EP0043547B1 - Concentré assouplissant pour tissus - Google Patents

Concentré assouplissant pour tissus Download PDF

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Publication number
EP0043547B1
EP0043547B1 EP81105085A EP81105085A EP0043547B1 EP 0043547 B1 EP0043547 B1 EP 0043547B1 EP 81105085 A EP81105085 A EP 81105085A EP 81105085 A EP81105085 A EP 81105085A EP 0043547 B1 EP0043547 B1 EP 0043547B1
Authority
EP
European Patent Office
Prior art keywords
weight
alkyl
carbon atoms
softener
fabric softener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP81105085A
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German (de)
English (en)
Other versions
EP0043547A1 (fr
Inventor
Siegfried Dr. Billenstein
Adolf Dr. May
Hans-Walter Dr. Bücking
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
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Hoechst AG
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Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT81105085T priority Critical patent/ATE6667T1/de
Publication of EP0043547A1 publication Critical patent/EP0043547A1/fr
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Publication of EP0043547B1 publication Critical patent/EP0043547B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • fabric softeners have so far generally been used in the form of dilute, about 2 to 10% solutions.
  • these diluted solutions have several disadvantages. You can e.g. B. not be stored cold, because after freezing and thawing they assume a gel consistency and can no longer be brought into homogeneous solution.
  • Suitable cationic plasticizers of the laundry softener concentrates according to the invention are the quaternary ammonium compounds known for this use and containing lipophilic radicals, as described, for example, in US Pat. B. in Chemistry and Industry, July 1969, pages 893/894, especially those compounds which are characterized by the general formulas I, II and 111.
  • these cationic plasticizers are expediently used in the form of their concentrated solutions in lower alcohols, preferably isopropanol or in a mixture of these alcohols with water.
  • the concentrates according to the invention therefore contain a certain amount of such lower alcohols.
  • a further essential component are reaction products from a fatty acid alkanolamide with ethylene oxide (EO) of the formula IV wherein R 4 is alkyl or alkenyl radicals with 8-22, preferably 8-16 carbon atoms, R 3 is hydrogen or an alkyl radical with 1-3 carbon atoms, in particular hydrogen or methyl, p is a number from 1 to 5, preferably 2 and y is a number of 1 to 15, preferably 5-8, are used as nonionic plasticizers. It is essential that this is a nitrogenous substance that has a pseudo-cationic character. As such, the substantivity of this type of compound on tissue is too weak.
  • EO ethylene oxide
  • nonionic plasticizer In combination with a quaternary ammonium compound of the formula I-III, however, the nonionic plasticizer mentioned is applied to the laundry and gives the fiber an additional soft feel. At the same time, these nonionic plasticizers also act as dispersants or emulsifiers.
  • nonionic dispersants are customary nonionic dispersants or emulsifiers based on oxalkylates, which contribute to the fact that the concentrate is readily dispersible in cold water.
  • Suitable nonionic dispersants are e.g. B. reaction products of about 2-12 moles of ethylene oxide with an alkylphenol such as. B.
  • xylenol but also with an alkylphenol with a long alkyl radical of 8-10 carbon atoms or with a fatty alcohol with 8 to 15 carbon atoms, in particular reaction products of about 5 to 8 moles of EO with 1 mole of alkylphenol or 1 mole of an 8th up to 15 carbon atoms containing fatty alcohol or a mixture of such fatty alcohols.
  • the fabric softener concentrates according to the invention can be produced by simply mixing the components or their concentrated solutions. If appropriate, perfume, dye, optical brighteners or other auxiliaries can also be added to the concentrate. To set the desired final concentration, it may be diluted with the necessary amount of water.
  • the amount of the fabric softener concentrate according to the invention is about 10 to 20 g per 4 kg of laundry. With regard to the softening effect, this corresponds to an amount of approximately 50 to 100 ml of a commercially available fabric softener with an active substance content of 5%.
  • the laundry fabric softener concentrates according to the invention which have good softening properties, can be dispersed well in cold water without causing troublesome gel formation. It is advantageous here that the concentrates can be fed directly into household machines with suitable metering devices. This good solubility also makes it possible to dilute the concentrates according to the invention shortly before they are put into the washing machine, so that the fabric softening agents can now be treated in the concentrated form according to the invention and no longer as diluted aqueous solutions as before. This eliminates the need to have to transport larger, ultimately superfluous amounts of water at all stages of the trade.
  • a liquid fabric softener concentrate is produced by intensively mixing the following components:
  • the product is clearly liquid and can be dispersed in cold water.
  • 10 g of the fabric softener concentrate according to Example 1 are comparable in the achieved softening effect to about 80 ml of a commercially available liquid fabric softener with an active substance content of 5% by weight.
  • Laundry softener concentrates of the following composition are produced in the same way as described in Example 1:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Claims (3)

1. Concentrés d'agents de rinçage assouplissants pour le linge, à base d'assouplissants cationiques, de dispersants non ioniques, d'alcools inférieurs et éventuellement d'eau, concentrés caractérisés en ce qu'ils consistent en:
a) 30 à 70% en poids d'un assouplissant cationique,
b) 5 à 50% en poids d'un assouplissant non ionique de formule:
Figure imgb0036
dans laquelle R4 représente un groupe alkyle ou alcényle ayant 8 à 22 atomes de carbone, R3 représente de l'hydrogène ou un groupe alkyle ayant 1 à 3 atomes de carbone, b est un nombre valant 1 à 5 et y est un nombre valant 1 à 15,
c) 5 à 20% en poids d'un dispersant non ionique,
d) 5 à 30% en poids d'un alcanol en C1 à C3,
e) 5 à 30% en poids d'un glycol liquide, d'un polyglycol ou de leurs éthers alkyliques en C1-C4, et
f) éventuellement de l'eau, du parfum et des colorants en des quantités correspondant au complément à 100% en poids.
2. Concentrés d'agents de rinçage assouplissants pour le linge selon la revendication 1, caractérisés en ce qu'ils consistent en:
a) 30 à 70% en poids d'un assouplissant cationique répondant aux formules:
Figure imgb0037
Figure imgb0038
Figure imgb0039
dans lesquelles R1 et R2 représentent un radical alkyle ou alcényle ayant 8 à 20 atomes de carbone, R3 représente de l'hydrogène ou un radical alkyle ayant 1 à 3 atomes de carbone, x est un nombre 1 à 5, m et n valent 2 ou 3, A- représente le chlore ou le brome et Y- le groupe méthosulfate,
b) 5 à 30% en poids d'un assouplissant non ionique de formule:
Figure imgb0040
dans laquelle R4 représente un groupe alkyle ou alcényle ayant 8 à 22 atomes de carbone, R3 représente de l'hydrogène ou un groupe alkyle ayant 1 à 3 atomes de carbone, p est un nombre valant 1 à 5 et y est un nombre valant 1 à 15,
c) 5 à 20% en poids d'un alkylphénol ou d'un alcool gras oxyéthylés,
d) 5 à 30% en poids d'un alcanol en Ci à C3,
e) 5 à 30% en poids de butyldiglycol, d'éthylèneglycol ou de propanediol-1,2, et
f) éventuellement de l'eau, du parfum et des colorants en des quantités représentant le complément à 100% en poids.
3. Concentrés d'agents de rinçage assouplissants pour le linge selon la revendication 1, caractérisés en ce qu'ils consistent en 40 à 50% en poids constituant a), 30 à 40% en poids du constituant b), 5 à 10% en poids du constituant c), 5 à 10% en poids du constituant d), 5 à 10% en poids du constituant e) et éventuellement de l'eau, du parfum et des colorants en des quantités correspondant au complément à 100% en poids.
EP81105085A 1980-07-04 1981-07-01 Concentré assouplissant pour tissus Expired EP0043547B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT81105085T ATE6667T1 (de) 1980-07-04 1981-07-01 Waescheweichspuelmittelkonzentrat.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19803025369 DE3025369A1 (de) 1980-07-04 1980-07-04 Waeschweichspuelmittelkonzentrat
DE3025369 1980-07-04

Publications (2)

Publication Number Publication Date
EP0043547A1 EP0043547A1 (fr) 1982-01-13
EP0043547B1 true EP0043547B1 (fr) 1984-03-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP81105085A Expired EP0043547B1 (fr) 1980-07-04 1981-07-01 Concentré assouplissant pour tissus

Country Status (8)

Country Link
US (1) US4351737A (fr)
EP (1) EP0043547B1 (fr)
JP (1) JPS5755999A (fr)
AT (1) ATE6667T1 (fr)
AU (1) AU7252481A (fr)
BR (1) BR8104269A (fr)
CA (1) CA1179806A (fr)
DE (2) DE3025369A1 (fr)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2482636A1 (fr) 1980-05-14 1981-11-20 Lesieur Cotelle Et Associes Sa Composition adoucissante concentree pour fibres textiles
DE3135014A1 (de) * 1981-09-04 1983-03-24 Hoechst Ag, 6000 Frankfurt Waescheweichspuelmittel
DE3150178A1 (de) * 1981-12-18 1983-06-30 Hoechst Ag, 6230 Frankfurt "konzentrierte waescheweichspuelmittel"
ZA834209B (en) * 1982-06-22 1985-01-30 Colgate Palmolive Co Concentrated fabric softening compositions and method for making same
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
FR2540901B1 (fr) * 1983-02-14 1986-08-29 Elf Aquitaine Compositions concentrees d'adoucissants textiles
DE3314677A1 (de) * 1983-04-22 1984-10-25 Henkel KGaA, 4000 Düsseldorf Konfektioniertes textilweichmacher-konzentrat
US4642258A (en) * 1983-07-05 1987-02-10 Economics Laboratory, Inc. Treatment of fabrics in machine dryers using treating means containing fabric treating composition having resistance to change in viscosity and release rate with temperature change
GB8410321D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous concentrated fabric softening composition
GB8410320D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous fabric softening composition
GB8410322D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous concentrated fabric softening composition
ZA858974B (en) * 1984-12-12 1987-07-29 Colgate Palmolive Co Concetrated stable non-aqueous fabric softener composition
US4851141A (en) * 1984-12-12 1989-07-25 Colgate-Palmolive Company Concentrated stable nonaqueous fabric softener composition
EP0275987A3 (fr) * 1987-01-20 1989-07-26 The Dow Chemical Company Composition et procédé de nettoyage de compresseurs de turbine à gaz
DE4420188A1 (de) 1994-06-09 1995-12-14 Hoechst Ag Wäscheweichspülmittelkonzentrate
US5525245A (en) * 1994-12-21 1996-06-11 Colgate-Palmolive Company Clear, concentrated liquid fabric softener compositions
US5656585A (en) * 1994-12-21 1997-08-12 Colgate-Palmolive Company Clear, concentrated liquid fabric softener compositions
JPH0959671A (ja) * 1995-08-25 1997-03-04 Asahi Denka Kogyo Kk 洗浄剤組成物
GB2313379A (en) * 1996-05-23 1997-11-26 Unilever Plc A detergent composition comprising perfume
US6147047A (en) * 1996-08-09 2000-11-14 The Clorox Company Microemulsion dilutable cleaner
CA2300403A1 (fr) * 1997-08-18 1999-02-25 The Procter & Gamble Company Compositions assouplissantes liquides transparentes
GB2368592B (en) * 1998-04-14 2002-09-18 Reckitt Benckiser Inc Aqueous disinfecting and cleaning compositions
WO2002031094A2 (fr) * 2000-10-06 2002-04-18 Dow Global Technologies Inc. Formulation adoucissantes limpides renfermant des additifs alcoxyles
DE10112318A1 (de) * 2001-02-05 2002-08-14 Henkel Kgaa Konditioniermittel
US20030162689A1 (en) * 2002-01-25 2003-08-28 Tatiana Schymitzek Conditioning preparation for fabric care
US20050119151A1 (en) * 2002-04-10 2005-06-02 Konstanze Mayer Textile cleaning agent which is gentle on textiles
US20050215449A1 (en) * 2002-11-20 2005-09-29 Josef Penninger Textile care product
DE102004020015A1 (de) * 2004-04-21 2005-11-10 Henkel Kgaa Textilpflegemittel
DE102004021732A1 (de) * 2004-04-30 2005-11-24 Henkel Kgaa Textilplegemittel mit amingruppenhaltigem Celluloseether
DE102004054620A1 (de) * 2004-11-11 2006-06-08 Henkel Kgaa Geranonitril-Substitut
US20060264346A1 (en) * 2005-05-19 2006-11-23 Sullivan Mary K Timed-release cleansing and/or treatment formulation and method for making and using the same
JP5124805B2 (ja) 2006-06-27 2013-01-23 信越化学工業株式会社 光酸発生剤並びにこれを用いたレジスト材料及びパターン形成方法
EP2159276A1 (fr) * 2008-08-30 2010-03-03 Clariant (Brazil) S.A. Composition d'un agent de surface solide ou en gel
DE102008053883A1 (de) 2008-10-30 2010-05-06 Henkel Ag & Co. Kgaa neues Verdickungssystem

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2459354C2 (de) * 1974-12-16 1986-03-27 Hoechst Ag, 6230 Frankfurt Waescheweichspuelmittelkonzentrat mit desinfizierenden eigenschaften
US4060505A (en) * 1975-01-16 1977-11-29 Basf Wyandotte Corporation Compositions for souring and softening laundered textile materials and stock solutions prepared therefrom
GB1599171A (en) * 1977-05-30 1981-09-30 Procter & Gamble Textile treatment composition
US4155855A (en) * 1977-07-06 1979-05-22 The Procter & Gamble Company Concentrated liquid fabric softener composition
US4179382A (en) * 1977-11-21 1979-12-18 The Procter & Gamble Company Textile conditioning compositions containing polymeric cationic materials
DE2911198C2 (de) * 1979-03-22 1982-10-07 Dalli-Werke Mäurer & Wirtz, 5190 Stolberg Konzentrierte Wäscheweichspülmittel und Verfahren zu deren Herstellung
US4233164A (en) * 1979-06-05 1980-11-11 The Proctor & Gamble Company Liquid fabric softener

Also Published As

Publication number Publication date
DE3162651D1 (en) 1984-04-19
BR8104269A (pt) 1982-03-23
DE3025369A1 (de) 1982-01-28
JPS5755999A (en) 1982-04-03
AU7252481A (en) 1982-01-07
EP0043547A1 (fr) 1982-01-13
US4351737A (en) 1982-09-28
ATE6667T1 (de) 1984-03-15
CA1179806A (fr) 1984-12-27

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