DE813212C - Verfahren zur Herstellung eines Anionen austauschenden Harzes - Google Patents
Verfahren zur Herstellung eines Anionen austauschenden HarzesInfo
- Publication number
- DE813212C DE813212C DEI361A DEI0000361A DE813212C DE 813212 C DE813212 C DE 813212C DE I361 A DEI361 A DE I361A DE I0000361 A DEI0000361 A DE I0000361A DE 813212 C DE813212 C DE 813212C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- resin
- formaldehyde
- water
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 6
- 238000002360 preparation method Methods 0.000 title claims 2
- 239000003957 anion exchange resin Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 48
- 229920005989 resin Polymers 0.000 claims description 43
- 239000011347 resin Substances 0.000 claims description 43
- 229920000768 polyamine Polymers 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims description 10
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 5
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 4
- 230000018984 mastication Effects 0.000 claims description 2
- 238000010077 mastication Methods 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 230000032683 aging Effects 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000002253 acid Substances 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 230000008929 regeneration Effects 0.000 description 8
- 238000011069 regeneration method Methods 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 6
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 238000005349 anion exchange Methods 0.000 description 3
- 239000008098 formaldehyde solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/13—Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB821/49A GB666410A (en) | 1949-01-12 | 1949-01-12 | New anion exchange resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE813212C true DE813212C (de) | 1951-09-10 |
Family
ID=9711067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI361A Expired DE813212C (de) | 1949-01-12 | 1950-01-10 | Verfahren zur Herstellung eines Anionen austauschenden Harzes |
Country Status (5)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2912390A (en) * | 1956-05-08 | 1959-11-10 | Pittsburgh Plate Glass Co | Synthetic resin from dihaloalkyl xylene and polyalkylene polyamines |
| US2994669A (en) * | 1959-08-28 | 1961-08-01 | Wolfen Filmfab Veb | Process for the production of modified phenylene diamine ion exchange resins |
| GB1153013A (en) * | 1966-01-26 | 1969-05-21 | Bridgestone Tire Co Ltd | A Method of Manufacturing Antioxidant for Rubber and a Rubber Composition Compounding the Antioxidant |
| FR2812254A1 (fr) | 2000-07-28 | 2002-02-01 | Lamberet Const Isothermes | Butoir amortisseur pour vehicule accostant contre un quai |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2223930A (en) * | 1936-12-05 | 1940-12-03 | Ig Farbenindustrie Ag | Amine resins |
| US2259169A (en) * | 1938-10-29 | 1941-10-14 | Us Rubber Co | Resinous material |
| BE472469A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1942-06-16 | |||
| US2373632A (en) * | 1942-06-24 | 1945-04-10 | Resinous Prod & Chemical Co | Removal of fluorine from water |
-
0
- NL NL75822D patent/NL75822C/xx active
-
1949
- 1949-01-12 GB GB821/49A patent/GB666410A/en not_active Expired
-
1950
- 1950-01-09 US US137668A patent/US2588784A/en not_active Expired - Lifetime
- 1950-01-09 FR FR1008120D patent/FR1008120A/fr not_active Expired
- 1950-01-10 DE DEI361A patent/DE813212C/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1008120A (fr) | 1952-05-14 |
| NL75822C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| GB666410A (en) | 1952-02-13 |
| US2588784A (en) | 1952-03-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1418604A1 (de) | Gelbildende hochmolekulare Substanzen und Verfahren zu ihrer Herstellung | |
| DE888096C (de) | Verfahren zur Herstellung von Oxyaldehyden und Oxyketonen aus Formaldehyd oder Formaldehyd liefernden Stoffen | |
| DE1418013A1 (de) | Hydrophiles,begrenzt quellbares Vernetzungsprodukt hohen Molekulargewichts eines Dextrans oder eines hydroxylgruppenhaltigen Dextranderivates und Verfahren zur Herstellung derartiger Produkte | |
| DE813212C (de) | Verfahren zur Herstellung eines Anionen austauschenden Harzes | |
| DE594083C (de) | Verfahren zur Herstellung von Methylvinylketon | |
| DE1817691C3 (de) | Verfahren zur Herstellung von Monoisopropylamin | |
| AT142583B (de) | Verfahren zur Herstellung von Hartkautschuk in Staubform. | |
| DE1016931B (de) | Verfahren zur Herstellung von neuen Anionenaustauschharzen auf der Basis von Thiuroniumsalzen | |
| AT207114B (de) | Verfahren zur Reinigung hochpolymerer Kohlenwasserstoffe | |
| DE897486C (de) | Verfahren zur Herstellung neuer AEthylenderivate | |
| AT244056B (de) | Verfahren zum Abtrennen von basischen Stickstoffpolykondensaten | |
| DE540513C (de) | Verfahren zur Herstellung von Glykol aus Chlorhydrinen | |
| DE1063807B (de) | Verfahren zur Herstellung von Kunstharzen mit anionenaustauschenden Eigenschaften | |
| DE962605C (de) | Anionenaustauscher fuer die Behandlung von Fluessigkeiten | |
| DE880133C (de) | Verfahren zur Herstellung von ungesättigten Aldehyden | |
| DE1803083C3 (de) | Verfahren zur Herstellung eines Ni-Katalysators zur selektiven Gewinnung von Monoisopropylamin | |
| AT205847B (de) | Kunstdarm und Verfahren zu seiner Herstellung | |
| AT114015B (de) | Verfahren zur nutzbaren Aufarbeitung von Lupinen u. dgl. | |
| AT231367B (de) | Verfahren zur Herstellung eines als Kationenaustauschharz verwendbaren vernetzten Copolymeren | |
| AT219279B (de) | Verfahren zur Herstellung von hochmolekularen Formaldehydpolymeren | |
| AT136993B (de) | Verfahren zur Herstellung von harzartigen Kondensationsprodukten. | |
| DE1030325B (de) | Verfahren zur Herstellung von Epoxyestergemischen | |
| AT120413B (de) | Verfahren zur Herstellung von porösen Formlingen. | |
| DE1495768C (de) | Verfahren zur Chlormethylierung von hochmolekularen, vinylaromatischen Verbin düngen | |
| AT96288B (de) | Verfahren zur Herstellung von Alkaliboraten. |