EP0037026A1 - Procédé de préparation d'un granulé, stable à l'entrepôt, facilement soluble et contenant un activeur de blanchiment - Google Patents

Procédé de préparation d'un granulé, stable à l'entrepôt, facilement soluble et contenant un activeur de blanchiment Download PDF

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Publication number
EP0037026A1
EP0037026A1 EP81102083A EP81102083A EP0037026A1 EP 0037026 A1 EP0037026 A1 EP 0037026A1 EP 81102083 A EP81102083 A EP 81102083A EP 81102083 A EP81102083 A EP 81102083A EP 0037026 A1 EP0037026 A1 EP 0037026A1
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EP
European Patent Office
Prior art keywords
weight
percent
granulating
mixing
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP81102083A
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German (de)
English (en)
Other versions
EP0037026B1 (fr
Inventor
Herbert Dr. Saran
Martin Dr. Witthaus
Eduard Dr. Smulders
Karl Schwadtke
Günther Dr. Vogt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Publication date
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT81102083T priority Critical patent/ATE14594T1/de
Publication of EP0037026A1 publication Critical patent/EP0037026A1/fr
Application granted granted Critical
Publication of EP0037026B1 publication Critical patent/EP0037026B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules

Definitions

  • Bleach activators are taken to mean compounds which react in aqueous solutions containing hydrogen peroxide or perhydrates to form peracids which have a bleaching action.
  • the particularly effective bleach activators include N-acylated amines, amides and glycolurils, as are known, for example, from DE-AS 11 62 967, DE-AS 12 91 317, DE-OS 20 38 106 and DE-AS 15 94 865.
  • DE-AS 11 62 967 it is proposed to provide these bleach activators with a water-soluble coating agent before further use, in particular before use in detergents and bleaching agents, wherein the coating agent can consist, for example, of carboxymethyl cellulose.
  • This coating agent dissolved in water, can be sprayed onto the activator in finely divided form, after which the coated material is dried.
  • the recommendation is made to granulate the activator before coating, but there are no indications as to how and with which granulation aids this should be carried out. If one works according to the specifications of DE-AS 11 62 967 and sprays such a bleach activator, for example tetraacetylethylene diamine, with an aqueous carboxymethyl cellulose solution in a granulator, considerable problems arise. This is because aqueous solutions containing more than 5 percent by weight of carboxymethyl cellulose can no longer be handled in industrial granulation processes because of their high viscosity and gel-like nature.
  • a process for the production of coated, granulated bleach activators in which the activator is first mixed dry with a suitable coating or granulation agent and sprayed in a second step with water or water-soluble granulation aids or film formers and is granulated.
  • a suitable coating or granulation agent for the preparation of the dry premixes, either water-soluble framework salts customary in detergents, such as water of crystallization, are used phates, polyphosphates, carbonates and silicates of alkali metals or water-insoluble fillers such as silica, magnesium silicate or magnesium oxide are proposed.
  • the same water-soluble salts which bind water of crystallization can also be used as granulation aids or the dry premixes can be sprayed with an aqueous solution of film-forming substances such as cellulose derivatives or other water-soluble polymers of natural or synthetic origin and granulated at the same time.
  • this process is only useful for the production of granules with a comparatively low content of bleach activators, that is to say those with less than 50 percent by weight.
  • the granules can therefore only be used in areas where the high proportion of additives does not interfere.
  • the invention is based on the object of developing a process for the production of readily pourable, uniformly coated and thus very stable bleach activator granules which have a substantially higher content, for example one of 90 percent by weight and more, of active substance.
  • the invention with which this object is achieved is a process for producing a storage-stable, bleach activator-containing granules by dry mixing a powdered bleach activator from the class of N-acylated amines, amides, diketopiperazines and glycolurils with a powdered granulating aid, moistening the dry Premixed with an aqueous solution of the granulating aid and granulating the moist mixture in a niche and granulating device, characterized in that for the preparation of a granulate containing 90 to 98 percent by weight of bleach activator and 10 to 2 percent by weight of granulating aid, based on anhydrous constituents Bleach activator, which is a medium grain Size from 0.01 to 0.8 mm, in a first mixing stage with 50 to 100 percent of the total granulation aid to be used, which consists of a compound from the class of water-soluble cellulose ether, starch and starch ether and as a pourable powder with an average grain
  • Average grain size of 0.01 to 0.8 mm is to be understood as meaning that in which more than 50 percent by weight, preferably at least 80 percent by weight of the particles have a grain size of 0.01 to 0.8 mm and not more than 25 percent by weight , preferably not more than 10% by weight have a grain size of 0.8 to at most ii6 mm and not more than 25% by weight, preferably not more than 10% by weight have a grain size of less than 0.01 mm.
  • the grain size of the fine particles is not limited at the bottom, but dust-fine particles can also be present. The additional use of such dusty fractions, which are common in technical, unclassified powder products with a broad grain spectrum, represents an additional advantage of the process.
  • N-acylated amines, diamines, amides and glycolurils are suitable as bleach activators.
  • These are, for example, tetraacetylmethylene diamine, tetraacetylethylene diamine, diacetylaniline, diacetyl-p-toluidine, 1,3-diacetyl-5,5-dimethylhydantoin, tetraacetylglycoluril, tetrapropionylglycoluril, 1,4-diacetyl-2,5-diketo-piperazine -Diacetyl-3,6-dimethyl-2,5-diketopiperazine.
  • Tetraacetylethylenediamine is preferably used as the bleach activator.
  • the powdery bleach activator is mixed with a part of the granulation aid, which is also in powder form.
  • the proportion of the granulation aid used in this stage is 50 to 100, preferably 80 to 95. Weight percent of the total granulation aid used. Accordingly, the total amount or only part of the granulation auxiliary can be added in the 1st mixing stage.
  • the second variant, in which only part of the granulation aid is dry-mixed and the rest is introduced as a solution in the second stage, is the preferred method of operation.
  • the average grain size of the granulation aid is 0.01 to 0.8 mm according to the above definition.
  • the grain size of the powdered granulation aid is expediently as large or smaller than the grain size of the bleach activator.
  • the particle size of the granulating aid is advantageously 0.01 to 0.4 mm, the proportion of particles with a particle size of 0.4 to 1.6 mm 25 Weight percent and in particular 10 weight percent does not exceed.
  • the granulation aid consists of a water-soluble cellulose ether, water-soluble starch or a water-soluble starch ether.
  • cellulose ethers are celluose, methylcellulose, ethylcellulose, hydroxyethyl cellulose, methylhydroxyethylcellulose, methylhydroxypropyl *, carboxymethyl cellulose (as the sodium salt) and methyl carboxymethyl cellulose (Na salt).
  • depolymerized starch can be considered as starch.
  • the two powdery components can be mixed in conventional batch-wise or continuously operating mixing devices, which are generally equipped with rotating mixing elements. Depending on the effectiveness of the mixing device, the mixing times for a homogeneous mixture are generally between 30 seconds and 5 minutes.
  • powdery disintegrants which are common in the tablet industry can also be added, provided that the cellulose and starch ethers used do not automatically develop a certain explosive effect.
  • Usable disintegrants are, for example, partially degraded starch, starch ether, polyvinylpolypyrrolidone, formaldehyde casein and swellable magnesium aluminosilicates (Veegum). The proportion of such disintegrants can be 0 to 2 percent by weight of the anhydrous granules.
  • the dry powder mixture is then moistened with water or an aqueous solution of the remaining granulating aid and granulated.
  • the mixer of the first mixing stage is also suitable for a granulation process, the mix can remain therein during the granulation process.
  • a pelletizer for example a pelletizing drum or onto a rotating pelletizer, and to carry out the pelletizing process there or to complete it.
  • part of the granulating liquid is expediently introduced into the mixer towards the end of the first mixing stage in order to moisten the material to be mixed and to counteract the formation of dust. For example, 5 to 70 percent of the granulation liquid is added during the post-mixing and 95 to 30 percent of the liquid during the subsequent granulation.
  • the granulating aid used in the second mixing and granulation stage is preferably used in a 0.5 to 5 percent by weight solution. Solutions with a higher concentration and containing up to 10 percent by weight of granulation aids are only recommended if they are sufficiently low-viscosity. If sodium carboxymethyl cellulose is used in a provenance as is usually used in detergents, the concentration is advantageously not more than 4 percent by weight.
  • the amount of granulation liquid applied is to be measured in such a way that moist granules are formed which are not yet prone to caking. This is achieved when the water content of the moist granules is between 10 and 35, preferably 15 to 25, weight percent. Powder mixtures with a small grain spectrum and a higher proportion of powdered granulating aid can absorb larger amounts of granulating liquid than less fine-grained mixtures with a small proportion of granulating aid.
  • a dye or a white pigment can be added to the dry powder mixture or the granulating liquid for coloring or to cover the inherent color of the raw materials.
  • a dye or a white pigment can be added to the dry powder mixture or the granulating liquid for coloring or to cover the inherent color of the raw materials.
  • generally 0.01 to 0.1 percent by weight, based on the finished product, of dye or pigment is sufficient.
  • the water content of the mixture is then reduced to less than 2, preferably less than 1 percent by weight.
  • the excess water can be removed by drying with the addition of heat, the temperature of the granules expediently not exceeding 100 ° C. and below the melting temperature of the bleach activator. Dryers that do not adversely change the granular structure of the product are suitable, for example tray, vacuum or fluidized bed dryers.
  • the dried granules should contain less than 2, preferably less than 1 percent by weight of water.
  • the Extraction of the excess water also by mixing the moist granules with such dehydrating, essentially water-free or low-water salts.
  • Such salts are sodium tripolyphosphate, sodium sulfate, sodium carbonate, sodium silicate and low-water sodium aluminosilicates capable of ion exchange and their genes. The amount to be used depends on the water binding capacity of the salts concerned and the water content of the moist granules.
  • the mixing ratio of tripolyphosphate to moist granules is, for example, 1: 3 to 1: 1.5, in particular 1: 2 to 1: 1.
  • Mixing can be carried out in conventional mixers or granulating devices, with the addition of Production of the moist granules used, equipped with mixing devices mixing device can be used immediately. In this way, simplified, in particular energy-saving, processing is possible since the necessary drying stage can be saved.
  • Suitable foam inhibitors are customary known defoamers, preferably polysiloxanes, and mixtures thereof with microfine silica. Examples of these are polydimethylsiloxane with a content of approximately 1 to 10 percent by weight of microfine silica. The proportion of such polysiloxane foaming can be 1 to 5 percent by weight, preferably 2 to 4 percent by weight, based on the finished granulate.
  • the defoamer can be added in the first mixing stage; however, the defoamer can also be dispersed in the granulating liquid which, in order to avoid segregation processes, should contain part of the granulating aid in this case.
  • the granules produced in the manner indicated have a favorable grain spectrum. Any overlap and fine fractions can be screened off and returned to the process after grinding the coarse fractions.
  • the granules are easy to pour, non-sticky and very stable considering the complete coating of the activator particles. Its high proportion of active substance, 90 and more percent by weight, is particularly advantageous. They can be used with advantage in detergents, bleaches, oxidizers and disinfectants and retain their good properties even when mixed with the active ingredients contained in these agents.
  • Tetraacetylethylenediamine with an average grain size of 0.01 to 0.8 mm was used as the bleach activator.
  • the grain fraction between 0.8 and 1.6 mm was 5 weight percent, the fraction under 0.01 mm 10 weight percent.
  • Example 42.0 kg of the powdery tetraacetylethylenediamine used in Example 1 were in a drum mixer equipped with rotating mixing elements (LöDIGE mixer) with 2.24 kg Na carboxymethyl cellulose of the grain size given in Example 1 (88.2 percent of the total amount used) for 2 minutes mixed and then sprayed with continuous mixing with a solution of 170.4 g Na carboxymethyl cellulose in 5.51 kg water (3 percent by weight) for the purpose of binding dust-like components.
  • the mix was transferred to a continuously operating mixing granulator (capacity 800 kg / h).
  • the outlet of this mixer was connected to the inlet via conveyor belts so that the product could be circulated.
  • the majority of the granules were dried in a vacuum dryer at 50 torr over 24 hours to a water content of less than 1 percent by weight. 3 kg of the moist granules were dried in a fluidized bed dryer with air having an inlet temperature of 57 ° C. for 10 minutes to the same degree of drying. In both cases, the proportion of the granules with a grain size of 0.5 to 1.5 mm was 65 percent by weight. The rollover and fine fractions were sieved out and, after grinding the coarse fractions, entered into the subsequent granulation process.
  • 91.45 parts by weight of tetraacetylethylenediamine which had the following grain size (in percent by weight), were obtained in accordance with the preparation procedure given in Example 1: mixed with 3.048 parts by weight of a polysiloxane defoamer (consisting of 93 percent by weight of polydimethylsiloxane and 7 percent by weight of silanized microfine silica) and 4.8 parts by weight of Na carboxymethyl cellulose. Then, through the hollow drive shaft of the mixer, 0.629 parts by weight of sodium carboxymethyl cellulose in the form of a 3% strength aqueous solution were fed in over the course of 5 minutes, and the granulation process was then continued for a further 1 minute.
  • Example 4 was repeated, but the polysiloxane defoamer had been dispersed in the aqueous granulation liquid containing carboxymethyl cellulose. In terms of its properties, the product corresponded to that of Example 4.
  • Example 42.0 kg of the powdery tetraacetylethylenediamine used in Example 1 were in a drum mixer equipped with rotating mixing elements (L ⁇ DIGE mixer) with 2.24 kg Na carboxymethyl cellulose of the grain size given in Example 1 (88.2 percent of the total amount used) for 2 minutes mixed and then sprayed with continuous mixing with a solution of 170.4 g Na carboxymethyl cellulose in 5.51 kg water (3 percent by weight) for the purpose of binding dust-like components.
  • the mix was transferred to a continuously operating mixing granulator (capacity 800 kg / h).
  • the outlet of this mixer was connected to the inlet via conveyor belts so that the product could be circulated.
  • 4.3 kg of a 3% solution of Na-carboxymethyl cellulose (corresponding to 129 g) were fed in through the rotating shaft of the granulation mixer.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
EP81102083A 1980-03-28 1981-03-20 Procédé de préparation d'un granulé, stable à l'entrepôt, facilement soluble et contenant un activeur de blanchiment Expired EP0037026B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT81102083T ATE14594T1 (de) 1980-03-28 1981-03-20 Verfahren zur herstellung eines lagerstabilen, leichtloeslichen granulates mit einem gehalt an bleichaktivatoren.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3011998 1980-03-28
DE3011998A DE3011998C2 (de) 1980-03-28 1980-03-28 Verfahren zur Herstellung eines lagerstabilen, leichtlöslichen Granulates mit einem Gehalt an Bleichaktivatoren

Publications (2)

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EP0037026A1 true EP0037026A1 (fr) 1981-10-07
EP0037026B1 EP0037026B1 (fr) 1985-07-31

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EP81102083A Expired EP0037026B1 (fr) 1980-03-28 1981-03-20 Procédé de préparation d'un granulé, stable à l'entrepôt, facilement soluble et contenant un activeur de blanchiment

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US (1) US4372868A (fr)
EP (1) EP0037026B1 (fr)
JP (1) JPS56149500A (fr)
AT (1) ATE14594T1 (fr)
DE (2) DE3011998C2 (fr)

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0070474A1 (fr) * 1981-07-17 1983-01-26 Henkel Kommanditgesellschaft auf Aktien Procédé pour la fabrication d'activateurs de blanchiment enrobés granulaires
EP0075818A2 (fr) * 1981-09-28 1983-04-06 BASF Aktiengesellschaft Activateur de blanchiment granulaire
DE3208216A1 (de) * 1982-03-06 1983-09-08 Basf Ag, 6700 Ludwigshafen Koerniger bleichaktivator
EP0241962A2 (fr) * 1986-03-25 1987-10-21 Unilever N.V. Compositions granuleuses détergentes et de blanchiment ne contenant pas de phosphore
EP0374867A1 (fr) * 1988-12-22 1990-06-27 Hoechst Aktiengesellschaft Procédé de préparation de granulés d'activateur de blanchiment stables au stockage, facilement solubles
EP0468824A2 (fr) * 1990-07-27 1992-01-29 WARWICK INTERNATIONAL GROUP LIMITED (Co. n 2864019) Compositions granulaires
WO1992011349A1 (fr) * 1990-12-19 1992-07-09 Henkel Kommanditgesellschaft Auf Aktien Granule avec un activateur de blanchiment enrobe
US5334324A (en) * 1990-08-03 1994-08-02 Henkel Kommanditgesellschaft Auf Aktien Bleach activators in granular form
EP0710716A2 (fr) 1994-11-02 1996-05-08 Hoechst Aktiengesellschaft Activateurs de blanchiment sous forme granulaire et leur production
US5691295A (en) * 1995-01-17 1997-11-25 Cognis Gesellschaft Fuer Biotechnologie Mbh Detergent compositions
EP0835926A2 (fr) * 1996-10-10 1998-04-15 Clariant GmbH Procédé de production d'un activateur de blanchiment sous forme de granules enrobés
US5904736A (en) * 1995-04-28 1999-05-18 Henkel Kommanditgesellschaft Auf Aktien Cellulase-containing washing agents
US5972668A (en) * 1994-06-28 1999-10-26 Henkel Kommanditgesellschaft Auf Aktien Production of multi-enzyme granules
WO2000019006A1 (fr) * 1998-09-30 2000-04-06 Warwick International Group Limited Blanchiment a l'oxygene au moyen d'un activateur agglomere
US6063750A (en) * 1997-09-16 2000-05-16 Clariant Gmbh Bleach activator granules
GB2345701A (en) * 1999-01-12 2000-07-19 Procter & Gamble Particulate bleaching components
US6214785B1 (en) 1998-09-09 2001-04-10 Clariant Gmbh Bleach activator granules
US6254892B1 (en) 1999-03-05 2001-07-03 Rohm And Haas Company Pellet formulations
US6270690B1 (en) 1997-09-16 2001-08-07 Clariant Gmbh Storage stable bleach activator granules
US6313081B1 (en) 1995-04-28 2001-11-06 Henkel Kommanditgesellschaft Auf Aktien (Kgaa) Detergents comprising cellulases
US6340662B1 (en) 1998-12-11 2002-01-22 Henkel Kommanditgesellschaft Auf Aktien (Kgaa) Aqueous foam regulator emulsion
US7098179B2 (en) 2001-10-22 2006-08-29 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Cotton active, dirt removing urethane-based polymers
US7431739B2 (en) 2005-06-08 2008-10-07 Henkel Kommanditgesellschaft Auf Aktien Boosting the cleaning performance of laundry detergents by polymer of styrene/methyl methacrylate/methyl polyethylene glycol
WO2008149069A1 (fr) * 2007-06-02 2008-12-11 Reckitt Benckiser N.V. Composition
EP2021454A1 (fr) * 2006-04-27 2009-02-11 OCI Chemical Corporation Co-granulés de composés d'activateur de blanchiment au peroxyde
US7550156B2 (en) 2001-11-23 2009-06-23 Rohm And Haas Company Optimised pellet formulations
US8034123B2 (en) 2005-06-08 2011-10-11 Henkel Ag & Co., Kgaa Boosting cleaning power of detergents by means of a polymer
WO2019233789A1 (fr) * 2018-06-07 2019-12-12 Henkel Ag & Co. Kgaa Composition de détergents à limite d'écoulement

Families Citing this family (35)

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Publication number Priority date Publication date Assignee Title
EP0074730B1 (fr) * 1981-09-08 1985-09-25 Interox Chemicals Limited Granulation
GB8310080D0 (en) * 1983-04-14 1983-05-18 Interox Chemicals Ltd Bleach composition
IT1180458B (it) * 1984-03-22 1987-09-23 Mira Lanza Spa Attivatore di sbianca in forma granulare e suo procedimento di fabbricazione
US4964870A (en) * 1984-12-14 1990-10-23 The Clorox Company Bleaching with phenylene diester peracid precursors
DE3504628A1 (de) * 1985-02-11 1986-08-14 Henkel KGaA, 4000 Düsseldorf Verfahren zur herstellung eines rieselfaehigen granulats
DE3522359A1 (de) * 1985-06-22 1987-01-02 Basf Ag Verfahren zum konfektionieren von kristallinen, organischen materialien
US5433881A (en) * 1986-03-19 1995-07-18 Warwick International Group Limited Granulation process for making granular bleach activator compositions and resulting product
DE3609735A1 (de) 1986-03-22 1987-09-24 Henkel Kgaa Verfahren zur reinigung von tetraacetylethylendiamin
US5112514A (en) * 1986-11-06 1992-05-12 The Clorox Company Oxidant detergent containing stable bleach activator granules
US5002691A (en) * 1986-11-06 1991-03-26 The Clorox Company Oxidant detergent containing stable bleach activator granules
US5269962A (en) 1988-10-14 1993-12-14 The Clorox Company Oxidant composition containing stable bleach activator granules
CA2001535C (fr) * 1988-11-02 1995-01-31 Peter Willem Appel Methode d'elaboration d'un produit detersif granulaire a haute densite
GB8907187D0 (en) * 1989-03-30 1989-05-10 Unilever Plc Detergent compositions and process for preparing them
US4988451A (en) * 1989-06-14 1991-01-29 Lever Brothers Company, Division Of Conopco, Inc. Stabilization of particles containing quaternary ammonium bleach precursors
GB8922018D0 (en) * 1989-09-29 1989-11-15 Unilever Plc Detergent compositions and process for preparing them
US5055217A (en) * 1990-11-20 1991-10-08 Lever Brothers Company, Division Of Conopco, Inc. Polymer protected bleach precursors
USH1604H (en) * 1993-06-25 1996-11-05 Welch; Robert G. Process for continuous production of high density detergent agglomerates in a single mixer/densifier
CA2201932A1 (fr) * 1994-10-07 1996-04-18 Bio-Lab, Inc. Procede de stabilisation des biocides et appareil utilisant ces biocides stabilises pour desinfecter des systemes de traitement des eaux
GB9519094D0 (en) * 1995-09-19 1995-11-22 Warwick Int Group Granulated active with controlled release
DE19535082A1 (de) * 1995-09-21 1997-03-27 Henkel Ecolab Gmbh & Co Ohg Pastenförmiges Wasch- und Reinigungsmittel
DE19725508A1 (de) 1997-06-17 1998-12-24 Clariant Gmbh Wasch- und Reinigungsmittel
AU2002231137A1 (en) * 2000-12-19 2002-07-01 Fmc Corporation Disintegrant composition
DE10108459A1 (de) * 2001-02-22 2002-09-12 Henkel Kgaa Schaumregulatorgranulat
EP1560910A1 (fr) * 2002-11-14 2005-08-10 The Procter & Gamble Company Adjuvant de rin age contenant un sel actif d'entretien de verrerie encapsule
WO2004058931A1 (fr) 2002-12-20 2004-07-15 Henkel Kommanditgesellschaft Auf Aktien Produits de lavage et de nettoyage contenant un agent de blanchiment
DE10351325A1 (de) * 2003-02-10 2004-08-26 Henkel Kgaa Wasch- oder Reinigungsmittel mit wasserlöslichem Buildersystem und schmutzablösevermögendem Cellulosederivat
DE10351321A1 (de) * 2003-02-10 2004-08-26 Henkel Kgaa Verstärkung der Reinigungsleistung von Waschmitteln durch eine Kombination von Cellulosderivaten
ES2275207T5 (es) * 2003-02-10 2011-12-09 HENKEL AG & CO. KGAA Agente de lavado, que contiene agentes de blanqueo, con derivado de la celulosa con capacidad para el desprendimiento de la suciedad, con actividad sobre el algodón.
EP1592768A2 (fr) * 2003-02-10 2005-11-09 Henkel Kommanditgesellschaft auf Aktien Utilisation de derives cellulosiques en tant que regulateurs de moussage
DE502004003950D1 (de) * 2003-02-10 2007-07-12 Henkel Kgaa Verstärkung der reinigungsleistung von waschmitteln durch cellulosederivat und hygroskopisches polymer
EP1592764B1 (fr) * 2003-02-10 2007-01-03 Henkel Kommanditgesellschaft auf Aktien Augmentation de la capacite d'absorption d'eau de textiles
JP4519122B2 (ja) * 2003-02-10 2010-08-04 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン 水溶性ビルダー系および汚れ解離性セルロース誘導体を含んでなる漂白剤含有洗濯または洗浄剤
EP1747259A1 (fr) * 2004-05-17 2007-01-31 Henkel Kommanditgesellschaft auf Aktien Agent de lavage comprenant un complexe de metal de transition qui renforce le blanchiment et est produit eventuellement in situ
EP2103675A1 (fr) * 2008-03-18 2009-09-23 The Procter and Gamble Company Composition détergente comprenant un polymère cellulosique
EP2103678A1 (fr) * 2008-03-18 2009-09-23 The Procter and Gamble Company Composition détergente comprenant un co-polyester d'acides dicarboxyliques et de diols

Citations (2)

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DE1162967B (de) * 1959-06-19 1964-02-13 Konink Ind Mij Voorheen Noury Wasch- und/oder Bleichmittel
DE2048331A1 (de) * 1970-10-01 1972-04-06 Henkel & Cie GmbH, 4000 Dusseldorf Feste, pulverförmige bis kornige Mittel zur Herstellung von kaltwirksamen Bleich flotten, insbesondere von kaltwirksamen blei chenden Waschlaugen, und Verfahren zur Her stellung dieser Mittel

Cited By (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0070474A1 (fr) * 1981-07-17 1983-01-26 Henkel Kommanditgesellschaft auf Aktien Procédé pour la fabrication d'activateurs de blanchiment enrobés granulaires
EP0075818A2 (fr) * 1981-09-28 1983-04-06 BASF Aktiengesellschaft Activateur de blanchiment granulaire
EP0075818A3 (en) * 1981-09-28 1984-03-07 Basf Aktiengesellschaft Granular bleach activator
US4695397A (en) * 1981-09-28 1987-09-22 Basf Aktiengesellschaft Granular bleaching activator
DE3208216A1 (de) * 1982-03-06 1983-09-08 Basf Ag, 6700 Ludwigshafen Koerniger bleichaktivator
EP0241962A3 (en) * 1986-03-25 1988-06-22 Unilever Nv Granular non-phosphorus detergent bleach compositions
EP0241962A2 (fr) * 1986-03-25 1987-10-21 Unilever N.V. Compositions granuleuses détergentes et de blanchiment ne contenant pas de phosphore
EP0374867A1 (fr) * 1988-12-22 1990-06-27 Hoechst Aktiengesellschaft Procédé de préparation de granulés d'activateur de blanchiment stables au stockage, facilement solubles
US5100576A (en) * 1988-12-22 1992-03-31 Hoechst Aktiengesellschaft Process for the preparation of a readily soluble bleach activator granulate with a long shelf life
EP0468824A2 (fr) * 1990-07-27 1992-01-29 WARWICK INTERNATIONAL GROUP LIMITED (Co. n 2864019) Compositions granulaires
EP0468824A3 (en) * 1990-07-27 1992-07-01 Warwick International Group Plc Granular compositions
US5334324A (en) * 1990-08-03 1994-08-02 Henkel Kommanditgesellschaft Auf Aktien Bleach activators in granular form
WO1992011349A1 (fr) * 1990-12-19 1992-07-09 Henkel Kommanditgesellschaft Auf Aktien Granule avec un activateur de blanchiment enrobe
US5972668A (en) * 1994-06-28 1999-10-26 Henkel Kommanditgesellschaft Auf Aktien Production of multi-enzyme granules
EP0710716A2 (fr) 1994-11-02 1996-05-08 Hoechst Aktiengesellschaft Activateurs de blanchiment sous forme granulaire et leur production
US5716569A (en) * 1994-11-02 1998-02-10 Hoechst Aktiengesellschaft Granulated bleaching activators and their preparation
US5855625A (en) * 1995-01-17 1999-01-05 Henkel Kommanditgesellschaft Auf Aktien Detergent compositions
US5691295A (en) * 1995-01-17 1997-11-25 Cognis Gesellschaft Fuer Biotechnologie Mbh Detergent compositions
US5904736A (en) * 1995-04-28 1999-05-18 Henkel Kommanditgesellschaft Auf Aktien Cellulase-containing washing agents
US6313081B1 (en) 1995-04-28 2001-11-06 Henkel Kommanditgesellschaft Auf Aktien (Kgaa) Detergents comprising cellulases
EP0835926A3 (fr) * 1996-10-10 1999-01-07 Clariant GmbH Procédé de production d'un activateur de blanchiment sous forme de granules enrobés
EP0835926A2 (fr) * 1996-10-10 1998-04-15 Clariant GmbH Procédé de production d'un activateur de blanchiment sous forme de granules enrobés
US6645927B1 (en) 1996-10-10 2003-11-11 Clariant Gmbh Process for producing coated bleach activator granules
US6107266A (en) * 1996-10-10 2000-08-22 Clariant Gmbh Process for producing coated bleach activator granules
US6270690B1 (en) 1997-09-16 2001-08-07 Clariant Gmbh Storage stable bleach activator granules
US6063750A (en) * 1997-09-16 2000-05-16 Clariant Gmbh Bleach activator granules
US6133216A (en) * 1997-09-16 2000-10-17 Clariant Gmbh Coated ammonium nitrile bleach activator granules
US6214785B1 (en) 1998-09-09 2001-04-10 Clariant Gmbh Bleach activator granules
WO2000019006A1 (fr) * 1998-09-30 2000-04-06 Warwick International Group Limited Blanchiment a l'oxygene au moyen d'un activateur agglomere
US6340662B1 (en) 1998-12-11 2002-01-22 Henkel Kommanditgesellschaft Auf Aktien (Kgaa) Aqueous foam regulator emulsion
GB2345701A (en) * 1999-01-12 2000-07-19 Procter & Gamble Particulate bleaching components
US6254892B1 (en) 1999-03-05 2001-07-03 Rohm And Haas Company Pellet formulations
US7098179B2 (en) 2001-10-22 2006-08-29 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Cotton active, dirt removing urethane-based polymers
US7550156B2 (en) 2001-11-23 2009-06-23 Rohm And Haas Company Optimised pellet formulations
US7431739B2 (en) 2005-06-08 2008-10-07 Henkel Kommanditgesellschaft Auf Aktien Boosting the cleaning performance of laundry detergents by polymer of styrene/methyl methacrylate/methyl polyethylene glycol
US8034123B2 (en) 2005-06-08 2011-10-11 Henkel Ag & Co., Kgaa Boosting cleaning power of detergents by means of a polymer
US7709437B2 (en) 2006-04-27 2010-05-04 Oci Chemical Corp. Co-granulates of bleach activator-peroxide compounds
EP2021454A1 (fr) * 2006-04-27 2009-02-11 OCI Chemical Corporation Co-granulés de composés d'activateur de blanchiment au peroxyde
US8431519B2 (en) 2006-04-27 2013-04-30 Oci Chemical Corp. Co-granulates of bleach activator-peroxide compounds
WO2008149069A1 (fr) * 2007-06-02 2008-12-11 Reckitt Benckiser N.V. Composition
WO2019233789A1 (fr) * 2018-06-07 2019-12-12 Henkel Ag & Co. Kgaa Composition de détergents à limite d'écoulement

Also Published As

Publication number Publication date
DE3171538D1 (en) 1985-09-05
JPS56149500A (en) 1981-11-19
DE3011998C2 (de) 1982-06-16
JPH0340080B2 (fr) 1991-06-17
US4372868A (en) 1983-02-08
DE3011998A1 (de) 1981-10-08
ATE14594T1 (de) 1985-08-15
EP0037026B1 (fr) 1985-07-31

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