ATE283866T1 - Ein katalysator für die (co)polymerisierung von ethylen und ein verfahren zu dessen herstellung - Google Patents

Ein katalysator für die (co)polymerisierung von ethylen und ein verfahren zu dessen herstellung

Info

Publication number
ATE283866T1
ATE283866T1 AT99903958T AT99903958T ATE283866T1 AT E283866 T1 ATE283866 T1 AT E283866T1 AT 99903958 T AT99903958 T AT 99903958T AT 99903958 T AT99903958 T AT 99903958T AT E283866 T1 ATE283866 T1 AT E283866T1
Authority
AT
Austria
Prior art keywords
polymerization
catalyst
ethylene
production
Prior art date
Application number
AT99903958T
Other languages
German (de)
English (en)
Inventor
Arild Follestad
Vidar Almquist
Ulf Palmqvist
Harri Hokkanen
Original Assignee
Borealis Tech Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Tech Oy filed Critical Borealis Tech Oy
Application granted granted Critical
Publication of ATE283866T1 publication Critical patent/ATE283866T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63925—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Peptides Or Proteins (AREA)
AT99903958T 1998-02-09 1999-02-09 Ein katalysator für die (co)polymerisierung von ethylen und ein verfahren zu dessen herstellung ATE283866T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO980552A NO980552D0 (no) 1998-02-09 1998-02-09 Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
PCT/NO1999/000043 WO1999040126A1 (en) 1998-02-09 1999-02-09 A catalyst for the (co)polymerisation of ethylene and a method for the preparation thereof

Publications (1)

Publication Number Publication Date
ATE283866T1 true ATE283866T1 (de) 2004-12-15

Family

ID=19901654

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99903958T ATE283866T1 (de) 1998-02-09 1999-02-09 Ein katalysator für die (co)polymerisierung von ethylen und ein verfahren zu dessen herstellung

Country Status (14)

Country Link
US (2) US6541581B1 (enExample)
EP (2) EP1053264A1 (enExample)
JP (2) JP2002502895A (enExample)
KR (1) KR20010040769A (enExample)
CN (2) CN1136241C (enExample)
AR (1) AR018078A1 (enExample)
AT (1) ATE283866T1 (enExample)
AU (2) AU740974B2 (enExample)
BR (2) BR9907708A (enExample)
CA (2) CA2320436C (enExample)
DE (1) DE69922340T2 (enExample)
ES (1) ES2234237T3 (enExample)
NO (1) NO980552D0 (enExample)
WO (2) WO1999040131A1 (enExample)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
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NO980552D0 (no) * 1998-02-09 1998-02-09 Borealis As Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
NO981631L (no) * 1998-04-08 1999-10-11 Borealis As Katalysator for polymerisasjon av etylen, og fremgangsmaate for fremstilling av denne
US6272384B1 (en) 1999-05-27 2001-08-07 Urologix, Inc. Microwave therapy apparatus
GB9919718D0 (en) * 1999-08-19 1999-10-20 Borealis As Process
US6433133B1 (en) * 1999-11-16 2002-08-13 Eastman Chemical Company Process for reducing the weight average molecular weight and melt index ratio of polyethylenes and polyethylene products
US6388017B1 (en) * 2000-05-24 2002-05-14 Phillips Petroleum Company Process for producing a polymer composition
ATE337343T1 (de) 2001-04-30 2006-09-15 Grace W R & Co Geträgerte dualübergangsmetallkatalysatorsysteme
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
EP1587844A1 (en) * 2002-12-17 2005-10-26 O & D Trading Limited Supported olefin polymerization catalyst
US7384885B2 (en) 2003-03-31 2008-06-10 Exxonmobil Chemical Patents Inc. Catalyst activation and resins therefrom
US20040192865A1 (en) * 2003-03-31 2004-09-30 Roger Scott T. Resin for extruded pipe
WO2004096868A1 (en) * 2003-03-31 2004-11-11 Exxonmobil Chemical Patents Inc. Resin for extruded pipe
WO2004096867A1 (en) * 2003-03-31 2004-11-11 Exxonmobil Chemical Patents Inc. Utility conduit resin
US20040192864A1 (en) * 2003-03-31 2004-09-30 Exxonmobil Chemical Company Utility conduit resin
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
EP2218752B1 (en) * 2006-04-07 2013-06-12 Dow Global Technologies LLC Polyolefin compositions and articles made therefrom
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
CA2605077C (en) * 2007-10-01 2014-07-08 Nova Chemicals Corporation A co-supported catalyst system
US7951881B2 (en) 2009-02-27 2011-05-31 Chevron Phillips Chemical Company Lp Polyethylene film having improved barrier properties and methods of making same
SG173773A1 (en) * 2009-02-27 2011-10-28 Chevron Phillips Chemical Co Polyethylene film having improved barrier properties and methods of making same
US8852748B2 (en) 2009-02-27 2014-10-07 Chevron Phillips Chemical Company Lp Polyethylene film having improved barrier properties and methods of making same
CA2713042C (en) 2010-08-11 2017-10-24 Nova Chemicals Corporation Method of controlling polymer architecture
US8148470B1 (en) 2010-11-19 2012-04-03 Exxonmobil Chemical Patents Inc. Processes for making multimodal molecular weight distribution polyolefins
RU2579518C2 (ru) * 2010-11-19 2016-04-10 Юнивейшн Текнолоджиз,ЛЛК Способы получения полиолефинов, обладающих мультимодальным молекулярно-массовым распределением
US8653208B2 (en) * 2012-05-18 2014-02-18 Union Carbide Chemicals & Plastics Technology Llc Process for preparing catalysts and catalysts made thereby
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
CN104877052B (zh) * 2015-05-06 2018-04-13 无锡耀汇科技有限公司 一种聚乙烯树脂
CN104877051B (zh) * 2015-05-06 2018-04-13 无锡耀汇科技有限公司 一种聚烯烃催化剂
CN108884179B (zh) * 2016-04-20 2021-09-21 尤尼威蒂恩技术有限责任公司 聚合物流动指数改性剂
WO2018130539A1 (en) * 2017-01-11 2018-07-19 Sabic Global Technologies B.V. Chromium oxide catalyst for ethylene polymerization
EP3568421B1 (en) 2017-01-11 2023-12-27 SABIC Global Technologies B.V. Chromium oxide catalyst for ethylene polymerization
US11952480B2 (en) 2018-02-05 2024-04-09 Exxonmobil Chemical Patents Inc. Enhanced processability of LLDPE by addition of ultra-high molecular weight density polyethylene
JP2023539244A (ja) * 2020-08-24 2023-09-13 セラニーズ・インターナショナル・コーポレーション 分子量分布の狭い高密度ポリエチレンから作製されるゲル押出物品

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NO172242C (no) * 1988-04-26 1993-06-23 Showa Denko Kk Fremgangsmaate for fremstilling av etylenpolymerer
DE69422410T2 (de) * 1993-08-06 2000-07-06 Exxon Chemical Patents, Inc. Polymerisationskataylsatoren, ihre herstellung und verwendung
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
BE1009186A3 (fr) * 1995-03-13 1996-12-03 Solvay Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene.
ATE198898T1 (de) * 1995-08-22 2001-02-15 Basf Ag Polymerisate des ethylens mit hoher spannungsrissbeständigkeit und katalysatorsystem für deren herstellung
DE19716239A1 (de) * 1997-04-18 1998-10-22 Basf Ag Verfahren zur Polymerisation von alpha-Olefinen in der Gasphase
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
NO980552D0 (no) * 1998-02-09 1998-02-09 Borealis As Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
US6013596A (en) * 1998-05-18 2000-01-11 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing cyclic, bidentate complexing agents
WO1999065949A2 (en) * 1998-06-16 1999-12-23 Borealis Technology Oy Olefin polymerization process
DE69908649T2 (de) * 1998-12-16 2004-04-29 Borealis Technology Oy Mehrstufenverfahren zur darstellung von polyolefinen mit hoher schmelzfestigkeit
DE60002056T2 (de) * 1999-02-22 2003-11-06 Borealis Technology Oy, Porvoo Olefinpolymerisationsverfahren

Also Published As

Publication number Publication date
CA2320271C (en) 2007-07-17
US6541581B1 (en) 2003-04-01
JP2002502897A (ja) 2002-01-29
EP1045866B1 (en) 2004-12-01
CA2320436A1 (en) 1999-08-12
EP1045866A1 (en) 2000-10-25
CA2320436C (en) 2007-08-14
WO1999040131A1 (en) 1999-08-12
KR20010040769A (ko) 2001-05-15
US6780809B1 (en) 2004-08-24
BR9907702A (pt) 2000-11-14
CN1290272A (zh) 2001-04-04
ES2234237T3 (es) 2005-06-16
CN1290274A (zh) 2001-04-04
CN1132853C (zh) 2003-12-31
AU740974B2 (en) 2001-11-15
EP1053264A1 (en) 2000-11-22
JP2002502895A (ja) 2002-01-29
BR9907708A (pt) 2000-11-14
DE69922340D1 (de) 2005-01-05
CN1136241C (zh) 2004-01-28
CA2320271A1 (en) 1999-08-12
WO1999040126A1 (en) 1999-08-12
DE69922340T2 (de) 2005-11-10
AU738712B2 (en) 2001-09-27
WO1999040126A9 (en) 1999-10-21
AU2443099A (en) 1999-08-23
AU2443199A (en) 1999-08-23
AR018078A1 (es) 2001-10-31
NO980552D0 (no) 1998-02-09

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