DE69922340T2 - Ein katalysator für die (co)polymerisierung von ethylen und ein verfahren zu dessen herstellung - Google Patents
Ein katalysator für die (co)polymerisierung von ethylen und ein verfahren zu dessen herstellung Download PDFInfo
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- DE69922340T2 DE69922340T2 DE69922340T DE69922340T DE69922340T2 DE 69922340 T2 DE69922340 T2 DE 69922340T2 DE 69922340 T DE69922340 T DE 69922340T DE 69922340 T DE69922340 T DE 69922340T DE 69922340 T2 DE69922340 T2 DE 69922340T2
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- Germany
- Prior art keywords
- catalyst
- transition metal
- polymerization
- chromium
- ethylene
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- 239000003054 catalyst Substances 0.000 title claims description 168
- 238000006116 polymerization reaction Methods 0.000 title claims description 73
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 33
- 239000005977 Ethylene Substances 0.000 title claims description 33
- 238000000034 method Methods 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title description 7
- 239000011651 chromium Substances 0.000 claims description 49
- -1 chromium oxide compound Chemical class 0.000 claims description 44
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 38
- 229910052804 chromium Inorganic materials 0.000 claims description 36
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 32
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 29
- 229910052723 transition metal Inorganic materials 0.000 claims description 24
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 18
- 150000003624 transition metals Chemical class 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 15
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims description 14
- 239000012018 catalyst precursor Substances 0.000 claims description 12
- 150000003623 transition metal compounds Chemical class 0.000 claims description 10
- 239000003446 ligand Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 8
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- 239000010936 titanium Substances 0.000 claims description 7
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- 238000002360 preparation method Methods 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
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- 150000004678 hydrides Chemical class 0.000 claims description 3
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- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 14
- 239000012968 metallocene catalyst Substances 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
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- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 12
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
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- 230000002902 bimodal effect Effects 0.000 description 6
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
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- RSPAIISXQHXRKX-UHFFFAOYSA-L 5-butylcyclopenta-1,3-diene;zirconium(4+);dichloride Chemical compound Cl[Zr+2]Cl.CCCCC1=CC=C[CH-]1.CCCCC1=CC=C[CH-]1 RSPAIISXQHXRKX-UHFFFAOYSA-L 0.000 description 3
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- 229910007926 ZrCl Inorganic materials 0.000 description 3
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- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- IQTGDGZBSKVCKJ-UHFFFAOYSA-L [Cl-].[Cl-].CCCCC1([Hf++]C2(CCCC)C=CC=C2)C=CC=C1 Chemical compound [Cl-].[Cl-].CCCCC1([Hf++]C2(CCCC)C=CC=C2)C=CC=C1 IQTGDGZBSKVCKJ-UHFFFAOYSA-L 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
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- 239000000126 substance Substances 0.000 description 2
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- 229920003002 synthetic resin Polymers 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 241001631457 Cannula Species 0.000 description 1
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
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- 229910052786 argon Inorganic materials 0.000 description 1
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- 125000003118 aryl group Chemical group 0.000 description 1
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- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- KZUKCLOWAMFDDB-UHFFFAOYSA-L butylcyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.CCCC[C]1[CH][CH][CH][CH]1.CCCC[C]1[CH][CH][CH][CH]1 KZUKCLOWAMFDDB-UHFFFAOYSA-L 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
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- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
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- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
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- 125000000623 heterocyclic group Chemical group 0.000 description 1
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- 229920002521 macromolecule Polymers 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
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- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
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- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Peptides Or Proteins (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO980552 | 1998-02-09 | ||
| NO980552A NO980552D0 (no) | 1998-02-09 | 1998-02-09 | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| PCT/NO1999/000043 WO1999040126A1 (en) | 1998-02-09 | 1999-02-09 | A catalyst for the (co)polymerisation of ethylene and a method for the preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69922340D1 DE69922340D1 (de) | 2005-01-05 |
| DE69922340T2 true DE69922340T2 (de) | 2005-11-10 |
Family
ID=19901654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69922340T Expired - Fee Related DE69922340T2 (de) | 1998-02-09 | 1999-02-09 | Ein katalysator für die (co)polymerisierung von ethylen und ein verfahren zu dessen herstellung |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US6541581B1 (enExample) |
| EP (2) | EP1053264A1 (enExample) |
| JP (2) | JP2002502895A (enExample) |
| KR (1) | KR20010040769A (enExample) |
| CN (2) | CN1136241C (enExample) |
| AR (1) | AR018078A1 (enExample) |
| AT (1) | ATE283866T1 (enExample) |
| AU (2) | AU740974B2 (enExample) |
| BR (2) | BR9907708A (enExample) |
| CA (2) | CA2320436C (enExample) |
| DE (1) | DE69922340T2 (enExample) |
| ES (1) | ES2234237T3 (enExample) |
| NO (1) | NO980552D0 (enExample) |
| WO (2) | WO1999040131A1 (enExample) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO980552D0 (no) * | 1998-02-09 | 1998-02-09 | Borealis As | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| NO981631L (no) * | 1998-04-08 | 1999-10-11 | Borealis As | Katalysator for polymerisasjon av etylen, og fremgangsmaate for fremstilling av denne |
| US6272384B1 (en) | 1999-05-27 | 2001-08-07 | Urologix, Inc. | Microwave therapy apparatus |
| GB9919718D0 (en) * | 1999-08-19 | 1999-10-20 | Borealis As | Process |
| US6433133B1 (en) * | 1999-11-16 | 2002-08-13 | Eastman Chemical Company | Process for reducing the weight average molecular weight and melt index ratio of polyethylenes and polyethylene products |
| US6388017B1 (en) * | 2000-05-24 | 2002-05-14 | Phillips Petroleum Company | Process for producing a polymer composition |
| ATE337343T1 (de) | 2001-04-30 | 2006-09-15 | Grace W R & Co | Geträgerte dualübergangsmetallkatalysatorsysteme |
| US6943224B2 (en) | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
| EP1587844A1 (en) * | 2002-12-17 | 2005-10-26 | O & D Trading Limited | Supported olefin polymerization catalyst |
| US7384885B2 (en) | 2003-03-31 | 2008-06-10 | Exxonmobil Chemical Patents Inc. | Catalyst activation and resins therefrom |
| US20040192865A1 (en) * | 2003-03-31 | 2004-09-30 | Roger Scott T. | Resin for extruded pipe |
| WO2004096868A1 (en) * | 2003-03-31 | 2004-11-11 | Exxonmobil Chemical Patents Inc. | Resin for extruded pipe |
| WO2004096867A1 (en) * | 2003-03-31 | 2004-11-11 | Exxonmobil Chemical Patents Inc. | Utility conduit resin |
| US20040192864A1 (en) * | 2003-03-31 | 2004-09-30 | Exxonmobil Chemical Company | Utility conduit resin |
| DE102005019393A1 (de) | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Polyethylenformmassen für Spritzgussanwendungen |
| DE102005019395A1 (de) * | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators |
| EP2218752B1 (en) * | 2006-04-07 | 2013-06-12 | Dow Global Technologies LLC | Polyolefin compositions and articles made therefrom |
| CA2605044C (en) * | 2007-10-01 | 2014-12-02 | Nova Chemicals Corporation | Polymerization process using a mixed catalyst system |
| CA2605077C (en) * | 2007-10-01 | 2014-07-08 | Nova Chemicals Corporation | A co-supported catalyst system |
| US7951881B2 (en) | 2009-02-27 | 2011-05-31 | Chevron Phillips Chemical Company Lp | Polyethylene film having improved barrier properties and methods of making same |
| SG173773A1 (en) * | 2009-02-27 | 2011-10-28 | Chevron Phillips Chemical Co | Polyethylene film having improved barrier properties and methods of making same |
| US8852748B2 (en) | 2009-02-27 | 2014-10-07 | Chevron Phillips Chemical Company Lp | Polyethylene film having improved barrier properties and methods of making same |
| CA2713042C (en) | 2010-08-11 | 2017-10-24 | Nova Chemicals Corporation | Method of controlling polymer architecture |
| US8148470B1 (en) | 2010-11-19 | 2012-04-03 | Exxonmobil Chemical Patents Inc. | Processes for making multimodal molecular weight distribution polyolefins |
| RU2579518C2 (ru) * | 2010-11-19 | 2016-04-10 | Юнивейшн Текнолоджиз,ЛЛК | Способы получения полиолефинов, обладающих мультимодальным молекулярно-массовым распределением |
| US8653208B2 (en) * | 2012-05-18 | 2014-02-18 | Union Carbide Chemicals & Plastics Technology Llc | Process for preparing catalysts and catalysts made thereby |
| CA2783494C (en) | 2012-07-23 | 2019-07-30 | Nova Chemicals Corporation | Adjusting polymer composition |
| CN104877052B (zh) * | 2015-05-06 | 2018-04-13 | 无锡耀汇科技有限公司 | 一种聚乙烯树脂 |
| CN104877051B (zh) * | 2015-05-06 | 2018-04-13 | 无锡耀汇科技有限公司 | 一种聚烯烃催化剂 |
| CN108884179B (zh) * | 2016-04-20 | 2021-09-21 | 尤尼威蒂恩技术有限责任公司 | 聚合物流动指数改性剂 |
| WO2018130539A1 (en) * | 2017-01-11 | 2018-07-19 | Sabic Global Technologies B.V. | Chromium oxide catalyst for ethylene polymerization |
| EP3568421B1 (en) | 2017-01-11 | 2023-12-27 | SABIC Global Technologies B.V. | Chromium oxide catalyst for ethylene polymerization |
| US11952480B2 (en) | 2018-02-05 | 2024-04-09 | Exxonmobil Chemical Patents Inc. | Enhanced processability of LLDPE by addition of ultra-high molecular weight density polyethylene |
| JP2023539244A (ja) * | 2020-08-24 | 2023-09-13 | セラニーズ・インターナショナル・コーポレーション | 分子量分布の狭い高密度ポリエチレンから作製されるゲル押出物品 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8333032D0 (en) | 1983-12-10 | 1984-01-18 | Bp Chem Int Ltd | Orientated polyolefins |
| NO172242C (no) * | 1988-04-26 | 1993-06-23 | Showa Denko Kk | Fremgangsmaate for fremstilling av etylenpolymerer |
| DE69422410T2 (de) * | 1993-08-06 | 2000-07-06 | Exxon Chemical Patents, Inc. | Polymerisationskataylsatoren, ihre herstellung und verwendung |
| US5614456A (en) * | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
| BE1009186A3 (fr) * | 1995-03-13 | 1996-12-03 | Solvay | Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene. |
| ATE198898T1 (de) * | 1995-08-22 | 2001-02-15 | Basf Ag | Polymerisate des ethylens mit hoher spannungsrissbeständigkeit und katalysatorsystem für deren herstellung |
| DE19716239A1 (de) * | 1997-04-18 | 1998-10-22 | Basf Ag | Verfahren zur Polymerisation von alpha-Olefinen in der Gasphase |
| GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
| NO980552D0 (no) * | 1998-02-09 | 1998-02-09 | Borealis As | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| US6013596A (en) * | 1998-05-18 | 2000-01-11 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing cyclic, bidentate complexing agents |
| WO1999065949A2 (en) * | 1998-06-16 | 1999-12-23 | Borealis Technology Oy | Olefin polymerization process |
| DE69908649T2 (de) * | 1998-12-16 | 2004-04-29 | Borealis Technology Oy | Mehrstufenverfahren zur darstellung von polyolefinen mit hoher schmelzfestigkeit |
| DE60002056T2 (de) * | 1999-02-22 | 2003-11-06 | Borealis Technology Oy, Porvoo | Olefinpolymerisationsverfahren |
-
1998
- 1998-02-09 NO NO980552A patent/NO980552D0/no unknown
-
1999
- 1999-02-08 AR ARP990100534A patent/AR018078A1/es active IP Right Grant
- 1999-02-09 ES ES99903958T patent/ES2234237T3/es not_active Expired - Lifetime
- 1999-02-09 BR BR9907708-6A patent/BR9907708A/pt not_active Application Discontinuation
- 1999-02-09 CN CNB998028142A patent/CN1136241C/zh not_active Expired - Fee Related
- 1999-02-09 JP JP2000530553A patent/JP2002502895A/ja active Pending
- 1999-02-09 AU AU24431/99A patent/AU740974B2/en not_active Ceased
- 1999-02-09 US US09/601,654 patent/US6541581B1/en not_active Expired - Fee Related
- 1999-02-09 EP EP99903959A patent/EP1053264A1/en not_active Withdrawn
- 1999-02-09 CN CN998028177A patent/CN1132853C/zh not_active Expired - Fee Related
- 1999-02-09 KR KR1020007008658A patent/KR20010040769A/ko not_active Abandoned
- 1999-02-09 WO PCT/NO1999/000044 patent/WO1999040131A1/en not_active Ceased
- 1999-02-09 CA CA002320436A patent/CA2320436C/en not_active Expired - Fee Related
- 1999-02-09 DE DE69922340T patent/DE69922340T2/de not_active Expired - Fee Related
- 1999-02-09 BR BR9907702-7A patent/BR9907702A/pt not_active IP Right Cessation
- 1999-02-09 AT AT99903958T patent/ATE283866T1/de not_active IP Right Cessation
- 1999-02-09 EP EP99903958A patent/EP1045866B1/en not_active Expired - Lifetime
- 1999-02-09 JP JP2000530558A patent/JP2002502897A/ja active Pending
- 1999-02-09 US US09/601,652 patent/US6780809B1/en not_active Expired - Fee Related
- 1999-02-09 CA CA002320271A patent/CA2320271C/en not_active Expired - Fee Related
- 1999-02-09 WO PCT/NO1999/000043 patent/WO1999040126A1/en not_active Ceased
- 1999-02-09 AU AU24430/99A patent/AU738712B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CA2320271C (en) | 2007-07-17 |
| US6541581B1 (en) | 2003-04-01 |
| JP2002502897A (ja) | 2002-01-29 |
| EP1045866B1 (en) | 2004-12-01 |
| CA2320436A1 (en) | 1999-08-12 |
| EP1045866A1 (en) | 2000-10-25 |
| CA2320436C (en) | 2007-08-14 |
| WO1999040131A1 (en) | 1999-08-12 |
| ATE283866T1 (de) | 2004-12-15 |
| KR20010040769A (ko) | 2001-05-15 |
| US6780809B1 (en) | 2004-08-24 |
| BR9907702A (pt) | 2000-11-14 |
| CN1290272A (zh) | 2001-04-04 |
| ES2234237T3 (es) | 2005-06-16 |
| CN1290274A (zh) | 2001-04-04 |
| CN1132853C (zh) | 2003-12-31 |
| AU740974B2 (en) | 2001-11-15 |
| EP1053264A1 (en) | 2000-11-22 |
| JP2002502895A (ja) | 2002-01-29 |
| BR9907708A (pt) | 2000-11-14 |
| DE69922340D1 (de) | 2005-01-05 |
| CN1136241C (zh) | 2004-01-28 |
| CA2320271A1 (en) | 1999-08-12 |
| WO1999040126A1 (en) | 1999-08-12 |
| AU738712B2 (en) | 2001-09-27 |
| WO1999040126A9 (en) | 1999-10-21 |
| AU2443099A (en) | 1999-08-23 |
| AU2443199A (en) | 1999-08-23 |
| AR018078A1 (es) | 2001-10-31 |
| NO980552D0 (no) | 1998-02-09 |
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| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |