BR9815185A - Ativador de catalisador zwiteriÈnico, sistema catalisador para polimerização de &-oleofinas e processo de polimerização - Google Patents

Ativador de catalisador zwiteriÈnico, sistema catalisador para polimerização de &-oleofinas e processo de polimerização

Info

Publication number
BR9815185A
BR9815185A BR9815185-1A BR9815185A BR9815185A BR 9815185 A BR9815185 A BR 9815185A BR 9815185 A BR9815185 A BR 9815185A BR 9815185 A BR9815185 A BR 9815185A
Authority
BR
Brazil
Prior art keywords
group
polymerization
hydrogen atoms
catalyst
zwiteriènico
Prior art date
Application number
BR9815185-1A
Other languages
English (en)
Inventor
Edmund M Carnahan
Grant B Jacobsen
Jerzy Klosin
Peter N Nickias
David J Schwartz
David R Neithamer
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of BR9815185A publication Critical patent/BR9815185A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"ATIVADOR DE CATALISADOR ZWITERIÈNICO, SISTEMA CATALISADOR PARA POLIMERIZAçãO DE <244>-OLEFINAS E PROCESSO DE POLIMERIZAçãO". Um ativador de catalisador particularmente adaptado para uso na ativação de complexos metálicos de metais do Grupo 3-10 para polimerização de monómeros polimerizáveis etilenicamente insaturados, especialmente olefinas, compreendendo um composto zwiteriónico correspondendo à fórmula (I) ou (II), onde: L+ é um derivado protonado de um elemento do Grupo 15 da Tabela Periódica dos Elementos, adicionalmente suportando dois substituintes hidrocarbonila de 1 a 50 carbonos cada, ou um derivado positivamente carregado de um elemento do Grupo 14 da Tabela Periódica dos Elementos, o citado elemento do Grupo 14 sendo substituído com três substituintes hidrocarbila de 1 a 50 carbonos cada; R1 é um grupo ligante divalente de 1 a 40 átomos não de hidrogênio; R2 independentemente em cada ocorrência é um grupo ligante de 1 a 50 átomos não de hidrogênio com a provisão que em um número suficiente de ocorrências para equilibrar a carga no composto. R2 é L+-R1-; R4 é um grupo hidreto ou haleto formador de ponte ou um grupo ligante divalente de 1 a 40 átomos não de hidrogênio; M1 é boro, alumínio ou gálio; Arf independentemente em cada ocorrência é um grupo orgânico fluorado, monovalente, contendo de 6 a 100 átomos não de hidrogênio; Y é um elemento do Grupo 15; e Z é um elemento do Grupo 14.
BR9815185-1A 1997-08-01 1998-06-29 Ativador de catalisador zwiteriÈnico, sistema catalisador para polimerização de &-oleofinas e processo de polimerização BR9815185A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5458897P 1997-08-01 1997-08-01
PCT/US1998/013504 WO1999006449A1 (en) 1997-08-01 1998-06-29 Zwitterionic catalyst activator

Publications (1)

Publication Number Publication Date
BR9815185A true BR9815185A (pt) 2000-10-10

Family

ID=21992140

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9815185-1A BR9815185A (pt) 1997-08-01 1998-06-29 Ativador de catalisador zwiteriÈnico, sistema catalisador para polimerização de &-oleofinas e processo de polimerização

Country Status (19)

Country Link
US (1) US6344529B1 (pt)
EP (1) EP1000093B1 (pt)
JP (1) JP2001512141A (pt)
KR (1) KR20010014290A (pt)
CN (1) CN1261898A (pt)
AR (1) AR016576A1 (pt)
AT (1) ATE210685T1 (pt)
AU (1) AU733487B2 (pt)
BR (1) BR9815185A (pt)
CA (1) CA2291616A1 (pt)
DE (1) DE69802939T2 (pt)
HU (1) HUP0004247A3 (pt)
ID (1) ID23037A (pt)
NO (1) NO996322L (pt)
PL (1) PL337711A1 (pt)
TR (1) TR199903150T2 (pt)
TW (1) TW482777B (pt)
WO (1) WO1999006449A1 (pt)
ZA (1) ZA986886B (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100674073B1 (ko) * 2000-03-07 2007-01-26 신에쓰 가가꾸 고교 가부시끼가이샤 화학 증폭 포지티브형 레지스트 재료
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
BR0115159A (pt) 2000-11-06 2003-08-19 Exxonmobil Chem Patents Inc Ativadores de co-catalisadores zwitteriÈnicos fluorados para polimerização de olefinas
US6660679B2 (en) * 2001-06-18 2003-12-09 Univation Technologies, Llc Catalyst system and its use in a polymerization process
JP2006519899A (ja) * 2003-03-06 2006-08-31 バセル ポリオレフィン ジーエムビーエイチ オレフィンの重合のための触媒系
ATE504349T1 (de) 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
EP1966229B1 (en) * 2005-09-12 2015-10-21 Abela Pharmaceuticals, Inc. Systems for removing dimethyl sulfoxide (dmso) or related compounds, or odors associated with same
US8299284B2 (en) 2006-11-14 2012-10-30 Stephan Consulting Corporation Frustrated lewis pair compositions
SG11202110448UA (en) * 2019-03-28 2021-10-28 Dow Global Technologies Llc Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators
JP7261890B2 (ja) 2019-08-26 2023-04-20 エルジー・ケム・リミテッド 触媒組成物およびこれを用いた炭化水素樹脂の製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5447895A (en) * 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts

Also Published As

Publication number Publication date
NO996322D0 (no) 1999-12-20
AU8473698A (en) 1999-02-22
CA2291616A1 (en) 1999-02-11
HUP0004247A3 (en) 2001-06-28
DE69802939D1 (de) 2002-01-24
AR016576A1 (es) 2001-07-25
WO1999006449A1 (en) 1999-02-11
TW482777B (en) 2002-04-11
ID23037A (id) 2000-01-06
JP2001512141A (ja) 2001-08-21
PL337711A1 (en) 2000-08-28
EP1000093A1 (en) 2000-05-17
HUP0004247A2 (hu) 2001-05-28
ATE210685T1 (de) 2001-12-15
TR199903150T2 (en) 2000-07-21
KR20010014290A (ko) 2001-02-26
US6344529B1 (en) 2002-02-05
ZA986886B (en) 2000-01-31
DE69802939T2 (de) 2002-11-21
AU733487B2 (en) 2001-05-17
NO996322L (no) 1999-12-20
CN1261898A (zh) 2000-08-02
EP1000093B1 (en) 2001-12-12

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENETE 5A,6A,7A E 8A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1855 DE 25/07/2006.