KR970707259A - 분자체 촉매를 사용하여 직쇄 및/또는 소수의 분지쇄를 갖는 고급 파라핀을 선택적으로 가수소이성질체화하는 방법(selective hydroisomerisation method for straight and/or slightly branched long paraffins, using a molecular sieve catalyst) - Google Patents

분자체 촉매를 사용하여 직쇄 및/또는 소수의 분지쇄를 갖는 고급 파라핀을 선택적으로 가수소이성질체화하는 방법(selective hydroisomerisation method for straight and/or slightly branched long paraffins, using a molecular sieve catalyst)

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KR970707259A
KR970707259A KR1019970702931A KR19970702931A KR970707259A KR 970707259 A KR970707259 A KR 970707259A KR 1019970702931 A KR1019970702931 A KR 1019970702931A KR 19970702931 A KR19970702931 A KR 19970702931A KR 970707259 A KR970707259 A KR 970707259A
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molecular sieve
process according
compound
group
treated
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KR1019970702931A
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KR100449389B1 (ko
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마르뗑 요한
수베린즈 빔
파르톤 루디
프로멘트 길버트
마르실리 크리스티앙
베나찌 에릭
죠르쥬-마샬 나탈리
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프랑스와 앙드레프
앵스띠뛰 프랑세 뒤 뻬뜨롤
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Priority claimed from FR9510425A external-priority patent/FR2738244B1/fr
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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Abstract

본 발명은 10개 이상의 탄소원자를 함유하는 하나 이상의 n-알칸 연쇄를 가진 화합물을 선택적으로 가수소 이성질체화하는 방법으로서, 처리하고자 하는 화합물을, 하나 이상의 가수소-탈수소 성분 및 1차원 또는 2차원적인 소공 망상구조를 가지며 접근가능한 소고의 개구가 10개의 산소 원자에 의해 한정되고 소공 개구간의 브리지(bridge) 폭에 상응하는 거리가 0.70㎚ 이하인 하나 이상의 분자체를 포함하는 촉매와 접촉시키며, 상기 촉매는 표준 n-헵타데칸 테스트로 시험하였을 때 95%의 전환율에 있어서 이성질체화된 생성물에 대해 70%이상의 선택율을 갖는 방법에 관한 것이다.
분자체는 NU-10, NU-23, NU-87, EU-13 또는 Theta-1 제올라이트인 것이 바람직하다.

Description

분자체 촉매를 사용하여 직쇄 및/또는 소수의 분지쇄를 갖는 고급 파라핀을 선택적으로 가수소이성질체화하는 방법(SELECTIVE HYDROISOMERISATION METTHOD FOR STRAIGHT AND/OR SLIGHTLY BRANCHED LONG PARAFFINS, USING A MOLECULAR SIEVE CATALYST)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (25)

10개 이상의 탄소원자를 함유하는 하나 이상의 n-알칸 연쇄를 가진 화합물을 선택적으로 가수소이성질체화하는 방법으로서, 처리하고자 하는 화합물을, 하나 이상의 가수소-탈수소 성분 및 1차원 또는 2차원적인 소공 망상구조를 가지며 접근가능한 소공의 개구가 10개의 산소 원자에 의해 한정되고 소공 개구간의 브리지(bridge)폭에 상응하는 거리가 0.70㎚ 이하인 하나 이상의 분자체를 포함하는 촉매와 접촉시키며, 상기 촉매는 표준 n-헵타데칸 테스트로 시험하였을 때 95%의 전환율에 대하여 이성질체화된 생성물에 대해 70% 이상의 선택율을 갖는 방법.
제1항에 있어서, 상기 브리지 폭이 0.50㎚ 내지 0.68㎚ 범위인 방법.
제1항 또는 제2항에 있어서, 상기 브리지 폭이 0.52㎚ 내지 0.65㎚ 범위인 방법.
제1항 내지 제3항 중 어느 한 항에 있어서, 상기 분자체가 2㎛ 이하의 소결정 크기를 갖는 방법.
제1항 내지 제4항 중 어느 한 항에 있어서, 상기 분자체가 1㎛ 이하의 소결정 크기를 갖는 방법.
제1항 내지 제5항 중 어느 한 항에 있어서, 상기 분자체가 0.4㎛ 이하의 소결정 크기를 갖는 방법.
제1항 내지 제6항 중 어느 한 항에 있어서, 상기 분자체가 NU-10인 방법.
제1항 내지 제6항 중 어느 한 항에 있어서, 상기 분자체가 NU-23인 방법.
제1항 내지 제6항 중 어느 한 항에 있어서, 상기 분자체가 NU-87인 방법.
제1항 내지 제6항 중 어느 한 항에 있어서, 상기 분자체가 Theta-1인 방법.
제1항 내지 제6항 중 어느 한 항에 있어서, 상기 분자체가 EU-23인 방법.
제7항 내지 제11항 중 어느 한 항에 있어서, 상기 분자체가 붕소, 철, 갈륨 및/또는 아연 원자를 함유하는 방법.
제1항 내지 제12항 중 어느 한 항에 있어서, 상기 가수소-탈수소 성분이 Ⅷ족 금속, ⅥB족 금속, 레늄 및 니오븀으로 이루어진 군중에서 선택되는 방법.
제1항 내지 제13항 중 어느 한 항에 있어서, 상기 촉매가 매트릭스, 0.5-99.9중량%의 분자체(매트릭스와 분자체의 혼합물을 기준으로 함) 및 5중량%이하의 가수소-탈수소 금속(들)(분자체를 기준으로 함)를 함유하는 방법.
제14항에 있어서, 상기 촉매가 10 내지 90중량%(매트릭스와 분자체의 혼합물을 기준으로 함)의 분자체를 함유하는 방법.
제1항 내지 제15항 중 어느 한 항에 있어서, 압력이 1 바아 내지 250 바아 범위이고, 온도는 170℃ 내지 500℃ 범위이고, 시간당 공간 속도는 0.05h-1내지 100h-1범위이며, 수소 농도는 공급원료 1리터당 수소 50리터 내지 2000 리터 범위인 방법.
제16항에 있어서, 상기 온도가 180-450℃ 범위인 방법.
제16항 또는 제17항에 있어서, 상기 압력이 10 바아 내지 200 바아 범위인 방법.
제16항 내지 제18항 중 어느 한 항에 있어서, 수소 농도가 공급원료 1리터당 수소 100리터 내지 1500리터 범위인 방법.
제1항 내지 제19항 중 어느 한 항에 있어서, 처리하고자 하는 화합물이 N-알칸, n-알킬시클로알칸 및 하나 이상의 방향족 기를 함유하는 화합물로 이루어진 군중에서 선택되는 방법.
제1항 내지 제20항 중 어느 한 항에 있어서, 처리하고자 하는 화합물이 175℃ 이상의 초기 비등점을 가진 공급원료내에 존재하는 방법.
제1항 내지 제21항 중 어느 한 항에 있어서, 처리하고자 하는 화합물이 380℃ 이상의 초기 비등점을 가진 공급원료내에 존재하는 방법.
제1항 내지 제22항 중 어느 한 항에 있어서, 처리하고자 하는 화합물이 15 내지 50개의 탄소원자를 함유하는 n-알칸 연쇄를 포함하는 방법.
제1항 내지 제23항 중 어느 한 항에 있어서, 처리하고자 하는 화합물이 15 내지 40개의 탄소원자를 함유하는 n-알칸 연쇄를 포함하는 방법.
제1항 내지 제24항 중 어느 한 항에 있어서, 처리하고자 하는 화합물이 중간 증류생성물, 진공 잔류물, 가수소분해 잔류물, 피셔-트롭쉬 방법으로부터 유래한 파리핀, 합성된 오일, 가스유 유분, FCC로부터의 중간 증류생성물, 윤활제 원료, 및 폴리알파올레핀으로 이루어진 군중에서 선택된 탄화수소 공급원료내에 존재하는 방법.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970702931A 1995-09-06 1996-09-05 분자체 촉매를 사용하여 직쇄 및/또는 소수의 분지쇄를 갖는 고급 파라핀의 선택적 수소화 이성질화 방법 KR100449389B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR9510424A FR2738243B1 (fr) 1995-09-06 1995-09-06 Procede d'hydroisomerisation de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de zeolithe nu-10
FR9510425A FR2738244B1 (fr) 1995-09-06 1995-09-06 Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire
FR9510424 1995-09-06
FR9510425 1995-09-06

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KR100449389B1 KR100449389B1 (ko) 2005-01-17

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EP (1) EP0789739B1 (ko)
JP (2) JPH10508900A (ko)
KR (1) KR100449389B1 (ko)
DE (1) DE69618923T2 (ko)
ES (1) ES2171715T3 (ko)
NO (1) NO315663B1 (ko)
WO (1) WO1997009397A1 (ko)

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NO315663B1 (no) 2003-10-06
ES2171715T3 (es) 2002-09-16
EP0789739A1 (fr) 1997-08-20
WO1997009397A1 (fr) 1997-03-13
US5990371A (en) 1999-11-23
NO972069L (no) 1997-07-04
NO972069D0 (no) 1997-05-05
JPH10508900A (ja) 1998-09-02
DE69618923T2 (de) 2002-11-14
EP0789739B1 (fr) 2002-01-30
KR100449389B1 (ko) 2005-01-17
DE69618923D1 (de) 2002-03-14
JP2009197234A (ja) 2009-09-03

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