金属蒸気放電灯

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3514659A (en) * 1967-07-03 1970-05-26 Sylvania Electric Prod High pressure vapor discharge lamp with cesium iodide
US3852630A (en) * 1972-03-20 1974-12-03 Philips Corp Halogen containing high-pressure mercury vapor discharge lamp
FR2270673A1 (fr) * 1974-05-09 1975-12-05 Philips Nv
FR2373157A1 (fr) * 1976-12-06 1978-06-30 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Lampe a decharge a haute pression contenant des halogenures metalliques
EP0173235A2 (fr) * 1984-08-20 1986-03-05 GTE Products Corporation Lampe à halogénure métallique à basse puissance
EP0215524B1 (fr) * 1985-09-13 1989-07-26 Koninklijke Philips Electronics N.V. Lampe à décharge à vapeur de mercure à haute pression
EP0276514A1 (fr) * 1986-12-29 1988-08-03 North American Philips Corporation Lampe à halogénures métalliques
FR2627627A1 (fr) * 1988-02-18 1989-08-25 Gen Electric Lampe a halogene-metal-xenon convenant particulierement pour les applications automobiles
EP0399288A2 (fr) * 1989-05-15 1990-11-28 General Electric Company Lampe à décharge utilisant des oscillations, résonantes acoustiques pour assurer une grande efficacité

Also Published As

Publication number Publication date
CN1073804A (zh) 1993-06-30
JPH05205697A (ja) 1993-08-13
US5363007A (en) 1994-11-08
DE4132530A1 (de) 1993-04-01
HU9202811D0 (en) 1992-11-30
EP0535311B1 (fr) 1994-03-16
KR930006808A (ko) 1993-04-21
CA2079438A1 (fr) 1993-03-31
CN1047689C (zh) 1999-12-22
KR100232590B1 (ko) 1999-12-01
HU214135B (en) 1997-12-29
HUT62422A (en) 1993-04-28
DE59200089D1 (de) 1994-04-21

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