EP0087740B1 - Verfahren zum kontinuierlichen Färben von textilen Warenbahnen - Google Patents

Verfahren zum kontinuierlichen Färben von textilen Warenbahnen Download PDF

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Publication number
EP0087740B1
EP0087740B1 EP83101733A EP83101733A EP0087740B1 EP 0087740 B1 EP0087740 B1 EP 0087740B1 EP 83101733 A EP83101733 A EP 83101733A EP 83101733 A EP83101733 A EP 83101733A EP 0087740 B1 EP0087740 B1 EP 0087740B1
Authority
EP
European Patent Office
Prior art keywords
dyestuffs
steam
temperature
fabric
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP83101733A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0087740A3 (en
EP0087740A2 (de
Inventor
Hans-Ulrich Dr. Von Der Eltz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT83101733T priority Critical patent/ATE22945T1/de
Publication of EP0087740A2 publication Critical patent/EP0087740A2/de
Publication of EP0087740A3 publication Critical patent/EP0087740A3/de
Application granted granted Critical
Publication of EP0087740B1 publication Critical patent/EP0087740B1/de
Expired legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P7/00Dyeing or printing processes combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2066Thermic treatments of textile materials
    • D06P5/2077Thermic treatments of textile materials after dyeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B19/00Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
    • D06B19/0005Fixing of chemicals, e.g. dyestuffs, on textile materials
    • D06B19/0047Fixing of chemicals, e.g. dyestuffs, on textile materials by air steam
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/916Natural fiber dyeing
    • Y10S8/917Wool or silk
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/916Natural fiber dyeing
    • Y10S8/918Cellulose textile
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/922Polyester fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/924Polyamide fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/927Polyacrylonitrile fiber

Definitions

  • the present invention relates to a continuous process for dyeing textile webs, the web being impregnated with an aqueous liquor which contains dissolved and / or dispersed dyestuffs, at a temperature between 20 and 95 ° C., and the dyestuffs are removed in a steam / Air mixture fixed, characterized in that the impregnated web is not dried before the dye fixation, the drying temperature of the steam / air mixture is kept between 110 and 140 ° C, the steam content of the steam / air mixture so it is dimensioned that the wet temperature of the wet web is between 50 and 95 ° C and the fixing time is at least 20 seconds.
  • Block drying and block heat setting processes are known, which are carried out in most cases on the pre-dried textile material. If damp textile goods are used for the dye fixation program, they are dried when entering the heat treatment field. As a variant of the dry fixing method, the drying speed has also been influenced by regulating the steam content in the drying medium (DE-A-25 52 562). A lot of energy is used both for drying and for heat setting. Another disadvantage here is the migration that takes place during the drying process, which can lead to uneven dyeings.
  • Block-steaming processes are also known, which, regardless of whether they are used as one- or two-bath processes, are very energy-intensive.
  • the dye is first impregnated; the fixing chemicals are then applied in a second padding process, which is why these processes are also known as chemical pad-steam processes.
  • These processes are even more energy-intensive because the textile material is both dried and steamed. This takes place at 103-105 ° C. Intermediate drying also takes place in the one-bath block-steaming process, which is why the same disadvantages of high energy consumption apply here.
  • the task set was thus to avoid the disadvantages mentioned above, to enable good dye fixation with good colouration and to be able to work at a high production speed using a method which nevertheless saves energy.
  • This object is achieved by the method according to the invention, as described at the outset.
  • the dyes are fixed at a temperature of 50-95 ° C. of the moist tissue (so-called "wet temperature”) over a period of at least 20 seconds and generally not more than 200 seconds. However, in individual cases, depending on the dye used or the textile material to be dyed, the required fixing time can also be more than 200 seconds.
  • the specified temperature range of 50-95 ° C of the damp tissue is determined by the ratio of water vapor and air in the steam / air mixture.
  • the temperature of the moist fabric web corresponds to the temperature of a thermometer kept moist in the existing steam / air mixture.
  • Psychrometers work according to the same principle to determine the air content in a vapor / air mixture.
  • the temperature of the steam / air mixture of 110-140 ° C is measured with a dry thermometer.
  • a hot flue equipped with additional infrared emitters is expediently used for the dyeing process according to the invention, which also offers the possibility of steam injection. Because the infrared emitters are located inside the fixing chamber, the energy supplied by these emitters is not lost. The steam is advantageously supplied on the intake side of the air.
  • the steam consumption in the process according to the invention is significantly lower.
  • no excess pressure is required.
  • the advantage of heating up the equipment used, for example a hot flue, is that the metal parts of the equipment are preheated with hot air before steam injection begins. This prevents condensation of the steam on the cold metal parts, which not least also significantly reduces the risk of water dripping. Since the dye fixation works at a wet temperature of 95 ° C or below, there is a vapor / air mixture. At a wet temperature of approximately 80 ° C., the steam content in the fixing chamber is below 30% by volume. This makes it possible, for example, to dispense with the use of stainless steel, which is particularly cost-effective for the construction of fixing devices for the dyeing process according to the invention.
  • the steam injection to produce the desired steam / air ratio can be done in a known manner Can be controlled very precisely by a psychrometer, which means that little steam is used. Because the goods are practically unable to dry, there is no dye migration and the result is optimal dyeing.
  • the advantages of the new process are mainly due to the possibility of saving energy, since you work with a lower proportion of steam compared to working in a steamer at 100-105 ° C.
  • a steamer at 100-105 ° C.
  • an air freedom of about 95 vol .-% is achieved, which is even for many dyes that are fixed in the presence of reducing agents, i.e. are sensitive to oxidation to atmospheric oxygen, is sufficient.
  • the following dyes can be used in the process according to the invention: reactive dyes, acid dyes, 1: 2 metal complex dyes, Leuco Küpenester dyes, dispersion dyes, cationic dyes and soluble sulfur dyes.
  • alkaline agents can be used for the reactive dyes on cellulose fibers.
  • fixation in the strongly acidic and weakly acidic range can also be considered in the neutral and weakly alkaline range.
  • the acid dyes and metal complex dyes are used for dyeing wool or polyamide fibers or mixtures of these fibers, the disperse dyes for dyeing polyamide fibers and modified polyester fibers.
  • Cationic dyes can be used for dyeing both acid-modified synthetic fibers and polyacrylonitrile fibers (e.g. in the gel state), if necessary in the presence of fixing accelerators).
  • Suitable modified polyester fibers are both the acid-modified polyester fibers and carrier-free dyeable fibers made from polyethylene terephthalate modified with hydroxycarboxylic acids or aliphatic dicarboxylic acids or from a polyethylene terephthalate modified with polyethylene oxide in the form of a block polymer.
  • the dye yield corresponds to that of a dyeing which was steamed in a 100% steam atmosphere for 30 seconds at 103 to 105 ° C. and then developed.
  • fixation for 2 minutes at a wet temperature of 60 ° C. and a dry temperature of 110 ° C. results in coloring with the same dye yield.
  • a dark brown coloration is obtained which, in terms of hue and dyeing yield, differs practically from a coloration which was fixed for 60 seconds at 103 ° C. in a 100% steam atmosphere.
  • the fixing process is carried out at 103 ° C. for 60 seconds in a 100% steam atmosphere, a significantly lighter color is obtained.
  • a luminous Schlarach coloration with good fastness properties is obtained without a gray haze.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coloring (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Polarising Elements (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Sampling And Sample Adjustment (AREA)
EP83101733A 1982-02-26 1983-02-23 Verfahren zum kontinuierlichen Färben von textilen Warenbahnen Expired EP0087740B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83101733T ATE22945T1 (de) 1982-02-26 1983-02-23 Verfahren zum kontinuierlichen faerben von textilen warenbahnen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3206895 1982-02-26
DE19823206895 DE3206895A1 (de) 1982-02-26 1982-02-26 Verfahren zum kontinuierlichen faerben von textilen warenbahnen

Publications (3)

Publication Number Publication Date
EP0087740A2 EP0087740A2 (de) 1983-09-07
EP0087740A3 EP0087740A3 (en) 1985-05-02
EP0087740B1 true EP0087740B1 (de) 1986-10-15

Family

ID=6156738

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83101733A Expired EP0087740B1 (de) 1982-02-26 1983-02-23 Verfahren zum kontinuierlichen Färben von textilen Warenbahnen

Country Status (13)

Country Link
US (1) US4465490A (pt)
EP (1) EP0087740B1 (pt)
JP (1) JPS58156088A (pt)
KR (1) KR900007097B1 (pt)
AT (1) ATE22945T1 (pt)
AU (1) AU555618B2 (pt)
BR (1) BR8300877A (pt)
CA (1) CA1192007A (pt)
DE (2) DE3206895A1 (pt)
ES (1) ES520045A0 (pt)
IN (1) IN157663B (pt)
PT (1) PT76291B (pt)
ZA (1) ZA831306B (pt)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4659333A (en) * 1984-09-28 1987-04-21 Ciba-Geigy Corporation Process for fixing dyes and prints with hot steam containing air
US4666454A (en) * 1985-09-09 1987-05-19 Celanese Corporation Production of a fabric containing polyethylene terephthalate fibers having a reduced tendency to pill
US4801303A (en) * 1987-06-01 1989-01-31 Sandoz Ltd. One-bath dyeing of polyester-cellulosic blends using disperse and sulfur dyes
DE3733219A1 (de) * 1987-10-01 1989-04-13 Hoechst Ag Verfahren und vorrichtung zum kontinuierlichen behandeln, vorzugsweise faerben, von strangfoermigem textilgut
CN1011991B (zh) * 1988-08-29 1991-03-13 里特机械公司 在纺织机械内的一种加热方法
JP3240674B2 (ja) * 1992-03-19 2001-12-17 タカタ株式会社 シートベルト装置のウェビングの染色方法
US5885305A (en) * 1995-10-16 1999-03-23 A. Monforts Textilmaschinen Gmbh & Co. Device for fixing dye in reactive dyeing
DE19709899A1 (de) * 1997-03-11 1998-09-17 Dystar Textilfarben Gmbh & Co Verfahren und Vorrichtung zum kontinuierlichen Färben von cellulosischen Rundstrick- und Rundwirkwaren und ihren Mischungen mit Synthesefasern
EP1055763B1 (de) * 1999-05-28 2006-10-18 Moenus Textilmaschinen GmbH Verfahren zur kontinuierlichen Behandlung einer textilen Warenbahn mit Dampf zum Fixieren von Reaktivfarbstoff auf nativen Fasern
WO2006002570A1 (de) * 2004-07-06 2006-01-12 Tex-A-Tec Ag Modulares mehrzweck-aggregat und verfahren zur applikation von reaktionskomponenten auf textilen substraten
DE102004053531B4 (de) * 2004-11-05 2007-01-11 Suchy Textilmaschinenbau Gmbh Vorrichtung zum kontinuierlichen Färben von textilen Materialien in Schlauchform
CN111041863A (zh) * 2019-12-17 2020-04-21 绍兴市柯桥区众诚印染有限公司 一种织物活性染料冷轧染色工艺

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1460483A1 (de) * 1963-10-14 1968-11-28 Artos Meier Windhorst Kg Verfahren zur Regelung der Raumtemperatur und der Warentemperatur in Behandlungskammern
DE1710510A1 (de) * 1968-02-07 1971-10-07 Vepa Ag Verfahren und Vorrichtung zum kontinuierlichen Behandeln von gasdurchlaessigen Guetern
BE788614R (fr) * 1970-09-22 1973-03-08 Sandoz Sa Procede de finissage de matieres
DE2552562A1 (de) * 1975-01-15 1976-07-22 Sandoz Ag Verfahren zum faerben von zellulosefasern oder daraus hergestellten textilien mit reaktivfarbstoffen
IT1040457B (it) * 1975-08-04 1979-12-20 Rimar Spa Apparecchiatura e procedimento per la tintura in continuo di manufat ti tesseili in bagno di solvente

Also Published As

Publication number Publication date
ES8401549A1 (es) 1983-12-01
IN157663B (pt) 1986-05-17
PT76291B (de) 1985-12-03
BR8300877A (pt) 1983-11-16
CA1192007A (en) 1985-08-20
EP0087740A3 (en) 1985-05-02
US4465490A (en) 1984-08-14
DE3206895A1 (de) 1983-09-15
KR840003713A (ko) 1984-09-15
ES520045A0 (es) 1983-12-01
PT76291A (de) 1983-03-01
JPH0255554B2 (pt) 1990-11-27
ZA831306B (en) 1983-11-30
AU1189083A (en) 1983-09-01
JPS58156088A (ja) 1983-09-16
KR900007097B1 (ko) 1990-09-28
DE3366979D1 (en) 1986-11-20
EP0087740A2 (de) 1983-09-07
ATE22945T1 (de) 1986-11-15
AU555618B2 (en) 1986-10-02

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