ES2138964T3 - Procedimiento para la isomerizacion de olefinas en isoolefinas. - Google Patents

Procedimiento para la isomerizacion de olefinas en isoolefinas.

Info

Publication number
ES2138964T3
ES2138964T3 ES92305090T ES92305090T ES2138964T3 ES 2138964 T3 ES2138964 T3 ES 2138964T3 ES 92305090 T ES92305090 T ES 92305090T ES 92305090 T ES92305090 T ES 92305090T ES 2138964 T3 ES2138964 T3 ES 2138964T3
Authority
ES
Spain
Prior art keywords
ferrierite
sapo
butene
demonstrated
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92305090T
Other languages
English (en)
Inventor
Donald H Powers
Brendan D Murray
Bruce H C Winquist
Edwin M Callender
James H Varner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Equistar Chemicals LP
Original Assignee
Equistar Chemicals LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/711,044 external-priority patent/US6323384B1/en
Application filed by Equistar Chemicals LP filed Critical Equistar Chemicals LP
Application granted granted Critical
Publication of ES2138964T3 publication Critical patent/ES2138964T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

ESTA INVENCION PROPORCIONA UN PROCESO PARA CONVERTIR ALQUENOS LINEALES COMO EL BUTENO-1 Y BUTENO-2 EN ALQUENOS DE CADENA RAMIFICADA DE METILO, TALES COMO ISOBUTILENO, UTILIZANDO UN CATALIZADOR DE ZEOLITA DE PORO MEDIO, DIMENSIONAL Y CATALIZADORES DE TIPO SIMILAR, TALES COMO SAPOS Y MEAPOS. EL TAMAÑO DEL PORO PARA EL CATALIZADOR DEBE SER SUPERIOR A 0,42 NM E INFERIOR A 0,7 NM, PREFERIBLEMENTE CON UNA DIMENSION SUPERIOR A DE 0,5 A 0,6 NM. ESTE TAMAÑO DE PORO PERMITE QUE SE FORMEN Y DIFUNDAN LOS ALQUENOS DE CADENA RAMIFICADA FUERA DEL CATALIZADOR MIENTRAS QUE SE REDUCE LA FORMACION DE SUBPRODUCTOS NO DESEADOS, ENTRE ELLOS DIMEROS, TRIMEROS, AROMATICOS Y COQUE. ESTA INVENCION SE HA PROBADO CON H-FERRIERITA, SAPO-11 Y MORDENITA DE MAGNESIO EN UN REACTOR DE ESCALA DE LABORATORIO. SE PROBARON SELECTIVIDADES COMPRENDIDAS ENTRE EL 50% Y CASI EL 100%, APROXIMADAMENTE, PARA LA FORMACION DE ISOBUTILENO UTILIZANDO H-FERRIERITA, A TEMPERATURAS COMPRENDIDAS ENTRE 340 (GRADOS) C Y 440 (GRADOS) C, APROXIMADAMENTE.
ES92305090T 1991-06-05 1992-06-03 Procedimiento para la isomerizacion de olefinas en isoolefinas. Expired - Lifetime ES2138964T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US71104191A 1991-06-05 1991-06-05
US07/711,044 US6323384B1 (en) 1991-06-05 1991-06-05 Process for isomerizing linear olefins to isoolefins
US87433592A 1992-04-24 1992-04-24

Publications (1)

Publication Number Publication Date
ES2138964T3 true ES2138964T3 (es) 2000-02-01

Family

ID=27418884

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92305090T Expired - Lifetime ES2138964T3 (es) 1991-06-05 1992-06-03 Procedimiento para la isomerizacion de olefinas en isoolefinas.

Country Status (12)

Country Link
EP (1) EP0523838B9 (es)
JP (1) JP3195413B2 (es)
AT (1) ATE184586T1 (es)
AU (2) AU1805292A (es)
CA (1) CA2070595C (es)
DE (1) DE69229980T2 (es)
ES (1) ES2138964T3 (es)
FI (1) FI110608B (es)
MX (1) MX9202721A (es)
NO (1) NO307655B1 (es)
RU (1) RU2127717C1 (es)
SG (1) SG67315A1 (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5449851A (en) * 1991-09-16 1995-09-12 Mobil Oil Corporation Highly selective n-olefin isomerization process using ZSM-35
US5516959A (en) * 1991-09-16 1996-05-14 Mobil Oil Corporation Highly selective n-olefin isomerization process using ZSM-35
FR2695636B1 (fr) * 1992-09-15 1994-12-02 Inst Francais Du Petrole Procédé pour l'isomérisation des oléfines.
US5382743A (en) * 1993-04-26 1995-01-17 Mobil Oil Corporation Skeletal isomerization of n-pentenes using ZSM-35 in the presence of hydrogen
CA2123631C (en) * 1993-05-18 2005-02-22 Bettina Kraushaar-Czarnetzki Process for the isomerisation of a hydrocarbonaceous feedstock
EP0627394B1 (en) * 1993-05-18 1997-04-02 Shell Internationale Researchmaatschappij B.V. Process for the preparation of branched olefins
GB9312245D0 (en) * 1993-06-14 1993-07-28 Exxon Chemical Patents Inc Hydrocarbon treatment
EP0655277A1 (en) * 1993-11-01 1995-05-31 Csir Amorphous aluminosilicate catalyst
US5648585A (en) * 1993-12-29 1997-07-15 Murray; Brendan Dermot Process for isomerizing linear olefins to isoolefins
US5510306A (en) * 1993-12-29 1996-04-23 Shell Oil Company Process for isomerizing linear olefins to isoolefins
FR2716879B1 (fr) * 1994-03-01 1996-05-31 Inst Francais Du Petrole Procédé pour l'isomérisation des oléfines.
JP3303947B2 (ja) * 1994-05-18 2002-07-22 花王株式会社 分岐脂肪酸及び分岐脂肪酸エステルの製造法
GB9420528D0 (en) * 1994-10-12 1994-11-30 Bp Chem Int Ltd Skeletal isomerization of olefins
IT1271313B (it) 1994-12-21 1997-05-27 Enichem Spa Processo integrato per la produzione di eteri alchilici ter-amilici
IN192774B (es) * 1995-06-07 2004-05-15 Sheel Oil Company
KR19990022549A (ko) * 1995-06-07 1999-03-25 존 브라운 엘링턴 페리어라이트의 제조 방법
US5990371A (en) * 1995-09-06 1999-11-23 Institut Francais Du Petrole Process for the selective hydroisomerization of long linear and/or slightly branched paraffins using a catalyst based on a molecular sieve
US5763726A (en) * 1996-07-03 1998-06-09 Chevron U.S.A. Inc. C4 /C5 olefin skeletal isomerization process
US6150322A (en) 1998-08-12 2000-11-21 Shell Oil Company Highly branched primary alcohol compositions and biodegradable detergents made therefrom
US5811623A (en) * 1997-06-09 1998-09-22 Catalytic Distillation Technologies Isomerization of olefins by alkylation and dealkylation of aromatic hydrocarbons
FR2766810B1 (fr) * 1997-07-31 1999-10-22 Total Raffinage Distribution Procede de preparation d'une zeolithe de type ferrierite et son utilisation comme catalyseur d'isomerisation d'une olefine lineaire en isoolefine
FI118516B (fi) 2003-03-14 2007-12-14 Neste Oil Oyj Menetelmä katalyytin valmistamiseksi
ES2304308B1 (es) 2007-03-23 2009-08-07 Consejo Superior Investg.Cientificas Procedimiento de preparacion de un aluminosilicato con estructura tipo ferrierita a partir de geles que contienen tetrametilamonio y bencil-metilpirrolidinio,y sus aplicaciones.
FR2936526A1 (fr) * 2008-09-29 2010-04-02 Arkema France Fabrication d'hydroperoxyde de tertiobutyle a partir de matieres renouvelables, hydroperoxyde de tertiobutyle obtenu et utilisations
RU2475470C1 (ru) * 2012-03-11 2013-02-20 Ирина Игоревна Иванова Способ скелетной изомеризации н-бутенов в изобутилен
JP6120316B2 (ja) * 2013-04-26 2017-04-26 国立大学法人東京工業大学 オレフィン異性化触媒
DE102013014802A1 (de) 2013-09-05 2015-03-05 Linde Aktiengesellschaft Verfahren und Anlage zur Erzeugung von Kohlenwasserstoffprodukten
EP2995599A1 (de) 2014-09-11 2016-03-16 Linde Aktiengesellschaft Verfahren und Anlage zur Herstellung von Kohlenwasserstoffen
RU2694829C2 (ru) * 2016-09-06 2019-07-17 Общество с ограниченной ответственностью ОКСО Способ каталитического окисления н-гексана
CN109833905A (zh) 2017-11-29 2019-06-04 中国科学院大连化学物理研究所 分子筛催化剂及其制备方法和应用
US20220135499A1 (en) 2020-11-05 2022-05-05 Lyondell Chemical Technology, L.P. Olefin isomerization with small crystallite zeolite catalyst
WO2022098965A1 (en) 2020-11-05 2022-05-12 Lyondell Chemical Technology, L.P. Method of improving olefin isomerization
US20220401934A1 (en) 2021-06-09 2022-12-22 Lyondell Chemical Technology, L.P. Method of improving isomerization catalyst lifetime

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405500A (en) * 1980-12-23 1983-09-20 Ec Erdolchemie Gmbh Halogen compound promoted Al2 O3 and/or SiO2 for the preparation of isoalkenes
DE3246495A1 (de) * 1982-12-16 1984-06-20 Bayer Ag, 5090 Leverkusen Neuer katalysator, ein verfahren zu seiner herstellung und ein isomerisierungsverfahren in gegenwart dieses katalysators
US4973785A (en) * 1984-04-13 1990-11-27 Uop Molecular sieve compositions
SU1377273A1 (ru) * 1985-12-16 1988-02-28 Ярославский политехнический институт Способ получени С @ -С @ -изоолефинов
US4727203A (en) * 1987-04-13 1988-02-23 Shell Oil Company Terminal to interior double bond isomerization process for an olefinic molecule with reduced dimerization
US4814519A (en) * 1987-12-30 1989-03-21 Mobil Oil Corporation Production of ethers from olefins
US4973485A (en) * 1989-02-24 1990-11-27 The Procter & Gamble Company Orange stripper essence and stripper oil having high ratios of more desirable to less desirable flavor compounds
US5091590A (en) * 1990-08-22 1992-02-25 Mobil Oil Corporation Ether production with staged reaction of olefins

Also Published As

Publication number Publication date
EP0523838A2 (en) 1993-01-20
DE69229980T2 (de) 2000-01-05
EP0523838B1 (en) 1999-09-15
DE69229980D1 (de) 1999-10-21
JPH05246901A (ja) 1993-09-24
NO922209D0 (no) 1992-06-04
SG67315A1 (en) 1999-09-21
ATE184586T1 (de) 1999-10-15
JP3195413B2 (ja) 2001-08-06
MX9202721A (es) 1992-12-01
NO922209L (no) 1992-12-07
CA2070595C (en) 2004-11-23
FI110608B (fi) 2003-02-28
EP0523838A3 (en) 1993-08-04
EP0523838B9 (en) 2001-10-24
AU1805292A (en) 1993-03-11
FI922581A0 (fi) 1992-06-04
FI922581A (fi) 1992-12-06
NO307655B1 (no) 2000-05-08
CA2070595A1 (en) 1992-12-06
AU3310295A (en) 1995-12-07
RU2127717C1 (ru) 1999-03-20

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