FR3055221B1 - Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse - Google Patents

Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse Download PDF

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Publication number
FR3055221B1
FR3055221B1 FR1657989A FR1657989A FR3055221B1 FR 3055221 B1 FR3055221 B1 FR 3055221B1 FR 1657989 A FR1657989 A FR 1657989A FR 1657989 A FR1657989 A FR 1657989A FR 3055221 B1 FR3055221 B1 FR 3055221B1
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France
Prior art keywords
oxyfluoride
compositions
preparation
gas phase
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FR1657989A
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English (en)
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FR3055221A1 (fr
Inventor
Anne Pigamo
Laurent Wendlinger
Dominique Garrait
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Arkema France SA
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Arkema France SA
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Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR1657989A priority Critical patent/FR3055221B1/fr
Priority to US16/324,806 priority patent/US10919824B2/en
Priority to EP17768838.9A priority patent/EP3504001B1/fr
Priority to CN201780052582.XA priority patent/CN109641205B/zh
Priority to PCT/FR2017/052286 priority patent/WO2018042114A1/fr
Publication of FR3055221A1 publication Critical patent/FR3055221A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/358—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/32—Regeneration or reactivation of catalysts comprising compounds of halogens
    • B01J35/30—
    • B01J35/612—
    • B01J35/613—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Abstract

La présente invention concerne un procédé de modification de la distribution en fluor dans un composé hydrocarbure en présence d'un catalyseur, caractérisée par l'utilisation comme catalyseur d'une composition solide comprenant au moins un composant contenant de l'oxyfluorure ou du fluorure de chrome de formule CrxM(1-x)OrFs, où 2r+s est supérieur ou égal à 2,9 et inférieur à 6, M est un métal choisi dans les colonnes 2 à 12 du tableau périodique des éléments, x vaut de 0,9 à 1, s est supérieur à 0 et inférieur ou égal à 6 et r est supérieur ou égal à 0 et inférieur à 3, ladite composition solide ayant une cristallinité inférieure à 20 % en poids. La présente invention se rapporte aussi à la composition solide per se.
FR1657989A 2016-08-29 2016-08-29 Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse Active FR3055221B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1657989A FR3055221B1 (fr) 2016-08-29 2016-08-29 Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse
US16/324,806 US10919824B2 (en) 2016-08-29 2017-08-28 Compositions of chromium oxyfluoride or fluoride catalysts, their preparation and their use in gas-phase processes
EP17768838.9A EP3504001B1 (fr) 2016-08-29 2017-08-28 Procédé de modification de la distribution en fluor dans un composé hydrocarbure à l'aide d'une composition de catalyseur comprenant un oxyfluorure ou fluorure de chrome
CN201780052582.XA CN109641205B (zh) 2016-08-29 2017-08-28 氧氟化铬或氟化铬催化剂的组合物、制备以及其在气相方法中的用途
PCT/FR2017/052286 WO2018042114A1 (fr) 2016-08-29 2017-08-28 Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1657989 2016-08-29
FR1657989A FR3055221B1 (fr) 2016-08-29 2016-08-29 Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse

Publications (2)

Publication Number Publication Date
FR3055221A1 FR3055221A1 (fr) 2018-03-02
FR3055221B1 true FR3055221B1 (fr) 2023-12-15

Family

ID=57045205

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1657989A Active FR3055221B1 (fr) 2016-08-29 2016-08-29 Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse

Country Status (5)

Country Link
US (1) US10919824B2 (fr)
EP (1) EP3504001B1 (fr)
CN (1) CN109641205B (fr)
FR (1) FR3055221B1 (fr)
WO (1) WO2018042114A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7166889B2 (ja) * 2018-11-20 2022-11-08 ダイキン工業株式会社 １，２－ジフルオロエチレンの製造方法
CN113527049A (zh) * 2020-04-22 2021-10-22 陕西中蓝化工科技新材料有限公司 一种反式/顺式-HFO-1234ze和HFO-1234yf的联产制备工艺
CN114054052B (zh) * 2021-12-03 2023-11-03 湖南有色郴州氟化学有限公司 一种氟氧化铬催化氧化去除氨氮的方法

Family Cites Families (30)

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Publication number Priority date Publication date Assignee Title
GB9104775D0 (en) 1991-03-07 1991-04-17 Ici Plc Fluorination catalyst and process
GB9219720D0 (en) * 1992-09-17 1992-10-28 Ici Plc Catalyst production
CA2263711A1 (fr) 1996-09-10 1998-03-19 Imperial Chemical Industries Plc Catalyseur et procede de fluoration
EP0957074B2 (fr) 1997-04-23 2006-01-11 Asahi Glass Company Ltd. Procede de production d'hydrocarbures halogenes
CN1867402B (zh) * 2003-10-14 2010-04-28 纳幕尔杜邦公司 含锌的氧化铬组合物、它们的制备以及它们作为催化剂和催化剂前体的用途
WO2007019353A1 (fr) 2005-08-05 2007-02-15 E. I. Du Pont De Nemours And Company Procede de preparation de 1,1,1,3,3-pentafluoropropane et de 1,1,1,2,3-pentafluoropropane
MX337217B (es) 2006-10-03 2016-02-18 Mexichem Amanco Holding Sa Procedimiento de dehidrogenacion-halogenacion para la produccion de (hidro)fluoroalquenos de c3-c6.
GB0806422D0 (en) 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
US20080207962A1 (en) * 2007-02-23 2008-08-28 Velliyur Nott Mallikarjuna Rao Compositions containing chromium, oxygen, and at least two modifier metals selected the group consisting of gold, silver, and palladium, their preparation, and their use as catalysts and catalyst precursors
GB0706978D0 (en) 2007-04-11 2007-05-16 Ineos Fluor Holdings Ltd Process
GB0721991D0 (en) 2007-11-09 2007-12-19 Ineos Fluor Holdings Ltd Preparation method
JP4849058B2 (ja) * 2007-11-21 2011-12-28 ダイキン工業株式会社 含フッ素オレフィンの製造方法
GB0806419D0 (en) 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
GB0806389D0 (en) 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
GB0808836D0 (en) 2008-05-15 2008-06-18 Ineos Fluor Ltd Process
JP2011525925A (ja) 2008-06-26 2011-09-29 アーケマ・インコーポレイテッド １２３０ｘａから１２３４ｙｆへの触媒的気相フッ素化
EP2318338B8 (fr) 2008-07-29 2013-12-18 Daikin Industries, Ltd. Procédé de préparation de propène fluoré par fluoration en phase gazeuse
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JP2013523882A (ja) * 2010-04-14 2013-06-17 アーケマ・インコーポレイテッド テトラフルオロオレフィンを製造するための方法
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FR3010996B1 (fr) * 2013-09-24 2015-09-25 Arkema France Procede de fluoration en phase gaz
FR3012137B1 (fr) * 2013-10-17 2016-09-16 Arkema France Procede de production de composes fluores
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KR20210057723A (ko) 2018-09-17 2021-05-21 셰브론 필립스 케미컬 컴퍼니 엘피 개질된 담지 크롬 촉매 및 이로부터 제조된 에틸렌계 중합체
GB2580623A (en) 2019-01-17 2020-07-29 Mexichem Fluor Sa De Cv Method

Also Published As

Publication number Publication date
FR3055221A1 (fr) 2018-03-02
CN109641205B (zh) 2022-08-02
US10919824B2 (en) 2021-02-16
CN109641205A (zh) 2019-04-16
WO2018042114A1 (fr) 2018-03-08
EP3504001B1 (fr) 2022-10-19
EP3504001A1 (fr) 2019-07-03
US20190169102A1 (en) 2019-06-06

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