EP0008059A1 - Procédé de lavage à la machine de la vaisselle utilisant des alcools polyvalents, des acides carboxyliques et/ou de leurs esters comme agents mouillants pour le rinçage - Google Patents
Procédé de lavage à la machine de la vaisselle utilisant des alcools polyvalents, des acides carboxyliques et/ou de leurs esters comme agents mouillants pour le rinçage Download PDFInfo
- Publication number
- EP0008059A1 EP0008059A1 EP79102708A EP79102708A EP0008059A1 EP 0008059 A1 EP0008059 A1 EP 0008059A1 EP 79102708 A EP79102708 A EP 79102708A EP 79102708 A EP79102708 A EP 79102708A EP 0008059 A1 EP0008059 A1 EP 0008059A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alcohols
- carboxylic acids
- esters
- acid
- hydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000002148 esters Chemical class 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 11
- 150000001735 carboxylic acids Chemical class 0.000 title claims abstract description 7
- 238000004851 dishwashing Methods 0.000 title claims abstract description 5
- 150000005846 sugar alcohols Polymers 0.000 title claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 title description 10
- 150000001298 alcohols Chemical class 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 11
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- 230000001476 alcoholic effect Effects 0.000 claims abstract description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims description 9
- 150000007513 acids Chemical class 0.000 claims description 8
- -1 hydroxypivalic acid ester Chemical class 0.000 claims description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 150000007522 mineralic acids Chemical class 0.000 claims 1
- CZZVAVMGKRNEAT-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diol;3-hydroxy-2,2-dimethylpropanoic acid Chemical class OCC(C)(C)CO.OCC(C)(C)C(O)=O CZZVAVMGKRNEAT-UHFFFAOYSA-N 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 239000012141 concentrate Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 229940117969 neopentyl glycol Drugs 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- SIKZECKPFAWRLZ-UHFFFAOYSA-N OCC(CO)(CO)CO.OCC(C(=O)O)(C)C Chemical class OCC(CO)(CO)CO.OCC(C(=O)O)(C)C SIKZECKPFAWRLZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000005355 lead glass Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229940079842 sodium cumenesulfonate Drugs 0.000 description 1
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT79102708T ATE51T1 (de) | 1978-08-03 | 1979-07-30 | Verfahren zum maschinellen spuelen von geschirr unter einsatz mehrwertiger alkohole, carbonsaeuren und/oder estern daraus als klarspuelmittel. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782833991 DE2833991A1 (de) | 1978-08-03 | 1978-08-03 | Verfahren zum mechanischen spuelen von geschirr unter einsatz mehrwertiger alkohole, carbonsaeuren und/oder estern daraus als klarspuelmittel |
| DE2833991 | 1978-08-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0008059A1 true EP0008059A1 (fr) | 1980-02-20 |
| EP0008059B1 EP0008059B1 (fr) | 1981-04-29 |
Family
ID=6046080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP79102708A Expired EP0008059B1 (fr) | 1978-08-03 | 1979-07-30 | Procédé de lavage à la machine de la vaisselle utilisant des alcools polyvalents, des acides carboxyliques et/ou de leurs esters comme agents mouillants pour le rinçage |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4239552A (fr) |
| EP (1) | EP0008059B1 (fr) |
| AT (1) | ATE51T1 (fr) |
| DE (2) | DE2833991A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4980271A (en) * | 1985-08-05 | 1990-12-25 | Hoechst Celanese Corporation | Developer compositions for lithographic printing plates with benzyl alcohol, potassium toluene sulfonate and sodium (xylene or cumene) sulfonate |
| US5066568A (en) * | 1985-08-05 | 1991-11-19 | Hoehst Celanese Corporation | Method of developing negative working photographic elements |
| EP3842510A1 (fr) * | 2019-12-17 | 2021-06-30 | Henkel AG & Co. KGaA | Agent de rinçage pour lave-vaisselles automatiques |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3002789A1 (de) * | 1980-01-26 | 1981-07-30 | Henkel KGaA, 4000 Düsseldorf | Fluessiges reinigung- und pflegemittel |
| US4517025A (en) * | 1982-05-17 | 1985-05-14 | Amchem Products, Inc. | Method for removing sealant contamination |
| US4529525A (en) * | 1982-08-30 | 1985-07-16 | Colgate-Palmolive Co. | Stabilized enzyme-containing detergent compositions |
| DE3240688A1 (de) * | 1982-11-04 | 1984-05-30 | Henkel KGaA, 4000 Düsseldorf | Verwendung von alkylmonophosphonsaeuren als keimtoetende substanzen |
| US4501680A (en) * | 1983-11-09 | 1985-02-26 | Colgate-Palmolive Company | Acidic liquid detergent composition for cleaning ceramic tiles without eroding grout |
| US4624713A (en) * | 1984-11-15 | 1986-11-25 | Economics Laboratory, Inc. | Solid rinse aids and methods of warewashing utilizing solid rinse aids |
| US5427707A (en) * | 1985-06-14 | 1995-06-27 | Colgate Palmolive Co. | Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer |
| US4935158A (en) * | 1986-10-30 | 1990-06-19 | Aszman Harry W | Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture |
| DE3930028A1 (de) * | 1989-09-08 | 1991-03-21 | Kaw Kiehl Kg | Hydrophobierungsmittel fuer die waesche von nutzfahrzeugen |
| US5286300A (en) * | 1991-02-13 | 1994-02-15 | Man-Gill Chemical Company | Rinse aid and lubricant |
| US5221362A (en) * | 1991-08-23 | 1993-06-22 | E. I. Du Pont De Nemours And Company | Non-halogenated aqueous cleaning systems |
| US5925606A (en) * | 1996-11-01 | 1999-07-20 | Amway Corporation | Concentrated acidic liquid detergent composition |
| JP3693441B2 (ja) * | 1996-12-27 | 2005-09-07 | 富士通株式会社 | 記録媒体の製造方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2244378A1 (de) | 1972-09-09 | 1974-03-14 | Henkel & Cie Gmbh | Klarspuelmittel mit verbessertem ablaufeffekt |
| DE2259830A1 (de) | 1972-12-07 | 1974-06-12 | Knapsack Ag | Reinigungs- und klarspuelmittelkombination fuer das maschinelle spuelen von geschirr |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3211659A (en) * | 1961-10-02 | 1965-10-12 | Purex Corp Ltd | Process and compositions for cleaning shell eggs |
| DE1263962B (de) * | 1965-02-06 | 1968-03-21 | Boehme Chemie Ges Mit Beschrae | Verwendung von Zuckerestern als Klarspuelmittel fuer die maschinelle Geschirreinigung |
| US3463735A (en) * | 1967-10-18 | 1969-08-26 | Drackett Co | Glass cleaning composition |
| US3592774A (en) * | 1968-05-03 | 1971-07-13 | Henkel & Cie Gmbh | Novel rinsing agents |
| SE352652B (fr) * | 1969-10-01 | 1973-01-08 | Hentschel V | |
| DE2062464A1 (fr) * | 1970-12-18 | 1972-06-22 | ||
| DE2106819C3 (de) * | 1971-02-12 | 1978-11-16 | Henkel Kgaa, 4000 Duesseldorf | Klarspülmittel für die maschinelle Geschirreinigung |
| GB1441588A (en) * | 1972-10-04 | 1976-07-07 | Unilever Ltd | Rinse composition |
-
1978
- 1978-08-03 DE DE19782833991 patent/DE2833991A1/de active Pending
-
1979
- 1979-07-23 US US06/059,776 patent/US4239552A/en not_active Expired - Lifetime
- 1979-07-30 AT AT79102708T patent/ATE51T1/de not_active IP Right Cessation
- 1979-07-30 EP EP79102708A patent/EP0008059B1/fr not_active Expired
- 1979-07-30 DE DE7979102708T patent/DE2960312D1/de not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2244378A1 (de) | 1972-09-09 | 1974-03-14 | Henkel & Cie Gmbh | Klarspuelmittel mit verbessertem ablaufeffekt |
| DE2259830A1 (de) | 1972-12-07 | 1974-06-12 | Knapsack Ag | Reinigungs- und klarspuelmittelkombination fuer das maschinelle spuelen von geschirr |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4980271A (en) * | 1985-08-05 | 1990-12-25 | Hoechst Celanese Corporation | Developer compositions for lithographic printing plates with benzyl alcohol, potassium toluene sulfonate and sodium (xylene or cumene) sulfonate |
| US5066568A (en) * | 1985-08-05 | 1991-11-19 | Hoehst Celanese Corporation | Method of developing negative working photographic elements |
| EP3842510A1 (fr) * | 2019-12-17 | 2021-06-30 | Henkel AG & Co. KGaA | Agent de rinçage pour lave-vaisselles automatiques |
Also Published As
| Publication number | Publication date |
|---|---|
| US4239552A (en) | 1980-12-16 |
| DE2960312D1 (en) | 1981-08-06 |
| EP0008059B1 (fr) | 1981-04-29 |
| DE2833991A1 (de) | 1980-02-21 |
| ATE51T1 (de) | 1981-05-15 |
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