DE69812901T2 - Katalytische herstellung von pentafluorpropenen - Google Patents

Katalytische herstellung von pentafluorpropenen

Info

Publication number
DE69812901T2
DE69812901T2 DE69812901T DE69812901T DE69812901T2 DE 69812901 T2 DE69812901 T2 DE 69812901T2 DE 69812901 T DE69812901 T DE 69812901T DE 69812901 T DE69812901 T DE 69812901T DE 69812901 T2 DE69812901 T2 DE 69812901T2
Authority
DE
Germany
Prior art keywords
catalyst
magnesium
zinc
aluminum
fluorides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69812901T
Other languages
German (de)
English (en)
Other versions
DE69812901D1 (de
Inventor
Joseph Nappa
N. Rao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of DE69812901D1 publication Critical patent/DE69812901D1/de
Publication of DE69812901T2 publication Critical patent/DE69812901T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/12Fluorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/084Decomposition of carbon-containing compounds into carbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/25Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69812901T 1997-01-31 1998-01-07 Katalytische herstellung von pentafluorpropenen Expired - Lifetime DE69812901T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3632797P 1997-01-31 1997-01-31
PCT/US1998/000429 WO1998033755A1 (en) 1997-01-31 1998-01-07 The catalytic manufacture of pentafluoropropenes

Publications (2)

Publication Number Publication Date
DE69812901D1 DE69812901D1 (de) 2003-05-08
DE69812901T2 true DE69812901T2 (de) 2003-11-06

Family

ID=21887975

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69812901T Expired - Lifetime DE69812901T2 (de) 1997-01-31 1998-01-07 Katalytische herstellung von pentafluorpropenen

Country Status (5)

Country Link
US (1) US6369284B1 (https=)
EP (1) EP0958265B1 (https=)
JP (1) JP4031052B2 (https=)
DE (1) DE69812901T2 (https=)
WO (1) WO1998033755A1 (https=)

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4001926B2 (ja) 1996-11-21 2007-10-31 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フッ化ビニルの接触製造
EP1198441A4 (en) * 1999-07-21 2003-01-22 Halocarbon Prod Corp PRODUCTION OF ALIPHATIC FLUOROCARBONS
US8033120B2 (en) * 2002-10-25 2011-10-11 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
US20040089839A1 (en) * 2002-10-25 2004-05-13 Honeywell International, Inc. Fluorinated alkene refrigerant compositions
US7279451B2 (en) 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US7230146B2 (en) * 2003-10-27 2007-06-12 Honeywell International Inc. Process for producing fluoropropenes
US8530708B2 (en) 2003-07-25 2013-09-10 Honeywell International Inc. Processes for selective dehydrohalogenation of halogenated alkanes
US7880040B2 (en) * 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
US9255046B2 (en) 2003-07-25 2016-02-09 Honeywell International Inc. Manufacturing process for HFO-1234ze
US7091388B2 (en) * 2003-09-26 2006-08-15 Honeywell International Inc. Method of making 1,1,3,3,3-pentafluoropropene
US7655610B2 (en) * 2004-04-29 2010-02-02 Honeywell International Inc. Blowing agent compositions comprising fluorinated olefins and carbon dioxide
US9499729B2 (en) * 2006-06-26 2016-11-22 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
US9308199B2 (en) * 2004-04-29 2016-04-12 Honeywell International Inc. Medicament formulations
US8084653B2 (en) 2004-04-29 2011-12-27 Honeywell International, Inc. Method for producing fluorinated organic compounds
US7674939B2 (en) * 2004-04-29 2010-03-09 Honeywell International Inc. Method for producing fluorinated organic compounds
KR20070011554A (ko) * 2004-04-29 2007-01-24 허니웰 인터내셔널 인코포레이티드 1,3,3,3-테트라플루오로프로펜의 합성 방법
US9102579B2 (en) * 2004-04-29 2015-08-11 Honeywell International Inc. Method for producing fluorinated organic compounds
US7659434B2 (en) * 2004-04-29 2010-02-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US7951982B2 (en) * 2004-04-29 2011-05-31 Honeywell International Inc. Method for producing fluorinated organic compounds
US8383867B2 (en) * 2004-04-29 2013-02-26 Honeywell International Inc. Method for producing fluorinated organic compounds
US9024092B2 (en) * 2006-01-03 2015-05-05 Honeywell International Inc. Method for producing fluorinated organic compounds
CA2564991C (en) * 2004-04-29 2013-03-19 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropene
US7897823B2 (en) * 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US20060094911A1 (en) * 2004-10-29 2006-05-04 Rao Velliyur N M Noncatalytic manufacture of 1,1,3,3,3-pentafluoropropene from 1,1,1,3,3,3-hexafluoropropane
US20060116538A1 (en) * 2004-10-29 2006-06-01 Ralph Newton Miller Azeotrope compositions comprising 1,1,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof
AU2016200229B2 (en) * 2005-03-04 2017-03-09 The Chemours Company Fc, Llc. Compositions comprising a fluoroolefin
US20220389297A1 (en) 2005-03-04 2022-12-08 The Chemours Company Fc, Llc Compositions comprising a fluoroolefin
US7569170B2 (en) 2005-03-04 2009-08-04 E.I. Du Pont De Nemours And Company Compositions comprising a fluoroolefin
JP4627045B2 (ja) * 2005-04-27 2011-02-09 セントラル硝子株式会社 金属製造保護ガス
US8574451B2 (en) * 2005-06-24 2013-11-05 Honeywell International Inc. Trans-chloro-3,3,3-trifluoropropene for use in chiller applications
US7476771B2 (en) 2005-11-01 2009-01-13 E.I. Du Pont De Nemours + Company Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
US7388117B2 (en) * 2005-11-01 2008-06-17 E.I. Du Pont De Nemours And Company Azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof
US7560602B2 (en) * 2005-11-03 2009-07-14 Honeywell International Inc. Process for manufacture of fluorinated olefins
US7902410B2 (en) 2005-11-03 2011-03-08 Honeywell International Inc. Process for the manufacture of fluorinated alkanes
CN103193584B (zh) * 2006-01-03 2015-07-01 霍尼韦尔国际公司 制备氟化有机化合物的方法
US7687670B2 (en) * 2006-03-31 2010-03-30 E.I. Du Pont De Nemours And Company Coproduction of hydrofluoroolefins
US20090005616A1 (en) * 2006-03-31 2009-01-01 Ralph Newton Miller Purification of 1,2,3,3,3-Pentafluoropropene by Extractive Distillation
JP5393454B2 (ja) * 2006-06-27 2014-01-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 1,2,3,3,3−ペンタフルオロプロペンの製造方法
JP2009542650A (ja) * 2006-06-27 2009-12-03 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー テトラフルオロプロペン製造方法
WO2008002500A1 (en) 2006-06-27 2008-01-03 E. I. Du Pont De Nemours And Company Tetrafluoropropene production processes
US20080003127A1 (en) * 2006-07-03 2008-01-03 Honeywell International Inc. Non-Ferrous Metal Cover Gases
US20100242677A1 (en) * 2006-07-03 2010-09-30 Honeywell International Inc. Non-ferrous metal cover gases
WO2008008351A2 (en) 2006-07-13 2008-01-17 E. I. Du Pont De Nemours And Company Catalytic isomerization between e and z isomers of 1,2,3,3,3-pentafluoropropene
ES2450945T3 (es) 2006-08-24 2014-03-25 E. I. Du Pont De Nemours And Company Procedimientos para la separación de fluoroolefinas a partir de fluoruro de hidrógeno por destilación azeotrópica
US8067650B2 (en) * 2006-08-24 2011-11-29 Honeywell International Inc. Process for the production of HFO trans-1234ze from HFC-245fa
US8053613B2 (en) * 2006-09-05 2011-11-08 E.I. Du Pont De Nemours And Company Processes for producing 1,2,3,3,3-pentafluoropropene and precursors thereof
CN101578252B (zh) * 2006-09-05 2013-11-27 纳幕尔杜邦公司 1,2,3,3,3-五氟丙烯生产方法
EP2069273B1 (en) * 2006-09-08 2018-02-21 The Chemours Company FC, LLC Azeotrope compositions comprising 1,1,1,2,3-pentafluoropropene and hydrogen fluoride and uses thereof
KR101397113B1 (ko) 2006-10-03 2014-05-19 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 탄소수 3-6의 (하이드로)플루오로알켄의 생성을 위한 탈수소할로겐화 방법
US8013194B2 (en) 2008-03-14 2011-09-06 Honeywell International Inc. Process for the manufacture of fluorinated olefins
TW200831446A (en) * 2006-11-15 2008-08-01 Du Pont Processes for producing pentafluoropropenes and certain azeotropes comprising HF and certain halopropenes of the formula C3HCIF4
WO2009003157A1 (en) * 2007-06-27 2008-12-31 Arkema Inc. Two step process for the manufacture of hydrofluoroolefins
TW200920721A (en) * 2007-07-13 2009-05-16 Solvay Fluor Gmbh Preparation of halogen and hydrogen containing alkenes over metal fluoride catalysts
WO2009026080A1 (en) 2007-08-16 2009-02-26 E.I. Du Pont De Nemours And Company Catalytic isomerization between e and z isomers of 1,2,3,3,3 pentafluoropropene using aluminum catalyst
WO2009026082A1 (en) * 2007-08-16 2009-02-26 E. I. Du Pont De Nemours And Company Catalytic isomerization between e and z isomers of 1,2,3,3,3 pentafluoropropene using aluminum catalyst
US7700815B2 (en) 2007-09-28 2010-04-20 Honeywell International Inc Method for producing fluorinated organic compounds
KR102136117B1 (ko) 2008-02-21 2020-07-22 더 케무어스 컴퍼니 에프씨, 엘엘씨 공비 증류에 의한 플루오르화수소로부터의 1,3,3,3-테트라플루오로프로펜의 분리 방법
US8710282B2 (en) 2008-03-14 2014-04-29 Honeywell International Inc. Integrated process for the manufacture of fluorinated olefins
FR2929272B1 (fr) * 2008-03-28 2010-04-09 Arkema France Procede pour la preparation du 2,3,3,3-tetrafluoro-1-propene
FR2929273B1 (fr) * 2008-03-28 2017-05-26 Arkema France Procede de preparation de composes fluores.
KR102884920B1 (ko) 2008-05-07 2025-11-12 더 케무어스 컴퍼니 에프씨, 엘엘씨 1,1,1,2,3-펜타플루오로프로판 또는 2,3,3,3-테트라플루오로프로펜을 포함하는 조성물
GB0808836D0 (en) 2008-05-15 2008-06-18 Ineos Fluor Ltd Process
FR2933691B1 (fr) * 2008-07-10 2012-11-09 Arkema France Hydro(chloro)fluoroolefines et leur procede de preparation
US8129574B2 (en) 2009-08-31 2012-03-06 Honeywell International Inc. Hydrogenation process for fluorocarbons
FI3812360T3 (fi) 2009-09-09 2024-01-16 Honeywell Int Inc Monoklooritrifluoripropeeniyhdisteitä ja -koostumuksia ja niitä käyttäviä menetelmiä
US20110269999A1 (en) * 2010-04-29 2011-11-03 Honeywell International Inc. Process for dehydrohalogenation of halogenated alkanes
US9012702B2 (en) 2011-02-21 2015-04-21 E. I. Du Pont De Nemours And Company Catalytic dehydrochlorination of hydrochlorofluorocarbons
JP6182989B2 (ja) * 2012-06-28 2017-08-23 セントラル硝子株式会社 1,3,3,3−テトラフルオロプロペンの製造方法
WO2014046251A1 (ja) * 2012-09-21 2014-03-27 セントラル硝子株式会社 1,2-ジクロロ-3,3,3-トリフルオロプロペンの製造方法
JP2017114766A (ja) * 2014-04-28 2017-06-29 旭硝子株式会社 (e)−1−クロロ−3,3,3−トリフルオロプロペンの製造方法
JP6749347B2 (ja) 2015-06-05 2020-09-02 スリーエム イノベイティブ プロパティズ カンパニー ハイドロフルオロオレフィン及びその使用方法
CN114375287B (zh) * 2019-09-12 2024-07-30 关东电化工业株式会社 具有=cf2或=chf的结构的氟烯烃的精制方法、以及高纯度氟烯烃及其制造方法
TW202430495A (zh) 2022-10-03 2024-08-01 日商關東電化工業股份有限公司 氟烯烴之製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2599631A (en) 1945-12-06 1952-06-10 Du Pont Preparation of vinyl fluoride
US2478933A (en) 1947-04-02 1949-08-16 Allied Chem & Dye Corp Manufacture of 1, 1-chlorofluoroethylenes
FR1330146A (fr) 1961-12-22 1963-06-21 Stauffer Chemical Co Procédé amélioré de préparation de composés organiques fluorés par pyrolyse
US3607955A (en) 1968-04-08 1971-09-21 Phillips Petroleum Co Hydrofluorination and dehydrofluorination and catalysts therefor
EP0234002B1 (en) * 1986-01-22 1991-01-09 ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) Process for converting a 1,1,1-trifluoroalkane into a 1,1-difluoroalkene
SU1706690A1 (ru) 1988-04-19 1992-01-23 Всесоюзный Научно-Исследовательский Институт Технического Углерода Пористый углеродный материал
CA2019913A1 (en) 1990-06-08 1991-12-08 Michael S. Bolmer Production of vinylidene fluoride from 1,1-difluoroethane
US5136113A (en) 1991-07-23 1992-08-04 E. I. Du Pont De Nemours And Company Catalytic hydrogenolysis
WO1993025510A1 (fr) * 1992-06-05 1993-12-23 Daikin Industries, Ltd. Procedes d'obtention de 1,1,1,2,3-pentafluoro-propene et de 1,1,1,2,3-pentafluoro-propane
US5396000A (en) 1993-05-24 1995-03-07 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2,3,-pentafluoropropane
US5559069A (en) 1994-05-26 1996-09-24 E. I. Du Pont De Nemours And Company Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use
JPH0967281A (ja) * 1995-09-01 1997-03-11 Daikin Ind Ltd 1,1,1,3,3−ペンタフルオロプロペンの製造方法及び1,1,1,3,3−ペンタフルオロプロパンの製造方法
JP4001926B2 (ja) 1996-11-21 2007-10-31 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フッ化ビニルの接触製造
US5945573A (en) * 1997-01-31 1999-08-31 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,3,3-pentafluoropropane

Also Published As

Publication number Publication date
EP0958265A1 (en) 1999-11-24
JP4031052B2 (ja) 2008-01-09
WO1998033755A1 (en) 1998-08-06
US6369284B1 (en) 2002-04-09
EP0958265B1 (en) 2003-04-02
JP2001509803A (ja) 2001-07-24
DE69812901D1 (de) 2003-05-08

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