DE69618923T2 - Verfahren zur selektiven hydroisomerierung von langen linearen und/oder wenig verzweigten paraffinen mit einem auf einen molekularsieb basierten katalysator - Google Patents

Verfahren zur selektiven hydroisomerierung von langen linearen und/oder wenig verzweigten paraffinen mit einem auf einen molekularsieb basierten katalysator

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Publication number
DE69618923T2
DE69618923T2 DE69618923T DE69618923T DE69618923T2 DE 69618923 T2 DE69618923 T2 DE 69618923T2 DE 69618923 T DE69618923 T DE 69618923T DE 69618923 T DE69618923 T DE 69618923T DE 69618923 T2 DE69618923 T2 DE 69618923T2
Authority
DE
Germany
Prior art keywords
hydroisomeration
selective
catalyst based
molecular screen
long linear
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69618923T
Other languages
English (en)
Other versions
DE69618923D1 (de
Inventor
Johan Martens
Wim Souverijns
Rudy Parton
Gilbert Froment
Christian Marcilly
Eric Benazzi
Nathalie George-Marchal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9510425A external-priority patent/FR2738244B1/fr
Priority claimed from FR9510424A external-priority patent/FR2738243B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of DE69618923D1 publication Critical patent/DE69618923D1/de
Application granted granted Critical
Publication of DE69618923T2 publication Critical patent/DE69618923T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7284—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7484—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7884—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69618923T 1995-09-06 1996-09-05 Verfahren zur selektiven hydroisomerierung von langen linearen und/oder wenig verzweigten paraffinen mit einem auf einen molekularsieb basierten katalysator Expired - Lifetime DE69618923T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9510425A FR2738244B1 (fr) 1995-09-06 1995-09-06 Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire
FR9510424A FR2738243B1 (fr) 1995-09-06 1995-09-06 Procede d'hydroisomerisation de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de zeolithe nu-10
PCT/FR1996/001364 WO1997009397A1 (fr) 1995-09-06 1996-09-05 Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire

Publications (2)

Publication Number Publication Date
DE69618923D1 DE69618923D1 (de) 2002-03-14
DE69618923T2 true DE69618923T2 (de) 2002-11-14

Family

ID=26232191

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69618923T Expired - Lifetime DE69618923T2 (de) 1995-09-06 1996-09-05 Verfahren zur selektiven hydroisomerierung von langen linearen und/oder wenig verzweigten paraffinen mit einem auf einen molekularsieb basierten katalysator

Country Status (8)

Country Link
US (1) US5990371A (de)
EP (1) EP0789739B1 (de)
JP (2) JPH10508900A (de)
KR (1) KR100449389B1 (de)
DE (1) DE69618923T2 (de)
ES (1) ES2171715T3 (de)
NO (1) NO315663B1 (de)
WO (1) WO1997009397A1 (de)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2760385B1 (fr) 1997-03-05 1999-04-16 Inst Francais Du Petrole Catalyseur a base de tamis moleculaire et procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec ce catalyseur
FR2765236B1 (fr) * 1997-06-25 1999-12-03 Inst Francais Du Petrole Procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines avec un catalyseur a base de zeolithe nu-87 modifiee
FR2765237B1 (fr) * 1997-06-25 1999-12-03 Inst Francais Du Petrole Catalyseur a base de zeolithe nu-87 modifiee et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
FR2765207B1 (fr) * 1997-06-25 1999-08-06 Inst Francais Du Petrole Zeolithe nu-85, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
FR2765206B1 (fr) * 1997-06-25 1999-08-06 Inst Francais Du Petrole Zeolithe eu-1, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
US6090989A (en) * 1997-10-20 2000-07-18 Mobil Oil Corporation Isoparaffinic lube basestock compositions
US6663768B1 (en) 1998-03-06 2003-12-16 Chevron U.S.A. Inc. Preparing a HGH viscosity index, low branch index dewaxed
FR2778582B1 (fr) * 1998-05-13 2000-06-16 Inst Francais Du Petrole Procede pour l'amelioration du point d'ecoulement et catalyseur a base d'au moins une zeolithe mtt, ton, fer
FR2779072B1 (fr) * 1998-05-28 2000-07-13 Inst Francais Du Petrole Catalyseur comprenant une zeolithe choisie dans le groupe forme par les zeolithes nu-85, nu-86 et nu-87, un element du groupe vb et son utilisation en hydroconversion de charges petrolieres hydrocarbonees
FR2780312B1 (fr) * 1998-06-25 2000-08-11 Inst Francais Du Petrole Catalyseur a base d'une zeolithe mtt, ton, fer et d'un element du groupe vb et son utilisation pour l'amelioration du point d'ecoulement de charges hydrocarbonees
US6080301A (en) 1998-09-04 2000-06-27 Exxonmobil Research And Engineering Company Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins
US6475960B1 (en) 1998-09-04 2002-11-05 Exxonmobil Research And Engineering Co. Premium synthetic lubricants
US20050256355A1 (en) * 1999-08-19 2005-11-17 Elisabeth Merlen Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons
FR2797593B1 (fr) * 1999-08-19 2002-05-24 Inst Francais Du Petrole Catalyseur comprenant au moins une zeolithe de type structural nes et du rhenium et son utilisation en transalkylation d'hydrocarbures alkylaromatiques
FR2798923B1 (fr) * 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des precurseurs specifiques du structurant
FR2798922B1 (fr) * 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des germes de materiaux zeolithiques
US7362028B2 (en) * 2004-02-26 2008-04-22 Lg Electronics Inc. Stator of outer rotor type motor for drum type washer
US20050284797A1 (en) * 2004-06-25 2005-12-29 Genetti William B Integrated plant process to produce high molecular weight basestocks from fischer-tropsch wax
JP5892764B2 (ja) * 2010-12-16 2016-03-23 日揮触媒化成株式会社 結晶性シリコアルミノリン酸塩成型体およびその製造方法
US9012710B2 (en) * 2011-07-29 2015-04-21 University Of Dayton Fuel compositions containing an isomerized component of a single carbon number and methods of preparing the fuel compositions
DE102016121067A1 (de) 2015-11-09 2017-05-11 China Petroleum And Chemical Corporation Modifiziertes Verbundmolekularsieb, Verfahren zu seiner Herstellung und Verwendung sowie Katalysator und seine Verwendung
US11572283B2 (en) 2017-10-26 2023-02-07 China Petroleum & Chemical Corporation Molecular sieve having mesopores, preparation method therefor, and application thereof
KR102365335B1 (ko) 2019-12-12 2022-02-18 한국화학연구원 합성가스로부터 가솔린 범위의 액상 탄화수소 혼합물을 제조하는 방법

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JPS57200218A (en) * 1981-05-20 1982-12-08 Ici Ltd Novel synthetic zeolite substance
EP0065400B1 (de) * 1981-05-20 1986-03-05 Imperial Chemical Industries Plc Zeolithe
EP0103981A1 (de) * 1982-09-03 1984-03-28 Imperial Chemical Industries Plc Zeolithe
EP0108486B1 (de) * 1982-10-05 1988-02-17 Imperial Chemical Industries Plc Herstellung von Zeolithen
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US5178748A (en) * 1988-12-22 1993-01-12 Imperial Chemical Industries Catalytic reactions using zeolites
EP0458895B1 (de) * 1989-02-17 1995-09-20 CHEVRON U.S.A. Inc. Isomerisierung von wachshaltigen schmierölen und erdoelwachsen durch anwendung eines silicoaluminophosphat molekularsiebkatalysts
US5282958A (en) * 1990-07-20 1994-02-01 Chevron Research And Technology Company Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons
DE69229980T2 (de) * 1991-06-05 2000-01-05 Equistar Chem Lp Verfahren zur Isomerisierung von geradlinigen Olefinen in Isoolefine

Also Published As

Publication number Publication date
ES2171715T3 (es) 2002-09-16
NO972069L (no) 1997-07-04
EP0789739B1 (de) 2002-01-30
WO1997009397A1 (fr) 1997-03-13
JP2009197234A (ja) 2009-09-03
DE69618923D1 (de) 2002-03-14
US5990371A (en) 1999-11-23
JPH10508900A (ja) 1998-09-02
KR100449389B1 (ko) 2005-01-17
KR970707259A (ko) 1997-12-01
NO972069D0 (no) 1997-05-05
NO315663B1 (no) 2003-10-06
EP0789739A1 (de) 1997-08-20

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Representative=s name: VONNEMANN, KLOIBER & KOLLEGEN, 80796 MUENCHEN

8327 Change in the person/name/address of the patent owner

Owner name: IFP ENERGIES NOUVELLES, RUEIL-MALMAISON, FR

8328 Change in the person/name/address of the agent

Representative=s name: VONNEMANN, KLOIBER & KOLLEGEN, 81667 MUENCHEN