DE69605765T3 - Aliphatische Harze auf Petroleumbasis und druckempfindliche Schmelzklebstoffe, die diese enthalten. - Google Patents
Aliphatische Harze auf Petroleumbasis und druckempfindliche Schmelzklebstoffe, die diese enthalten. Download PDFInfo
- Publication number
- DE69605765T3 DE69605765T3 DE69605765T DE69605765T DE69605765T3 DE 69605765 T3 DE69605765 T3 DE 69605765T3 DE 69605765 T DE69605765 T DE 69605765T DE 69605765 T DE69605765 T DE 69605765T DE 69605765 T3 DE69605765 T3 DE 69605765T3
- Authority
- DE
- Germany
- Prior art keywords
- resin
- weight
- pressure sensitive
- hot melt
- sensitive adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920005989 resin Polymers 0.000 title claims description 163
- 239000011347 resin Substances 0.000 title claims description 163
- 239000003208 petroleum Substances 0.000 title claims description 43
- 125000001931 aliphatic group Chemical group 0.000 title claims description 38
- 239000004831 Hot glue Substances 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims description 57
- 239000012943 hotmelt Substances 0.000 claims description 37
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 36
- 125000003118 aryl group Chemical group 0.000 claims description 31
- 229920000642 polymer Polymers 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 23
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 21
- 239000004606 Fillers/Extenders Substances 0.000 claims description 13
- 230000001070 adhesive effect Effects 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 11
- 238000005160 1H NMR spectroscopy Methods 0.000 claims description 10
- 229920001400 block copolymer Polymers 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims description 9
- ARPPLBPJWJEDIJ-UHFFFAOYSA-N aniline;methylcyclohexane Chemical compound CC1CCCCC1.NC1=CC=CC=C1 ARPPLBPJWJEDIJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 230000000171 quenching effect Effects 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 32
- 125000004122 cyclic group Chemical group 0.000 description 26
- 239000003054 catalyst Substances 0.000 description 21
- 238000006116 polymerization reaction Methods 0.000 description 21
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 18
- 239000000155 melt Substances 0.000 description 16
- 229920002633 Kraton (polymer) Polymers 0.000 description 15
- 239000003921 oil Substances 0.000 description 14
- 239000012986 chain transfer agent Substances 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 7
- 150000001993 dienes Chemical class 0.000 description 7
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 7
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 6
- 239000013032 Hydrocarbon resin Substances 0.000 description 6
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 6
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 6
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 6
- 229920006270 hydrocarbon resin Polymers 0.000 description 6
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 5
- 238000005481 NMR spectroscopy Methods 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 239000003849 aromatic solvent Substances 0.000 description 5
- 239000000539 dimer Substances 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- -1 cyclic diolefins Chemical class 0.000 description 4
- 150000001925 cycloalkenes Chemical class 0.000 description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 4
- 229920001195 polyisoprene Polymers 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 229920000428 triblock copolymer Polymers 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000012442 inert solvent Substances 0.000 description 3
- NFWSQSCIDYBUOU-UHFFFAOYSA-N methylcyclopentadiene Chemical compound CC1=CC=CC1 NFWSQSCIDYBUOU-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PMJHHCWVYXUKFD-PLNGDYQASA-N (3z)-penta-1,3-diene Chemical compound C\C=C/C=C PMJHHCWVYXUKFD-PLNGDYQASA-N 0.000 description 2
- QMMOXUPEWRXHJS-HWKANZROSA-N (e)-pent-2-ene Chemical compound CC\C=C\C QMMOXUPEWRXHJS-HWKANZROSA-N 0.000 description 2
- QMMOXUPEWRXHJS-HYXAFXHYSA-N (z)-pent-2-ene Chemical compound CC\C=C/C QMMOXUPEWRXHJS-HYXAFXHYSA-N 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000006471 dimerization reaction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- JJHTYXOJDCGTIH-UHFFFAOYSA-H [Al+3].[Al+3].[Cl-].[Cl-].[Cl-].[Br-].[Br-].[Br-] Chemical compound [Al+3].[Al+3].[Cl-].[Cl-].[Cl-].[Br-].[Br-].[Br-] JJHTYXOJDCGTIH-UHFFFAOYSA-H 0.000 description 1
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 235000012171 hot beverage Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- UCMSRHPIFRZHDO-FXRZFVDSSA-N penta-1,3-diene (3E)-penta-1,3-diene Chemical compound CC=CC=C.C\C=C\C=C UCMSRHPIFRZHDO-FXRZFVDSSA-N 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 1
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 210000002023 somite Anatomy 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F240/00—Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
- Y10T428/2883—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer of diene monomer [e.g., SBR, SIS, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesive Tapes (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96103478A EP0794202B2 (en) | 1996-03-06 | 1996-03-06 | Aliphatic petroleum-based resins and hot melt pressure sentitive adhesive containing same |
| US08/813,969 US6106939A (en) | 1996-03-06 | 1997-03-03 | Aliphatic petroleum-based resins having controlled softening points and molecular weights and hot melt pressure sensitive adhesive containing same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE69605765D1 DE69605765D1 (de) | 2000-01-27 |
| DE69605765T2 DE69605765T2 (de) | 2000-06-08 |
| DE69605765T3 true DE69605765T3 (de) | 2004-09-30 |
Family
ID=26141790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69605765T Expired - Fee Related DE69605765T3 (de) | 1996-03-06 | 1996-03-06 | Aliphatische Harze auf Petroleumbasis und druckempfindliche Schmelzklebstoffe, die diese enthalten. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6106939A (enExample) |
| EP (1) | EP0794202B2 (enExample) |
| JP (1) | JP4054084B2 (enExample) |
| CN (1) | CN1165829A (enExample) |
| CA (1) | CA2199331A1 (enExample) |
| DE (1) | DE69605765T3 (enExample) |
| ES (1) | ES2139969T3 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0936229B1 (en) * | 1998-02-12 | 2004-04-28 | Eastman Chemical Resins, Inc. | Process for the preparation of aromatic modified aliphatic hydrocarbon resins giving an excellent balance between tack and shear properties |
| US6180229B1 (en) | 1998-06-17 | 2001-01-30 | H. B. Fuller Licensing & Financing, Inc. | Hot melt pressure sensitive adhesive composition useful for contact coating on heat sensitive substrates |
| US6162859A (en) * | 1999-06-07 | 2000-12-19 | National Starch And Chemical Investment Holding Corporation | Hot melt pressure sensitive adhesives based on compatibilized blends of elastomers |
| KR100408222B1 (ko) * | 2000-10-30 | 2003-12-01 | 주식회사 에벡스 | 이브이에이 수지를 이용한 핫멜트 접착필름 |
| KR100856602B1 (ko) * | 2001-01-18 | 2008-09-03 | 크레이튼 폴리머즈 리서치 비.브이. | 접착제 조성물 |
| US20060263420A1 (en) * | 2005-03-10 | 2006-11-23 | Hisamitsu Pharmaceutical Co., Inc. | Adhesive and plaster |
| US20060229411A1 (en) * | 2005-04-06 | 2006-10-12 | Stephen Hatfield | Hot melt pressure sensitive adhesives based on blends of styrene/butadiene copolymers |
| JP2010132761A (ja) * | 2008-12-04 | 2010-06-17 | Tosoh Corp | 粘着剤組成物 |
| US8946365B2 (en) | 2012-01-18 | 2015-02-03 | Eastman Chemical Company | Low molecular weight polystyrene resin and methods of making and using the same |
| CN102618194A (zh) * | 2012-04-13 | 2012-08-01 | 佛山南宝高盛高新材料有限公司 | 高速自动贴标用的热熔压敏胶及其制备方法 |
| JP6102436B2 (ja) * | 2013-03-31 | 2017-03-29 | 日本ゼオン株式会社 | 炭化水素樹脂およびホットメルト粘接着剤組成物 |
| JP6676542B2 (ja) | 2014-01-17 | 2020-04-08 | ボスティック，インコーポレイテッド | ホットメルトポジショニング接着剤 |
| CN106279538A (zh) * | 2015-09-25 | 2017-01-04 | 中国石油化工股份有限公司 | 适用于c5石油树脂加氢过程的脱氯方法及装置 |
| CN108779195B (zh) * | 2016-03-31 | 2020-10-16 | 日本瑞翁株式会社 | 改性烃树脂及热熔粘接剂组合物 |
| CN106279539A (zh) * | 2016-06-03 | 2017-01-04 | 中国石油化工股份有限公司 | 石油树脂加氢过程脱硫、脱氯的工业方法 |
| JP6801512B2 (ja) * | 2017-02-27 | 2020-12-16 | 日本ゼオン株式会社 | 変性炭化水素樹脂およびホットメルト粘接着剤組成物 |
| KR102160602B1 (ko) * | 2017-12-27 | 2020-09-28 | 한화솔루션 주식회사 | 탄화수소 함유 용액 내의 방향족 함량의 측정 방법 |
| EP3783078B1 (en) | 2018-04-18 | 2023-08-09 | Mitsui Chemicals, Inc. | Tackifier and hot melt adhesive composition |
| KR102334253B1 (ko) * | 2018-04-27 | 2021-12-01 | 한화솔루션 주식회사 | 핫멜트 접착제 |
| WO2021153417A1 (ja) * | 2020-01-31 | 2021-08-05 | 日本ゼオン株式会社 | 粘接着剤組成物 |
| WO2022163395A1 (ja) * | 2021-01-28 | 2022-08-04 | 日本ゼオン株式会社 | 炭化水素樹脂およびホットメルト粘接着剤組成物 |
| JP7771988B2 (ja) * | 2021-01-28 | 2025-11-18 | 日本ゼオン株式会社 | 炭化水素樹脂およびホットメルト粘接着剤組成物 |
| WO2024095878A1 (ja) * | 2022-11-01 | 2024-05-10 | 荒川化学工業株式会社 | 熱可塑性樹脂用の改質剤、樹脂組成物、水素化芳香族系炭化水素樹脂の使用、粘着付与剤及び粘・接着剤組成物 |
| WO2024095880A1 (ja) * | 2022-11-01 | 2024-05-10 | 荒川化学工業株式会社 | 熱可塑性樹脂用の改質剤、樹脂組成物及び水素化芳香族系炭化水素樹脂の使用 |
| JPWO2024095883A1 (enExample) * | 2022-11-01 | 2024-05-10 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951928A (en) * | 1972-12-04 | 1976-04-20 | Imperial Chemical Industries Limited | Petroleum resins |
| US4130704A (en) † | 1974-08-06 | 1978-12-19 | Toyo Soda Manufacturing Co., Ltd. | Process for producing sulfur modified polychloroprene in the presence of quaternary ammonium salts |
| US4680333A (en) * | 1986-04-14 | 1987-07-14 | National Starch And Chemical Corporation | Removable hot melt pressure sensitive adhesive |
| GB8925685D0 (en) * | 1989-11-14 | 1990-01-04 | Exxon Chemical Patents Inc | Resin use for tackification |
| CN1089792C (zh) * | 1993-12-15 | 2002-08-28 | 埃克森美孚化学专利公司 | 低粘度热熔体压敏粘合剂组合物 |
-
1996
- 1996-03-06 ES ES96103478T patent/ES2139969T3/es not_active Expired - Lifetime
- 1996-03-06 EP EP96103478A patent/EP0794202B2/en not_active Expired - Lifetime
- 1996-03-06 DE DE69605765T patent/DE69605765T3/de not_active Expired - Fee Related
-
1997
- 1997-03-03 US US08/813,969 patent/US6106939A/en not_active Expired - Lifetime
- 1997-03-06 CA CA002199331A patent/CA2199331A1/en not_active Abandoned
- 1997-03-06 JP JP05147297A patent/JP4054084B2/ja not_active Expired - Fee Related
- 1997-03-06 CN CN97109517.5A patent/CN1165829A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09328524A (ja) | 1997-12-22 |
| DE69605765T2 (de) | 2000-06-08 |
| CA2199331A1 (en) | 1997-09-06 |
| US6106939A (en) | 2000-08-22 |
| EP0794202B1 (en) | 1999-12-22 |
| ES2139969T3 (es) | 2000-02-16 |
| EP0794202B2 (en) | 2004-03-31 |
| JP4054084B2 (ja) | 2008-02-27 |
| CN1165829A (zh) | 1997-11-26 |
| EP0794202A1 (en) | 1997-09-10 |
| DE69605765D1 (de) | 2000-01-27 |
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| 8363 | Opposition against the patent | ||
| 8366 | Restricted maintained after opposition proceedings | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: EASTMAN CHEMICAL RESINS, INC., KINGSPORT, TENN., U |
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| 8339 | Ceased/non-payment of the annual fee |