DE69618485T2 - Verfahren zur herstellung von epoxidierungskatalysatoren - Google Patents
Verfahren zur herstellung von epoxidierungskatalysatorenInfo
- Publication number
- DE69618485T2 DE69618485T2 DE69618485T DE69618485T DE69618485T2 DE 69618485 T2 DE69618485 T2 DE 69618485T2 DE 69618485 T DE69618485 T DE 69618485T DE 69618485 T DE69618485 T DE 69618485T DE 69618485 T2 DE69618485 T2 DE 69618485T2
- Authority
- DE
- Germany
- Prior art keywords
- promoter
- catalyst
- amount
- support
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims description 138
- 238000006735 epoxidation reaction Methods 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title description 8
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- 239000004332 silver Substances 0.000 claims description 53
- 229910052702 rhenium Inorganic materials 0.000 claims description 43
- 229910052783 alkali metal Inorganic materials 0.000 claims description 41
- 150000001340 alkali metals Chemical class 0.000 claims description 41
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 39
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 30
- 150000002910 rare earth metals Chemical class 0.000 claims description 29
- 150000003839 salts Chemical class 0.000 claims description 29
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 26
- 229910052723 transition metal Inorganic materials 0.000 claims description 26
- 150000003624 transition metals Chemical class 0.000 claims description 24
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 22
- -1 allyl hydrogen Chemical class 0.000 claims description 22
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 17
- 229910052792 caesium Inorganic materials 0.000 claims description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 13
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 8
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- 239000010937 tungsten Substances 0.000 claims description 8
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
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- 239000011574 phosphorus Substances 0.000 claims description 4
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- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
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- 229910052691 Erbium Inorganic materials 0.000 claims description 3
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- 239000011591 potassium Substances 0.000 claims description 3
- 229910052701 rubidium Inorganic materials 0.000 claims description 3
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- 229910052763 palladium Inorganic materials 0.000 claims description 2
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- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 49
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- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/540,233 US5739075A (en) | 1995-10-06 | 1995-10-06 | Process for preparing ethylene oxide catalysts |
| PCT/EP1996/004298 WO1997013579A1 (en) | 1995-10-06 | 1996-10-02 | Process for preparing epoxidation catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69618485D1 DE69618485D1 (de) | 2002-02-14 |
| DE69618485T2 true DE69618485T2 (de) | 2002-08-01 |
Family
ID=24154573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69618485T Expired - Fee Related DE69618485T2 (de) | 1995-10-06 | 1996-10-02 | Verfahren zur herstellung von epoxidierungskatalysatoren |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5739075A (enExample) |
| EP (1) | EP0874688B1 (enExample) |
| JP (1) | JP3961568B2 (enExample) |
| AU (1) | AU7284396A (enExample) |
| CA (1) | CA2232942C (enExample) |
| DE (1) | DE69618485T2 (enExample) |
| ES (1) | ES2166468T3 (enExample) |
| WO (1) | WO1997013579A1 (enExample) |
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|---|---|---|---|---|
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| US5861519A (en) * | 1997-05-23 | 1999-01-19 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters |
| US6383974B1 (en) * | 1997-08-26 | 2002-05-07 | Japan Energy Corporation | Hydrorefining catalyst and method for manufacturing hydrorefining catalyst |
| US6812180B2 (en) * | 1997-12-10 | 2004-11-02 | Idemitsu Kosan Co., Ltd. | Method for preparing catalyst |
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| US7504525B2 (en) * | 1998-09-14 | 2009-03-17 | Shell Oil Company | Catalyst composition |
| TR200100749T2 (tr) * | 1998-09-14 | 2001-10-22 | Shell Internationale Research Maatschappij B.V. | Epoksitleme katalizörü taşıyıcı, bunun hazırlanması ve kullanılması |
| CA2343783C (en) * | 1998-09-14 | 2008-02-12 | Shell Internationale Research Maatschappij B.V. | Process for removing ionizable species from catalyst surface to improve catalytic properties |
| US20070066480A1 (en) * | 1999-10-25 | 2007-03-22 | Moser William R | Method of preparing compounds using cavitation and compounds formed therefrom |
| WO2001051202A1 (en) * | 2000-01-14 | 2001-07-19 | Worcester Polytechnic Institute | Method of preparing compounds using cavitation and compounds formed therefrom |
| US6403523B1 (en) * | 2000-09-18 | 2002-06-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for the oxidative dehydrogenation of hydrocarbons |
| DE10048844A1 (de) * | 2000-10-02 | 2002-04-11 | Basf Ag | Verfahren zur Herstellung von Platinmetall-Katalysatoren |
| US7193094B2 (en) * | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| US6831037B2 (en) * | 2002-02-25 | 2004-12-14 | Saint-Gobain Norpro Corporation | Catalyst carriers |
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| RU2342993C2 (ru) | 2003-05-07 | 2009-01-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Катализаторы, содержащие серебро, получение таких катализаторов и их применение |
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-
1995
- 1995-10-06 US US08/540,233 patent/US5739075A/en not_active Expired - Fee Related
-
1996
- 1996-10-02 WO PCT/EP1996/004298 patent/WO1997013579A1/en not_active Ceased
- 1996-10-02 DE DE69618485T patent/DE69618485T2/de not_active Expired - Fee Related
- 1996-10-02 ES ES96934517T patent/ES2166468T3/es not_active Expired - Lifetime
- 1996-10-02 EP EP96934517A patent/EP0874688B1/en not_active Expired - Lifetime
- 1996-10-02 JP JP51468497A patent/JP3961568B2/ja not_active Expired - Fee Related
- 1996-10-02 CA CA002232942A patent/CA2232942C/en not_active Expired - Fee Related
- 1996-10-02 AU AU72843/96A patent/AU7284396A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP3961568B2 (ja) | 2007-08-22 |
| CA2232942C (en) | 2005-01-04 |
| ES2166468T3 (es) | 2002-04-16 |
| US5739075A (en) | 1998-04-14 |
| EP0874688B1 (en) | 2002-01-09 |
| DE69618485D1 (de) | 2002-02-14 |
| AU7284396A (en) | 1997-04-30 |
| EP0874688A1 (en) | 1998-11-04 |
| JPH11513305A (ja) | 1999-11-16 |
| CA2232942A1 (en) | 1997-04-17 |
| WO1997013579A1 (en) | 1997-04-17 |
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