EP0023333B1 - Agent assouplissant pour le linge - Google Patents

Agent assouplissant pour le linge Download PDF

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Publication number
EP0023333B1
EP0023333B1 EP80104268A EP80104268A EP0023333B1 EP 0023333 B1 EP0023333 B1 EP 0023333B1 EP 80104268 A EP80104268 A EP 80104268A EP 80104268 A EP80104268 A EP 80104268A EP 0023333 B1 EP0023333 B1 EP 0023333B1
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EP
European Patent Office
Prior art keywords
methyl
weight
formula
alkyl
carbon atoms
Prior art date
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Application number
EP80104268A
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German (de)
English (en)
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EP0023333A1 (fr
Inventor
Karl-Heinz Dr. Keil
Adolf Dr. May
Hans-Walter Dr. Bücking
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
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Hoechst AG
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Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT80104268T priority Critical patent/ATE1756T1/de
Publication of EP0023333A1 publication Critical patent/EP0023333A1/fr
Application granted granted Critical
Publication of EP0023333B1 publication Critical patent/EP0023333B1/fr
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This is particularly the case when the laundry is done in the washing machine.
  • This undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
  • the water-dispersible dialkyldimethylammonium salts have been introduced for this purpose.
  • these products have the disadvantage that the treated tissue becomes hydrophobic when overdosed and the rewettability is thereby delayed.
  • the invention thus relates to fabric softeners in the form of an aqueous solution or dispersion which comprise 3 to 15, preferably 4 to 7% by weight of one or more compounds of the formulas III where R, alkyl or alkenyl with 10-30 carbon atoms, preferably 8-14 carbon atoms, R 2 alkyl with 1-4 carbon atoms, preferably methyl, R 3 methyl or hydrogen and A is an anion such as Cl (-) , Br (-) , CH 3 OSO 3 (-) or (CH 3 O) 2 PO 2 (-) means 0.1-3, preferably 0.5-1.5% by weight of a glycerol ether derivative of the formula IV where R 4 can be alkyl or alkenyl having 4-20 carbon atoms, preferably 8-16 carbon atoms, cyclohexyl or aryl optionally substituted by al
  • the glycerol ether derivatives of the formula IV are known from DE-A 1 256 640 and GB-A 1 370 916.
  • This combination of compounds I and 111 with a compound of formula IV gives any textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, triacetate, polyamide, polyacrylonitrile, polyester, polypropylene, a pleasant and soft feel.
  • the use as a laundry aftertreatment for terry cloth and underwear made of cotton is particularly advantageous.
  • These fabric softeners are produced by simply mixing or dispersing the individual components in water.
  • These fabric softeners according to the invention can either contain only one compound of the formulas I to III or they contain a mixture of two or more compounds of these formulas I to III within the stated limits. If a mixture of two or more compounds of the formula I to III is present, their mixing ratio with one another is completely uncritical and can take on any value.
  • the fabric softener according to the invention can also contain other substances and auxiliaries which are either already mixed in the concentrate of the fabric softener or added separately to the ready-to-use, diluted fabric softener.
  • auxiliaries which have already been used in fabric softeners, e.g. cationic or nonionic surface-active substances, electrolytes, acidifying agents, organic complexing agents, optical brightening agents or solubilizers as well as colors and fragrances. They serve to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Claims (2)

1. Produits de rinçage assouplissants pour le linge sous la forme de solutions ou dispersions aqueuses qui contiennent de 3 à 15% en poids d'un ou plusieurs composés répondant à l'une des formules I à III
Figure imgb0018
Figure imgb0019
Figure imgb0020
dans lesquelles R1 représente un radical alkyle ou alcényle contenant de 10 à 30 atomes de carbone, R2 un alkyle contenant de 1 à 4 atomes de carbone, de préférence un méthyle, R3 un méthyle ou l'hydrogène, et A un anion, par exemple Cl(-), Br(-), CH3OSO3 (-) ou (CH3O)2PO2 (-), de 0,1 à 3 % en poids d'un éther du glycérol répondant à la formule IV
Figure imgb0021
dans laquelle R4 représente un radical alkyle ou alcényle contenant de 4 à 20 atomes de carbone, un cyclohexyle ou un aryle éventuellement porteur de radicaux alkyles, x et y représentent chacun l'hydrogène ou un méthyle mais ne peuvent pas représenter chacun en même temps un méthyle, n désigne un nombre entier de 0 à 20, Z représente un radical de formule ―(CH2)mCOOMe, ―SO3Me ou ―PO3Me2, m désigne un nombre entier de 0 à 3 et Me représente un ion de métal alcalin ou d'ammonium, et éventuellement d'autres adjuvants et additifs usuels.
2. Produits de rinçage assouplissants pour le linge selon la revendication 1, qui contiennent de 4 à 7 % en poids d'un ou plusieurs composés de formule i, Il ou III et de 0,5 à 1,5 % en poids d'un éther du glycérol de formule IV.
EP80104268A 1979-07-25 1980-07-19 Agent assouplissant pour le linge Expired EP0023333B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80104268T ATE1756T1 (de) 1979-07-25 1980-07-19 Waescheweichspuelmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2930111 1979-07-25
DE19792930111 DE2930111A1 (de) 1979-07-25 1979-07-25 Waescheweichspuelmittel

Publications (2)

Publication Number Publication Date
EP0023333A1 EP0023333A1 (fr) 1981-02-04
EP0023333B1 true EP0023333B1 (fr) 1982-11-03

Family

ID=6076716

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80104268A Expired EP0023333B1 (fr) 1979-07-25 1980-07-19 Agent assouplissant pour le linge

Country Status (7)

Country Link
US (1) US4399043A (fr)
EP (1) EP0023333B1 (fr)
JP (1) JPS5620678A (fr)
AT (1) ATE1756T1 (fr)
BR (1) BR8004658A (fr)
CA (1) CA1154207A (fr)
DE (2) DE2930111A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3271812D1 (en) * 1981-03-07 1986-07-31 Procter & Gamble Textile treatment compositions and preparation thereof
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
DE3416472A1 (de) * 1984-05-04 1985-11-07 Hoechst Ag, 6230 Frankfurt Weichmacher enthaltende waschmittel
GB8414944D0 (en) * 1984-06-12 1984-07-18 Ici Plc Fabric conditioners
JPS6110046A (ja) * 1984-06-23 1986-01-17 新日本製鐵株式会社 粒状スラグの脱水促進処理方法及び処理剤
GB8430301D0 (en) * 1984-11-30 1985-01-09 Swan Thomas & Co Ltd Compositions of matter for fabric softeners
US4622173A (en) * 1984-12-31 1986-11-11 Colgate-Palmolive Co. Non-aqueous liquid laundry detergents containing three surfactants including a polycarboxylic acid ester of a non-ionic
US5176850A (en) * 1988-07-21 1993-01-05 Ciba-Geigy Corporation Substituted glycerol compounds
AU614636B2 (en) * 1988-07-21 1991-09-05 Ciba Specialty Chemicals Holding Inc. Corrosion inhibition
DE19651447C1 (de) * 1996-12-11 1997-10-02 Henkel Kgaa Mittel für die Avivage von Textil- und Keratinfasern und Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln
DE19708133C1 (de) * 1997-02-28 1997-12-11 Henkel Kgaa Mittel für die Avivage von Textil- und Keratinfasern sowie die Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1256640B (de) 1965-08-04 1967-12-21 Bayer Ag Verfahren zur Herstellung grenzflaechenaktiver Verbindungen
US3607765A (en) * 1968-11-29 1971-09-21 Colgate Polmolive Co Detergent softener compositions
FR2102537A5 (fr) 1970-08-07 1972-04-07 Ugine Kuhlmann
US3997453A (en) * 1974-02-11 1976-12-14 Colgate-Palmolive Company Softener dispersion
NL7714317A (nl) * 1976-12-31 1978-07-04 Hoechst Ag Avivagemiddel en werkwijze voor het aviveren van textielmateriaal.
GB1596791A (en) * 1977-02-15 1981-08-26 Unilever Ltd Deodorant detergent composition

Also Published As

Publication number Publication date
US4399043A (en) 1983-08-16
DE2930111A1 (de) 1981-02-12
ATE1756T1 (de) 1982-11-15
CA1154207A (fr) 1983-09-27
BR8004658A (pt) 1981-02-10
EP0023333A1 (fr) 1981-02-04
DE3061036D1 (en) 1982-12-09
JPS5620678A (en) 1981-02-26

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