DE69705309T2 - Epoxidierungskatalysator und verfahren - Google Patents

Epoxidierungskatalysator und verfahren

Info

Publication number
DE69705309T2
DE69705309T2 DE69705309T DE69705309T DE69705309T2 DE 69705309 T2 DE69705309 T2 DE 69705309T2 DE 69705309 T DE69705309 T DE 69705309T DE 69705309 T DE69705309 T DE 69705309T DE 69705309 T2 DE69705309 T2 DE 69705309T2
Authority
DE
Germany
Prior art keywords
catalyst
support
oxide
silver
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69705309T
Other languages
German (de)
English (en)
Other versions
DE69705309D1 (de
Inventor
Mary Kowaleski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of DE69705309D1 publication Critical patent/DE69705309D1/de
Publication of DE69705309T2 publication Critical patent/DE69705309T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
DE69705309T 1996-04-30 1997-04-25 Epoxidierungskatalysator und verfahren Expired - Lifetime DE69705309T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/643,158 US5801259A (en) 1996-04-30 1996-04-30 Ethylene oxide catalyst and process
PCT/EP1997/002236 WO1997040933A1 (en) 1996-04-30 1997-04-25 Epoxidation catalyst and process

Publications (2)

Publication Number Publication Date
DE69705309D1 DE69705309D1 (de) 2001-07-26
DE69705309T2 true DE69705309T2 (de) 2001-11-15

Family

ID=24579602

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69705309T Expired - Lifetime DE69705309T2 (de) 1996-04-30 1997-04-25 Epoxidierungskatalysator und verfahren

Country Status (12)

Country Link
US (1) US5801259A (enrdf_load_stackoverflow)
EP (1) EP0900128B1 (enrdf_load_stackoverflow)
JP (1) JP4052673B2 (enrdf_load_stackoverflow)
CN (1) CN1093002C (enrdf_load_stackoverflow)
AU (1) AU711973B2 (enrdf_load_stackoverflow)
CA (1) CA2252780C (enrdf_load_stackoverflow)
DE (1) DE69705309T2 (enrdf_load_stackoverflow)
ES (1) ES2158559T3 (enrdf_load_stackoverflow)
IN (2) IN2004DE02379A (enrdf_load_stackoverflow)
MX (1) MX217137B (enrdf_load_stackoverflow)
TW (1) TW344675B (enrdf_load_stackoverflow)
WO (1) WO1997040933A1 (enrdf_load_stackoverflow)

Families Citing this family (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5939569A (en) * 1998-03-10 1999-08-17 Jones; C. Andrew Epoxidation process
EP1086743B1 (en) * 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Catalyst for production of epoxides and methods for production thereof and epoxides
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
US7193094B2 (en) * 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
DE60300995T2 (de) * 2002-04-04 2006-04-20 Nippon Shokubai Co. Ltd. Silberkatalysator enthaltend einen Träger auf der Basis von Silika-Alumina und seine Verwendung in der Herstellung von Epoxiden
US6750173B2 (en) * 2002-04-08 2004-06-15 Scientific Design Company, Inc. Ethylene oxide catalyst
KR100980123B1 (ko) 2002-06-28 2010-09-03 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매 선택성을 향상시키는 방법 및 올레핀 에폭시화 방법
CN1665797B (zh) 2002-06-28 2011-09-14 国际壳牌研究有限公司 环氧化方法的开车方法和烯烃环氧化方法
DE10300526A1 (de) * 2003-01-09 2004-07-22 Hte Ag The High Throughput Experimentation Company Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
US7319156B2 (en) * 2003-03-25 2008-01-15 Sumitomo Chemical Company, Limited Process for producing olefin oxide
TWI346574B (en) 2003-03-31 2011-08-11 Shell Int Research A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition
CA2520776C (en) * 2003-04-01 2012-05-08 Shell Internationale Research Maatschappij B.V. An olefin epoxidation process and a catalyst for use in the process
US7348444B2 (en) * 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
RU2342993C2 (ru) 2003-05-07 2009-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализаторы, содержащие серебро, получение таких катализаторов и их применение
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
RU2372342C2 (ru) * 2003-08-22 2009-11-10 Дау Текнолоджи Инвестментс Ллс. Улучшенные носители из оксида алюминия и катализаторы на основе серебра для получения алкиленоксидов
CN101757914A (zh) * 2003-10-16 2010-06-30 陶氏技术投资有限责任公司 用于烯化氧制备的具有提高稳定性、效率和/或活性的催化剂
CN1301791C (zh) * 2003-12-31 2007-02-28 中国石油化工股份有限公司北京燕山分公司研究院 用于环氧乙烷生产用银催化剂的载体、其制备方法及其应用
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
CA2575165C (en) 2004-08-12 2014-03-18 Velocys Inc. Process for converting ethylene to ethylene oxide using microchannel process technology
RU2007115405A (ru) * 2004-09-24 2008-10-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ выбора формированных частиц, способ сборки системы, способ реагирования газообразного сырья в такой системе, компьютерный программный продукт и компьютерная система
EA011641B1 (ru) * 2005-03-22 2009-04-28 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Реакторная система и способ для производства окиси этилена
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
MX2007015271A (es) 2005-06-07 2008-02-22 Shell Int Research Catalizador, proceso para preparar el mismo, y proceso para producir oxido de olefina, 1,2-diol, 1,2-diol eter o una alcanolamina.
MX2007015465A (es) * 2005-06-07 2008-02-25 Saint Gobain Ceramics Un portador catalizador y un procedimiento para preparar el portador catalizador.
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203348A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7704908B2 (en) * 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
KR20080080181A (ko) * 2005-12-22 2008-09-02 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀 또는 산화올레핀에서 유도할 수 있는화학물질의 제조방법
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
CN100577289C (zh) * 2006-01-28 2010-01-06 中国石油化工股份有限公司 环氧乙烷生产用银催化剂的载体、其制备方法及其应用
EP1979092A2 (en) * 2006-02-03 2008-10-15 Shell Internationale Research Maatschappij B.V. A process for treating a catalyst, the catalyst, and use of the catalyst
CA2646722C (en) * 2006-02-10 2012-06-19 Saint-Gobain Ceramics & Plastics, Inc. Process for making porous ceramic material
US10159961B2 (en) 2006-04-18 2018-12-25 Dow Global Technologies Llc Alkylene oxide catalyst and use thereof
MX2008013433A (es) * 2006-04-18 2009-03-06 Dow Global Technologies Inc Catalizador de oxido de alquileno y uso del mismo.
US8097557B2 (en) * 2006-08-08 2012-01-17 Sd Lizenverwertungsgesellschaft Mbh & Co. Kg Two-stage calcination for catalyst production
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
BRPI0719024A2 (pt) 2006-11-20 2013-11-05 Shell Internationale Res Maartschappij B V Processo para o tratamento de um veícul, processo para a preparação de um catalisador, catalisador e o uso do catalisador
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
BRPI0811282B1 (pt) * 2007-05-09 2016-12-27 Shell Int Research processos para a epoxidação de uma olefina e para preparar um 1,2-diol, um 1,2-diol éter, um 1,2-carbonato ou uma alcanolamina
CN101678332A (zh) 2007-05-09 2010-03-24 国际壳牌研究有限公司 环氧化催化剂及其制备方法和生产环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺的方法
AR069263A1 (es) 2007-05-09 2010-01-13 Shell Int Research Un catalizador de expodiacion, un proceso para preparar el mismo , y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2- diol eter, un 1,2- carbonato, o una alcanolamina
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
CN101678267A (zh) * 2007-05-18 2010-03-24 国际壳牌研究有限公司 反应器系统和用于制备1,2-二醇、1,2-二醇醚、1,2-碳酸酯和烷醇胺的方法
AR066573A1 (es) 2007-05-18 2009-08-26 Shell Int Research Un sistema reactor un absorbente y un proceso para la reaccion de una fuente
US7803957B2 (en) * 2007-09-11 2010-09-28 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Ethylene oxide production using fixed moderator concentration
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst
WO2009088040A1 (ja) * 2008-01-11 2009-07-16 Nippon Shokubai Co., Ltd. エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
EP2293872A1 (en) * 2008-04-30 2011-03-16 Dow Technology Investments LLC Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CA2723177A1 (en) 2008-04-30 2009-11-05 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CA2723160A1 (en) * 2008-04-30 2009-11-05 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
US7763096B2 (en) * 2008-05-06 2010-07-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Recovery of rhenium
CN102066348B (zh) 2008-05-07 2013-09-25 国际壳牌研究有限公司 环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法
CA2723517C (en) 2008-05-07 2017-03-07 Shell Internationale Research Maatschappij B.V. A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
JP2011520895A (ja) 2008-05-15 2011-07-21 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー アルキレンカーボネートおよび/またはアルキレングリコールの調製のための方法
RU2506123C2 (ru) 2008-05-15 2014-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения алкиленкарбоната и алкиленгликоля
CN102414189B (zh) * 2009-04-21 2014-09-17 陶氏技术投资有限公司 环氧化反应及其操作条件
WO2010123844A1 (en) * 2009-04-21 2010-10-28 Dow Technology Investments Llc Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst
US8389751B2 (en) * 2009-04-21 2013-03-05 Dow Technology Investments Llc Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages
SG175294A1 (en) 2009-04-21 2011-11-28 Dow Technology Investments Llc Rhenium-promoted epoxidation catalysts and methods of making and using them
JP2012522061A (ja) * 2009-12-28 2012-09-20 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルキレンオキサイドの製造における銀触媒上への塩化銀の生成の制御方法
JP2013521119A (ja) 2010-03-01 2013-06-10 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エポキシ化触媒、前記触媒の調製方法及びオレフィンオキシドの製造方法
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US9018126B2 (en) 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
CA2812771C (en) 2010-09-29 2019-02-19 Wayne Errol Evans Improved ethylene oxide process control
US8742146B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8815769B2 (en) 2011-04-11 2014-08-26 Dow Technology Investments Llc Process for conditioning a high efficiency ethylene oxide catalyst
BR112013027585B1 (pt) 2011-04-29 2020-09-29 Shell Internationale Research Maatschappij B.V Método para melhorar a seletividade de um catalisador de alta seletividade suportado usado na epoxidação de etileno e método para preparar um 1,2-diol, um 1,2-diol éter, um 1,2-carbonato ou uma alcanolamina
CN103357442B (zh) * 2012-03-28 2016-03-30 中国石油化工股份有限公司 烯烃环氧化用银催化剂的载体、其制备方法及其应用
CN103357440B (zh) * 2012-03-28 2015-03-11 中国石油化工股份有限公司 氧化铝载体的改性、及其负载的银催化剂的制备及其应用
CN103357436B (zh) * 2012-03-28 2016-02-24 中国石油化工股份有限公司 氧化铝载体碱处理改性、其负载的银催化剂的制备及应用
CN103566980B (zh) * 2012-07-23 2015-08-19 中国石油化工股份有限公司 氧化铝载体及其负载的银催化剂的制备方法及应用
CN103816940B (zh) * 2012-11-19 2019-03-26 中国石油化工股份有限公司 一种氧化铝载体及其制备方法
CN104884167B (zh) * 2012-12-31 2017-07-07 科学设计公司 用于生产改善的环氧乙烷催化剂的煅烧方法
CN104069893B (zh) * 2013-03-27 2016-05-25 中国石油化工股份有限公司 生产环氧乙烷用银催化剂载体、制备方法及其应用
CN104549546B (zh) * 2013-10-29 2017-08-22 中国石油化工股份有限公司 氧化铝载体、制备方法及银催化剂
TWI703108B (zh) 2015-06-02 2020-09-01 美商科學設計有限公司 用於製造具有增強的性能的多孔體的方法
CN106311231A (zh) * 2015-06-30 2017-01-11 中国石油化工股份有限公司 用于烯烃环氧化的银催化剂的制备方法、银催化剂及应用
CN106311230B (zh) * 2015-06-30 2019-05-31 中国石油化工股份有限公司 用于烯烃环氧化的银催化剂的制备方法、催化剂及应用
BR112019011162B1 (pt) 2016-12-02 2022-08-16 Shell Internationale Research Maatschappij B.V. Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
US11331652B2 (en) 2017-05-15 2022-05-17 Scientific Design Company, Inc. Porous bodies with enhanced pore architecture prepared without a high-temperature burnout material
TWI808125B (zh) 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
US10676401B2 (en) 2018-04-23 2020-06-09 Scientific Design Company, Inc. Porous bodies with enhanced pore architecture prepared with oxalic acid

Family Cites Families (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172866A (en) * 1965-03-09 Method of preparing alumina catalyst carriers and the product thereof
US3316279A (en) * 1964-06-09 1967-04-25 Union Oil Co Preparation of olefin oxides
US3844981A (en) * 1969-12-23 1974-10-29 Exxon Research Engineering Co Method for preparation of olefin oxidation catalyst
GB1325715A (en) * 1969-12-23 1973-08-08 Exxon Research Engineering Co Bimetallic catalyst manufacture and use in ethylene oxidation
US3702259A (en) * 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US3962136A (en) * 1972-01-07 1976-06-08 Shell Oil Company Catalyst for production of ethylene oxide
US4010115A (en) * 1972-01-07 1977-03-01 Shell Oil Company Catalyst for the oxidation of ethylene to ethylene oxide
US3962285A (en) * 1972-06-05 1976-06-08 Exxon Research And Engineering Company Olefin oxidation process
US3972829A (en) * 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
US4005049A (en) * 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
US4212772A (en) * 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
EP0002045B1 (de) * 1977-11-19 1981-09-02 BASF Aktiengesellschaft Verfahren zur Herstellung eines Äthylenoxydkatalysators
DE2844402A1 (de) * 1978-10-12 1980-04-30 Basf Ag Silber enthaltende traegerkatalysatoren, verfahren zu ihrer herstellung und verfahren zur herstellung von aethylenoxid mittels dieser katalysatoren
DE2904919A1 (de) * 1979-02-09 1980-08-21 Basf Ag Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid
JPS56108533A (en) * 1980-01-30 1981-08-28 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for preparing ethylene oxide
JPS56149320A (en) * 1980-04-21 1981-11-19 Sumitomo Alum Smelt Co Ltd Manufacture of activated alumina molding with low density
NL8201396A (nl) * 1982-04-01 1983-11-01 Dow Chemical Nederland Zilver katalysator en een werkwijze voor de bereiding daarvan.
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
US4459372A (en) * 1982-08-25 1984-07-10 Uop Inc. Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides
GB8304749D0 (en) * 1983-02-21 1983-03-23 Ici Plc Catalysts
EP0172280B1 (en) * 1983-03-14 1988-03-09 E.I. Du Pont De Nemours And Company Catalyst composition
FR2556236B1 (fr) * 1983-12-09 1988-04-01 Pro Catalyse Procede de fabrication d'un catalyseur pour le traitement des gaz d'echappement
US4579728A (en) * 1985-04-24 1986-04-01 Shell Oil Company Wide pore alumina supports
DE3669668D1 (de) * 1985-07-31 1990-04-26 Ici Plc Verfahren zur aktivierung der katalysatoren zur herstellung von alkylenoxiden.
EP0211448B1 (en) * 1985-08-16 1990-11-14 Sumitomo Chemical Company, Limited Process for preparing solid base
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4897498A (en) * 1988-01-28 1990-01-30 Eastman Kodak Company Selective monoepoxidation of olefins
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
US5072886A (en) * 1988-09-09 1991-12-17 Simon Fraser University Method of preparing a new ultra-fine particle transition alumina
US5081324A (en) * 1989-01-11 1992-01-14 Amoco Corporation Lower alkane conversion
US5130286A (en) * 1989-01-11 1992-07-14 Amoco Corporation Catalyst for lower alkane conversion
US5028577A (en) * 1989-01-11 1991-07-02 Amoco Corporation Lower alkane conversion catalysts
US4992409A (en) * 1989-01-11 1991-02-12 Amoco Corporation Catalyst and method of preparing the catalyst for lower alkane conversion
EP0383636A1 (en) * 1989-02-17 1990-08-22 Nippon Shokubai Co., Ltd. Carrier for catalyst and method for production thereof
DE3905578A1 (de) * 1989-02-23 1990-08-30 Basf Ag Verfahren zur herstellung eines silberkatalysators
US5071815A (en) * 1989-09-01 1991-12-10 British Columbia Research Corporation Method for producing catalysts
US5037794A (en) * 1989-09-12 1991-08-06 The B. F. Goodrich Company Attrition resistant catalyst support
US5081096A (en) * 1990-07-25 1992-01-14 Eastman Kodak Company Epoxidation catalyst
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
DE4106508A1 (de) * 1991-03-01 1992-09-03 Basf Ag Silberkatalysator
US5153165A (en) * 1991-05-09 1992-10-06 Phillips Petroleum Company Preparation of alkaline earth oxide catalysts
JP3312916B2 (ja) * 1991-06-06 2002-08-12 三菱化学株式会社 酸化エチレン製造用銀触媒
CA2089510C (en) * 1992-02-27 1998-09-01 Shinichi Nagase Silver catalyst for production of ethylene oxide and method for production of the catalyst
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5384302A (en) * 1993-09-08 1995-01-24 Norton Chemical Process Products Corp. Catalyst carrier
DE69600628T2 (de) * 1995-02-01 1999-02-25 Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage Alkylenoxidkatalysator und verfahren

Also Published As

Publication number Publication date
MX217137B (en) 2003-10-24
EP0900128A1 (en) 1999-03-10
WO1997040933A1 (en) 1997-11-06
CN1093002C (zh) 2002-10-23
ES2158559T3 (es) 2001-09-01
MX9808843A (en) 1999-05-31
IN2004DE02379A (enrdf_load_stackoverflow) 2009-06-19
JP4052673B2 (ja) 2008-02-27
EP0900128B1 (en) 2001-06-20
IN1997DE01084A (enrdf_load_stackoverflow) 2008-01-18
CA2252780A1 (en) 1997-11-06
US5801259A (en) 1998-09-01
JP2000508969A (ja) 2000-07-18
CN1216940A (zh) 1999-05-19
AU2776097A (en) 1997-11-19
DE69705309D1 (de) 2001-07-26
IN222717B (enrdf_load_stackoverflow) 2008-09-12
TW344675B (en) 1998-11-11
AU711973B2 (en) 1999-10-28
CA2252780C (en) 2006-10-17

Similar Documents

Publication Publication Date Title
DE69705309T2 (de) Epoxidierungskatalysator und verfahren
DE69409536T2 (de) Epoxydierungskatalysator und verfahren
DE69600628T2 (de) Alkylenoxidkatalysator und verfahren
DE69205845T2 (de) Katalysatorträger, zusammensetzung und Verfahren zu seiner Herstellung.
DE69200450T2 (de) Ethylenoxidkatalysator und Verfahren zu seiner Herstellung und seiner Anwendung.
DE69411591T2 (de) Epoxydierungskatalysator und verfahren
DE69520409T2 (de) Verfahren zur Herstellung von Äthylenoxid-Katalysatoren
DE69521329T2 (de) Äthylenoxidkatelysator und verfahren zu seiner herstellung
DE69032957T2 (de) Alkylenoxidkatalysatoren mit einem hohen Silbergehalt
DE69618485T2 (de) Verfahren zur herstellung von epoxidierungskatalysatoren
DE69705391T2 (de) Dampfphase oxydierung von propylen zu propylenoxid
DE69015863T2 (de) Alkylenoxid-Katalysator mit verbesserter Aktivität und/oder Stabilität.
DE68921777T2 (de) Hochwirksame Silberkatalysatoren zur Herstellung von Ethylenoxid durch Ethylenoxidation.
DE69912113T2 (de) Herstellung ungesättigter säuren oder von säureestern und dafür geeignete katalysatoren
US5733842A (en) Method of making porous catalyst carrier without the addition of pore forming agents
DE69700911T2 (de) Verfahren zur herstellung von propylenoxid unter verwendung von einem silberkatalysator auf einem erdalkalträger
DE69404748T2 (de) Ethylenoxidkatalysator und Verfahren zu seiner Herstellung und seiner Anwendung
DE3785014T2 (de) Verfahren zur behandlung von schwefelverbindungen enthaltendenindustriellen gasen.
DE69707281T2 (de) Katalysatorträger
DE2300512A1 (de) Neue silberkatalysatoren sowie deren herstellung und deren verwendung
WO2012140617A1 (de) Katalysator für die herstellung von ehtylenoxid
DD291484A5 (de) Silberkatalysator fuer die produktion von ethylenoxid und verfahren zu seiner herstellung
DE69402555T2 (de) Epoxyolierungskatalysator
DE69904438T2 (de) Verfahren zur entfernung von halogenverbindungen in einem gas oder einer flüssigkeit
DE2935903A1 (de) Oxidationskatalysator und seine verwendung bei einem verfahren zur herstellung von methacrolein

Legal Events

Date Code Title Description
8364 No opposition during term of opposition