EA199901032A2 - Композиция для активирования мелаллоценовых комплексных соединений при катализе процессов (со)полимеризации олефинов - Google Patents

Композиция для активирования мелаллоценовых комплексных соединений при катализе процессов (со)полимеризации олефинов

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Publication number
EA199901032A2
EA199901032A2 EA199901032A EA199901032A EA199901032A2 EA 199901032 A2 EA199901032 A2 EA 199901032A2 EA 199901032 A EA199901032 A EA 199901032A EA 199901032 A EA199901032 A EA 199901032A EA 199901032 A2 EA199901032 A2 EA 199901032A2
Authority
EA
Eurasian Patent Office
Prior art keywords
composition
olefins
polymerization
organic compound
fluorinated organic
Prior art date
Application number
EA199901032A
Other languages
English (en)
Other versions
EA199901032A3 (ru
EA003246B1 (ru
Inventor
Анна Соммадзи
Франческо Мази
Джампьетро Борсотти
Антонио Прото
Роберто Санти
Original Assignee
ЭНИКЕМ С.п.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ЭНИКЕМ С.п.А. filed Critical ЭНИКЕМ С.п.А.
Publication of EA199901032A2 publication Critical patent/EA199901032A2/ru
Publication of EA199901032A3 publication Critical patent/EA199901032A3/ru
Publication of EA003246B1 publication Critical patent/EA003246B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/16—Preparation of halogenated hydrocarbons by replacement by halogens of hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/266—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of hydrocarbons and halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/269—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of only halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C07C25/22—Polycyclic aromatic halogenated hydrocarbons with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Металлоорганическая композиция, не содержащая бора, включающая глубоко фторированное органическое соединение, устойчивое в воздушной среде и обладающее диненасыщенным кольцом с пятью или шестью атомами углерода, и алкилированное производное магния или, в предпочтительном варианте, алюминия. Данную композицию можно применять в качестве активатора металлоценового комплексного соединения элементов 4 группы Периодической таблицы элементов с целью образования высокоактивного катализатора с низким содержанием металла для полимеризации α-олефинов.
EA199901032A 1998-12-17 1999-06-14 Металлоорганическая композиция, каталитическая композиция для (со)полимеризации олефинов, способ ее получения и фторированное органическое соединение EA003246B1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1998MI002718A IT1304181B1 (it) 1998-12-17 1998-12-17 Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine.

Publications (3)

Publication Number Publication Date
EA199901032A2 true EA199901032A2 (ru) 2000-06-26
EA199901032A3 EA199901032A3 (ru) 2000-12-25
EA003246B1 EA003246B1 (ru) 2003-02-27

Family

ID=11381260

Family Applications (1)

Application Number Title Priority Date Filing Date
EA199901032A EA003246B1 (ru) 1998-12-17 1999-06-14 Металлоорганическая композиция, каталитическая композиция для (со)полимеризации олефинов, способ ее получения и фторированное органическое соединение

Country Status (31)

Country Link
US (1) US6596891B1 (ru)
EP (1) EP1013675B1 (ru)
JP (1) JP4808297B2 (ru)
KR (1) KR100388280B1 (ru)
CN (1) CN1137157C (ru)
AR (1) AR023354A1 (ru)
AT (1) ATE221545T1 (ru)
AU (1) AU770138B2 (ru)
BG (1) BG64129B1 (ru)
BR (1) BR9905894B1 (ru)
CA (1) CA2292243C (ru)
CZ (1) CZ300869B6 (ru)
DE (1) DE69902343T2 (ru)
DK (1) DK1013675T3 (ru)
EA (1) EA003246B1 (ru)
ES (1) ES2179594T3 (ru)
HK (1) HK1028900A1 (ru)
HR (1) HRP990391B1 (ru)
HU (1) HU228311B1 (ru)
ID (1) ID24013A (ru)
IT (1) IT1304181B1 (ru)
MY (1) MY118967A (ru)
NO (1) NO324453B1 (ru)
NZ (1) NZ501743A (ru)
PL (1) PL197085B1 (ru)
PT (1) PT1013675E (ru)
SI (1) SI1013675T1 (ru)
SK (1) SK285306B6 (ru)
TR (1) TR199903132A3 (ru)
TW (1) TW462971B (ru)
UA (1) UA70920C2 (ru)

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BG103994A (en) 2001-08-31
DE69902343T2 (de) 2003-03-27
EP1013675A3 (en) 2000-10-25
PL197085B1 (pl) 2008-02-29
CN1260351A (zh) 2000-07-19
AU770138B2 (en) 2004-02-12
PL337268A1 (en) 2000-06-19
ITMI982718A1 (it) 2000-06-17
JP4808297B2 (ja) 2011-11-02
EP1013675B1 (en) 2002-07-31
ID24013A (id) 2000-06-22
HK1028900A1 (en) 2001-03-09
MY118967A (en) 2005-02-28
ATE221545T1 (de) 2002-08-15
BG64129B1 (bg) 2004-01-30
JP2000186108A (ja) 2000-07-04
SK174599A3 (en) 2001-02-12
DK1013675T3 (da) 2002-11-04
PT1013675E (pt) 2002-12-31
HUP9904609A3 (en) 2001-01-29
DE69902343D1 (de) 2002-09-05
SK285306B6 (sk) 2006-10-05
CA2292243C (en) 2012-01-31
HRP990391A2 (en) 2000-10-31
TR199903132A2 (xx) 2000-07-21
NO996211L (no) 2000-06-19
TR199903132A3 (tr) 2000-07-21
HU228311B1 (en) 2013-03-28
TW462971B (en) 2001-11-11
UA70920C2 (ru) 2004-11-15
BR9905894A (pt) 2000-08-15
KR100388280B1 (ko) 2003-06-19
CA2292243A1 (en) 2000-06-17
ES2179594T3 (es) 2003-01-16
CZ9904446A3 (cs) 2000-10-11
EA199901032A3 (ru) 2000-12-25
HUP9904609A2 (hu) 2000-11-28
KR20000048162A (ko) 2000-07-25
CN1137157C (zh) 2004-02-04
CZ300869B6 (cs) 2009-09-02
EA003246B1 (ru) 2003-02-27
NO324453B1 (no) 2007-10-22
AR023354A1 (es) 2002-09-04
BR9905894B1 (pt) 2009-05-05
HU9904609D0 (en) 2000-02-28
EP1013675A2 (en) 2000-06-28
NZ501743A (en) 2001-03-30
IT1304181B1 (it) 2001-03-08
NO996211D0 (no) 1999-12-15
US6596891B1 (en) 2003-07-22
HRP990391B1 (en) 2006-11-30
SI1013675T1 (en) 2002-12-31
AU6449999A (en) 2000-06-22

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