ES2188000T3 - Catalizador que tiene un ligando de cetimida. - Google Patents

Catalizador que tiene un ligando de cetimida.

Info

Publication number
ES2188000T3
ES2188000T3 ES98941200T ES98941200T ES2188000T3 ES 2188000 T3 ES2188000 T3 ES 2188000T3 ES 98941200 T ES98941200 T ES 98941200T ES 98941200 T ES98941200 T ES 98941200T ES 2188000 T3 ES2188000 T3 ES 2188000T3
Authority
ES
Spain
Prior art keywords
ligand
catalyst
cetimide
link
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98941200T
Other languages
English (en)
Inventor
John Mcmeeking
Xiaoliang Gao
Rupert Edward Von Haken Spence
Stephen John Brown
Dusan Jeremic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals International SA
Original Assignee
Nova Chemicals International SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals International SA filed Critical Nova Chemicals International SA
Application granted granted Critical
Publication of ES2188000T3 publication Critical patent/ES2188000T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

Sistema catalizador para la polimerización de olefinas, que comprende: a) un catalizador, el cual es un complejo organometálico de un metal del grupo 4; y b) un activador, caracterizado por el hecho de que dicho complejo organometálico contiene un ligando cetimida.
ES98941200T 1997-09-15 1998-09-03 Catalizador que tiene un ligando de cetimida. Expired - Lifetime ES2188000T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA002215444A CA2215444C (en) 1997-09-15 1997-09-15 Catalyst having a ketimide ligand

Publications (1)

Publication Number Publication Date
ES2188000T3 true ES2188000T3 (es) 2003-06-16

Family

ID=4161469

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98941200T Expired - Lifetime ES2188000T3 (es) 1997-09-15 1998-09-03 Catalizador que tiene un ligando de cetimida.

Country Status (11)

Country Link
US (2) US6114481A (es)
EP (1) EP1021470B1 (es)
JP (1) JP4245801B2 (es)
CN (1) CN1210312C (es)
AT (1) ATE229042T1 (es)
AU (1) AU8970098A (es)
CA (1) CA2215444C (es)
DE (1) DE69809957T2 (es)
DK (1) DK1021470T3 (es)
ES (1) ES2188000T3 (es)
WO (1) WO1999014250A1 (es)

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DE60201340T2 (de) 2001-03-05 2005-02-17 Stichting Dutch Polymer Institute Katalysatorbestandteil für olefinpolymerisation und katalysatorsystem und polymerisationsverfahren unter verwendung eines solchen katalysatorsystems
JP5156167B2 (ja) 2001-04-12 2013-03-06 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンポリマー及び製造法
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EP1403293A1 (en) * 2002-09-27 2004-03-31 ATOFINA Research Société Anonyme Silicon containing cyclopentadienyl ring for metallocene catalyst component
DE60304595T3 (de) 2002-10-02 2012-01-12 Dow Global Technologies Inc. Flüssige und gelartige niedermolekulare ethylenpolymere
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CA2557796C (en) * 2004-03-17 2012-10-23 Dsm Ip Assets B.V. Polymerization catalyst comprising an amidine ligand
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EP1764376A1 (en) * 2005-09-16 2007-03-21 DSM IP Assets B.V. Process for the preparation of a metal-organic compound comprising a spectator ligand
EP1764379A1 (en) * 2005-09-19 2007-03-21 DSM IP Assets B.V. Polymerization catalyst comprising an amidine ligand
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WO2010151433A1 (en) 2009-06-26 2010-12-29 Dow Global Technologies Inc. Process selectively polymerizing ethylene and catalyst therefor
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EP2336204A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. Borane activated ti catalyst system comprising amidine and diene ligand
BR112012020718A2 (pt) * 2010-02-19 2016-04-26 Dow Global Technologies Inc complexo de metal-ligante e catalisador
EP3549960B1 (en) * 2010-02-19 2021-03-24 Dow Global Technologies LLC Process for polymerizing an olefin monomer and catalyst therefor
EP2508540A1 (en) * 2011-04-01 2012-10-10 Lanxess Elastomers B.V. Borane activated titanium catalyst system comprising guanidine and diene ligands
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US9783663B2 (en) 2012-12-14 2017-10-10 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
CA2798854C (en) 2012-12-14 2020-02-18 Nova Chemicals Corporation Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
EP2837634A1 (en) 2013-08-12 2015-02-18 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
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US9873753B2 (en) 2013-12-20 2018-01-23 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
JP6358852B2 (ja) * 2014-05-23 2018-07-18 ポリプラスチックス株式会社 環状オレフィン共重合体の製造方法
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JP7423332B2 (ja) * 2019-03-29 2024-01-29 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法
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Also Published As

Publication number Publication date
CN1210312C (zh) 2005-07-13
CA2215444A1 (en) 1999-03-15
DE69809957D1 (de) 2003-01-16
EP1021470A1 (en) 2000-07-26
AU8970098A (en) 1999-04-05
CA2215444C (en) 2005-08-02
WO1999014250A1 (en) 1999-03-25
ATE229042T1 (de) 2002-12-15
CN1270601A (zh) 2000-10-18
US6114481A (en) 2000-09-05
JP2001516776A (ja) 2001-10-02
DK1021470T3 (da) 2003-03-17
US6420300B1 (en) 2002-07-16
DE69809957T2 (de) 2003-09-04
JP4245801B2 (ja) 2009-04-02
EP1021470B1 (en) 2002-12-04

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