DK0790259T3 - Støttede metallocenaluminiumoxankatalysatorer til fremstilling af polyethylen med en bred monomodal molekylvægtfordeling - Google Patents
Støttede metallocenaluminiumoxankatalysatorer til fremstilling af polyethylen med en bred monomodal molekylvægtfordelingInfo
- Publication number
- DK0790259T3 DK0790259T3 DK97102116T DK97102116T DK0790259T3 DK 0790259 T3 DK0790259 T3 DK 0790259T3 DK 97102116 T DK97102116 T DK 97102116T DK 97102116 T DK97102116 T DK 97102116T DK 0790259 T3 DK0790259 T3 DK 0790259T3
- Authority
- DK
- Denmark
- Prior art keywords
- production
- molecular weight
- weight distribution
- polyethylene
- supported metallocene
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/934—Electrodeposit, e.g. electrophoretic, xerographic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96200422 | 1996-02-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK0790259T3 true DK0790259T3 (da) | 2002-09-09 |
Family
ID=8223694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK97102116T DK0790259T3 (da) | 1996-02-19 | 1997-02-11 | Støttede metallocenaluminiumoxankatalysatorer til fremstilling af polyethylen med en bred monomodal molekylvægtfordeling |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5914289A (da) |
| EP (1) | EP0790259B1 (da) |
| JP (1) | JPH09227613A (da) |
| AT (1) | ATE217891T1 (da) |
| CA (1) | CA2197848C (da) |
| DE (1) | DE69712652T2 (da) |
| DK (1) | DK0790259T3 (da) |
| ES (1) | ES2176536T3 (da) |
| PT (1) | PT790259E (da) |
Families Citing this family (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5968864A (en) * | 1996-12-20 | 1999-10-19 | Fina Technology, Inc. | Catalyst efficiency for supported metallocene catalyst |
| EP0953582A1 (en) * | 1998-04-27 | 1999-11-03 | Fina Research S.A. | Polyolefin production |
| EP0989141A1 (en) * | 1998-09-25 | 2000-03-29 | Fina Research S.A. | Production of multimodal polyethelene |
| US6346586B1 (en) * | 1999-10-22 | 2002-02-12 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
| JP4542664B2 (ja) * | 2000-04-13 | 2010-09-15 | 日本ポリプロ株式会社 | プロピレン系重合体の製造方法 |
| RU2348653C2 (ru) | 2003-02-21 | 2009-03-10 | Дау Глобал Текнолоджиз Инк. | Способ гомо- или сополимеризации сопряженных олефинов |
| ES2285295T3 (es) * | 2004-03-12 | 2007-11-16 | Saudi Basic Industries Corporation | Composicion catalizadora para la polimerizacion de olefinas y proceso de polimerizacion usando la misma. |
| KR100753478B1 (ko) | 2005-02-15 | 2007-08-31 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리에틸렌 공중합체의 제조방법 |
| WO2008047173A1 (es) * | 2006-10-19 | 2008-04-24 | Centro De Investigacion En Quimica Aplicada | Catalizador para polimerizar en fase heterogenea olefinas y dienos conjugados, proceso de obtencion y empleo del mismo |
| KR101249995B1 (ko) | 2008-12-11 | 2013-04-03 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매, 이의 제조방법 및 이를 이용한 올레핀계 중합체의 제조방법 |
| WO2015056974A1 (ko) | 2013-10-18 | 2015-04-23 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법 |
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| EP3056524B1 (en) | 2014-10-13 | 2021-09-22 | LG Chem, Ltd. | Ethylene/1-butene copolymer having excellent processibility and environmental stress cracking resistance |
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| KR102227351B1 (ko) | 2016-12-23 | 2021-03-11 | 주식회사 엘지화학 | 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀 중합체의 제조 방법 |
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| WO2019132450A1 (ko) | 2017-12-26 | 2019-07-04 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
| KR102363189B1 (ko) | 2018-01-11 | 2022-02-15 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법 |
| WO2019139355A1 (ko) | 2018-01-11 | 2019-07-18 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조방법 |
| WO2019212307A1 (ko) | 2018-05-04 | 2019-11-07 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체, 이의 제조방법 |
| KR102527751B1 (ko) | 2018-05-04 | 2023-05-03 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 광학필름용 수지 조성물 및 이를 포함하는 광학필름 |
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| ES2947462T3 (es) | 2018-05-04 | 2023-08-09 | Lg Chemical Ltd | Composición de adhesivo que incluye un copolímero de etileno/alfa-olefina |
| KR102622329B1 (ko) | 2018-05-04 | 2024-01-09 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체, 이의 제조방법 및 이를 포함하는 광학필름용 수지 조성물 |
| KR20190127591A (ko) | 2018-05-04 | 2019-11-13 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 접착제 조성물 |
| WO2019212302A1 (ko) | 2018-05-04 | 2019-11-07 | 주식회사 엘지화학 | 올레핀계 공중합체 및 이의 제조방법 |
| KR102219312B1 (ko) | 2018-08-30 | 2021-02-24 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| WO2020046051A1 (ko) | 2018-08-30 | 2020-03-05 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| KR102294563B1 (ko) * | 2018-10-19 | 2021-08-26 | 한화솔루션 주식회사 | 올레핀 중합용 촉매 |
| KR102427755B1 (ko) | 2018-12-10 | 2022-08-01 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| KR102431339B1 (ko) | 2018-12-10 | 2022-08-10 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| WO2020122563A1 (ko) | 2018-12-10 | 2020-06-18 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| KR102427756B1 (ko) | 2018-12-10 | 2022-08-01 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| WO2020122562A1 (ko) | 2018-12-10 | 2020-06-18 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| WO2020122560A1 (ko) | 2018-12-10 | 2020-06-18 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| WO2021060907A1 (ko) | 2019-09-27 | 2021-04-01 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| WO2021060908A1 (ko) | 2019-09-27 | 2021-04-01 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이용한 폴리올레핀의 제조 방법 |
| EP3865522A4 (en) | 2019-09-27 | 2022-05-18 | LG Chem, Ltd. | POLYETHYLENE AND RELATED CHLORINATED POLYETHYLENE |
| WO2021071154A1 (ko) | 2019-10-11 | 2021-04-15 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 제조방법 |
| US20220403070A1 (en) | 2020-09-29 | 2022-12-22 | Lg Chem, Ltd. | Polyethylene Composition and Method for Preparing the Same |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| CA1327673C (en) * | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US5036034A (en) * | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| JP2826362B2 (ja) * | 1990-02-13 | 1998-11-18 | 三井化学株式会社 | オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法 |
| ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
| US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| EP0572990B2 (en) * | 1992-06-04 | 2000-08-16 | MITSUI TOATSU CHEMICALS, Inc. | Method for preparing ethylene copolymer |
| EP0598543B1 (en) * | 1992-11-10 | 1997-01-15 | Mitsubishi Chemical Corporation | Method for producing Alpha-olefin polymers |
| IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| WO1995018836A1 (en) * | 1994-01-11 | 1995-07-13 | Exxon Chemical Patents Inc. | Alumoxanes and catalysts comprising alumoxanes |
| DE69534436T2 (de) * | 1994-04-07 | 2006-02-23 | Innovene Europe Limited, Sunbury On Thames | Copolymere |
| DE69500979T2 (de) * | 1994-07-22 | 1998-03-05 | Mitsubishi Chem Corp | Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung desselben |
-
1997
- 1997-02-07 US US08/797,800 patent/US5914289A/en not_active Expired - Fee Related
- 1997-02-11 ES ES97102116T patent/ES2176536T3/es not_active Expired - Lifetime
- 1997-02-11 DE DE69712652T patent/DE69712652T2/de not_active Revoked
- 1997-02-11 PT PT97102116T patent/PT790259E/pt unknown
- 1997-02-11 DK DK97102116T patent/DK0790259T3/da active
- 1997-02-11 EP EP97102116A patent/EP0790259B1/en not_active Revoked
- 1997-02-11 AT AT97102116T patent/ATE217891T1/de not_active IP Right Cessation
- 1997-02-14 JP JP9044964A patent/JPH09227613A/ja active Pending
- 1997-02-18 CA CA002197848A patent/CA2197848C/en not_active Expired - Fee Related
-
1999
- 1999-06-18 US US09/336,011 patent/US6225428B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2176536T3 (es) | 2002-12-01 |
| ATE217891T1 (de) | 2002-06-15 |
| US6225428B1 (en) | 2001-05-01 |
| EP0790259B1 (en) | 2002-05-22 |
| EP0790259A1 (en) | 1997-08-20 |
| US5914289A (en) | 1999-06-22 |
| JPH09227613A (ja) | 1997-09-02 |
| PT790259E (pt) | 2002-09-30 |
| DE69712652D1 (de) | 2002-06-27 |
| CA2197848A1 (en) | 1997-08-20 |
| CA2197848C (en) | 2007-04-17 |
| DE69712652T2 (de) | 2002-12-12 |
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