WO2001036737A1 - Composition d'adoucissant - Google Patents

Composition d'adoucissant Download PDF

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Publication number
WO2001036737A1
WO2001036737A1 PCT/JP2000/007897 JP0007897W WO0136737A1 WO 2001036737 A1 WO2001036737 A1 WO 2001036737A1 JP 0007897 W JP0007897 W JP 0007897W WO 0136737 A1 WO0136737 A1 WO 0136737A1
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WO
WIPO (PCT)
Prior art keywords
carbon atoms
group
alkyl group
alkyl
general formula
Prior art date
Application number
PCT/JP2000/007897
Other languages
English (en)
Japanese (ja)
Inventor
Hiromitsu Hayashi
Noriko Yamaguchi
Shuji Tagata
Ikuo Sugano
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2000102428A external-priority patent/JP3389549B2/ja
Priority claimed from JP2000114097A external-priority patent/JP3389550B2/ja
Application filed by Kao Corporation filed Critical Kao Corporation
Priority to EP00974874A priority Critical patent/EP1154068B1/fr
Priority to DE60027138T priority patent/DE60027138T2/de
Priority to US09/868,920 priority patent/US6780833B1/en
Publication of WO2001036737A1 publication Critical patent/WO2001036737A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the present invention relates to softener compositions.
  • 7-36949 discloses a dilong chain alkyl (alkyl or alkenyl group having 6 to 24 carbon atoms which may be interrupted by an ether bond, an ester bond or an acid amide bond). And a mono-long-chain alkyl (alkyl or alkenyl group having 6 to 24 carbon atoms, which may be interrupted by a polyester bond, an ester bond or an acid amide bond), of a weight ratio of Disclosed is a softening composition for textile products having a pH of 2 to 5 containing a ratio of 9: 1 to 5: 5.
  • an antibacterial fiber softener composition suitable for imparting antibacterial performance to fibers, which is used in combination with a conventional fiber softener composition.
  • an antimicrobial fabric softener composition comprising one or more cationic antimicrobial agents in a greater amount required for antimicrobial performance.
  • the antibacterial water-soluble quaternary ammonium salt has the problem of reducing the softening effect, and it was necessary to sacrifice the softening effect to obtain a satisfactory antibacterial effect.
  • an object of the present invention is to provide a softener composition which suppresses body odor derived from sweat or the like for a long time and has an excellent softening effect.
  • the present invention provides (a) a quaternary ammonium compound represented by the following general formula (1), and (b)
  • a softener composition containing a quaternary ammonium compound represented by the general formula (2) and further containing a compound selected from the following component (c) or component (d): Z '(1)
  • R 1 R 2 each independently represents an alkyl group or an alkenyl group having 12 to 22 carbon atoms
  • X and Y each independently represent —COO—, CONR 7 —
  • ⁇ CO— one NR 7 CO—, preferably at least one is one CO
  • R 7 represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group.
  • R 3 and R ′′ 1 are each independently an alkylene group having 1 to 5 carbon atoms;
  • R 5 and R 6 are an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms or R 1 —X—R 3 —
  • Z— is an anionic group.
  • R s represents an alkyl group or alkenyl group having 12 to 22 carbon atoms
  • W is a group selected from —CO—, one CONR 7 —, one OCO—, and one NR 7 CO—.
  • R 7 is a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, preferably Preferably, it is a hydrogen atom.
  • R 9 is an alkylene group having 5 to several carbon atoms
  • R 1 0, R 11 is an alkyl group or hydroxycarboxylic alkyl group having 1 to 3 carbon atoms
  • R 12 is alkyl of 1 to 3 carbon atoms Or —R 26 — ⁇ H.
  • R 26 is an alkylene group having 1 to 5 carbon atoms.
  • Z— is an anionic group.
  • R 13 and R 18 are each independently an alkyl group having 5 to 19 carbon atoms or an alkenyl group
  • R 14 and R 15 are each independently an alkyl group having 1 to 3 carbon atoms or It is a hydroxyalkyl group.
  • T is one COO-, one C-one, one CONH-,-NHCO
  • R 16 is an alkylene group having 1 to 3 carbon atoms
  • R 17 is an alkylene group having 1 to 6 carbon atoms or 1 (O—R 19 ) n—.
  • R 19 is an ethylene group or a propylene group
  • n is a number of 1 to 10.
  • W— is an anionic group.
  • R 2 . , R 2 ⁇ R 22 , R 23 is an alkyl group having 8 to 12 carbon atoms And the remainder is an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group having 1 to 3 carbon atoms, or an arylalkyl group having 7 to 15 total carbon atoms, and Z— is an anionic group. . ]
  • the connecting hand means a covalent bond directly connecting R 13 and R 17 .
  • the component (a) of the present invention is a compound represented by the following general formula (1).
  • each of R 1 R 2 independently represents an alkyl group or alkenyl group having 12 to 22, preferably 14 to 22, and particularly preferably 14 to 18 carbon atoms
  • X and Y each represent independently, one COO-, one CONR 7 -, one OCO-, is an NR 7 CO- color selection Bareru groups, preferably at least one is _C_ ⁇ _ ⁇ one, -OCO-.
  • One COO— or one CONR 7 — is preferred.
  • R 7 represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group.
  • R 3 and R 4 are each independently an alkylene group having 1 to 5 carbon atoms;
  • R 5 and R 6 are an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms or R 1 — X—R 3— and
  • Z— is an anionic group.
  • Z_ is preferably a halogen ion, a sulfate ion, a phosphate ion, an alkyl sulfate ion having 1 to 3 carbon atoms, or a fatty acid ion having 1 to 12 carbon atoms.
  • the following compounds are particularly preferred as the component (a).
  • R ′, R ′′ an alkyl group or an alkenyl group having 12 to 18 carbon atoms, which may be the same or different, R ′ ′′ ′ is an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms, R "" is an alkyl group having 1 to 3 carbon atoms.
  • the component (b) of the present invention is a compound represented by the following general formula (2).
  • R 8 is 12 to 22 carbon atoms, preferably 14 to 22, particularly preferably an alkyl or alkenyl group of 14 ⁇ 1 8
  • W is one C_rei_0_, -CONR 7 one, ten C ⁇ one, one NR 7 CO—, preferably one COO— or one CONR 7 —.
  • R 7 represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, preferably a hydrogen atom.
  • R 9 is an alkylene group having 1 to 5 carbon atoms, and R 1Q and R 11 each independently represent an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group.
  • R 12 is an alkyl group having 1 to 3 carbon atoms or one R 26 —OH.
  • R 26 is an alkylene group having 1 to 5 carbon atoms.
  • Z— is an anionic group, preferably a halogen ion, a fatty acid ion, or an alkyl sulfate ion having 1 to 3 carbon atoms. ].
  • the component (c) of the present invention is a compound represented by the above general formula (3) or (4), and the most preferred component (c) includes the following compounds. In the formula, Z— and have the meaning described above.
  • R is an alkyl group having 12 to 16 carbon atoms
  • R is an optionally branched alkyl group having 6 to 10 carbon atoms, m is a number of 1 to 5)
  • the component (d) of the present invention is a compound represented by the general formula (5). Acid ions or alkyl sulfate ions having 1 to 3 carbon atoms are preferred.
  • the softener composition of the present invention preferably contains the component (a) in an amount of 3 to 50% by weight, more preferably 3 to 40% by weight. /. And particularly preferably 5 to 35% by weight.
  • the component (b) weighs 0.5 to 10 weight. / 0 , preferably 0.5-5% by weight. Further, it is preferred from the viewpoint of the softening effect and the deodorizing effect that the component (a) contains the component Z (b) in a weight ratio of 80 / 20-99 / 1, particularly 85/15 to 951.
  • the component (c) is used in an amount of 0.1 to 15% by weight. /. , Preferably 1 to 15 weight. /. Particularly preferred is 3 to 10 weight. / 0 contained. Further, (c) / (a) is desirably 1Z30 to 1Z1, preferably 1Z10 0 to 1/1 by weight in terms of the feeling of clothing and the deodorizing effect.
  • the component (d) is preferably 0.1 to 15 weight. /. And more preferably 0.2 to 10 weights. / 0 , and (a) / (d) is 50Zl to 2Zl, preferably 30Zl to 2/1, more preferably 2 OZl to 2 ⁇ 1 ⁇ , is desirable from the viewpoint of the texture and deodorizing effect of clothing.
  • the softener composition of the present invention is preferably in the form of an aqueous solution obtained by diluting at least the component (a) and the component (c) or the component (b) and the component (d) with water.
  • the water used is preferably distilled water or ion-exchanged water. Further, it is desirable from the viewpoint of storage stability that water is contained in the composition in an amount of 40 to 90% by weight, more preferably 50 to 85% by weight, and particularly preferably 60 to 85% by weight.
  • the composition of the present invention is preferably adjusted to have a pH at 20 ° C. of 1 to 6, more preferably 2 to 5, particularly 2.5 to 4, from the viewpoint of deodorizing effect and storage stability.
  • a nonionic surfactant in addition to the components (a), (b), (c) and (d).
  • a nonionic surfactant a polyoxyethylene alkyl ether having at least one alkyl or alkenyl group having 8 to 20 carbon atoms is preferable, and a nonionic surfactant represented by the general formula (6) is particularly preferable.
  • R 24 is an alkyl group or an alkenyl group having 10 to 18 carbon atoms, preferably 12 to 18 carbon atoms
  • R 25 is an alkylene group having 2 or 3 carbon atoms, preferably an ethylene group. It is. p represents a number of 2 to 100, preferably 5 to 80, more preferably 1 to 80, and particularly preferably 20 to 60.
  • U is one O—, one CON— or —N—, q is 1 when U is — ⁇ one, and q is two when U is one CON— or one N—. ].
  • R 24 has the meaning described above. r is 8 to 100 when the component (c) is included, When the component (d) is contained, the number is 5 to 100, preferably 10 to 80, and more preferably 20 to 80. ] R 2 -0- (C 2 H 4 0) s (C 3 H 6 0) tH
  • R 24 has the meaning described above.
  • s and t are each independently 2 to 40, preferably 5 to 40, preferably s + t is a number from 10 to 80, and ethylene oxide and propylene oxide are random or block adducts. It may be.
  • R 24 has the above-mentioned meaning.
  • the sum of u and V is 5 to 100 when the component (c) is included, 10 to 80 when the component (d) is included, and preferably 5 to 80.
  • the amount of the nonionic surfactant is 0.5 to 10% by weight from the viewpoint of stability, preferably:! ⁇ 8% by weight.
  • (f) a fatty acid having 8 to 22 carbon atoms or a salt thereof is preferably 0.1 to 5% by weight, particularly preferably 0.5 to 3% by weight for the purpose of improving the texture of the textile product.
  • Fatty acids or salts thereof are power prillic acid, power pric acid, lauric acid, myristic acid, nonoremitic acid, stearic acid, oleic acid, or a mixture thereof, particularly selected from lauric acid, stearic acid, and oleic acid.
  • One or more types are good.
  • fatty acids having an alkyl composition derived from coconut oil, palm oil, palm kernel oil, and tallow are also preferable.
  • an ester compound of a saturated or unsaturated fatty acid having 8 to 22 carbon atoms and a polyhydric alcohol is contained in the composition in an amount of 0.1 to 10% by weight, especially 0.5 to 10% by weight.
  • the content be 5 to 5% by weight.
  • ester compound triglyceride, diglyceride, monodalicelide, and pentaerythritol mono, di, triester, and sorbitan esters are preferred.
  • an inorganic salt for example, calcium chloride
  • an inorganic salt for example, calcium chloride
  • surfactants such as fatty acid salts include sodium salts and magnesium salts, but inorganic salts mixed into the composition by use of such surfactants are not subject to the above restrictions.
  • storage stability can be achieved by blending a solvent component selected from ethanol, isopropanol, glycerin, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, and polyoxyethylene phenyl ether. It is preferable from the viewpoint of properties. These solvent components are preferably incorporated in the composition in an amount of 0 to 20% by weight, more preferably 0.1 to 20% by weight, and particularly preferably 0.5 to 10% by weight. When ethanol is used, it is preferable to use polyoxyethylene alkyl ether sulfate-modified ethanol 8- 8-acetylated sucrose-modified ethanol.
  • the softener composition of the present invention contains a silicone and a fragrance (particularly preferably those represented by components (c) and (d) described in Japanese Patent Application Laid-Open No. Or a combination of components such as pigments.
  • a silicone and a fragrance particularly preferably those represented by components (c) and (d) described in Japanese Patent Application Laid-Open No. Or a combination of components such as pigments.
  • R a saturated alkyl group in which C18 and C16 are mixed (C18: C16
  • R a saturated alkyl group in which C18 and C16 are mixed (C18: C16
  • R a saturated alkyl group in which C17 and C15 are mixed (C17: C15
  • R a saturated alkyl group in which C17 and C15 are mixed (C17: C15
  • the softener compositions shown in Table 1 were prepared using the above compounds (Products 1 to 6 of the present invention and Comparative products 1 to 3). Two sweaters (100% cotton) were washed in a washing machine using a commercially available weak alkaline detergent (Kao Attack) (Toshiba 2-tub washing machine VH-360 S1, detergent concentration 0.0667 weight / , 30 L of tap water, water temperature 20 ° C, 10 minutes). After that, the washing liquid was drained, and after dehydration for 1 minute, 30 L of tap water was injected, rinsed for 5 minutes, and dewatered for 1 minute after drainage. After injecting 30 L of tap water again, 5 g of the softener composition shown in Table 1 was added to the mixture and stirred for 5 minutes. Then, it was dehydrated and dried for 12 hours in a constant temperature room at 70% humidity and 25 ° C.
  • Kao Attack Toshiba 2-tub washing machine VH-360 S1, detergent concentration 0.0667 weight / , 30 L of tap water, water
  • the above softening treatment was performed using the softener composition shown in Table 1 and the corresponding composition excluding the antibacterial component [(c) component or (d) component], and 10 panelists were compared with each other.
  • the evaluation was performed according to the following criteria, and the average score was obtained.
  • the smell of the clothes dried in the constant temperature room and the smell of the clothes after putting them on five men in their twenties for 12 hours was determined by 10 panelists (10 men in their 30s). Judgment was made according to the following criteria, and the average score was determined for each.
  • a softener composition having the composition shown in Table 2 (product 7111 of the present invention) was prepared in the same manner as in Example 1.
  • the fragrance used was a mixture of 100 parts by weight of the composition shown in Table 3 and 10 parts by weight of dipropylene glycol. When they were evaluated in the same manner as in Example 1, excellent odor control effect and softness were recognized in all cases.
  • Table 2 A softener composition having the composition shown in Table 2 (product 7111 of the present invention) was prepared in the same manner as in Example 1.
  • the fragrance used was a mixture of 100 parts by weight of the composition shown in Table 3 and 10 parts by weight of dipropylene glycol.
  • softener compositions shown in Table 4 were prepared. Five pieces of Wishash (100% cotton) and five pieces of towel (100% cotton) (total weight of clothing: 1.5 kg) were washed in a washing machine using a commercially available weak alkaline detergent (Kao Attack) (Toshiba 2-tub washing machine VH_360 S1, detergent concentration 0.0667% by weight, tap water 30L used, water temperature 20 ° G, 10 minutes). After that, the washing solution was drained, and after dehydration for 1 minute, 30 L of tap water was injected, rinsed for 5 minutes, and dewatered for 1 minute after drainage. Thereafter, 30 L of tap water was injected again, and then 7 ml of the composition shown in Table 1 was added thereto, followed by stirring for 5 minutes. After that, it was dehydrated and air-dried.
  • Kao Attack Toshiba 2-tub washing machine VH_360 S1, detergent concentration 0.0667% by weight, tap water 30L used, water temperature 20 ° G, 10 minutes.
  • Table 1 shows the average score of less than 0.8 as “ ⁇ ”, 0.8 or more and less than 1.2 as mouth, 1.2 or more and less than 1.7 as “ ⁇ ”, and 1.7 or more as “X”.
  • Table 1 shows the results when the average score was 2 or more, rated as ⁇ , 1 or more, but less than 1.5, as mouth, 0.5 or more, but less than 1 as ⁇ , and X, less than 0.5. +3: very soft than the control + 2; softer than the control + 1; slightly softer than the control 0; equivalent to the control
  • pH is adjusted by 10 N hydrochloric acid aqueous solution and 0 N sodium hydroxide aqueous solution.

Abstract

La présente invention concerne une composition d'adoucissant constituée d'un composé de formule générale (1), d'un composé de formule générale (2), et d'un composé d'ammonium quaternaire présentant une activité antibactérienne et d'excellentes qualités en terme de douceur et d'effet désodorisant pour le corps. Dans ces formules, R?1, R2 et R8¿ représentent chacun C¿12-22? alkyle ou alcényle; X, Y et W représentent chacun un groupe choisi parmi COOC-, -CONR?7¿-, -OCO-, et NR7CO-, soit X soit Y représentant COOc- ou OO- (R7 représentant H, C¿1-3? alkyle, ou hydroxyalkyle); R?3, R4 et R9¿ représentent chacun C¿1-5? alkylène; R?5, R6, R10 et R11¿ représentent chacun C¿1-2? alkyle ou hydroxyalkyle; R?12¿ représente C¿1-3? alkyle ou C1-5-OH; et Z?-¿ est un anion.
PCT/JP2000/007897 1999-11-12 2000-11-09 Composition d'adoucissant WO2001036737A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP00974874A EP1154068B1 (fr) 1999-11-12 2000-11-09 Composition d'adoucissant
DE60027138T DE60027138T2 (de) 1999-11-12 2000-11-09 Weichmacherzusammensetzung
US09/868,920 US6780833B1 (en) 1999-11-12 2000-11-09 Softener composition

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP11/323180 1999-11-12
JP32318099 1999-11-12
JP2000/102428 2000-04-04
JP2000102428A JP3389549B2 (ja) 1999-11-12 2000-04-04 柔軟剤組成物
JP2000/114097 2000-04-14
JP2000114097A JP3389550B2 (ja) 2000-04-14 2000-04-14 柔軟剤組成物

Publications (1)

Publication Number Publication Date
WO2001036737A1 true WO2001036737A1 (fr) 2001-05-25

Family

ID=27339962

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2000/007897 WO2001036737A1 (fr) 1999-11-12 2000-11-09 Composition d'adoucissant

Country Status (5)

Country Link
EP (1) EP1154068B1 (fr)
CN (1) CN1157511C (fr)
DE (1) DE60027138T2 (fr)
ES (1) ES2260065T3 (fr)
WO (1) WO2001036737A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101711275A (zh) * 2007-03-13 2010-05-19 伊莱门蒂斯专业有限公司 可生物降解的清洁组合物
JP5394215B2 (ja) 2008-12-11 2014-01-22 花王株式会社 柔軟剤組成物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0022555A1 (fr) * 1979-07-12 1981-01-21 Hoechst Aktiengesellschaft Adoucissant pour matières textiles
JPH03287867A (ja) * 1990-03-30 1991-12-18 Kao Corp 柔軟仕上剤
JPH0598571A (ja) * 1991-10-04 1993-04-20 Lion Corp 液体柔軟剤組成物
JPH09137379A (ja) * 1995-11-13 1997-05-27 Kao Corp 柔軟仕上剤組成物
JPH1161640A (ja) * 1997-08-06 1999-03-05 Nof Corp 柔軟剤組成物

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0687291B2 (fr) * 1993-03-01 2005-08-24 The Procter & Gamble Company Compositions adoucissantes pour tissus concentrees et biodegradables a base d'ammonium quaternaire et composes contenant des chaines d'acide gras insature a indice d'iode intermediaire
US5399272A (en) * 1993-12-17 1995-03-21 The Procter & Gamble Company Clear or translucent, concentrated biodgradable quaternary ammonium fabric softener compositions
IL121037A0 (en) * 1997-06-09 1997-11-20 Innoscent Ltd Laundry fabric softener which inhibits bacterial growth and odor formation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0022555A1 (fr) * 1979-07-12 1981-01-21 Hoechst Aktiengesellschaft Adoucissant pour matières textiles
JPH03287867A (ja) * 1990-03-30 1991-12-18 Kao Corp 柔軟仕上剤
JPH0598571A (ja) * 1991-10-04 1993-04-20 Lion Corp 液体柔軟剤組成物
JPH09137379A (ja) * 1995-11-13 1997-05-27 Kao Corp 柔軟仕上剤組成物
JPH1161640A (ja) * 1997-08-06 1999-03-05 Nof Corp 柔軟剤組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1154068A4 *

Also Published As

Publication number Publication date
EP1154068B1 (fr) 2006-04-05
ES2260065T3 (es) 2006-11-01
DE60027138T2 (de) 2006-12-28
EP1154068A1 (fr) 2001-11-14
EP1154068A4 (fr) 2002-09-04
CN1336973A (zh) 2002-02-20
CN1157511C (zh) 2004-07-14
DE60027138D1 (de) 2006-05-18

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