ES2171715T3 - Procedimiento de hidroisomerizacion selectiva de parafinas largas lineales y/o poco ramificadas con un catalizador a base de tamiz molecular. - Google Patents

Procedimiento de hidroisomerizacion selectiva de parafinas largas lineales y/o poco ramificadas con un catalizador a base de tamiz molecular.

Info

Publication number
ES2171715T3
ES2171715T3 ES96930218T ES96930218T ES2171715T3 ES 2171715 T3 ES2171715 T3 ES 2171715T3 ES 96930218 T ES96930218 T ES 96930218T ES 96930218 T ES96930218 T ES 96930218T ES 2171715 T3 ES2171715 T3 ES 2171715T3
Authority
ES
Spain
Prior art keywords
procedure
molecular size
based catalyst
size based
long linear
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96930218T
Other languages
English (en)
Inventor
Johan Martens
Wim Souverijns
Rudy Parton
Gilbert Froment
Christian Marcilly
Eric Benazzi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9510424A external-priority patent/FR2738243B1/fr
Priority claimed from FR9510425A external-priority patent/FR2738244B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2171715T3 publication Critical patent/ES2171715T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7284—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7484—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7884—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCEDIMIENTO DE HIDROISOMERIZACION SELECTIVA DE COMPUESTOS QUE TIENEN AL MENOS UNA CADENA N-ALCANO DE MAS DE 10 ATOMOS DE CARBONO, EN EL QUE DICHO COMPUESTO A TRATAR ES PUESTO EN CONTACTO CON UN CATALIZADOR QUE COMPRENDE AL MENOS UN ELEMENTO HIDRODESHIDROGENANTE Y AL MENOS UN TAMIZ MOLECULAR QUE TIENE UNA RED POROSA MONO O BIDIMENSIONAL, CUYAS ABERTURAS DE POROS ACCESIBLES ESTAN DELIMITADAS POR 10 ATOMOS DE OXIGENO, Y SIENDO LA DISTANCIA LLAMADA ANCHO DE PUENTE ENTRE DICHOS POROS INFERIOR A 0,70 NM, Y DICHO CATALIZADOR SOMETIDOS A LA PRUEBA ESTANDAR DE ISOMERIZACION DEL N-HEPATDECANO PRESENTA, PARA UNA CONVERSION DE 95%, UNA SELECTIVIDAD EN PRODUCTOS ISOMERIZADOS DE AL MENOS 70%. PREFERENTEMENTE, EL TAMIZ ES UNA ZEOLITA NU-10, NU-23, NU-87, EU13, O THETA-1.
ES96930218T 1995-09-06 1996-09-05 Procedimiento de hidroisomerizacion selectiva de parafinas largas lineales y/o poco ramificadas con un catalizador a base de tamiz molecular. Expired - Lifetime ES2171715T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9510424A FR2738243B1 (fr) 1995-09-06 1995-09-06 Procede d'hydroisomerisation de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de zeolithe nu-10
FR9510425A FR2738244B1 (fr) 1995-09-06 1995-09-06 Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire

Publications (1)

Publication Number Publication Date
ES2171715T3 true ES2171715T3 (es) 2002-09-16

Family

ID=26232191

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96930218T Expired - Lifetime ES2171715T3 (es) 1995-09-06 1996-09-05 Procedimiento de hidroisomerizacion selectiva de parafinas largas lineales y/o poco ramificadas con un catalizador a base de tamiz molecular.

Country Status (8)

Country Link
US (1) US5990371A (es)
EP (1) EP0789739B1 (es)
JP (2) JPH10508900A (es)
KR (1) KR100449389B1 (es)
DE (1) DE69618923T2 (es)
ES (1) ES2171715T3 (es)
NO (1) NO315663B1 (es)
WO (1) WO1997009397A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2760385B1 (fr) * 1997-03-05 1999-04-16 Inst Francais Du Petrole Catalyseur a base de tamis moleculaire et procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec ce catalyseur
FR2765206B1 (fr) * 1997-06-25 1999-08-06 Inst Francais Du Petrole Zeolithe eu-1, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
FR2765236B1 (fr) * 1997-06-25 1999-12-03 Inst Francais Du Petrole Procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines avec un catalyseur a base de zeolithe nu-87 modifiee
FR2765237B1 (fr) * 1997-06-25 1999-12-03 Inst Francais Du Petrole Catalyseur a base de zeolithe nu-87 modifiee et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
FR2765207B1 (fr) * 1997-06-25 1999-08-06 Inst Francais Du Petrole Zeolithe nu-85, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
US6090989A (en) * 1997-10-20 2000-07-18 Mobil Oil Corporation Isoparaffinic lube basestock compositions
US6663768B1 (en) 1998-03-06 2003-12-16 Chevron U.S.A. Inc. Preparing a HGH viscosity index, low branch index dewaxed
BR9901875A (pt) * 1998-05-13 2000-05-09 Inst Francais Du Petrole Processo para a melhora do ponto de escoamento e catalisador à base de pelo menos um zeólito mtt,ton, fer.
FR2779072B1 (fr) * 1998-05-28 2000-07-13 Inst Francais Du Petrole Catalyseur comprenant une zeolithe choisie dans le groupe forme par les zeolithes nu-85, nu-86 et nu-87, un element du groupe vb et son utilisation en hydroconversion de charges petrolieres hydrocarbonees
FR2780312B1 (fr) * 1998-06-25 2000-08-11 Inst Francais Du Petrole Catalyseur a base d'une zeolithe mtt, ton, fer et d'un element du groupe vb et son utilisation pour l'amelioration du point d'ecoulement de charges hydrocarbonees
US6080301A (en) 1998-09-04 2000-06-27 Exxonmobil Research And Engineering Company Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins
US6475960B1 (en) 1998-09-04 2002-11-05 Exxonmobil Research And Engineering Co. Premium synthetic lubricants
US20050256355A1 (en) * 1999-08-19 2005-11-17 Elisabeth Merlen Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons
FR2797593B1 (fr) * 1999-08-19 2002-05-24 Inst Francais Du Petrole Catalyseur comprenant au moins une zeolithe de type structural nes et du rhenium et son utilisation en transalkylation d'hydrocarbures alkylaromatiques
FR2798923B1 (fr) * 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des precurseurs specifiques du structurant
FR2798922B1 (fr) * 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des germes de materiaux zeolithiques
US7362028B2 (en) * 2004-02-26 2008-04-22 Lg Electronics Inc. Stator of outer rotor type motor for drum type washer
US20050284797A1 (en) * 2004-06-25 2005-12-29 Genetti William B Integrated plant process to produce high molecular weight basestocks from fischer-tropsch wax
JP5892764B2 (ja) * 2010-12-16 2016-03-23 日揮触媒化成株式会社 結晶性シリコアルミノリン酸塩成型体およびその製造方法
US9012710B2 (en) * 2011-07-29 2015-04-21 University Of Dayton Fuel compositions containing an isomerized component of a single carbon number and methods of preparing the fuel compositions
DE102016121067A1 (de) 2015-11-09 2017-05-11 China Petroleum And Chemical Corporation Modifiziertes Verbundmolekularsieb, Verfahren zu seiner Herstellung und Verwendung sowie Katalysator und seine Verwendung
WO2019080922A1 (zh) 2017-10-26 2019-05-02 中国石油化工股份有限公司 具有介孔的分子筛及其制备方法和应用
KR102365335B1 (ko) 2019-12-12 2022-02-18 한국화학연구원 합성가스로부터 가솔린 범위의 액상 탄화수소 혼합물을 제조하는 방법

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ATE184586T1 (de) * 1991-06-05 1999-10-15 Equistar Chem Lp Verfahren zur isomerisierung von geradlinigen olefinen in isoolefine

Also Published As

Publication number Publication date
NO972069L (no) 1997-07-04
DE69618923T2 (de) 2002-11-14
KR970707259A (ko) 1997-12-01
KR100449389B1 (ko) 2005-01-17
EP0789739A1 (fr) 1997-08-20
WO1997009397A1 (fr) 1997-03-13
JP2009197234A (ja) 2009-09-03
NO972069D0 (no) 1997-05-05
DE69618923D1 (de) 2002-03-14
EP0789739B1 (fr) 2002-01-30
JPH10508900A (ja) 1998-09-02
NO315663B1 (no) 2003-10-06
US5990371A (en) 1999-11-23

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