EP0082456B1 - Prémélanges concentrés d'agents adoucissant le linge - Google Patents

Prémélanges concentrés d'agents adoucissant le linge Download PDF

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Publication number
EP0082456B1
EP0082456B1 EP82111555A EP82111555A EP0082456B1 EP 0082456 B1 EP0082456 B1 EP 0082456B1 EP 82111555 A EP82111555 A EP 82111555A EP 82111555 A EP82111555 A EP 82111555A EP 0082456 B1 EP0082456 B1 EP 0082456B1
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EP
European Patent Office
Prior art keywords
weight
carbon atoms
alkyl
methyl
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP82111555A
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German (de)
English (en)
Other versions
EP0082456A3 (en
EP0082456A2 (fr
Inventor
Adolf Dr. May
Hans-Walter Dr. Bücking
Manfred Schreiber
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Hoechst AG
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Hoechst AG
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Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT82111555T priority Critical patent/ATE22919T1/de
Publication of EP0082456A2 publication Critical patent/EP0082456A2/fr
Publication of EP0082456A3 publication Critical patent/EP0082456A3/de
Application granted granted Critical
Publication of EP0082456B1 publication Critical patent/EP0082456B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/645—Mixtures of compounds all of which are cationic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This occurs particularly when the laundry is done in the washing machine.
  • Such undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
  • the water-dispersible dialkyldimethylammonium salts or imidazoline derivatives of the formulas I ⁇ III are used in particular for this purpose:
  • R alkyl or alkenyl with 8-22, preferably 10-18, carbon atoms
  • R 3 is methyl or hydrogen
  • x is a number from 1-5
  • A is an anion such as Cl (-) , Br-I, CH 3 OSO 3 (-) or CH 3 OPO 3 (-) .
  • the products of these formulas I ⁇ III have a liquid or solid consistency. If R is a saturated residue, the product is solid at room temperature. The transport then takes place in heated tankers or rail tank cars. It is delivered in barrels for overseas transport. The manufacturers of fabric softeners then have the products transferred to heated tank systems. If the raw material is processed, the warmed-up product is dispersed in hot water. If barrel goods are processed, the products must first be liquefied in a barrel heating system and can then be further processed.
  • the alkyl radicals of the compounds I ⁇ III consist of unsaturated units
  • these derivatives are liquid at room temperature. They can be processed into dispersions with cold water. Liquid fabric softener raw materials, however, have a reduced softening effect compared to the saturated derivatives. In order to achieve comparable grip properties, much more cationic substance has to be offered to the tissue in the case of unsaturated compounds.
  • the softening effect corresponds to 1 kg of the compound types Formula to III with saturated radical R, approximately 1.33 kg of the compound types of Formula 1 to 111 with unsaturated radical R ,.
  • the quaternary ammonium compounds are mixed with a liquid fatty amine oxyethylate and combined with a paraffin, a fatty alcohol, a fatty acid, a fatty acid ester, a polyglycol or a polyglycol ester or mixtures thereof.
  • the premixes according to the invention can also contain further substances and auxiliaries.
  • auxiliaries such as cationic or nonionic surface-active substances, solubilizers such as e.g. p-cumene sulfonate, electrolytes, acidifying agents such as e.g. Phosphoric acid, acetic acid, organic complexing agents, optical brighteners as well as colors and fragrances. They serve to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.
  • this premix can be diluted with water without further ado. With correspondingly less water, it is also possible to produce so-called 3-fold, 4-fold, 6-fold or 8-fold concentrate.
  • These fabric softeners are used as usual by adding them to the last rinsing bath after the textile wash and then drying the textile material.
  • laundry softener premixes according to the invention are described. Percentages are percentages by weight in all cases. In all cases, these premixes are prepared by simply stirring the liquid individual components in the cold.
  • Example 2 25 g of the premix from Example 2 are mixed with 0.9 g of perfume and 1 g of a nonionic emulsifier of the isotridecyl alcohol type with 10 EO. 5 ml of a 10% CaCl 2 solution in 61.4 ml of cold water are added. This solution is stirred into the premix. A stable emulsion is obtained. The viscosity is approx. 150 mPas.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Claims (2)

1. Prémélanges concentrés d'assouplisseurs pour linge, caractérisés en ce qu'ils sont constitués:
a) de 20 à 70% en poids d'un ou de plusieurs des composés répondant aux formules 1 à III:
Figure imgb0025
Figure imgb0026
dans lesquelles R, représente un radical alkyle ou alcényle contenant de 8 à 22 atomes de carbone, de préférence de 10 à 18, R2 un alkyle contenant de 1 à 4 atomes de carbone, de préférence un méthyle, R3 un méthyle ou l'hydrogène, x un nombre de 1 à 5 et A un anion,
b) de 20 à 60% en poids, de préférence de 40 à 60% en poids, d'une paraffine en C8―C22, de préférence en C13―C18, d'un alcool gras en C8―C22, de préférence en C16-C18, d'un acide gras en C8―C22, de préférence en C16―C18, d'un ester d'alkyle en C1―C13 dérivant d'un acide gras en C8―C22, de préférence en C16―C18, d'un polyéthylène-glycol ayant une masse moléculaire de 200 à 600, d'un ester d'alkyle en C8―C22, de préférence en C14―C16, dérivant d'un polyéthylène-glycol de masse moléculaire comprise entre 200 et 600 ou d'un polypropytèneglycol de masse moléculaire comprise entre 200 et 1 000,
c) de 5 à 25% en poids d'un produit d'éthoxylation d'une amine qui répond à la formule IV:
Figure imgb0027
dans laquelle R représente un radical alkyle ou alcényle contenant de 8 à 22 atomes de carbone, de préférence de 16 à 18, x et y représentent chacun l'hydrogène ou un méthyle mais ne peuvent pas représenter chacun en même temps un méthyle, n représente un nombre entier de 2 à 40, de préférence le nombre 10, p représente un nombre de 0 à 1, de préférence 0, et m représente un nombre de 0 à 3, de préférence le nombre 3 lorsque p est égale à 1, ainsi que d'eau et d'autres substances et adjuvants en des quantités formant le complément à 100% en poids.
2. Prémélanges concentrés selon la revendication 1 qui sont constitués de 35 à 45% en poids de la composant a), de 40 à 60% en poids de la composant b) et de 5 à 20% en poids de la composante c) ainsi que d'eau en une quantité complétant à 100%.
EP82111555A 1981-12-18 1982-12-13 Prémélanges concentrés d'agents adoucissant le linge Expired EP0082456B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82111555T ATE22919T1 (de) 1981-12-18 1982-12-13 Konzentrierte vormischungen von waescheweichspuelmitteln.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3150179 1981-12-18
DE19813150179 DE3150179A1 (de) 1981-12-18 1981-12-18 Konzentrierte vormischungen von waescheweichspuelmitteln

Publications (3)

Publication Number Publication Date
EP0082456A2 EP0082456A2 (fr) 1983-06-29
EP0082456A3 EP0082456A3 (en) 1984-11-28
EP0082456B1 true EP0082456B1 (fr) 1986-10-15

Family

ID=6149087

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82111555A Expired EP0082456B1 (fr) 1981-12-18 1982-12-13 Prémélanges concentrés d'agents adoucissant le linge

Country Status (8)

Country Link
US (1) US4476030A (fr)
EP (1) EP0082456B1 (fr)
JP (1) JPS58109681A (fr)
AT (1) ATE22919T1 (fr)
BR (1) BR8207359A (fr)
CA (1) CA1193403A (fr)
DE (2) DE3150179A1 (fr)
ZA (1) ZA829282B (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3204165A1 (de) * 1982-02-06 1983-08-11 Hoechst Ag, 6230 Frankfurt Konzentrierte waescheweichspuelmittel
US4555349A (en) * 1983-04-08 1985-11-26 Lever Brothers Company Fabric softening compositions
NZ207932A (en) * 1983-05-11 1986-03-14 Colgate Palmolive Co Fabric softener compositions containing quaternary ammonium compounds
GB8410322D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous concentrated fabric softening composition
GB8410320D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous fabric softening composition
GB8410321D0 (en) * 1984-04-19 1984-05-31 Unilever Plc Aqueous concentrated fabric softening composition
DE3416472A1 (de) * 1984-05-04 1985-11-07 Hoechst Ag, 6230 Frankfurt Weichmacher enthaltende waschmittel
GB8414944D0 (en) * 1984-06-12 1984-07-18 Ici Plc Fabric conditioners
GB8430301D0 (en) * 1984-11-30 1985-01-09 Swan Thomas & Co Ltd Compositions of matter for fabric softeners
US4772403A (en) * 1985-01-30 1988-09-20 Colgate Palmolive Company Fabric softener composition
US4654152A (en) * 1985-10-07 1987-03-31 Domtar Inc. Base mix fabric softener
US4741842A (en) * 1986-01-27 1988-05-03 Colgate-Palmolive Company Particulate detergent softener compositions comprising a mixture of cationic softener and ethoxylated amine
DE3706664A1 (de) * 1987-02-28 1988-09-08 Henkel Kgaa Fluessige textilbehandlungsmittel
US4885102A (en) * 1987-07-17 1989-12-05 Kao Corporation Cloth-softening liquid composition containing quaternary ammonium compound and a polyether derivative or cationic surfactant polymer
DE68919236T2 (de) * 1988-01-28 1995-04-06 Unilever Nv Textilbehandlungszubereitung und deren Herstellung.
JPH0756112B2 (ja) * 1988-02-17 1995-06-14 花王株式会社 濃縮型衣料用柔軟仕上剤
JP2631389B2 (ja) * 1988-05-19 1997-07-16 ライオン株式会社 柔軟剤組成物
DE3842571A1 (de) * 1988-12-17 1990-06-21 Pfersee Chem Fab Hydrophile weichgriffmittel fuer faserige materialien und deren verwendung
FR2655658B1 (fr) * 1989-12-08 1994-11-18 Rhone Poulenc Chimie Compose lessiviel a base d'un polyphosphate et notamment d'un agent optiquement actif, son procede de preparation et son utilisation en detergence.
GB9122486D0 (en) * 1991-10-23 1991-12-04 Cussons Int Ltd Fabric softener composition
GB2281316A (en) * 1993-08-24 1995-03-01 Sasol Chemical Ind Fabric treatment composition
DE4441029A1 (de) * 1994-11-17 1996-05-23 Henkel Kgaa Kationische Wachsdispersionen
NZ286025A (en) * 1995-03-01 1997-04-24 Colgate Palmolive Co Laundry detergent concentrates; contains nonionic surfactant and water insoluble oil with a hydrophilic polar group, converts to liquid crystal phase dispersion on dilution
CA2230298A1 (fr) * 1995-08-31 1997-03-06 Colgate-Palmolive Company Compositions d'assouplisseur stables pour textiles
US5861370A (en) * 1996-03-22 1999-01-19 The Procter & Gamble Company Concentrated, stable, premix for forming fabric softening composition
US5830845A (en) * 1996-03-22 1998-11-03 The Procter & Gamble Company Concentrated fabric softening composition with good freeze/thaw recovery and highly unsaturated fabric softener compound therefor
GB0121802D0 (en) 2001-09-10 2001-10-31 Unilever Plc Fabric conditioning compositions
GB0121806D0 (en) 2001-09-10 2001-10-31 Unilever Plc A method of reducing the viscosity of fabric conditioning compositions
GB2613660A (en) * 2021-12-06 2023-06-14 Reckitt Benckiser Health Ltd Laundry sanitizing and softening composition
WO2023105205A1 (fr) 2021-12-06 2023-06-15 Reckitt Benckiser Health Limited Composition de désinfection et d'adoucissement du linge

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3154489A (en) * 1960-07-18 1964-10-27 Armour & Co Surface active compositions
EP0013780B2 (fr) * 1979-01-11 1988-08-31 THE PROCTER & GAMBLE COMPANY Composition concentrée d'adoucissement pour tissus
DE3066798D1 (en) * 1979-04-21 1984-04-12 Procter & Gamble Fabric softening composition
GR67665B (fr) * 1979-05-21 1981-09-02 Unilever Nv
DE2928141A1 (de) * 1979-07-12 1981-02-05 Hoechst Ag Waescheweichspuelmittel
DE2930061A1 (de) * 1979-07-25 1981-02-19 Hoechst Ag Waescheweichspuelmittel
DE3263800D1 (en) * 1981-01-16 1985-07-04 Procter & Gamble Textile treatment compositions

Also Published As

Publication number Publication date
EP0082456A3 (en) 1984-11-28
CA1193403A (fr) 1985-09-17
DE3150179A1 (de) 1983-06-23
ATE22919T1 (de) 1986-11-15
DE3273801D1 (en) 1986-11-20
JPH0325549B2 (fr) 1991-04-08
EP0082456A2 (fr) 1983-06-29
JPS58109681A (ja) 1983-06-30
ZA829282B (en) 1983-09-28
US4476030A (en) 1984-10-09
BR8207359A (pt) 1983-10-18

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