EP0082457B1 - Agents concentrés adoucissant le linge - Google Patents

Agents concentrés adoucissant le linge Download PDF

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Publication number
EP0082457B1
EP0082457B1 EP82111556A EP82111556A EP0082457B1 EP 0082457 B1 EP0082457 B1 EP 0082457B1 EP 82111556 A EP82111556 A EP 82111556A EP 82111556 A EP82111556 A EP 82111556A EP 0082457 B1 EP0082457 B1 EP 0082457B1
Authority
EP
European Patent Office
Prior art keywords
weight
water
fabric softener
carbon atoms
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP82111556A
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German (de)
English (en)
Other versions
EP0082457A2 (fr
EP0082457A3 (en
Inventor
Adolf Dr. May
Hans-Walter Dr. Bücking
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
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Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT82111556T priority Critical patent/ATE20535T1/de
Publication of EP0082457A2 publication Critical patent/EP0082457A2/fr
Publication of EP0082457A3 publication Critical patent/EP0082457A3/de
Application granted granted Critical
Publication of EP0082457B1 publication Critical patent/EP0082457B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This is especially true when washing is done in the washing machine.
  • Such undesirable hardening of the handle can be eliminated by post-treating the textiles in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
  • the water-dispersible dialkyldimethylammonium chlorides or imidazoline derivatives of the formulas I ⁇ III are used in particular for this purpose
  • R 1 is alkyl or alkenyl with 8-22, preferably 16-18, carbon atoms
  • R 3 is methyl or hydrogen
  • X is a number from 1-5
  • A is an anion such as CI s , Br ", CH 3 OSO 3 ⁇ or CH 3 OPO 3 ⁇ .
  • Aqueous dispersions of the raw materials mentioned have the disadvantage that they look milky cloudy.
  • formulations are required that look clearly transparent as aqueous, concentrated formulations.
  • the mixtures should be readily dispersible in cold water. Further criteria are: no thickening of the formulation when stored, stability after long standing, no formation of sediment.
  • nonionic dispersants are customary nonionic dispersants or emulsifiers based on oxalkylates, which contribute to the fact that the concentrate is readily dispersible in cold water.
  • Suitable nonionic dispersants are, for example, reaction products of in each case about 2-15 mol of ethylene oxide with an alkylphenol, for example xylenol, but also with an alkylphenol with a long alkyl radical of 8-10 carbon atoms or with a fatty alcohol with 8 to 15 carbon atoms, in particular reaction products of about 5-10 moles of EO with 1 mole of alkylphenol or 1 mole of a fatty alcohol containing 8 to 15 carbon atoms or a mixture of such fatty alcohols.
  • the cationic softening compounds of the formulas 1-111 are expediently used in the form of their concentrated solutions in lower alcohols, preferably isopropanol or in a mixture of these alcohols with water.
  • the fabric softeners according to the invention therefore contain a certain amount of such lower alcohols.
  • the concentrated fabric softener according to the invention may also contain other substances and auxiliaries which are either already mixed in the concentrate of the fabric softener or added separately to the ready-to-use fabric softener.
  • substances or auxiliaries that have already been used in fabric softeners, such as. B. cationic or nonionic surface-active substances.
  • the concentrated fabric softening agents according to the invention give any textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, triacetate, polyamide, polyacrylonitrile, polyester, polypropylene, a pleasant and soft feel.
  • the use as a laundry treatment agent for terry cloth and underwear is particularly advantageous.
  • These fabric softener mixtures are produced by simply mixing or dispersing the individual components in water.
  • These fabric softeners according to the invention can either contain a compound of the formula 1 to III or IV to VII or else they contain a mixture of 2 or more compounds of the formula I to III or IV to VII within the stated limits. If a mixture of two or more compounds of the formula III or IV to VII is present, the mixing ratio with one another is completely uncritical and can have any value.
  • the fabric softener concentrates described above which have good softening properties, are completely clear. They are characterized by good stability. The cold water dispersibility is excellent. No gel formation was observed. The formulations also show a low viscosity in a highly concentrated form. After-gelling after a longer storage period does not occur.
  • anionic surfactant not only acts as an emulsifier but also as a softening component.
  • anionic surfactants alone do not have a softening effect because they do not absorb onto the fabric.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Claims (3)

1. Assouplisseurs concentrés pour linge, liquides et limpides, caractérisés en ce qu'ils sont constitués:
a) de 26 à 40% en poids d'un ou de plusieurs assouplisseurs cationiques,
b) de 0,01 à 8% en poids d'un ou de plusieurs surfactifs anioniques,
c) de 0,01 à 8% en poids d'un dispersant non ionique,
d) de 3 à 30% en poids d'un alcanol en C1―C3,
e) d'eau et, éventuellement, de parfums et de colorants ainsi que d'adjuvants, en des quantités formant le complément à 100% en poids.
2. Concentrés assouplisseurs pour linge selon la revendication 1 caractérisé en ce qu'ils sont constitués:
a) de 26 à 40% en poids d'un assouplisseur cationique répondant à l'une des formules:
Figure imgb0031
Figure imgb0032
Figure imgb0033
dans lesquelles R1 représente un radical alkyle ou alcényle contenant de 8 à 22 atomes de carbone, de préférence de 16 à 18, R2 représente un alkyle contenant de 1 à 4 atomes de carbone, de préférence un méthyle, R3 un méthyle ou l'hydrogène, x un nombre de 1 à 5 et A un anion, par exemple Cl⊖, Br8, CH3OPO3 ⊖, ou CH3OSO3 ⊖,
b) de 0,01 à 8% en poids, de préférence de 1 à 3% en poids, d'un surfactif anionique répondant à l'une des formules IV à VII:
Figure imgb0034
Figure imgb0035
Figure imgb0036
Figure imgb0037
dans lesquelles R4, R5 et R6 représentent chacun un alkyle contenant de 8 à 20 atomes de carbone, de préférence de 10 à 15, n représente un nombre de 8 à 18, de préférence de 11 à 14, m un nombre de 0 à 5, de préférence le nombre 3, et Y représente Na, K ou NH4,
c) de 0,01 à 8% en poids d'un alkylphénol éthoxylé ou d'un alcool gras éthoxylé,
d) de 3 à 30% en poids d'un alcanol contenant de 1 à 3 atomes de carbone,
e) d'eau et, éventuellement, de parfums et de colorants ainsi que d'autres adjuvants, en des quantités représentant le complément à 100% en poids.
3. Concentrés assouplisseurs pour linge selon la revendication 1 qui sont constitués de 26 à 30% en poids de la composante a), de 1 à 3% en poids de la composante b), de 0,5 à 3% en poids de la composante c), de 5 à 15% en poids de la composante d), d'eau et, éventuellement, d'un parfum et d'un colorant en des quantités formant le complément à 100% en poids.
EP82111556A 1981-12-18 1982-12-13 Agents concentrés adoucissant le linge Expired EP0082457B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82111556T ATE20535T1 (de) 1981-12-18 1982-12-13 Konzentrierte waescheweichspuelmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3150178 1981-12-18
DE19813150178 DE3150178A1 (de) 1981-12-18 1981-12-18 "konzentrierte waescheweichspuelmittel"

Publications (3)

Publication Number Publication Date
EP0082457A2 EP0082457A2 (fr) 1983-06-29
EP0082457A3 EP0082457A3 (en) 1984-12-27
EP0082457B1 true EP0082457B1 (fr) 1986-06-25

Family

ID=6149086

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82111556A Expired EP0082457B1 (fr) 1981-12-18 1982-12-13 Agents concentrés adoucissant le linge

Country Status (8)

Country Link
US (1) US4447343A (fr)
EP (1) EP0082457B1 (fr)
JP (1) JPS58109682A (fr)
AT (1) ATE20535T1 (fr)
BR (1) BR8207362A (fr)
CA (1) CA1188860A (fr)
DE (2) DE3150178A1 (fr)
ZA (1) ZA829283B (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA833016B (en) * 1982-05-10 1984-12-24 Colgate Palmolive Co Fabric softening composition
GB8312619D0 (en) * 1983-05-07 1983-06-08 Procter & Gamble Surfactant compositions
GB8410322D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous concentrated fabric softening composition
JPS6170073A (ja) * 1984-09-12 1986-04-10 花王株式会社 柔軟剤組成物
SE8504661L (sv) * 1984-10-17 1986-04-18 Colgate Palmolive Co Mjukgorande och antistatisk vetskeformig detergentkomposition
JPS61102481A (ja) * 1984-10-25 1986-05-21 ライオン株式会社 柔軟剤組成物
US4624713A (en) * 1984-11-15 1986-11-25 Economics Laboratory, Inc. Solid rinse aids and methods of warewashing utilizing solid rinse aids
GB8430301D0 (en) * 1984-11-30 1985-01-09 Swan Thomas & Co Ltd Compositions of matter for fabric softeners
US4654152A (en) * 1985-10-07 1987-03-31 Domtar Inc. Base mix fabric softener
GB8704711D0 (en) * 1987-02-27 1987-04-01 Unilever Plc Fabric softening composition
US4851139A (en) * 1987-08-26 1989-07-25 The Clorox Company Isotropic fabric softener composition containing fabric mildewstat
DE3739143A1 (de) * 1987-11-19 1989-06-01 Henkel Kgaa Waessriges weichspuelmittel fuer die behandlung von textilien
US4810409A (en) * 1987-12-16 1989-03-07 Sterling Drug Inc. Stable, isotropic liquid laundry detergents
US4857213A (en) * 1988-02-08 1989-08-15 The Procter & Gamble Company Liquid detergent containing conditioning agent and high levels of alkyl sulfate/alkyl ethoxylated sulfate
JPH0723581B2 (ja) * 1988-08-24 1995-03-15 花王株式会社 衣料用柔軟仕上剤
GB9122486D0 (en) * 1991-10-23 1991-12-04 Cussons Int Ltd Fabric softener composition
US5490944A (en) * 1994-08-11 1996-02-13 Colgate-Palmolive Company Liquid fabric softener compositions
US5525245A (en) * 1994-12-21 1996-06-11 Colgate-Palmolive Company Clear, concentrated liquid fabric softener compositions
US5656585A (en) * 1994-12-21 1997-08-12 Colgate-Palmolive Company Clear, concentrated liquid fabric softener compositions
GB2313379A (en) * 1996-05-23 1997-11-26 Unilever Plc A detergent composition comprising perfume
EP1018541A1 (fr) * 1999-01-07 2000-07-12 Goldschmidt Rewo GmbH & Co. KG Compositions adoucissantes et transparentes
JP2003519293A (ja) * 1999-07-02 2003-06-17 ザ ダウ ケミカル カンパニー アルコキシレート化添加剤を含有する透明な軟化用調合物
DE60120567T2 (de) 2000-01-19 2007-06-06 Kao Corporation Weichmacherzusammensetzung für die textilausrüstung
EP1354872A1 (fr) * 2002-04-17 2003-10-22 Kao Corporation Sels d'amines d'esters d'acide sulfurique, sels d'amines d'acides sulfuriques, leur préparation et compositions adoucissantes
WO2015052146A1 (fr) * 2013-10-10 2015-04-16 Akzo Nobel Chemicals International B.V. Composition d'adoucissant pour textiles, et son utilisation
WO2016023139A1 (fr) * 2014-08-12 2016-02-18 中国石油化工股份有限公司 Peptide antibiotique et son procédé de préparation et son administration

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3954634A (en) * 1973-07-27 1976-05-04 S. C. Johnson & Son, Inc. Stable, low-viscosity fabric softener
US3997453A (en) * 1974-02-11 1976-12-14 Colgate-Palmolive Company Softener dispersion
JPS54108812A (en) * 1978-02-15 1979-08-25 Kao Corp Detergent composition for dry cleaning
DE2930061A1 (de) * 1979-07-25 1981-02-19 Hoechst Ag Waescheweichspuelmittel
US4264457A (en) * 1980-02-04 1981-04-28 Desoto, Inc. Cationic liquid laundry detergent and fabric softener
DE3025369A1 (de) * 1980-07-04 1982-01-28 Hoechst Ag, 6000 Frankfurt Waeschweichspuelmittelkonzentrat

Also Published As

Publication number Publication date
EP0082457A2 (fr) 1983-06-29
JPS58109682A (ja) 1983-06-30
CA1188860A (fr) 1985-06-18
DE3271850D1 (en) 1986-07-31
EP0082457A3 (en) 1984-12-27
DE3150178A1 (de) 1983-06-30
JPH0320512B2 (fr) 1991-03-19
BR8207362A (pt) 1983-10-18
ZA829283B (en) 1983-09-28
ATE20535T1 (de) 1986-07-15
US4447343A (en) 1984-05-08

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