HUP0004247A2 - Ikerionos katalizátoraktivátor - Google Patents

Ikerionos katalizátoraktivátor

Info

Publication number
HUP0004247A2
HUP0004247A2 HU0004247A HUP0004247A HUP0004247A2 HU P0004247 A2 HUP0004247 A2 HU P0004247A2 HU 0004247 A HU0004247 A HU 0004247A HU P0004247 A HUP0004247 A HU P0004247A HU P0004247 A2 HUP0004247 A2 HU P0004247A2
Authority
HU
Hungary
Prior art keywords
group
atoms
hydrogen
activator
regardless
Prior art date
Application number
HU0004247A
Other languages
English (en)
Inventor
Edmund M. Carnahan
Grant B. Jacobsen
Jerzy Klosin
David R. Neithamer
Peter N. Nickias
David J. Schwartz
Original Assignee
The Dow Chemical Co.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Co. filed Critical The Dow Chemical Co.
Publication of HUP0004247A2 publication Critical patent/HUP0004247A2/hu
Publication of HUP0004247A3 publication Critical patent/HUP0004247A3/hu

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06Aluminium compounds
    • C07F5/061Aluminium compounds with C-aluminium linkage
    • C07F5/066Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02Boron compounds
    • C07F5/027Organoboranes and organoborohydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A találmány katalizátor aktivátor vegyületekre vonatkozik, amelyektelítetlen vegyületek addíciós polimerizációjában alkalmazhatók egy 3-10 csoportbeli fém komplexével együtt. Az aktivátor egy (I) vagy (II)általános képletű ikerionos vegyületet tartalmaz, ahol a képletben L+jelentése az Elemek Periódusos Rendszerének 15. csoportjába tartozóelem protonált származéka, amely további két hidrokarbil-szubsztituenst hordoz, amelyek egyenként 1-50 szénatomot tartalmaznak,vagy egy, az Elemek Periódusos Rendszerének 14. csoportjába tartozóelem pozitívan töltött származéka, amely 14. csoportbeli elem háromhidrokarbil-szubsztituenssel szubsztituált, amelyek egyenként 1-50szénatomot tartalmaznak; Rl jelentése kétértékű, 1-40 hidrogénatomtóleltérő atomot tartalmazó kapcsolódó csoport; R2 jelentése -függetlenül az egyes előfordulásainál - 1-50 hidrogénatomtól eltérőatomot tartalmazó ligandumcsoport, azzal a megkötéssel, hogy atöltésegyensúlyhoz megfelelő számban fordul elő, R2 jelentése L+-R1-;R4 jelentése áthidaló hidrid- vagy halogenidcsoport, vagy egykétértékű kapcsolódó csoport, amely 1-40 hidrogénatomtól eltérő atomottartalmaz; M1 jelentése bór-, alumínium- vagy galliumatom; Arfjelentése - függetlenül az egyes előfordulásainál - egyvegyértékű,fluorozott szerves csoport, amely 6-100 hidrogénatomtól eltérő atomottartalmaz; Y jelentése 15. csoportba tartozó elem; és Z jelentése 14. csoportba tartozó elem. A találmány vonatkoziktovábbá az aktivátor vegyületeket tartalmazó katalizátorrendszerekreés az ezek jelenlétében kivitelezett a-olefin polimerizációs eljárásrais. Ó
HU0004247A 1997-08-01 1998-06-29 Zwitterionic catalyst activator HUP0004247A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5458897P 1997-08-01 1997-08-01
PCT/US1998/013504 WO1999006449A1 (en) 1997-08-01 1998-06-29 Zwitterionic catalyst activator

Publications (2)

Publication Number Publication Date
HUP0004247A2 true HUP0004247A2 (hu) 2001-05-28
HUP0004247A3 HUP0004247A3 (en) 2001-06-28

Family

ID=21992140

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0004247A HUP0004247A3 (en) 1997-08-01 1998-06-29 Zwitterionic catalyst activator

Country Status (19)

Country Link
US (1) US6344529B1 (hu)
EP (1) EP1000093B1 (hu)
JP (1) JP2001512141A (hu)
KR (1) KR20010014290A (hu)
CN (1) CN1261898A (hu)
AR (1) AR016576A1 (hu)
AT (1) ATE210685T1 (hu)
AU (1) AU733487B2 (hu)
BR (1) BR9815185A (hu)
CA (1) CA2291616A1 (hu)
DE (1) DE69802939T2 (hu)
HU (1) HUP0004247A3 (hu)
ID (1) ID23037A (hu)
NO (1) NO996322D0 (hu)
PL (1) PL337711A1 (hu)
TR (1) TR199903150T2 (hu)
TW (1) TW482777B (hu)
WO (1) WO1999006449A1 (hu)
ZA (1) ZA986886B (hu)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6838224B2 (en) * 2000-03-07 2005-01-04 Shi-Etsu Chemical Co., Ltd. Chemical amplification, positive resist compositions
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6919291B2 (en) 2000-11-06 2005-07-19 Exxonmobil Chemical Patents Inc. Fluorinated zwitterionic cocatalyst activators for olefin polymerization
US6660679B2 (en) * 2001-06-18 2003-12-09 Univation Technologies, Llc Catalyst system and its use in a polymerization process
EP1599514A2 (en) * 2003-03-06 2005-11-30 Basell Polyolefine GmbH Catalyst system for the polymerization of olefins
CN103102442B (zh) 2004-06-16 2016-01-20 陶氏环球技术有限责任公司 选择聚合改性剂的方法
EP1966229B1 (en) * 2005-09-12 2015-10-21 Abela Pharmaceuticals, Inc. Systems for removing dimethyl sulfoxide (dmso) or related compounds, or odors associated with same
SG176482A1 (en) * 2006-11-14 2011-12-29 Stephan Consulting Corp Hydrogen splitting composition
ES2944469T3 (es) * 2019-03-28 2023-06-21 Dow Global Technologies Llc Complejos aniónicos del grupo iii como aniones de coordinación débil para activadores de catalizadores de polimerización de olefinas
WO2021040384A1 (ko) 2019-08-26 2021-03-04 주식회사 엘지화학 촉매 조성물 및 이를 이용한 탄화수소 수지의 제조방법

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5447895A (en) * 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts

Also Published As

Publication number Publication date
AU733487B2 (en) 2001-05-17
EP1000093A1 (en) 2000-05-17
EP1000093B1 (en) 2001-12-12
CN1261898A (zh) 2000-08-02
DE69802939T2 (de) 2002-11-21
US6344529B1 (en) 2002-02-05
ZA986886B (en) 2000-01-31
ID23037A (id) 2000-01-06
KR20010014290A (ko) 2001-02-26
BR9815185A (pt) 2000-10-10
ATE210685T1 (de) 2001-12-15
WO1999006449A1 (en) 1999-02-11
HUP0004247A3 (en) 2001-06-28
DE69802939D1 (de) 2002-01-24
JP2001512141A (ja) 2001-08-21
NO996322L (no) 1999-12-20
CA2291616A1 (en) 1999-02-11
NO996322D0 (no) 1999-12-20
TR199903150T2 (en) 2000-07-21
PL337711A1 (en) 2000-08-28
TW482777B (en) 2002-04-11
AU8473698A (en) 1999-02-22
AR016576A1 (es) 2001-07-25

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