DK1021470T3 - Katalysator med en ketimidligand - Google Patents

Katalysator med en ketimidligand

Info

Publication number
DK1021470T3
DK1021470T3 DK98941200T DK98941200T DK1021470T3 DK 1021470 T3 DK1021470 T3 DK 1021470T3 DK 98941200 T DK98941200 T DK 98941200T DK 98941200 T DK98941200 T DK 98941200T DK 1021470 T3 DK1021470 T3 DK 1021470T3
Authority
DK
Denmark
Prior art keywords
ligand
catalyst
metal
organometallic complex
ketimide
Prior art date
Application number
DK98941200T
Other languages
English (en)
Inventor
John Mcmeeking
Xiaoliang Gao
Rupert Edward Von Haken Spence
Stephen John Brown
Dusan Jeremic
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Application granted granted Critical
Publication of DK1021470T3 publication Critical patent/DK1021470T3/da

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/05Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
DK98941200T 1997-09-15 1998-09-03 Katalysator med en ketimidligand DK1021470T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002215444A CA2215444C (en) 1997-09-15 1997-09-15 Catalyst having a ketimide ligand
PCT/CA1998/000839 WO1999014250A1 (en) 1997-09-15 1998-09-03 Catalyst having a ketimide ligand

Publications (1)

Publication Number Publication Date
DK1021470T3 true DK1021470T3 (da) 2003-03-17

Family

ID=4161469

Family Applications (1)

Application Number Title Priority Date Filing Date
DK98941200T DK1021470T3 (da) 1997-09-15 1998-09-03 Katalysator med en ketimidligand

Country Status (11)

Country Link
US (2) US6114481A (da)
EP (1) EP1021470B1 (da)
JP (1) JP4245801B2 (da)
CN (1) CN1210312C (da)
AT (1) ATE229042T1 (da)
AU (1) AU8970098A (da)
CA (1) CA2215444C (da)
DE (1) DE69809957T2 (da)
DK (1) DK1021470T3 (da)
ES (1) ES2188000T3 (da)
WO (1) WO1999014250A1 (da)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100581789B1 (ko) 1998-07-01 2006-05-23 엑손모빌 케미칼 패턴츠 인코포레이티드 프로필렌의 결정성 중합체 및 결정화가능한 중합체를포함하는 탄성 블렌드 조성물
US6239242B1 (en) * 1999-08-21 2001-05-29 Nova Chemicals Corporation Vinylaromatic and olefin pseudoblock polymers
CA2311068C (en) * 2000-06-08 2010-03-09 Nova Chemicals Corporation Process to prepare ethylene propylene elastomer
KR100421552B1 (ko) * 2000-12-18 2004-03-09 삼성아토피나주식회사 올레핀 중합용 촉매 및 이를 이용한 중합 방법
JP4197949B2 (ja) 2001-03-05 2008-12-17 スティヒティング ダッチ ポリマー インスティテュート オレフィン重合触媒成分及び触媒システム、並びにそのような触媒システムを用いた重合プロセス
DE60238049D1 (de) 2001-04-12 2010-12-02 Exxonmobil Chem Patents Inc Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
CN1276018C (zh) 2001-06-22 2006-09-20 埃克森美孚化学专利公司 作为抗冲改性剂的茂金属生产的极低密聚乙烯或线型低密度聚乙烯
EP1403293A1 (en) * 2002-09-27 2004-03-31 ATOFINA Research Société Anonyme Silicon containing cyclopentadienyl ring for metallocene catalyst component
US7795365B2 (en) 2002-10-02 2010-09-14 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers
ATE402222T1 (de) 2002-10-17 2008-08-15 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
CA2411183C (en) * 2002-11-05 2011-06-14 Nova Chemicals Corporation Heterogeneous/homogeneous copolymer
EP1422249A1 (en) * 2002-11-20 2004-05-26 ATOFINA Research New metallocene catalyst system
EP1506974A1 (en) * 2003-08-04 2005-02-16 DSM IP Assets B.V. Process for the preparation of a metalloorganic compound comprising at least one imine ligand
CN101831022B (zh) 2003-08-19 2012-07-04 陶氏环球技术有限责任公司 适用于热熔粘合剂的共聚体及其制备方法
KR101289564B1 (ko) * 2004-03-17 2013-07-24 란세스 엘라스토머즈 비.브이. 아미딘 리간드를 포함하는 중합촉매
US20060189769A1 (en) * 2005-02-22 2006-08-24 Nova Chemicals (International) S.A. Broad/bimodal resins with controlled comonomer distribution
JP2007063409A (ja) * 2005-08-31 2007-03-15 Asahi Kasei Chemicals Corp 環状オレフィン系共重合体の製造方法
EP1764376A1 (en) * 2005-09-16 2007-03-21 DSM IP Assets B.V. Process for the preparation of a metal-organic compound comprising a spectator ligand
EP1764379A1 (en) * 2005-09-19 2007-03-21 DSM IP Assets B.V. Polymerization catalyst comprising an amidine ligand
CA2625385A1 (en) * 2007-04-04 2008-10-04 Nova Chemicals Corporation Produce packaging
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
CA2605077C (en) * 2007-10-01 2014-07-08 Nova Chemicals Corporation A co-supported catalyst system
WO2009063084A2 (en) * 2007-11-15 2009-05-22 Dsm Ip Assets Bv Process for the preparation of ultra high molecular weight polyethylene
CA2629576C (en) * 2008-04-21 2016-01-05 Nova Chemicals Corporation Closures for bottles
EP2315788B1 (en) * 2008-08-21 2019-11-13 Dow Global Technologies LLC Metal-ligand complexes and catalysts
WO2010151433A1 (en) 2009-06-26 2010-12-29 Dow Global Technologies Inc. Process selectively polymerizing ethylene and catalyst therefor
EP2319874A1 (en) 2009-11-06 2011-05-11 DSM IP Assets B.V. Catalyst component for the polymerization of olefins having a guanidinate ligand
EP2336204A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. Borane activated ti catalyst system comprising amidine and diene ligand
EP2536735B1 (en) * 2010-02-19 2018-08-01 Dow Global Technologies LLC Metal-ligand complexes and catalysts
KR101854480B1 (ko) * 2010-02-19 2018-05-03 다우 글로벌 테크놀로지스 엘엘씨 올레핀 단량체의 중합 방법 및 이를 위한 촉매
EP2508540A1 (en) * 2011-04-01 2012-10-10 Lanxess Elastomers B.V. Borane activated titanium catalyst system comprising guanidine and diene ligands
EP2508539A1 (en) * 2011-04-01 2012-10-10 Lanxess Elastomers B.V. Titanium-catalyst system comprising substituted cyclopentadienyl, guanidine and diene ligands
US9371442B2 (en) 2011-09-19 2016-06-21 Nova Chemicals (International) S.A. Polyethylene compositions and closures made from them
CA2752407C (en) 2011-09-19 2018-12-04 Nova Chemicals Corporation Polyethylene compositions and closures for bottles
CA2783494C (en) * 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
US9475927B2 (en) 2012-12-14 2016-10-25 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
US9783663B2 (en) 2012-12-14 2017-10-10 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
CA2798854C (en) 2012-12-14 2020-02-18 Nova Chemicals Corporation Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
EA032503B1 (ru) 2013-08-12 2019-06-28 Сауди Бейсик Индастриз Корпорейшн Каталитическая система для полимеризации олефинов
EP2837634A1 (en) 2013-08-12 2015-02-18 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
WO2015091966A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
JP6358852B2 (ja) * 2014-05-23 2018-07-18 ポリプラスチックス株式会社 環状オレフィン共重合体の製造方法
WO2016135590A1 (en) 2015-02-24 2016-09-01 Nova Chemicals (International) S.A. Bottle cap
US9758653B2 (en) 2015-08-19 2017-09-12 Nova Chemicals (International) S.A. Polyethylene compositions, process and closures
CA2914354C (en) 2015-12-10 2022-11-08 Nova Chemicals Corp. Hot fill process with closures made frm bimodal polyethylene compositions
CA2914353C (en) 2015-12-10 2023-01-24 Nova Chemicals Corp. Hot fill process with closures made from high density polyethylene compositions
US9783664B1 (en) 2016-06-01 2017-10-10 Nova Chemicals (International) S.A. Hinged component comprising polyethylene composition
EP3592780A1 (en) 2017-03-09 2020-01-15 ExxonMobil Chemical Patents Inc. Process for producing polyethylene polymers
CN111032772B (zh) 2017-06-14 2022-07-15 埃克森美孚化学专利公司 用于交联应用的乙烯共聚物共混物
CA3022700A1 (en) 2017-11-27 2019-05-27 Nova Chemicals Corporation Bottle closure assembly comprising a polyethylene composition having good dimensional stability
CA3022996A1 (en) 2017-12-04 2019-06-04 Nova Chemicals Corporation Bottle closure assembly comprising a polyethylene composition
CN112771113B (zh) 2018-09-27 2023-07-18 三井化学株式会社 环状烯烃系树脂组合物、成型体及光学部件
CA3026095A1 (en) 2018-12-03 2020-06-03 Nova Chemicals Corporation Polyethylene homopolymer compositions having good barrier properties
CA3026098A1 (en) 2018-12-03 2020-06-03 Nova Chemicals Corporation Narrow polyethylene homopolymer compositions having good barrier properties
CA3028148A1 (en) 2018-12-20 2020-06-20 Nova Chemicals Corporation Polyethylene copolymer compositions and articles with barrier properties
CA3028157A1 (en) 2018-12-20 2020-06-20 Nova Chemicals Corporation Polyethylene copolymer compositions and their barrier properties
CA3032082A1 (en) 2019-01-31 2020-07-31 Nova Chemicals Corporation Polyethylene compositions and articles with good barrier properties
JP7423332B2 (ja) 2019-03-29 2024-01-29 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法
JP7308644B2 (ja) * 2019-03-29 2023-07-14 三井化学株式会社 オレフィン・環状オレフィン共重合体の製造方法
WO2021014244A1 (en) 2019-07-25 2021-01-28 Nova Chemicals (International) S.A. Rotomolded parts prepared from bimodal polyethylene
BR112022007224A2 (pt) 2019-10-16 2022-07-05 Nova Chem Int Sa Uso de polietileno reciclado em fechamentos para garrafas
MX2022008210A (es) 2020-01-17 2022-08-04 Nova Chem Int Sa Composiciones y articulos de copolimero de polietileno con propiedades de barrera.
US20230391906A1 (en) * 2020-10-02 2023-12-07 Polyplastics Co., Ltd. Cyclic olefin copolymer production method
JP2024515258A (ja) 2021-04-09 2024-04-08 アランセオ・ネザーランズ・ベー・フェー スルフィルイミン型リガンドとの金属錯体及び重合触媒としてのその使用
CN114031703B (zh) * 2021-11-29 2023-07-11 万华化学集团股份有限公司 一种双核金属催化剂、制备方法及应用
CN114933665B (zh) * 2022-06-06 2023-11-21 中国科学院长春应用化学研究所 一种异金属双核催化剂及其制法和组合物及应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4543399A (en) * 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
US5352749A (en) * 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
BR9500663A (pt) * 1994-02-17 1995-10-31 Union Carbide Chem Plastic Composição de catalisador processo de preparação de uma composição de catalisador e processo para a produção de homopolímeros ou copolímeros de etileno
JPH08134122A (ja) * 1994-11-11 1996-05-28 Idemitsu Kosan Co Ltd 重合用触媒及びそれを用いたスチレン系重合体の製造方法

Also Published As

Publication number Publication date
EP1021470B1 (en) 2002-12-04
DE69809957D1 (de) 2003-01-16
JP4245801B2 (ja) 2009-04-02
CA2215444A1 (en) 1999-03-15
ES2188000T3 (es) 2003-06-16
CA2215444C (en) 2005-08-02
CN1210312C (zh) 2005-07-13
US6420300B1 (en) 2002-07-16
CN1270601A (zh) 2000-10-18
WO1999014250A1 (en) 1999-03-25
ATE229042T1 (de) 2002-12-15
US6114481A (en) 2000-09-05
DE69809957T2 (de) 2003-09-04
JP2001516776A (ja) 2001-10-02
EP1021470A1 (en) 2000-07-26
AU8970098A (en) 1999-04-05

Similar Documents

Publication Publication Date Title
DK1021470T3 (da) Katalysator med en ketimidligand
FI973451A0 (fi) Ny organometalfoerening och metod foer polymerisation av olefiner med hjaelp av en katalytkomposition som innehaoller denna organometalfoerening
MXPA02005766A (es) Complejos sustituidos con metal del grupo 4, catalizadores y proceso de polimerizacion de olefinas.
CA2262910A1 (en) 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
NZ217040A (en) Olefin polymerisation using prepolymer-based ziegler-natta type catalyst and two organometallic cocatalysts
DE60109812D1 (de) Herstellung von polymerisationskatalysatoren
NO996038L (no) Nye katalysatorsystemer for kopolymerisasjonsreaksjoner, metallocen-amidhalogenider, deres fremstilling og anvendelse
FR2532649B1 (fr) Copolymerisation d'ethylene et d'hexene-1 en lit fluidise
TR200100965T2 (tr) Gaz fazı polimerizasyonları için köprülü metal kompleksleri
ATE208796T1 (de) Olefinpolymerisation
TW430674B (en) Process for preparing ethylene copolymers
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
RU98109935A (ru) Металлокомплексы, содержащие замещенный инденил, и способ полимеризации олефинов
CA2278282A1 (en) Olefin copolymers from bridged bis(arylamido) group 4 catalyst compounds
ID24621A (id) Katalis polietilena aktivitas tinggi
BR0012201A (pt) Complexos de alcóxidos de metais mistos, catalisadores de polimerização feitos destes, e seu uso
DK0560455T3 (da) Katalytisk system og fremgangsmåde til copolymerisation af carbonmonoxid med en eller flere olefiner
EA199800976A1 (ru) СПОСОБ ПОЛИМЕРИЗАЦИ α-ОЛЕФИНОВ
MY122542A (en) Cocatalytic composition which is usable for the polymerisation of alpha-olefins.
DE69519049D1 (de) Polymerisationskatalysatoren
WO1998039369A3 (de) Chirale halbsandwich-metallocen-katalysatoren und verfahren zur stereospezifischen polymerisation von olefinen damit
JPS52126690A (en) Catalysts for reduction of nox
BR0113238A (pt) Complexos de metal de transição tardia, seu uso como catalisadores e polìmeros destes
AU1416599A (en) Catalyst compositions for olefin polymerization based on metallocene complexes and novel cocatalysts produced from trialkylaluminum compounds, sterically hindered phenols, and water
CA2190146A1 (en) Olefin polymerization catalyst