DE69212183D1 - Verfahren und Katalysator zum Fluorieren - Google Patents

Verfahren und Katalysator zum Fluorieren

Info

Publication number
DE69212183D1
DE69212183D1 DE69212183T DE69212183T DE69212183D1 DE 69212183 D1 DE69212183 D1 DE 69212183D1 DE 69212183 T DE69212183 T DE 69212183T DE 69212183 T DE69212183 T DE 69212183T DE 69212183 D1 DE69212183 D1 DE 69212183D1
Authority
DE
Germany
Prior art keywords
zinc
catalyst
chromium
activity
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69212183T
Other languages
English (en)
Other versions
DE69212183T2 (de
Inventor
John David Scott
Michael John Watson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Fluor Holdings Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of DE69212183D1 publication Critical patent/DE69212183D1/de
Publication of DE69212183T2 publication Critical patent/DE69212183T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00Acyclic saturated compounds containing halogen atoms
    • C07C19/08Acyclic saturated compounds containing halogen atoms containing fluorine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/26Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/21Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Glass Compositions (AREA)
DE69212183T 1991-03-07 1992-01-23 Verfahren und Katalysator zum Fluorieren Expired - Lifetime DE69212183T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB919104775A GB9104775D0 (en) 1991-03-07 1991-03-07 Fluorination catalyst and process

Publications (2)

Publication Number Publication Date
DE69212183D1 true DE69212183D1 (de) 1996-08-22
DE69212183T2 DE69212183T2 (de) 1996-12-05

Family

ID=10691125

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69233583T Expired - Lifetime DE69233583T2 (de) 1991-03-07 1992-01-23 Verfahren zum Fluorieren
DE69212183T Expired - Lifetime DE69212183T2 (de) 1991-03-07 1992-01-23 Verfahren und Katalysator zum Fluorieren

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE69233583T Expired - Lifetime DE69233583T2 (de) 1991-03-07 1992-01-23 Verfahren zum Fluorieren

Country Status (25)

Country Link
US (3) US5281568A (de)
EP (3) EP0502605B1 (de)
JP (1) JPH05220400A (de)
KR (1) KR100217353B1 (de)
CN (2) CN1064628A (de)
AT (2) ATE313377T1 (de)
AU (1) AU658161B2 (de)
CA (1) CA2059983C (de)
CS (1) CS17192A3 (de)
DE (2) DE69233583T2 (de)
DK (1) DK0502605T3 (de)
ES (2) ES2255705T3 (de)
FI (1) FI920273A (de)
GB (2) GB9104775D0 (de)
GR (1) GR3020970T3 (de)
HU (1) HUT63825A (de)
IE (1) IE75727B1 (de)
IN (1) IN185352B (de)
MY (1) MY108102A (de)
NO (1) NO920299L (de)
PL (1) PL293283A1 (de)
RU (1) RU2032464C1 (de)
SG (1) SG50565A1 (de)
YU (1) YU13292A (de)
ZA (1) ZA92396B (de)

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185482A (en) * 1989-02-03 1993-02-09 E. I. Du Pont De Nemours And Company Manufacture of 1,1,1,2-tetrafluoroethane
IT1230779B (it) * 1989-07-12 1991-10-29 Ausimont Srl Procedimento per preparare 1,1,1,2 tetrafluoroetano.
GB9104775D0 (en) * 1991-03-07 1991-04-17 Ici Plc Fluorination catalyst and process
US5849658A (en) * 1991-05-24 1998-12-15 Daikin Industries Ltd. Method for preparing fluorination catalyst used to fluorinate halogenated hydrocarbons
GB9219720D0 (en) * 1992-09-17 1992-10-28 Ici Plc Catalyst production
GB9404715D0 (en) * 1993-03-24 1994-04-27 Ici Plc Production of difluoromethane
ES2111207T3 (es) * 1993-06-18 1998-03-01 Showa Denko Kk Catalizador de fluoracion y procedimiento de fluoracion.
CA2131361C (en) * 1993-09-07 2005-02-08 Katsuyuki Tsuji Chromium-based fluorination catalyst, process for producing the catalyst, and fluorination process using the catalyst
KR960010775B1 (ko) * 1993-12-01 1996-08-08 한국과학기술연구원 염화수소의 산화에 의한 염소제조용 염화세륨-삼산화이크롬 촉매 및 이의 제조방법
KR960016683B1 (en) * 1993-12-09 1996-12-20 Korea Inst Sci & Tech Method of producing fluorization catalyst for preparing 1,1,1,2-tetrafluoroethane
GB9406813D0 (en) * 1994-04-06 1994-05-25 Ici Plc Production of pentafluoroethane
US5494877A (en) * 1994-06-20 1996-02-27 Showa Denko K. K. Chromium-based fluorination catalyst containing gallium and production method thereof
GB9417116D0 (en) * 1994-08-24 1994-10-12 Ici Plc Process for the manufacture of pentafluoroethane
JP3558385B2 (ja) * 1994-10-13 2004-08-25 昭和電工株式会社 クロム系フッ素化触媒、及びフッ素化方法
KR0125143B1 (ko) * 1994-12-02 1997-11-27 김은영 1,1,1-트리플루오로-2,2-디클로로에탄의 불소화 촉매 및 그것의 제조방법
JP3853397B2 (ja) * 1995-05-11 2006-12-06 イネオス フラウアー ホールデイングス リミテッド ペンタフルオロエタンの製造方法及びペンタフルオロエタンに転化するのに適当な組成物
US5654494A (en) * 1995-08-18 1997-08-05 Alliedsignal Inc. Process for the manufacture of 1,1,1,2-tetrafluoroethane
KR0152580B1 (ko) * 1995-08-23 1998-10-15 김은영 1,1,1,2-테트라플루오로에탄, 펜타플루오로에탄 및 1,1,1-트리플루오로에탄의 병산 방법
FR2740994B1 (fr) 1995-11-10 1997-12-05 Atochem Elf Sa Catalyseurs massiques a base d'oxyde de chrome, leur procede de preparation et leur application a la fluoration d'hydrocarbures halogenes
US5864859A (en) * 1996-02-20 1999-01-26 International Business Machines Corporation System and method of compression and decompression using store addressing
EP0925112A1 (de) * 1996-09-10 1999-06-30 Imperial Chemical Industries Plc Verfahren und katalisator zum fluorieren
US6172270B1 (en) 1997-04-23 2001-01-09 Asahi Glass Company, Ltd. Process for producing halogenated hydrocarbons
AU8228998A (en) * 1997-07-31 1999-02-22 Imperial Chemical Industries Plc Vapour phase preparation of 1,1,1,2,3,3,3-heptafluoropropane
JP3552887B2 (ja) * 1997-10-09 2004-08-11 ダイキン工業株式会社 1,1,1,2,2−ペンタフルオロエタンの製造方法
JP3520900B2 (ja) * 1997-12-12 2004-04-19 ダイキン工業株式会社 ペンタフルオロエタンの製造方法、並びにフッ素化用触媒及びその製造方法
AU777841B2 (en) * 2000-03-31 2004-11-04 Council Of Scientific And Industrial Research A process for the preparation of 1,1,1,2-tetrafluoroethane
US7485598B2 (en) * 2006-06-21 2009-02-03 Arkema Inc. High pressure catalyst activation method and catalyst produced thereby
RU2004102799A (ru) * 2001-06-28 2005-06-27 Хонейвелл Интернэшнл, Инк. (Us) Способ получения катализатора фторирования
FR2828193B1 (fr) 2001-08-03 2004-04-02 Atofina Nouveau procede de preparation du 1,1,1,-trifluoro-2,2-dichloroethane
CA2539933A1 (en) * 2003-10-14 2005-04-28 E.I. Du Pont De Nemours And Company Process for the preparation of 1,1,1,3,3,3-hexafluoropropane and at least one of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2,3,3,3-heptafluoropropane
US7285690B2 (en) 2003-10-14 2007-10-23 E.I. Du Pont De Nemours And Company Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,3,3,3-hexafluoropropane
JP2007508140A (ja) * 2003-10-14 2007-04-05 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 亜鉛を含有するクロム酸化物組成物、それらの調製、ならびにそれらの触媒および触媒前駆体としての使用
WO2005037743A1 (en) * 2003-10-14 2005-04-28 E.I. Dupont De Nemours And Company Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropane
WO2005058489A1 (en) * 2003-12-16 2005-06-30 E.I. Dupont De Nemours And Company Selective chromium catalyst compositions, their preparation and use for producing 1,1,2-trichloropentafluoropropane
CN100372607C (zh) * 2004-12-23 2008-03-05 西安近代化学研究所 氟化催化剂及其制造方法和用途
DE102005012632A1 (de) * 2005-03-18 2006-09-21 Infineon Technologies Ag Verfahren und Schaltungsanordnung zur geschützten Übertragung von Datenworten
GB0507139D0 (en) 2005-04-08 2005-05-18 Ineos Fluor Holdings Ltd Catalyst
CN1911512B (zh) * 2005-07-07 2011-12-07 独立行政法人产业技术综合研究所 氟化催化剂及其制备方法、以及使用了该催化剂的氟化合物的制备方法
CN100434166C (zh) * 2005-09-09 2008-11-19 北京宇极科技发展有限公司 氢氟烃的制备工艺及其专用催化剂的制备方法
CN100427207C (zh) * 2005-09-12 2008-10-22 山东东岳化工有限公司 用于气相法生产1,1一二氟乙烷的催化剂
CN1308072C (zh) * 2005-09-30 2007-04-04 山东东岳化工有限公司 一种用于1,1,1,2-四氟乙烷的铁系铬基催化剂
GB0525701D0 (en) 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525700D0 (en) 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525699D0 (en) 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0806422D0 (en) 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
KR101394583B1 (ko) * 2006-10-03 2014-05-12 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 탄소수 3-6의 (하이드로)플루오로알켄의 생성을 위한 탈수소할로겐화 방법
GB0625214D0 (en) 2006-12-19 2007-01-24 Ineos Fluor Holdings Ltd Process
GB0706978D0 (en) 2007-04-11 2007-05-16 Ineos Fluor Holdings Ltd Process
GB0721991D0 (en) * 2007-11-09 2007-12-19 Ineos Fluor Holdings Ltd Preparation method
GB0806419D0 (en) * 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
GB0806389D0 (en) 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
GB0808836D0 (en) 2008-05-15 2008-06-18 Ineos Fluor Ltd Process
GB0816208D0 (en) * 2008-09-05 2008-10-15 Ineos Fluor Holdings Ltd Catlyst and process using the catalyst
KR101343618B1 (ko) * 2008-09-05 2013-12-19 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 불소화 촉매 및 불소화된 탄화수소의 제조방법
GB0906191D0 (en) 2009-04-09 2009-05-20 Ineos Fluor Holdings Ltd Process
US8158549B2 (en) * 2009-09-04 2012-04-17 Honeywell International Inc. Catalysts for fluoroolefins hydrogenation
US9340473B2 (en) 2011-01-21 2016-05-17 Arkema France Catalytic gas phase fluorination
JP6165061B2 (ja) * 2011-01-21 2017-07-19 アルケマ フランス 気相触媒フッ素化
GB2492847A (en) 2011-07-15 2013-01-16 Mexichem Amanco Holding Sa A process for reducing TFMA content in R-1234
DK2766117T3 (en) * 2011-10-12 2018-06-25 Bayer Ip Gmbh CATALYTIC GAS PHASE FLUORATION OF 1,1,2-TRICHLORETHANE AND / OR 1,2-DICHLORETHANE TO PREPARE 1-CHLOR-2,2-DIFLUORETHANE
GB2540427B (en) 2015-07-17 2017-07-19 Mexichem Fluor Sa De Cv Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf)
GB2540428B (en) 2015-07-17 2017-09-13 Mexichem Fluor Sa De Cv Process for preparing 3,3,3-trifluoropropene
GB2559056B (en) 2015-07-17 2019-09-11 Mexichem Fluor Sa De Cv Process for preparing 245cb and 1234yf from 243db
CN105688890B (zh) * 2016-02-01 2019-03-01 乳源东阳光氟有限公司 一种氟化催化剂及其制备方法
FR3055221B1 (fr) * 2016-08-29 2023-12-15 Arkema France Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse
GB201615197D0 (en) 2016-09-07 2016-10-19 Mexichem Fluor Sa De Cv Catalyst and process using the catalyst
GB201615209D0 (en) 2016-09-07 2016-10-19 Mexichem Fluor Sa De Cv Catalyst and process using the catalyst
JP6753434B2 (ja) * 2018-06-13 2020-09-09 ダイキン工業株式会社 ジフルオロエチレンの製造方法
JP2021508668A (ja) * 2018-11-08 2021-03-11 福建永晶科技股▲ふん▼有限公司Fujian Yongjing Technology Co., Ltd 1,1,1−トリフルオロ−2−クロロエタン(HCFC−133a)及び/又はトリフルオロエチルアミン(TFEA)の新しい製造方法
GB2580623A (en) * 2019-01-17 2020-07-29 Mexichem Fluor Sa De Cv Method
JP7123958B2 (ja) * 2019-02-15 2022-08-23 福建永晶科技股▲ふん▼有限公司 フルオロアリール化合物及びその誘導体の新しい製造方法
JP7353013B2 (ja) 2019-08-29 2023-09-29 フジアン ヨンジン テクノロジー カンパニー リミテッド フルオロベンゼンおよびその触媒の製造プロセス
CN111604092B (zh) * 2020-06-16 2022-12-06 中国民航大学 一种铬单原子氟化催化剂的制备方法及其应用

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Also Published As

Publication number Publication date
CN1049647C (zh) 2000-02-23
IN185352B (de) 2001-01-06
CS17192A3 (en) 1992-09-16
DE69233583D1 (de) 2006-01-26
US5449656A (en) 1995-09-12
ZA92396B (en) 1992-11-25
HUT63825A (en) 1993-10-28
KR920017708A (ko) 1992-10-21
ATE313377T1 (de) 2006-01-15
CN1130615A (zh) 1996-09-11
FI920273A0 (fi) 1992-01-22
HU9200220D0 (en) 1992-05-28
IE920163A1 (en) 1992-09-09
ATE140399T1 (de) 1996-08-15
DE69212183T2 (de) 1996-12-05
CA2059983C (en) 2002-10-29
EP1350564A1 (de) 2003-10-08
CA2059983A1 (en) 1992-09-08
PL293283A1 (en) 1992-10-05
EP0502605A1 (de) 1992-09-09
US5623092A (en) 1997-04-22
EP0666105A2 (de) 1995-08-09
EP0502605B1 (de) 1996-07-17
NO920299D0 (no) 1992-01-22
US5281568A (en) 1994-01-25
DK0502605T3 (da) 1996-10-28
YU13292A (sh) 1994-09-09
KR100217353B1 (ko) 1999-09-01
NO920299L (no) 1992-09-08
JPH05220400A (ja) 1993-08-31
EP0666105B1 (de) 2005-12-21
IE75727B1 (en) 1997-09-24
MY108102A (en) 1996-08-15
FI920273A (fi) 1992-09-08
AU658161B2 (en) 1995-04-06
CN1064628A (zh) 1992-09-23
GB9104775D0 (en) 1991-04-17
SG50565A1 (en) 1998-07-20
GB9200841D0 (en) 1992-03-11
ES2089381T3 (es) 1996-10-01
EP0666105A3 (de) 1995-09-06
ES2255705T3 (es) 2006-07-01
AU1032492A (en) 1992-09-10
GR3020970T3 (en) 1996-12-31
RU2032464C1 (ru) 1995-04-10
DE69233583T2 (de) 2006-08-03

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Owner name: INEOS FLUOR HOLDINGS LTD., SOUTHAMPTON, HAMPSHIRE,