EA201592176A1 - Термоэластопласты, полученные посредством полимеризации триглицеридов с обратимой передачей цепи по механизму присоединения-фрагментации - Google Patents

Термоэластопласты, полученные посредством полимеризации триглицеридов с обратимой передачей цепи по механизму присоединения-фрагментации

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EA201592176A1
EA201592176A1 EA201592176A EA201592176A EA201592176A1 EA 201592176 A1 EA201592176 A1 EA 201592176A1 EA 201592176 A EA201592176 A EA 201592176A EA 201592176 A EA201592176 A EA 201592176A EA 201592176 A1 EA201592176 A1 EA 201592176A1
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Prior art keywords
monomer
block
triglycerides
polymerization
thermoelastoplastes
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EA201592176A
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English (en)
Inventor
Эрик В. Кокран
Рональд Кристофер Уилльямс
Наку Эрнандес
Эндрю Кашоне
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Айова Стейт Юниверсити Рисерч Фаундейшн, Инк.
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Publication of EA201592176A1 publication Critical patent/EA201592176A1/ru

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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F122/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F122/10—Esters
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    • C08F122/20—Esters containing oxygen in addition to the carboxy oxygen
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    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
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    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
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    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
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    • C09J135/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Adhesives based on derivatives of such polymers
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    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
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    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
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    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
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    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
    • C08L2555/80—Macromolecular constituents
    • C08L2555/82—Macromolecular constituents from natural renewable resources, e.g. starch, cellulose, saw dust, straw, hair or shells

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  • Chemical & Material Sciences (AREA)
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  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Данное изобретение относится к термопластичному блок-сополимеру, содержащему по меньшей мере один блок РА и по меньшей мере один блок РВ. Блок РА представляет собой полимерный блок, содержащий одну или более единиц мономера А, а РВ блок представляет собой полимерный блок содержащий одну или более единиц мономера В. Мономер А представляет собой виниловый, акриловый, диолефиновый, нитриловый, динитриловый, акрилонитриловый мономер, мономер с реакционноспособными функциональными группами или сшивающий мономер. Мономер В представляет собой радикально полимеризуемые триглицериды или их смеси, в основном в виде растительного масла или животного жира. Данное изобретение также относится к способу получения термопластичного блок-сополимера или новых термопластичных статистических сополимеров, полученным путем полимеризации способного к радикальной полимеризации мономера со способными к радикальной полимеризации триглицеридами или их смесью, посредством полимеризации с обратимой передачей цепи по механизму присоединения-фрагментации (RAFT) в присуствии инициатора свободных радикалов и агента передачи цепи.
EA201592176A 2013-05-20 2014-05-20 Термоэластопласты, полученные посредством полимеризации триглицеридов с обратимой передачей цепи по механизму присоединения-фрагментации EA201592176A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361825241P 2013-05-20 2013-05-20
PCT/US2014/038799 WO2014189939A2 (en) 2013-05-20 2014-05-20 Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides

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EA201592176A1 true EA201592176A1 (ru) 2016-04-29

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US (5) US9650463B2 (ru)
EP (3) EP3327047A1 (ru)
JP (1) JP2016528306A (ru)
KR (1) KR20160009583A (ru)
CN (3) CN108641054A (ru)
AU (1) AU2014268692B2 (ru)
BR (2) BR122017010545B1 (ru)
CA (1) CA2910680A1 (ru)
CL (1) CL2015003375A1 (ru)
EA (1) EA201592176A1 (ru)
HK (1) HK1220219A1 (ru)
PH (1) PH12015502467A1 (ru)
SG (3) SG10201606742UA (ru)
WO (1) WO2014189939A2 (ru)

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