EP0022555A1 - Adoucissant pour matières textiles - Google Patents

Adoucissant pour matières textiles Download PDF

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Publication number
EP0022555A1
EP0022555A1 EP80103918A EP80103918A EP0022555A1 EP 0022555 A1 EP0022555 A1 EP 0022555A1 EP 80103918 A EP80103918 A EP 80103918A EP 80103918 A EP80103918 A EP 80103918A EP 0022555 A1 EP0022555 A1 EP 0022555A1
Authority
EP
European Patent Office
Prior art keywords
carbon atoms
methyl
alkyl
compound
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP80103918A
Other languages
German (de)
English (en)
Other versions
EP0022555B1 (fr
Inventor
Adolf Dr. May
Hans-Walter Dr. Bücking
Karl Prof. Dr. Wallhäusser
Werner Skrypzak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT80103918T priority Critical patent/ATE10383T1/de
Publication of EP0022555A1 publication Critical patent/EP0022555A1/fr
Application granted granted Critical
Publication of EP0022555B1 publication Critical patent/EP0022555B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/645—Mixtures of compounds all of which are cationic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides

Definitions

  • washed textiles especially those made from cellulose fibers
  • This undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
  • the water-dispersible dialkyldimethylammonium salts have been introduced for this purpose.
  • these products have the disadvantage that the treated tissue becomes too hydrophobic when overdosed and the * rewettability is thereby delayed. It is also very difficult to combine such long-chain dialkyldimethylammonium salts with short-chain dialkylquats, e.g.
  • the invention thus relates to fabric softeners in the form of an aqueous solution or dispersion which comprise 3 to 15, preferably 3 to 8% by weight of one or more compounds of the formulas I to IV where R 1 is alkyl or alkenyl having 6 to 18 carbon atoms, preferably 8 to 14 carbon atoms, x and Y are hydrogen or methyl, but x and y are not simultaneously methyl, n is a number from 1 to 20, preferably 3 to 10, R 2 Alkyl with 1-4 carbon atoms, preferably methyl, R 3 methyl or hydrogen, m is a number from 1 to 15, preferably 1 and A is an anion such as Cl (-) Br (-) CH 3 OSO 3 (1) or (CH 3 ) 2 OPO 3 (-) means 3 - 15% by weight of a compound of formula V
  • R 4 is alkyl with 8-30, preferably 10-18 carbon atoms
  • n, x and y have the meaning given above and optionally contain 3 to 5% by weight of a bactericidal quaternary ammonium compound and other customary auxiliaries and additives.
  • This combination of compounds I to V gives any textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, triacetate, polyamide, polyacrylonitrile, polyester, polypropylene, a pleasant and soft feel. Use as a laundry treatment agent for terry and underwear is particularly advantageous.
  • These fabric softeners are produced by simply mixing or dispersing the individual components in water. These fabric softeners according to the invention can either contain only one compound of the formulas I to IV or they contain a mixture of two or more compounds of these formulas I to IV within the stated limits. If a mixture of two or more compounds of the formulas II to IV is present, their mixing ratio with one another is completely uncritical and can have any value.
  • the fabric softeners according to the invention can also contain 3 to 5% by weight of a bactericidal compound.
  • bactericidal compounds are in particular those of the formulas VI to VIII, where R 1 ' R 2 and A have the meaning given above and R7 is an aliphatic radical having 6 to 12, preferably 10 carbon atoms.
  • the fabric softener according to the invention can also contain other substances and auxiliaries which are either already mixed in the concentrate of the fabric softener or added separately to the ready-to-use, diluted fabric softener.
  • auxiliaries which have already been used in fabric softeners, e.g. cationic or nonionic surface-active substances, electrolytes, acidifying agents, organic complexing agents, optical brightening agents or solubilizers as well as colors and fragrances. They serve to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.
  • the fabric softeners described above are completely clear and have the advantage that the rewettability of cotton is significantly improved compared to commercially available agents. It is also surprising that those compounds of the formulas I to IV in combination with a compound of the formula V which have more than 50% alkyl groups with only 12 carbon atoms, have a good softening effect, since it is known that such compounds are suitable for have only a medium softening effect compared to di-tallow fatty alkyl dimethyl ammonium chloride. The fatty acid alkylolamide oxyethylates alone have no softening effect.
EP80103918A 1979-07-12 1980-07-09 Adoucissant pour matières textiles Expired EP0022555B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80103918T ATE10383T1 (de) 1979-07-12 1980-07-09 Waescheweichspuelmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2928141 1979-07-12
DE19792928141 DE2928141A1 (de) 1979-07-12 1979-07-12 Waescheweichspuelmittel

Publications (2)

Publication Number Publication Date
EP0022555A1 true EP0022555A1 (fr) 1981-01-21
EP0022555B1 EP0022555B1 (fr) 1984-11-21

Family

ID=6075520

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80103918A Expired EP0022555B1 (fr) 1979-07-12 1980-07-09 Adoucissant pour matières textiles

Country Status (7)

Country Link
EP (1) EP0022555B1 (fr)
JP (1) JPS5615472A (fr)
AR (1) AR224163A1 (fr)
AT (1) ATE10383T1 (fr)
BR (1) BR8004320A (fr)
CA (1) CA1152707A (fr)
DE (2) DE2928141A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0082456A2 (fr) * 1981-12-18 1983-06-29 Hoechst Aktiengesellschaft Prémélanges concentrés d'agents adoucissant le linge
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
US4622154A (en) * 1984-04-19 1986-11-11 Lever Brothers Company Aqueous fabric softening composition
US4627925A (en) * 1984-04-19 1986-12-09 Lever Brothers Company Aqueous concentrated fabric softening composition
WO2001036737A1 (fr) * 1999-11-12 2001-05-25 Kao Corporation Composition d'adoucissant
US6780833B1 (en) 1999-11-12 2004-08-24 Kao Corporation Softener composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58144175A (ja) * 1982-02-23 1983-08-27 ライオン株式会社 繊維製品処理用物品
GB8334226D0 (en) * 1983-12-22 1984-02-01 Learonal Uk Ltd Electrodeposition of gold alloys

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1339069A (en) * 1970-03-09 1973-11-28 Colgate Palmolive Co Detergent compositions
DE2436145A1 (de) * 1973-08-01 1975-02-13 Unilever Nv Verfahren zur herstellung von teilchenfoermigen reinigungsmittelzusammensetzungen
EP0000595A1 (fr) * 1977-06-29 1979-02-07 THE PROCTER & GAMBLE COMPANY Composition détergente à faible teneur en phosphates pour le lavage des tissus
DE2733970A1 (de) * 1977-07-28 1979-02-15 Henkel Kgaa Alpha-cyanofettsaeure-n-hydroxyalkylamide und ihre verwendung als waschaktivsubstanzen
US4155882A (en) * 1973-08-01 1979-05-22 Lever Brothers Company Process for preparing particulate detergent compositions containing nonionic surfactants

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3451927A (en) * 1964-07-08 1969-06-24 Lever Brothers Ltd Fabric conditioner
DE2605502A1 (de) * 1976-02-12 1977-08-18 Exquisit Kosmetik Gmbh Fluessiges feinwaschmittel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1339069A (en) * 1970-03-09 1973-11-28 Colgate Palmolive Co Detergent compositions
DE2436145A1 (de) * 1973-08-01 1975-02-13 Unilever Nv Verfahren zur herstellung von teilchenfoermigen reinigungsmittelzusammensetzungen
US4155882A (en) * 1973-08-01 1979-05-22 Lever Brothers Company Process for preparing particulate detergent compositions containing nonionic surfactants
EP0000595A1 (fr) * 1977-06-29 1979-02-07 THE PROCTER & GAMBLE COMPANY Composition détergente à faible teneur en phosphates pour le lavage des tissus
DE2733970A1 (de) * 1977-07-28 1979-02-15 Henkel Kgaa Alpha-cyanofettsaeure-n-hydroxyalkylamide und ihre verwendung als waschaktivsubstanzen

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0082456A2 (fr) * 1981-12-18 1983-06-29 Hoechst Aktiengesellschaft Prémélanges concentrés d'agents adoucissant le linge
EP0082456A3 (en) * 1981-12-18 1984-11-28 Hoechst Aktiengesellschaft Concentrated premixes of fabric-softening agents
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
US4622154A (en) * 1984-04-19 1986-11-11 Lever Brothers Company Aqueous fabric softening composition
US4627925A (en) * 1984-04-19 1986-12-09 Lever Brothers Company Aqueous concentrated fabric softening composition
WO2001036737A1 (fr) * 1999-11-12 2001-05-25 Kao Corporation Composition d'adoucissant
US6780833B1 (en) 1999-11-12 2004-08-24 Kao Corporation Softener composition

Also Published As

Publication number Publication date
AR224163A1 (es) 1981-10-30
CA1152707A (fr) 1983-08-30
DE2928141A1 (de) 1981-02-05
DE3069660D1 (en) 1985-01-03
JPS5615472A (en) 1981-02-14
ATE10383T1 (de) 1984-12-15
EP0022555B1 (fr) 1984-11-21
BR8004320A (pt) 1981-01-27

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