DE69212121T2 - Verfahren und Vorrichtung zur Herstellung von Synthesegas und deren Anwendung - Google Patents
Verfahren und Vorrichtung zur Herstellung von Synthesegas und deren AnwendungInfo
- Publication number
- DE69212121T2 DE69212121T2 DE69212121T DE69212121T DE69212121T2 DE 69212121 T2 DE69212121 T2 DE 69212121T2 DE 69212121 T DE69212121 T DE 69212121T DE 69212121 T DE69212121 T DE 69212121T DE 69212121 T2 DE69212121 T2 DE 69212121T2
- Authority
- DE
- Germany
- Prior art keywords
- fuel
- process according
- oxygen
- combustion chamber
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 20
- 230000015572 biosynthetic process Effects 0.000 title claims description 12
- 238000003786 synthesis reaction Methods 0.000 title claims description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 44
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 33
- 238000002485 combustion reaction Methods 0.000 claims description 33
- 239000001301 oxygen Substances 0.000 claims description 33
- 229910052760 oxygen Inorganic materials 0.000 claims description 33
- 239000000446 fuel Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 25
- 239000007800 oxidant agent Substances 0.000 claims description 24
- 230000003197 catalytic effect Effects 0.000 claims description 23
- 239000007789 gas Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 229930195733 hydrocarbon Natural products 0.000 claims description 19
- 150000002430 hydrocarbons Chemical class 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 230000036961 partial effect Effects 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 238000007084 catalytic combustion reaction Methods 0.000 claims description 2
- 230000007812 deficiency Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 235000011089 carbon dioxide Nutrition 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 31
- 239000003054 catalyst Substances 0.000 description 28
- 229910002092 carbon dioxide Inorganic materials 0.000 description 21
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 11
- 239000003345 natural gas Substances 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 239000001569 carbon dioxide Substances 0.000 description 7
- 238000002407 reforming Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 238000001994 activation Methods 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000004071 soot Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 150000004645 aluminates Chemical class 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000036284 oxygen consumption Effects 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005262 decarbonization Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
- B01J8/0484—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being placed next to each other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0405—Apparatus
- C07C1/041—Reactors
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9115060A FR2684313B1 (fr) | 1991-12-03 | 1991-12-03 | Procede et dispositif pour la fabrication de gaz de synthese et application. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69212121D1 DE69212121D1 (de) | 1996-08-14 |
| DE69212121T2 true DE69212121T2 (de) | 1996-11-21 |
Family
ID=9419694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69212121T Expired - Fee Related DE69212121T2 (de) | 1991-12-03 | 1992-11-26 | Verfahren und Vorrichtung zur Herstellung von Synthesegas und deren Anwendung |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5755841A (OSRAM) |
| EP (1) | EP0545275B1 (OSRAM) |
| JP (1) | JP3748899B2 (OSRAM) |
| KR (1) | KR100245781B1 (OSRAM) |
| CA (1) | CA2084476C (OSRAM) |
| DE (1) | DE69212121T2 (OSRAM) |
| ES (1) | ES2092002T3 (OSRAM) |
| FR (1) | FR2684313B1 (OSRAM) |
| MY (1) | MY109757A (OSRAM) |
| RU (1) | RU2117626C1 (OSRAM) |
| TW (1) | TW239159B (OSRAM) |
| ZA (1) | ZA929307B (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004010014A1 (de) * | 2004-03-01 | 2005-09-29 | Webasto Ag | Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2726821B1 (fr) * | 1994-11-16 | 1997-01-03 | Patillet Henri | Procede et appareil de production de methanol par gazeification de matieres carbonees |
| JPH11130405A (ja) * | 1997-10-28 | 1999-05-18 | Ngk Insulators Ltd | 改質反応装置、触媒装置、それらに用いる発熱・触媒体、及び改質反応装置の運転方法 |
| DE69732781T2 (de) | 1997-11-28 | 2006-02-02 | Ammonia Casale S.A. | Verfahren zur in-situ Modernisierung eines heterogenen exothermen Synthesereaktors |
| JP2002193858A (ja) | 2000-12-28 | 2002-07-10 | Mitsubishi Heavy Ind Ltd | バイオマス原料によるメタノール製造方法及びその装置 |
| US6713657B2 (en) | 2002-04-04 | 2004-03-30 | Chevron U.S.A. Inc. | Condensation of olefins in fischer tropsch tail gas |
| JP2004075438A (ja) * | 2002-08-14 | 2004-03-11 | Toyo Eng Corp | 改質器 |
| US20040086432A1 (en) * | 2002-10-31 | 2004-05-06 | Labarge William J. | Reformer, systems utilizing the reformer, and methods for operating the systems |
| US7094730B2 (en) * | 2002-10-31 | 2006-08-22 | Delphi Technologies, Inc. | Gas treatment device, methods for making and using the same, and a vehicle exhaust system |
| RU2337874C2 (ru) * | 2003-03-06 | 2008-11-10 | ДжФЕ ХОЛДИНГЗ, ИНК. | Способ получения синтетического газа (синтез-газа), способ получения диметилового эфира с использованием синтез-газа (варианты) и печь для получения синтез-газа (варианты) |
| US20060120953A1 (en) | 2003-03-06 | 2006-06-08 | Keiichi Okuyama | Method for preparing synthesis gas, method for preparing dimethyl ether using synthesis gas, and furnace for preparing synthesis gas |
| FR2868413B1 (fr) * | 2004-04-01 | 2007-01-19 | Abderrezack Djenani | Procede de production de gaz de synthese, et une installation pour sa mise en oeuvre |
| GB0510514D0 (en) * | 2005-05-24 | 2005-06-29 | Johnson Matthey Plc | Steam reforming |
| DE102006039118B4 (de) * | 2006-08-21 | 2010-09-23 | Enerday Gmbh | Reformer |
| FR2918904B1 (fr) * | 2007-07-20 | 2011-07-15 | Inst Francais Du Petrole | Reacteur echangeur a tube baionnette permettant de fonctionner avec des differences de pression de l'ordre de 100 bars entre le cote tube et le cote calandre. |
| US20100187479A1 (en) * | 2009-01-23 | 2010-07-29 | Carbona Oy | Process and apparatus for reforming of heavy and light hydrocarbons from product gas of biomass gasification |
| CN102690169B (zh) * | 2012-05-25 | 2015-06-24 | 四川天一科技股份有限公司 | 一种焦炉气和转炉气联产甲醇和cng、lng的方法 |
| RU2513622C2 (ru) * | 2012-08-17 | 2014-04-20 | Общество С Ограниченной Ответственностью "Плазма-Про" | Способ микроволновый конверсии метан-водяной смеси в синтез-газ |
| US8697759B1 (en) * | 2012-10-09 | 2014-04-15 | University Of Southern California | Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming |
| RU2571149C1 (ru) * | 2014-06-09 | 2015-12-20 | Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" | Реактор конверсии метана |
| CN104177227B (zh) * | 2014-09-11 | 2016-01-20 | 四川天一科技股份有限公司 | 焦炉气和煤气制甲醇联产天然气的方法 |
| SE539758C2 (en) * | 2014-12-04 | 2017-11-21 | Powercell Sweden Ab | Catalytic burner arragement |
| KR20200002058A (ko) * | 2018-06-29 | 2020-01-08 | 주식회사 경동나비엔 | 개질장치 및 이를 구비한 연료전지 시스템 |
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| BE552748A (OSRAM) * | ||||
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| FR489995A (fr) * | 1917-08-14 | 1919-03-26 | Joergen Thomas Jensen | Bras et main artificiels |
| FR552748A (fr) * | 1922-06-10 | 1923-05-05 | Construction perfectionnée de l'amortisseur pour cycles, voiturettes et autres véhicules analogues | |
| US2171596A (en) * | 1934-09-11 | 1939-09-05 | George M Parker | Continuous process of gas making |
| US2220849A (en) * | 1938-08-29 | 1940-11-05 | Kellogg M W Co | Method for forming synthesis gas |
| US2482866A (en) * | 1944-11-01 | 1949-09-27 | Stanolind Oil & Gas Co | Production of carbon monoxide and hydrogen |
| US2635952A (en) * | 1946-07-05 | 1953-04-21 | Standard Oil Co | Manufacture of hydrogen-carbon monoxide mixture |
| GB702035A (en) * | 1948-07-07 | 1954-01-06 | Montedison Spa | Process and apparatus for the production of synthesis-gas from gaseous aliphatic hydrocarbons and oxygen |
| US2655442A (en) * | 1948-08-23 | 1953-10-13 | Phillips Petroleum Co | Process and apparatus for the manufacture of synthesis gas |
| US2585737A (en) * | 1948-10-21 | 1952-02-12 | Standard Oil Dev Co | Catalytic reforming process |
| US2767233A (en) * | 1952-01-07 | 1956-10-16 | Chemical Construction Corp | Thermal transformation of hydrocarbons |
| US2942958A (en) * | 1953-07-03 | 1960-06-28 | Kellogg M W Co | Process for the conversion of a normally gaseous hydrocarbon to carbon monoxide and hydrogen |
| GB775334A (en) * | 1954-06-22 | 1957-05-22 | Basf Ag | Improvements in the reaction of gaseous hydrocarbons with oxygen |
| US2943062A (en) * | 1956-01-19 | 1960-06-28 | Kellogg M W Co | Conversion of hydrocarbons to a hydrogen-rich gas |
| US3477824A (en) * | 1966-12-15 | 1969-11-11 | Zink Co John | Burner and apparatus for reforming hydrocarbons |
| GB2139644B (en) * | 1983-04-06 | 1987-06-24 | Ici Plc | Synthesis gas |
| EP0303438A3 (en) * | 1987-08-14 | 1989-12-27 | DAVY McKEE CORPORATION | Production of synthesis gas from hydrocarbonaceous feedstock |
| US4973453A (en) * | 1988-02-05 | 1990-11-27 | Gtg, Inc. | Apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons |
| FR2638443B1 (fr) * | 1988-11-03 | 1991-01-11 | Inst Francais Du Petrole | Procede pour la production de gaz de synthese par oxydation partielle d'hydrocarbures legers |
| US5106590A (en) * | 1990-05-11 | 1992-04-21 | Davy Mckee (London) Limited | Gas mixer and distributor with heat exchange between incoming gases |
| FR2679217B1 (fr) * | 1991-07-18 | 1994-04-01 | Institut Francais Petrole | Procede et dispositif pour la fabrication de gaz de synthese et application. |
-
1991
- 1991-12-03 FR FR9115060A patent/FR2684313B1/fr not_active Expired - Lifetime
-
1992
- 1992-11-26 ES ES92120156T patent/ES2092002T3/es not_active Expired - Lifetime
- 1992-11-26 EP EP92120156A patent/EP0545275B1/fr not_active Expired - Lifetime
- 1992-11-26 DE DE69212121T patent/DE69212121T2/de not_active Expired - Fee Related
- 1992-11-26 MY MYPI92002159A patent/MY109757A/en unknown
- 1992-12-01 ZA ZA929307A patent/ZA929307B/xx unknown
- 1992-12-01 KR KR1019920022953A patent/KR100245781B1/ko not_active Expired - Fee Related
- 1992-12-02 JP JP35026592A patent/JP3748899B2/ja not_active Expired - Fee Related
- 1992-12-02 RU RU92004493A patent/RU2117626C1/ru active
- 1992-12-03 CA CA002084476A patent/CA2084476C/fr not_active Expired - Fee Related
-
1993
- 1993-01-05 TW TW082100031A patent/TW239159B/zh active
-
1996
- 1996-04-12 US US08/631,909 patent/US5755841A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004010014A1 (de) * | 2004-03-01 | 2005-09-29 | Webasto Ag | Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat |
| US7578861B2 (en) | 2004-03-01 | 2009-08-25 | Enerday Gmbh | Reformer and process for reacting fuel and oxidizer into reformate |
| DE102004010014B4 (de) * | 2004-03-01 | 2011-01-05 | Enerday Gmbh | Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat |
Also Published As
| Publication number | Publication date |
|---|---|
| TW239159B (OSRAM) | 1995-01-21 |
| DE69212121D1 (de) | 1996-08-14 |
| EP0545275B1 (fr) | 1996-07-10 |
| JP3748899B2 (ja) | 2006-02-22 |
| MY109757A (en) | 1997-06-30 |
| CA2084476C (fr) | 2003-04-01 |
| EP0545275A1 (fr) | 1993-06-09 |
| CA2084476A1 (fr) | 1993-06-04 |
| FR2684313A1 (fr) | 1993-06-04 |
| ZA929307B (en) | 1994-06-01 |
| KR930013073A (ko) | 1993-07-21 |
| RU2117626C1 (ru) | 1998-08-20 |
| ES2092002T3 (es) | 1996-11-16 |
| FR2684313B1 (fr) | 1994-01-28 |
| JPH05254802A (ja) | 1993-10-05 |
| KR100245781B1 (ko) | 2000-03-02 |
| US5755841A (en) | 1998-05-26 |
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