EP0044003B1 - Agent de lavage liquide avec une teneur en additifs inhibant le changement de couleur - Google Patents
Agent de lavage liquide avec une teneur en additifs inhibant le changement de couleur Download PDFInfo
- Publication number
- EP0044003B1 EP0044003B1 EP81105166A EP81105166A EP0044003B1 EP 0044003 B1 EP0044003 B1 EP 0044003B1 EP 81105166 A EP81105166 A EP 81105166A EP 81105166 A EP81105166 A EP 81105166A EP 0044003 B1 EP0044003 B1 EP 0044003B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- polyglycol ether
- alkyl polyglycol
- liquid detergent
- amounting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 title claims description 12
- 239000000654 additive Substances 0.000 title claims description 7
- 238000005406 washing Methods 0.000 title description 13
- 230000002401 inhibitory effect Effects 0.000 title description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000003599 detergent Substances 0.000 claims abstract description 36
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 31
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920000151 polyglycol Polymers 0.000 claims abstract description 24
- 239000010695 polyglycol Substances 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920002472 Starch Polymers 0.000 claims abstract description 17
- 239000008107 starch Substances 0.000 claims abstract description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
- 235000019698 starch Nutrition 0.000 claims abstract description 16
- 125000002091 cationic group Chemical group 0.000 claims abstract description 12
- 239000001257 hydrogen Substances 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000002431 hydrogen Chemical group 0.000 claims abstract description 7
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims abstract description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 4
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 4
- -1 alkyl dimethyl ammonium salt Chemical class 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000975 dye Substances 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 239000008139 complexing agent Substances 0.000 claims description 4
- 229910001385 heavy metal Inorganic materials 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000003605 opacifier Substances 0.000 claims description 3
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 230000003165 hydrotropic effect Effects 0.000 claims description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 description 10
- 239000004435 Oxo alcohol Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 239000004753 textile Substances 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 238000002845 discoloration Methods 0.000 description 5
- 239000003752 hydrotrope Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 229920001592 potato starch Polymers 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical class CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- XIUCEANTZSXBQQ-UHFFFAOYSA-N (3-chloro-2-hydroxypropyl)-trimethylazanium Chemical class C[N+](C)(C)CC(O)CCl XIUCEANTZSXBQQ-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- CVLHGLWXLDOELD-UHFFFAOYSA-N 4-(Propan-2-yl)benzenesulfonic acid Chemical class CC(C)C1=CC=C(S(O)(=O)=O)C=C1 CVLHGLWXLDOELD-UHFFFAOYSA-N 0.000 description 1
- 241001136792 Alle Species 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 101001096355 Homo sapiens Replication factor C subunit 3 Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical class CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102100037855 Replication factor C subunit 3 Human genes 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 244000274883 Urtica dioica Species 0.000 description 1
- 235000009108 Urtica dioica Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000004665 cationic fabric softener Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 239000008096 xylene Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
- C11D1/8355—Mixtures of non-ionic with cationic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the present invention relates to a liquid washing and cleaning agent based on nonionic surfactants and laundry softening quaternary ammonium compounds, which additionally contains cationic starch ethers, as a result of which the dye transfer from colored textiles to white or light-colored textiles is counteracted during washing together.
- DE-A-2 828 619 describes a detergent composed of nonionic surfactants, zwitterionic or semipolar surfactants and cationic surfactants in certain proportions.
- US-A-4005029 and 4 006 092 describe compositions containing per-compounds.
- EP-A1-5 850 discloses a liquid detergent based on two different nonionic surfactants with a special cationic fabric softener; the dye transfer properties of this detergent are not fully satisfactory.
- Cationic starch ethers are known commercially available substances that are used as additives to improve the quality of paper and cardboard manufacture.
- the starch ethers can be prepared in a manner known per se, e.g. by reacting the starch, for example potato starch, with ethyleneimine (see US Pat. No. 3,303,184) and then partially or completely quaternizing the amino group.
- ethers are preferably used as a discoloration-inhibiting additive in combination with textile-softening quaternary ammonium compounds which are obtained, for example, by reacting starch with 2,3-epoxypropyltrialkylammonium salts or 3-chloro-2-hydroxypropyltrimethylammonium salts, in particular with 2,3-epoxypropyltrimethylammonium chloride.
- Such reaction products are described for example in GB-A-1 136 842.
- the quaternary salts can be used as halides, especially chlorides, sulfates, alkyl sulfates, nitrates, phosphates and as salts of organic acids, e.g. B.
- a typical product is Empresol N from Emsland -force GmbH, Emlichheim, Federal Republic of Germany. This is a cationic potato starch derivative with tertiary and quaternary nitrogen atoms, the cationic charge of which is evenly distributed over the entire starch chain.
- the concentration of the starch ether additive in the detergent is between 5 and 50% by weight, based on the amount of nonionic surfactants used, and the ratio of the starch ether to the plasticizing quaternary ammonium compound is between 3: 1 and 1: 3.
- the quaternary ammonium compounds are, in particular, derivatives of ammonia, ie the quaternary salts obtainable by alkylation of long-chain secondary amines, such as, for example, the compounds distearyldimethylammonium chloride or ditalgalkyldimethylammonium chloride.
- the compounds distearyldimethylammonium chloride or ditalgalkyldimethylammonium chloride such as, for example, the compounds distearyldimethylammonium chloride or ditalgalkyldimethylammonium chloride.
- bromide, methyl sulfate, ethyl sulfate, methane, ethane or toluenesulfonate are also suitable as anions.
- quaternary ammonium compounds are the imidazoline compounds obtainable by reacting 1 mol of an aminoalkylethylenediamine or hydroxyalkylethylenediamine with 2 mol of a long-chain C 14 -C 26 fatty acid or its ester, which are then converted into the quaternary imidazolinium compounds by alkylation.
- Typical preferred textile plasticizers are, for example, the commercial products Repagen WK “and Repagen WKT” (Hoechst), Adogen 442 "(Ashland), which are ditallow alkyl dimethyl ammonium salts. These compounds are 1 to 10, preferably 2 to 6% by weight in contain the detergent according to the invention.
- the alkyl polyglycol ethers of the formula I which are suitable as constituent a) are derived from alcohols which are prepared by reacting linear olefins with carbon monoxide and hydrogen in accordance with the known oxo process by hydroformylation and subsequent hydrogenation.
- Commercially available oxo-alcohol mixtures which are suitable for the preparation of the surfactant component a) are, for example, the oxo-alcohols available from the Deutsche Shell Chemie Deutschen under the trade name Dobanol ii , which have about 25% by weight of 2-alkyl branches.
- Other suitable oxo alcohols are available under the name Synprolli from Imperial Chemical Industries Ltd. available alcohol mixtures with about 50 to 70 wt .-% 2-alkyl branches.
- Suitable products based on oxo alcohols are, for example, various Lutensol® types from BASF with approx. 30 to 35% by weight of branched alcohols and some Lial® types from Liquichimica SpA with approx. 60% by weight of branched alcohols.
- alkyl polyglycol ethers which are ethylene oxide condensates of the aforementioned oxo alcohols having 13 to 15 carbon atoms and an average ethylene oxide content of approximately 55 to 65% by weight.
- Typical preferred products are, for example, Dobanol 45-7®, which consists of at least 95% C 14 / C 15 oxo oxo alcohol with an average of 7 moles of ethylene oxide, and Lutensol AO-B ", which is a C 13 / C 15 oxo Represents alcohol ethoxylate with an average of 8 moles of ethylene oxide.
- alkyl polyglycol ethers whose alcohol base is natural or synthetic primary fatty alcohols or oxo alcohols which contain 9 to 12 carbon atoms and have an ethylene oxide content of approximately 60 to 70% by weight.
- Typical preferred products include the commercial product Marlipal KF "(Chemische Werke Hüls), which is a C 10 / C 12 fatty alcohol ethoxylate with an average of 6 moles of ethylene oxide, and the Lutensol ON-70®, which is a C 9 / C 11 - Oxo-alcohol ethoxylate with an average of 7 moles of ethylene oxide
- Suitable fatty alcohols as the basis for preferred alkyl polyglycol ethers are also the commercial products Lorol C-8 to 12® (Henkel).
- the ratio of the amount of component a) used to the amount of component b) essentially determines the parameters of washing power, foaming behavior and softening effect. Optimal results are obtained if the ratio of a): b) is between approximately 2: 1 and 1: 2.
- component a) and component b) of 10 to 30% by weight, based on the total weight of the detergent, are used, an amount of 15 to 30% by weight being preferred.
- Preferred detergents according to the invention contain, as constituent a), compounds whose radicals R 1 + R 2 have 11 to 13 carbon atoms and in particular 55 to 65% by weight of ethylene oxide.
- the detergents according to the invention preferably contain, as component b), compounds whose radical R 1 has 7 to 10 carbon atoms and whose radical R 2 is hydrogen, and which in particular have 60 to 70% by weight of ethylene oxide.
- Water is preferably used as the solvent for the detergents according to the invention.
- organic solvents can also be used in amounts of up to 20, preferably up to 16% by weight of the total liquid detergent.
- additional solvents are either lower alkanols or lower diols or polyols such as ethanol, isopropyl alcohol, ethylene glycol, propylene glycol or glycerin.
- polyols with ether compounds such as methyl, ethyl, butyl or diethylene glycol or their acetates (for example products of the "Cell-solve " type from Union Carbide Corp.) can also be used.
- solubilizers so-called hydrotropes
- hydrotropes are non-surfactant organic sulfonates, such as. B. C 6 -C 10 alkanesulfonates, and the salts of toluene, xylene and cumene sulfonic acid, preferably their alkanolamine and alkali salts, especially their potassium salts.
- Urea is also suitable as a hydrotrope.
- Hydrotropes are added in amounts of 2 to 12, preferably 3 to 9,% by weight, based on the total liquid detergent.
- auxiliaries which are usually also effective in small amounts, can be added to the detergents according to the invention.
- opacifiers and viscosity regulators which are usually present in the detergent to about 0.05 to 2% by weight.
- esters of alkanols or partial esters of polyols with longer-chain fatty acids e.g. Palmitic or stearic acid.
- a typical product is ethylene glycol stearate.
- Formalin is usually used as a preservative in an amount of 0.05 to 1% by weight.
- complexing agent for heavy metal ions is added.
- Common complexing agents are the sodium, potassium or triethanolamine salts of aminopolycarboxylic acids, such as, for example, ethylenediaminetetraacetic acid or nitrilotriacetic acid. They are used in amounts of 0.1 to 1% by weight.
- Suitable fragrances are substances with a floral / fresh or fruity fragrance or those designated as cosmetic or creamy.
- Suitable dyes are e.g. water-soluble red xanthene dyes, such as rhodamine B extra.
- the detergents according to the invention can be used for washing and simultaneously improving the touch of colored and light-colored or white textiles made of cotton, linen, wool, cellulosic chemical fibers, synthetic fibers such as polyester, polyacrylonitrile, polyamide and mixtures of cotton, wool linen, cellulosic chemical fibers and synthetic fibers, the dye transfer is largely suppressed.
- the washing and softening process can take place at washing temperatures up to about 60 ° C.
- the application concentration of the agents is generally 2 to 20 ml per liter of wash liquor, preferably 3 to 8 ml per liter.
- the textiles are not only cleaned properly, but also get a pleasant grip.
- the good foaming behavior allows the agents to be used both in the washing machine and for hand washing. Examples
- Example 1 For comparison, an agent of the composition of Example 1 was prepared with the exception of the potato starch ether, which was replaced by the same amount of ditallow alkyl dimethyl ammonium chloride. This detergent corresponds to an agent of the prior art.
- Another agent was prepared which had a composition similar to that of Example 2, except that the ditallow alkyl dimethyl ammonium chloride was replaced with the same amount of water.
- washing tests were carried out in a commercially available drum washing machine.
- Cotton bleaching nettle, white was washed at a liquor ratio of 1 20, without contamination, in the presence of a section of fabric weighing approx. 20 g, which was colored with 3.5% Sirius light red F 4 BL, 154%.
- 84 g of the detergents from Examples 1 to 3 were added to a drum filling and, after washing, the reflectance values were measured using the Zeiss Elrepho RFC3, filter R 560.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81105166T ATE12252T1 (de) | 1980-07-10 | 1981-07-03 | Fluessiges waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19803026090 DE3026090A1 (de) | 1980-07-10 | 1980-07-10 | Fluessiges waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen |
DE3026090 | 1980-07-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0044003A1 EP0044003A1 (fr) | 1982-01-20 |
EP0044003B1 true EP0044003B1 (fr) | 1985-03-20 |
Family
ID=6106835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81105166A Expired EP0044003B1 (fr) | 1980-07-10 | 1981-07-03 | Agent de lavage liquide avec une teneur en additifs inhibant le changement de couleur |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0044003B1 (fr) |
AT (1) | ATE12252T1 (fr) |
DE (2) | DE3026090A1 (fr) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3413292A1 (de) * | 1984-04-09 | 1985-10-17 | Henkel KGaA, 4000 Düsseldorf | Textil-waschmittel fuer farbige textilien |
US4840676A (en) * | 1985-06-24 | 1989-06-20 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
US4929381A (en) * | 1985-06-24 | 1990-05-29 | The Dow Chemical Company | Inorganic anion exchangers and preparation thereof |
US4769079A (en) * | 1985-06-24 | 1988-09-06 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
US4773936A (en) * | 1985-06-24 | 1988-09-27 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
US4769080A (en) * | 1985-06-24 | 1988-09-06 | The Dow Chemical Company | Insoluble pigments and preparation thereof |
DE3606729A1 (de) * | 1986-03-01 | 1987-09-03 | Henkel Kgaa | Wasch- und reinigungsmittel mit verringertem chemikalienbedarf |
NL9201939A (nl) * | 1992-11-05 | 1994-06-01 | Avebe Coop Verkoop Prod | Vloeibare wasverzachtersamenstellingen. |
DE4301459A1 (de) * | 1993-01-20 | 1994-07-21 | Huels Chemische Werke Ag | Wäßriges Weichspülmittel für die Behandlung von Textilien |
DE4334368C2 (de) * | 1993-10-08 | 1995-12-14 | Henkel Kgaa | Schwach schäumende polymerfreie Reinigungsmittel |
AU5977496A (en) * | 1996-06-03 | 1998-01-05 | Procter & Gamble Company, The | Fabric softening compositions |
CN102844422B (zh) * | 2010-04-22 | 2016-01-20 | 荷兰联合利华有限公司 | 涉及织物调理剂的改进 |
DE102010043066A1 (de) * | 2010-10-28 | 2012-05-03 | Henkel Ag & Co. Kgaa | Wasch- oder Reinigungsmittel mit antimikrobieller Wirkung |
EP4108748A1 (fr) * | 2021-06-24 | 2022-12-28 | The Procter & Gamble Company | Compositions de détergent pour le soin des couleurs |
WO2022271897A1 (fr) * | 2021-06-24 | 2022-12-29 | The Procter & Gamble Company | Composition de détergent pour le soin des couleurs |
EP4108749A1 (fr) | 2021-06-24 | 2022-12-28 | The Procter & Gamble Company | Compositions de détergent pour le soin des couleurs |
WO2022271898A1 (fr) | 2021-06-24 | 2022-12-29 | The Procter & Gamble Company | Compositions de détergents pour le soin des couleurs |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1136842A (en) * | 1965-03-24 | 1968-12-18 | Gen Mills Inc | Gum derivatives |
US3303184A (en) * | 1965-05-25 | 1967-02-07 | Gen Mills Inc | Aminoethyl gums and process for preparing same |
JPS5140884B2 (fr) * | 1972-12-12 | 1976-11-06 | ||
DE2529444C3 (de) * | 1975-07-02 | 1982-04-15 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Flüssiges Feinwaschmittel |
US4119487A (en) * | 1977-09-06 | 1978-10-10 | National Starch & Chemical Corporation | Starch ether derivatives, a method for the preparation thereof and their use in paper |
US4165290A (en) * | 1978-03-13 | 1979-08-21 | The Procter & Gamble Company | Fabric care composition containing starch and quaternary ammonium compound |
DE2824024C2 (de) * | 1978-06-01 | 1987-01-29 | Henkel KGaA, 4000 Düsseldorf | Flüssiges Waschmittel |
DE2918364A1 (de) * | 1979-05-07 | 1980-11-20 | Henkel Kgaa | Waschmittel fuer textilien |
DE2918363A1 (de) * | 1979-05-07 | 1980-11-27 | Henkel Kgaa | Waschmittel fuer textilien |
-
1980
- 1980-07-10 DE DE19803026090 patent/DE3026090A1/de not_active Withdrawn
-
1981
- 1981-07-03 EP EP81105166A patent/EP0044003B1/fr not_active Expired
- 1981-07-03 DE DE8181105166T patent/DE3169367D1/de not_active Expired
- 1981-07-03 AT AT81105166T patent/ATE12252T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE3169367D1 (en) | 1985-04-25 |
DE3026090A1 (de) | 1982-02-18 |
EP0044003A1 (fr) | 1982-01-20 |
ATE12252T1 (de) | 1985-04-15 |
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